JPS63485A - Radiation cooling film - Google Patents
Radiation cooling filmInfo
- Publication number
- JPS63485A JPS63485A JP14229986A JP14229986A JPS63485A JP S63485 A JPS63485 A JP S63485A JP 14229986 A JP14229986 A JP 14229986A JP 14229986 A JP14229986 A JP 14229986A JP S63485 A JPS63485 A JP S63485A
- Authority
- JP
- Japan
- Prior art keywords
- phosphate
- molybdate
- film
- thin
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001816 cooling Methods 0.000 title claims abstract description 18
- 230000005855 radiation Effects 0.000 title claims abstract description 11
- 239000010408 film Substances 0.000 claims abstract description 14
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010409 thin film Substances 0.000 claims abstract description 12
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 10
- 239000010452 phosphate Substances 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 abstract description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract description 4
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 abstract description 4
- 229910000165 zinc phosphate Inorganic materials 0.000 abstract description 4
- RCMWGBKVFBTLCW-UHFFFAOYSA-N barium(2+);dioxido(dioxo)molybdenum Chemical compound [Ba+2].[O-][Mo]([O-])(=O)=O RCMWGBKVFBTLCW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001506 calcium phosphate Substances 0.000 abstract description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 abstract description 2
- 235000011010 calcium phosphates Nutrition 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 229910000159 nickel phosphate Inorganic materials 0.000 abstract description 2
- JOCJYBPHESYFOK-UHFFFAOYSA-K nickel(3+);phosphate Chemical compound [Ni+3].[O-]P([O-])([O-])=O JOCJYBPHESYFOK-UHFFFAOYSA-K 0.000 abstract description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 abstract description 2
- 235000011009 potassium phosphates Nutrition 0.000 abstract description 2
- 238000004544 sputter deposition Methods 0.000 abstract description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract description 2
- 238000001771 vacuum deposition Methods 0.000 abstract description 2
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 2
- -1 for example Chemical compound 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910000684 Cobalt-chrome Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010952 cobalt-chrome Substances 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、放射冷却膜に関する。更に詳しくは、赤外領
域において８〜１３μｍの波長光を吸収し、他の領域の
波長光をカットすることにより放射冷却せしめるように
した放射冷却膜に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a radiation cooling film. More specifically, the present invention relates to a radiative cooling film that absorbs light with a wavelength of 8 to 13 μm in the infrared region and cuts light with wavelengths in other regions to perform radiative cooling.
〔従来の技術〕および〔発明が解決しようとする問題点
〕各種物体および大気のそれぞれの熱放射は、０．３〜
５０μｍ（３００に前後における放射スペクトル）の波
長領域においてはほぼ一致しているが、この範囲内の波
長の内８〜１３μｍの領域では、大気からの放射量が著
しく減少している。[Prior art] and [Problems to be solved by the invention] The thermal radiation of various objects and the atmosphere is 0.3 to
In the wavelength region of 50 μm (emission spectrum around 300 μm), they almost match, but within this range, in the wavelength region of 8 to 13 μm, the amount of radiation from the atmosphere is significantly reduced.
そこで、この領域以外の波長光をカットするように工夫
すれば、物体からの熱放射が大気からのそれを上廻り、
しかも一般に大気の方が低温なので物体は冷却されるこ
とになる。Therefore, if we devised a way to cut out the wavelengths of light outside of this range, the heat radiation from the object would exceed that from the atmosphere.
Moreover, the atmosphere is generally cooler, so objects are cooled down.
特開昭６０−８６１７３号公報には、かかる考え方に基
く被覆組成物が提案されており、この被覆組成物は、
ＣｏＣｒ、Ｏ，、Ｋ、Ｓｏ、、 Ｓｉ３Ｎ４．に２ｓｏ
、、ＳｉＯ□、Ａ Ｑ ２Ｓｉｎ、などの無機材料、フ
ッ化ビニル−フッ化ビニリデン共重合体、ポリプロピレ
ンオキサイド、ポリ（塩化三フッ化エチレン）、ポリ（
四フッ化エチレン）などの有機材料およびルチル型酸化
チタンから構成されている。JP-A-60-86173 proposes a coating composition based on this idea, and this coating composition has the following characteristics:
CoCr, O, K, So, Si3N4. ni2so
, , SiO
It is composed of organic materials such as (tetrafluoroethylene) and rutile-type titanium oxide.
しかしながら、この被覆組成物で用いられているフッ素
化ポリマーは８〜１０μｍの波長光の一部に吸収しない
領域があり、放射冷却能になお改善されなければならな
い余地のあることが判明した。However, it has been found that the fluorinated polymer used in this coating composition has a region in which it does not absorb a portion of light with a wavelength of 8 to 10 μm, and there is still room for improvement in the radiation cooling ability.
本発明者は、フッ素化ポリマーを用いた場合よりも高い
放射冷却能を示すような放射冷却膜を求めて種々検討の
結果、アルミニウム基質上にリン酸塩およびモリブデン
酸塩の薄膜を形成させることにより、かかる課題が効果
的に解決されることを見出した。As a result of various studies in search of a radiative cooling film that exhibits a higher radiative cooling ability than when using a fluorinated polymer, the present inventor has discovered that a thin film of phosphate and molybdate can be formed on an aluminum substrate. It has been found that this problem can be effectively solved.
従って、本発明は放射冷却膜に係り、この放射冷却膜は
、アルミニウム基質上にリン酸塩およびモリブデン酸塩
の薄膜を任意の順序で形成せしめてなる。Accordingly, the present invention relates to a radiative cooling film comprising thin films of phosphate and molybdate formed in any order on an aluminum substrate.
リン酸塩としては、例えばリン酸亜鉛、リン酸カルシウ
ム、リン酸カリウム、リン酸ニッケル、リン酸鉄などが
用いられ、好ましくはリン酸亜鉛が用いられる。また、
モリブデン酸塩としては。As the phosphate, for example, zinc phosphate, calcium phosphate, potassium phosphate, nickel phosphate, iron phosphate, etc. are used, and zinc phosphate is preferably used. Also,
As a molybdate.
例えばモリブデン酸カルシウム、例えばモリブデン酸バ
リウム、モリブデン酸鉄などが用いられ。For example, calcium molybdate, barium molybdate, iron molybdate, etc. are used.
好ｉ−シ＜はモリブデン酸カルシウムが用いられる。Preferably, calcium molybdate is used.
これらのリン酸塩およびモリブデン酸塩は、厚さ約３０
〜７０μｍ、好ましくは約５ｏμｍ程度のアルミニウム
基質上に、真空蒸着法、プラズマ重合法、スパッタリン
グ法などにより、やはり約３ｏ〜７０μｍ、好ましくは
約５０μｍ程度の厚さでそれぞれ薄膜層を形成させる。These phosphates and molybdates have a thickness of about 30
A thin film layer is formed on an aluminum substrate having a thickness of about 30 to 70 μm, preferably about 50 μm, by a vacuum evaporation method, a plasma polymerization method, a sputtering method, etc. on an aluminum substrate having a thickness of about 30 to 70 μm, preferably about 50 μm.
形成される薄膜の順序は任意であるが、大気中の酸素や
水分などの影響を考えたとき、リン酸塩およびモリブデ
ン酸塩の順序で薄膜をそれぞれ形成させ１表面側をモリ
ブデン酸塩薄膜層とした方が冷却能の低下がより抑制さ
れる。The order in which the thin films are formed is arbitrary, but considering the influence of oxygen and moisture in the atmosphere, thin films are formed in the order of phosphate and molybdate, and one surface is covered with a molybdate thin film layer. In this case, the decrease in cooling capacity is more suppressed.
〔作用〕および〔発明の効果〕
本発明に係る放射冷却膜は、モリブデン酸塩薄膜層にお
いて１０〜１３μｍの波長光を吸収し、またリン酸塩薄
膜層において８〜１０μｍの波長光を吸収し、更にアル
ミニウム基板層において入射光を全反射するので、大気
から放射される８〜１３μｍの波長光を選択的にむらな
く吸収させ、他の領域の波長光を殆んど吸収しないため
、冷却能の高い放射冷却膜が得られることになる。[Function] and [Effects of the Invention] The radiation cooling film according to the present invention absorbs wavelength light of 10 to 13 μm in the molybdate thin film layer, and absorbs wavelength light of 8 to 10 μm in the phosphate thin film layer. Furthermore, since the aluminum substrate layer totally reflects the incident light, it selectively and evenly absorbs light with a wavelength of 8 to 13 μm emitted from the atmosphere, and hardly absorbs light with wavelengths in other regions, which improves cooling performance. This results in a radiation cooling film with high radiative cooling.
Claims (1)
塩の薄膜を任意の順序で形成せしめてなる放射冷却膜。 ２、リン酸塩およびモリブデン酸塩の順序で薄膜を形成
させた特許請求の範囲第１項記載の放射冷却膜。 ３、各薄膜層を約３０〜７０μｍの厚さで形成された特
許請求の範囲第１項または第２項記載の放射冷却膜。[Claims] 1. A radiant cooling film comprising thin films of phosphate and molybdate formed in any order on an aluminum substrate. 2. The radiation cooling film according to claim 1, wherein the thin film is formed in the order of phosphate and molybdate. 3. The radiation cooling film according to claim 1 or 2, wherein each thin film layer is formed to have a thickness of about 30 to 70 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14229986A JPS63485A (en) | 1986-06-18 | 1986-06-18 | Radiation cooling film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14229986A JPS63485A (en) | 1986-06-18 | 1986-06-18 | Radiation cooling film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63485A true JPS63485A (en) | 1988-01-05 |
Family
ID=15312147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14229986A Pending JPS63485A (en) | 1986-06-18 | 1986-06-18 | Radiation cooling film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63485A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3928593A1 (en) * | 1988-08-29 | 1990-03-15 | Suzuki Motor Co | TRANSMISSION DEVICE FOR A VEHICLE |
| JPH03117885A (en) * | 1989-09-28 | 1991-05-20 | Hoshino Sansho:Kk | Modification of electric furnace slag |
| WO2005010103A3 (en) * | 2003-07-29 | 2005-04-07 | Dmitry Vyacheslavov Romanovsky | Anticorrosive pigment |
| WO2021017524A1 (en) * | 2019-07-30 | 2021-02-04 | 南京工业大学 | Infrared selective radiation cooling nano-functional composition and preparation method therefor |
-
1986
- 1986-06-18 JP JP14229986A patent/JPS63485A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3928593A1 (en) * | 1988-08-29 | 1990-03-15 | Suzuki Motor Co | TRANSMISSION DEVICE FOR A VEHICLE |
| DE3928593C2 (en) * | 1988-08-29 | 1996-03-07 | Suzuki Motor Co | Switching device for a vehicle transmission |
| JPH03117885A (en) * | 1989-09-28 | 1991-05-20 | Hoshino Sansho:Kk | Modification of electric furnace slag |
| WO2005010103A3 (en) * | 2003-07-29 | 2005-04-07 | Dmitry Vyacheslavov Romanovsky | Anticorrosive pigment |
| EA008800B1 (en) * | 2003-07-29 | 2007-08-31 | Дмитрий Вячеславович Романовский | Anticorrosive pigment |
| WO2021017524A1 (en) * | 2019-07-30 | 2021-02-04 | 南京工业大学 | Infrared selective radiation cooling nano-functional composition and preparation method therefor |
| US20220274882A1 (en) * | 2019-07-30 | 2022-09-01 | Nanjing Tech University | Infrared selective radiation cooling nano-functional composition and preparation method thereof |
| JP2022542325A (en) * | 2019-07-30 | 2022-09-30 | 南京工▲業▼大学 | Infrared selective nano-functional composition for radiative cooling and method of making same |
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