JPS634892A - Treatment of night soil - Google Patents

Treatment of night soil

Info

Publication number
JPS634892A
JPS634892A JP61150066A JP15006686A JPS634892A JP S634892 A JPS634892 A JP S634892A JP 61150066 A JP61150066 A JP 61150066A JP 15006686 A JP15006686 A JP 15006686A JP S634892 A JPS634892 A JP S634892A
Authority
JP
Japan
Prior art keywords
secondary treatment
synthetic
water
liquid
treated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61150066A
Other languages
Japanese (ja)
Inventor
Takayuki Moribe
隆行 森部
Takero Misaki
岳郎 三崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Priority to JP61150066A priority Critical patent/JPS634892A/en
Publication of JPS634892A publication Critical patent/JPS634892A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Activated Sludge Processes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

PURPOSE:To effectively remove the chromaticity components and COD components of a secondary treatment liquid of night soil by passing the secondary treatment liquid of night soil through a synthetic adsorbent resin. CONSTITUTION:The secondary treatment liquid formed by the biological treatment of the night soil by activated sludge is adjusted to 3-5pH and is passed through an adsorption column in which the synthetic adsorbent resin such as styrene/divinyl benzene copolymer is packed. The chromaticity components and COD components in the secondary treatment liquid of the night soil are effectively removed by such simple equipment. The above-mentioned synthetic adsorbent resin can be easily regenerated by bringing a 1-5% caustic soda soln. or aq. 5-50% alcohol soln. into contact with the synthetic adsorbent resin layer.

Description

【発明の詳細な説明】 く産業上の利用分野〉 本発明はし尿処理方法VC関し、詳しく(=活性汚泥で
処理したし尿の二次処理、准の色度成分、COD Ej
、分またはこれら両方の成分を除去する方法に係る。
[Detailed description of the invention] Industrial application field> The present invention relates to a human waste treatment method VC, in detail (= secondary treatment of human waste treated with activated sludge, secondary chromaticity components, COD Ej
, or both.

く従来技術〉 し尿を活性汚泥で処理した二次処理液は褐色系の独特の
色彩を有しているので、その菫ま放流すると消色公害の
問題を引き起こす。
Prior art> The secondary treatment liquid obtained by treating human waste with activated sludge has a unique brownish color, so if it is discharged into the violet, it will cause the problem of discoloration and pollution.

また、この二次処理i!1活性汚泥によりBOD反分(
ユ効釆的に除S:されているが、COD反分1;低下し
ていない。このため、し尿の二次処理?1f1−オゾン
による酸化分解や活性炭による吸着等により処理されて
いる。
Also, this secondary processing i! 1. BOD separation by activated sludge (
S: has been removed in terms of efficiency, but COD has not decreased by 1. For this reason, secondary treatment of human waste? It is treated by oxidative decomposition using 1f1-ozone, adsorption using activated carbon, etc.

〈発明コS解決しようとする問題点〉 し力)しながら、オゾン処理!10.o酸化力をオリ用
して色度成分やCOD成分を分解し、除去するものであ
るか、実用N 備K Sいてにオゾンを祷るために空気
(または酸素)供A@機、四酊却乾燥装鉦、オゾン元主
器、尚圧−源装置を、また得られたオゾンと被処理液(
し尿二次処理液)中の色度、600敗分とを反応させる
ための接触憎を、さらに排ガス中に外画するオゾンを除
去するための反オゾン処4塔を8受とするため、装置が
複雑になるという間眺点を有するものである。
〈Problem to be solved by invention〉 ozone treatment! 10. o Is it a device that uses oxidizing power to decompose and remove chromaticity components and COD components? The drying equipment, the ozone source main equipment, the pressure source equipment, and the obtained ozone and the liquid to be treated (
The chromaticity in the human waste secondary treatment liquid), the contact resistance for reacting with 600 filtration liquid, and the anti-ozone treatment 4 towers for 8 towers to remove the ozone outside the exhaust gas. This has the disadvantage that it becomes complicated.

また、活性炭処理はカラムに充填した活性炭層に被処理
液を通して脱色、脱CODを行うものではあるが、活性
炭は薬品ではなく、高温加熱により再生を行うため、吸
着カラム内での再生は不可能である。従って、吸着カラ
ムと再生炉の間の活性炭移し換えという面世1な作業を
費する。これ8解決するために移送とへ生が自動化され
た設備かあるか、吸着装置として吸渣梧、抜出し活性炭
tl量僧、新炭IFi−僧、同gt重憎との)らなり、
また再生装置として11再生炉、屍ガスサイクロン、廃
ガス燃焼炉、発炭貯憎、同計濾槽、杏生炭冷却槽、内生
炭スラリー化楯等カ)らなつ、オゾン処理の場合と同様
に複雑な装置を必要とするという間聴点8有するもので
ある。
In addition, activated carbon treatment decolorizes and removes COD by passing the liquid to be treated through an activated carbon layer packed in a column, but since activated carbon is not a chemical and is regenerated by high-temperature heating, it is impossible to regenerate it in an adsorption column. It is. Therefore, the tedious work of transferring activated carbon between the adsorption column and the regeneration furnace is required. In order to solve this problem, is there any automated equipment for transfer and production, such as suction as an adsorption device, extracted activated carbon TL, new charcoal IFi, same GT), etc.
In addition, there are 11 regeneration devices such as a regeneration furnace, a corpse gas cyclone, a waste gas combustion furnace, a coal storage tank, an apricot charcoal cooling tank, an internal coal slurry shield, etc., and in the case of ozone treatment. Similarly, there are 8 listening points which require complicated equipment.

本発明は上記の如き従来の間ら点8解消し、し尿二次処
PM液O色&成分と、COD底分を簡単な設備により有
効に除去し得る処理方法を提供することを目的とするも
のである。
It is an object of the present invention to solve the above-mentioned drawbacks of the conventional method and to provide a treatment method that can effectively remove the O color and components of the PM solution for night soil secondary treatment and the COD bottom fraction using simple equipment. It is something.

く問ね点を解決するための手段〉 本発明はし尿を活性汚泥で生物処理した二次処理液をp
H3〜5に調堅して合成液源り(脂か充填された吸着カ
ラム内 る。
Means for Solving the Problems〉 The present invention uses a secondary treatment liquid obtained by biologically treating human waste with activated sludge.
After adjusting to H3-5, the synthetic liquid source (inside the fat-filled adsorption column).

@1図は本発明を冥施する場合070−シートである。@1 Figure is 070-sheet when practicing the present invention.

図において、被処理水(二次処理液)は二次処理水水!
f41からIンプ2により弁3を通り、合成液着樹BF
18か充填された吸着カラム7の上6tよりカラム内に
給液される。こoeiカラム7への給戒に際し、被処理
水は塩酸等によりそOpHが3〜5の範囲となるように
調整される。被処理水のpHは通常的7〜8であるか、
これに塩酸等の酸を注入してpHri−3〜5のl11
a白とすることにより、色度成分、COD成分の除去性
が著しく改善されるようrこなる。
In the figure, the water to be treated (secondary treatment liquid) is secondary treatment water!
From f41, it passes through valve 3 by Imp 2, and the synthetic liquid lands on BF.
The liquid is supplied into the column from the upper 6t of the adsorption column 7 packed with 18 ml of liquid. When feeding the water to the OEI column 7, the water to be treated is adjusted with hydrochloric acid or the like so that its OpH is in the range of 3 to 5. Is the pH of the water to be treated normally between 7 and 8?
Inject acid such as hydrochloric acid into this to obtain l11 pHri of -3 to 5.
By making it white, the removability of chromaticity components and COD components is significantly improved.

なお、合成液N樹脂8としては、イオン交換基をもたな
い吸着性のある合Iy、m脂であり、例えばスチレン−
ジビニルベンゼン共賞合体、メタアクリル酸エステル系
等力S例示できる。
The synthetic liquid N resin 8 is an adsorbent synthetic Iy, m resin that does not have ion exchange groups, such as styrene-
Examples include divinylbenzene copolymerization and methacrylic acid ester type S.

そして、そC粒径はα1〜LO■の範占のものp5好ま
しく使用される。
The C particle size is preferably in the range α1 to LO■p5.

上記のようにしてpHカ53〜5にυ1整され、a看カ
ラム7JCM液された被処理水はカラム内に充填された
合成液4f脂8と接触することにより色度成分および/
またはCOD匡分が合a吸看舅脂8により除去され、吸
着カラム70下端から升9を通り処理水水槽10に貯え
られる。その後処理水(=、中和処理や希釈水の伶m等
の仮処理彼に放yLされる。
The water to be treated, which has been adjusted to pH 53-5 in the above manner and filled with a column 7 JCM, comes into contact with the synthetic liquid 4f and fat 8 filled in the column, thereby changing the chromaticity components and/or
Alternatively, the COD fraction is removed by the aqueous absorber 8, passed from the lower end of the adsorption column 70 through the square 9, and stored in the treated water tank 10. The treated water is then subjected to temporary treatment such as neutralization and dilution.

な8、前述のpH3〜5への二次処理水の調贅は、合成
液7g樹脂による処理に先立って、塩化第2跣等の鉄塩
で凝〉処理されている場合It、pHC)調整力j不要
かまたは簡単にできる。
8. The above-mentioned adjustment of the secondary treated water to pH 3 to 5 is carried out if the water is coagulated with an iron salt such as dichloride chloride prior to treatment with 7 g of synthetic liquid (pHC) adjustment. No force required or easy to do.

そnは、鉄塩6加によりpHか3前後になってい6カ)
らである。もしp)(か3以下であれば、苛性ソーダで
上述したpHに間単にFA!することかできる。
The pH is around 3 due to the addition of iron salt (6)
It is et al. If p)(≦3), you can simply FA! to the above pH with caustic soda.

このように、@居カラム7Vc被処理水を通液していく
と、カラム内の合成@N樹脂8による色!f Iiy、
分および/またはCOD成分の除去効率が低下してくる
ため、合成吸im脂8の再生を行うようにする。
In this way, when the water to be treated is passed through column 7Vc, the color due to the synthetic @N resin 8 in the column! f Iiy,
Since the removal efficiency of COD components and/or COD components decreases, the synthetic absorbent fat 8 is regenerated.

合成吸李樹瘤の再生は、合収吸′M切脂鳩に1〜5チの
苛性ソーダ溶液又は5〜50チのアルコール水浴液8接
触させて行う。さらには、これら両fLを併用の場合は
どちらを先に接触させてもよい。なお、併用の場合は、
合成吸層腐脂力)ら液層した色度成分とCOD匠分を効
果的に18なtいし1悦路力1できる。
Regeneration of the synthetic sorbent buds is carried out by contacting the synthetic sorbet with 1 to 5 grams of caustic soda solution or 5 to 50 grams of alcohol water bath. Furthermore, when both fLs are used together, either one may be brought into contact first. In addition, if used together,
The chromaticity components and COD components of the liquid layer can be effectively reduced from 18 to 1 by 1.

再生は、先ず二次処理水水槽1円の二次処理液をポンプ
2で汲み上げ、弁58辿り吸着カラム内の下端よりカラ
ム7内に送り、!i已浄さnる。この洸沖抜の該はカラ
ム上端から升4を辿り、二次処理水水(図示せず〕へと
送らnる。
For regeneration, first, 1 yen of the secondary treatment liquid from the secondary treatment water tank is pumped up by the pump 2, followed by the valve 58, and sent into the column 7 from the lower end of the adsorption column. I am pure. This water flowing off the coast follows square 4 from the top of the column and is sent to the secondary treated water (not shown).

次に合成′$1.宥樹)II sの再生1ゴ、桑液貯慟
11に貯えられたアルコール*浴液または苛性ン−ダ水
+’J m j) y!fンプ12により弁13を通し
てカラム内の合成吸着樹脂層上に設けられた珂生用薬液
散布器14から合成吸着樹脂層上に散布して行う。この
再生薬液は処理水水種lOから一ンゾ16で汲み上げた
処理水により上述した範囲の過当な濃度に希釈されて使
用ざnる。散布器14から散水された薬液は合ば吸着@
脂8¥再生したのち、カラム下端から弁15’)経て排
出される。この排出液は例えば焼却炉へ送られ、そこで
焼却処理される。薬液か注入された後の合成吸着樹脂8
はその後洗浄される。洗浄は、処理工程時に開となる弁
9を閉じておき弁6を開にして行う。
Next, synthesis'$1. Alcohol stored in the mulberry liquor storage tank 11 *bath solution or caustic powder water + 'J m j) y! This is carried out by spraying onto the synthetic adsorption resin layer from an f-pump 12 through a valve 13 and from a chemical sprayer 14 provided on the synthetic adsorption resin layer in the column. This regenerated chemical solution is diluted to an excessive concentration within the above-mentioned range with the treated water pumped up from the treated water type 10 by the water pump 16, and is not used. If the chemical solution sprayed from the sprayer 14 is combined, it will be adsorbed@
After regenerating 8 yen of fat, it is discharged from the bottom end of the column via valve 15'). This discharged liquid is sent to an incinerator, for example, and is incinerated there. Synthetic adsorption resin 8 after injection of chemical solution
is then washed. Cleaning is performed by closing valve 9, which is opened during the treatment process, and opening valve 6.

升6そ介したりし水は二次処理g17c宏へ戻される。The water passed through the tank 6 is returned to the secondary treatment g17c Hiroshi.

そして−定時間又は所定≧の洗#g通過後に升6を閉じ
、弁9を開にして処理工程へと移る。なお、第1図中、
lフは流量計である。
Then, after passing through washing #g for a predetermined time or a predetermined time or more, the cell 6 is closed, the valve 9 is opened, and the process proceeds to the processing step. In addition, in Figure 1,
lf is a flow meter.

く作  用〉 本発明では、活性汚泥で生物処理されたし尿の二次処理
液そそOpHの53〜5となるようにして合成吸着樹脂
力1充t14i!れた吸着カラム内に7液することによ
り、二次処理液中に含まれる色度成分および/またはC
OD成分か合成吸着樹脂に吸着除去され、そのt才放流
できる処理水か得られる。また合成吸着樹脂の褥生も吸
着カラム内で行うことかでき、その廃液も焼却すること
などにより簡単に処理できる。
Function> In the present invention, the secondary treatment solution of human waste that has been biologically treated with activated sludge is adjusted to have an OpH of 53 to 5, so that the synthetic adsorption resin power is 1 t14i! By placing 7 liquids in the adsorption column, the chromaticity components and/or C contained in the secondary treatment liquid are removed.
The OD components are adsorbed and removed by a synthetic adsorption resin, resulting in treated water that can be discharged. Furthermore, the synthetic adsorption resin can be left in the adsorption column, and its waste liquid can be easily disposed of by incineration, etc.

以下に実Thf18示す。Actual Thf18 is shown below.

実施例 被処理水として、し尿を活性汚泥で生物処理したものを
固液分離したし尿二次処理8I(無希釈処理水1色g 
1600 [、COD 530ppm 。
Example Water to be treated was human waste that was biologically treated with activated sludge and then solid-liquid separated.
1600 [, COD 530ppm.

pH7,6)を第1図に示すようなフローシートに従っ
て処理した。@着カラムとしては内径26w0透明アク
リルカラムに、栗田工莱■販売の合底吸N倒脂(8−1
07)(有効径025〜α35■のスチレン−ジビニル
ベンゼン共重合体からなる合成@9f!樹脂) 300
ccを充填したもので、この充填層iC被処理水を5V
=3〜5 (1/h)で−!4液した。この通液に先だ
ち塩酸を用いて被処理水のpHを3〜5の範囲となるよ
うにした。なお、比較のためpHrI4!llLない場
合についても試験した。それらの結果(−第29に示す
pH 7.6) was treated according to the flow sheet shown in FIG. As for the column, I used a clear acrylic column with an inner diameter of 26W0 and a Gosoku-N-type oil (8-1) sold by Korai Kurita.
07) (Synthesized @9f! resin consisting of styrene-divinylbenzene copolymer with an effective diameter of 025 to α35■) 300
cc, and this packed bed iC water to be treated is connected to 5V.
=3~5 (1/h) -! I used 4 liquids. Prior to this liquid passage, the pH of the water to be treated was adjusted to a range of 3 to 5 using hydrochloric acid. For comparison, pHrI4! The case where LL was not present was also tested. The results (-shown in No. 29).

このような逍g% 125B、V、続げた後、合成吸着
樹脂の元JJ層に苛性ソーダ2%水浴液(SVSで通液
(褥生しベtv 100 f Na0)l/L−n )
したのちメチルアルコール10%水溶液をSVSで通液
(再% Ly ヘル500 j’ CH,OH/1−R
)して再任したところ、合成吸着有脂にa層された色度
成分8よびCOD 12i分か再生用集成により除去さ
れ、被処理水の処理に好ましく痺使用できるものとなっ
た。
After continuing with such treatment at g% 125B, V, the former JJ layer of the synthetic adsorption resin was passed through a 2% caustic soda water bath solution (SVS (bedbed bed TV 100 f Na0) l/L-n).
After that, a 10% aqueous solution of methyl alcohol was passed through SVS (re-% Ly Hell 500 j' CH,OH/1-R
) and was reappointed, the chromaticity component 8 and COD 12i in the a-layer of the synthetic adsorbent fat were removed by the regeneration assembly, making it suitable for use in the treatment of water to be treated.

く効  来〉 以上のような本発明によれば、し尿二次処理液を合成吸
着樹脂に通液するものであり、こnVCより二次処理液
中の色度成分とCOD成分が簡単を設備により除去でき
、また合成吸着樹脂の再生も簡単に行えるという効果を
有する。
Effects> According to the present invention as described above, the secondary treatment liquid for human waste is passed through a synthetic adsorption resin, and the chromaticity components and COD components in the secondary treatment liquid can be easily adjusted using this nVC. It has the effect that it can be removed by the method, and the synthetic adsorption resin can be easily regenerated.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明を実施する場合の一例を示すフローシー
トである。 第2図および第3図は$、施例に2ける色度成分2よび
COD成分のそれぞれの除去度合を示す処理−i (B
、 V、  ベッドボリーム)との関係図である。 l・・・二次処理水水槽  2,12.16・・・ポン
プ3.4,5,6,9,13.15・・・弁 フ・・・
吸着カラム8・・・合成板N樹脂 】O・・・処理水水
ツ11・・・薬液貯槽   14・・・散布器17・・
・流量計 %託出願人 栗田工業株式会社 外1名
FIG. 1 is a flow sheet showing an example of implementing the present invention. FIGS. 2 and 3 show the respective removal degrees of chromaticity component 2 and COD component in $, Example 2, Process-i (B
, V, bed volume). l... Secondary treated water tank 2, 12.16... Pump 3.4, 5, 6, 9, 13.15... Valve...
Adsorption column 8...Synthetic plate N resin] O...Treatment water water tank 11...Chemical solution storage tank 14...Scatterer 17...
・Flowmeter % Consignee: 1 person other than Kurita Water Industries, Ltd.

Claims (1)

【特許請求の範囲】 1、し尿処理方法において、し尿を活性汚泥で生物処理
した二次処理液をpH3〜5に調整し、合成吸着樹脂が
充填された吸着カラムに通液して被処理液中の色度およ
び/またはCOD成分を除去することを特徴とするし尿
処理方法。 2、合成吸着樹脂はアルコール水溶液または苛性ソーダ
溶液で再生されたものである特許請求の範囲第1項記載
の方法。 3、合成吸着樹脂はアルコール水浴液および苛性ソーダ
溶液で再生されたものである特許請求の範囲第1項記載
の方法。
[Claims] 1. In the human waste treatment method, the secondary treatment liquid obtained by biologically treating human waste with activated sludge is adjusted to pH 3 to 5, and the liquid is passed through an adsorption column filled with a synthetic adsorption resin to obtain the treated liquid. A method for treating human waste characterized by removing chromaticity and/or COD components therein. 2. The method according to claim 1, wherein the synthetic adsorption resin is regenerated with an alcohol aqueous solution or a caustic soda solution. 3. The method according to claim 1, wherein the synthetic adsorption resin is regenerated with an alcohol water bath solution and a caustic soda solution.
JP61150066A 1986-06-25 1986-06-25 Treatment of night soil Pending JPS634892A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61150066A JPS634892A (en) 1986-06-25 1986-06-25 Treatment of night soil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61150066A JPS634892A (en) 1986-06-25 1986-06-25 Treatment of night soil

Publications (1)

Publication Number Publication Date
JPS634892A true JPS634892A (en) 1988-01-09

Family

ID=15488770

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61150066A Pending JPS634892A (en) 1986-06-25 1986-06-25 Treatment of night soil

Country Status (1)

Country Link
JP (1) JPS634892A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995006009A1 (en) * 1993-08-26 1995-03-02 Schering Aktiengesellschaft Device for purifying waste water or ground water and use thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995006009A1 (en) * 1993-08-26 1995-03-02 Schering Aktiengesellschaft Device for purifying waste water or ground water and use thereof
EP0715607A1 (en) * 1993-08-26 1996-06-12 Schering Aktiengesellschaft Device for purifying waste water or ground water

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