JPS6343999A - Acidic liquid detergent composition - Google Patents
Acidic liquid detergent compositionInfo
- Publication number
- JPS6343999A JPS6343999A JP62195144A JP19514487A JPS6343999A JP S6343999 A JPS6343999 A JP S6343999A JP 62195144 A JP62195144 A JP 62195144A JP 19514487 A JP19514487 A JP 19514487A JP S6343999 A JPS6343999 A JP S6343999A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- active compound
- detergent
- detergent composition
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 32
- 239000003599 detergent Substances 0.000 title claims description 19
- 230000002378 acidificating effect Effects 0.000 title claims description 13
- 239000007788 liquid Substances 0.000 title claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 9
- 125000002091 cationic group Chemical group 0.000 claims description 8
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、金属表面、ガラス表面及びセラミック表面の
ような耐酸性の硬質面を洗浄するのに適当な水性の酸性
液体洗剤組成物に係わる。この組成物は、便器の洗浄に
特に適当である。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an aqueous acidic liquid detergent composition suitable for cleaning acid-resistant hard surfaces such as metal surfaces, glass surfaces and ceramic surfaces. This composition is particularly suitable for cleaning toilet bowls.
酸性液体の便器用洗剤組成物は、当業者に公知である。Acidic liquid toilet bowl detergent compositions are known to those skilled in the art.
この組成物は普通、洗浄活性化合物、殺菌剤、香料、腐
食防止剤、着色剤等の様々な望ましい添加物を添加され
た強酸の水；ｇ液から成る。The composition usually consists of strongly acidic water; liquid to which are added various desired additives such as cleaning active compounds, disinfectants, fragrances, corrosion inhibitors, colorants, etc.
このような酸性液体の便器用洗剤組成物に含有される洗
浄活性化合物としては、陰イオン性、非イオン性及び陽
イオン性の洗剤が有る。所望であれば、上記のような組
成物には青色染料のような適当な染１″毒の添加によっ
て好ましい色が付与される。The cleaning active compounds contained in such acidic liquid toilet bowl detergent compositions include anionic, nonionic and cationic detergents. If desired, compositions such as those described above may be imparted with a desirable color by the addition of a suitable dye, such as a blue dye.
この組成物は、ｌＩ！器への給水の結果便器に付着する
水垢の除去に特に有効である。This composition is lI! It is particularly effective in removing limescale that adheres to the toilet bowl as a result of water supply to the bowl.
１：のような（■成物を使用する時、利用者がその水中
稀釈濃度を監視−できるようにするため、その時々の濃
度の目安を利用者が容易に確認することを可能にするよ
うな成分を含有させることが望ましい。このような成分
としては、例えば英国特許第１，３１３，１８０号明細
書に液体洗剤用として２整、さ２トげることができる。1: When using a product, the user can monitor its dilution concentration in water, so that the user can easily check the approximate concentration at that time. It is desirable to contain such ingredients. Examples of such ingredients are listed in British Patent No. 1,313,180 for use in liquid detergents.
。 .
しかし、本発明者は、酸性の便器用洗剤の上記のような
変色をらたらず成分の作用は組成物中に存在する洗浄活
性ｆヒ合物の特性に関連すること、及び上記のような変
色は、組成物の酸性条件下に陽イオンの形態で存在する
洗浄活性化合物を組成物が含有する場合にのみ実現する
ことを知見した。However, the present inventor has discovered that the effects of the above-mentioned discoloration of acidic toilet bowl detergents are related to the properties of the detergent-active compound present in the composition, and that the above-mentioned It has been found that discoloration is only achieved when the composition contains detergent active compounds that are present in cationic form under the acidic conditions of the composition.
陽イオン性の界面活性剤は、その公知の殺菌特性の故に
、酸性の便器用洗剤オｎ成物に持に有ｆ１１に含有され
る。Cationic surfactants are often included in acidic toilet bowl detergent formulations because of their known germicidal properties.
従って、本発明は、強酸の水溶；ｙと、洗浄活性１ヒ合
物と、染料とを３有する水性の酸性液体洗剤組成物であ
って、洗浄活性化合物が組成物中に陽イオンの形態で存
在すること、及び染料が酸のｐｌ！ｌｌ範囲内Ｈに依存
して変色することを特徴とする洗剤組成物に係わる。Accordingly, the present invention provides an aqueous acidic liquid detergent composition comprising an aqueous solution of a strong acid, a detersive active compound, and a dye, wherein the detergent active compound is present in the composition in the form of a cation. presence and that the dye is acidic pl! The present invention relates to a detergent composition characterized in that it changes color depending on H within the 11 range.
組成物中酸性条件下に陽イオン性である洗浄活性化合物
は、例えば第四級のアンモニウム及びイミダゾリン化合
物のような常時陽イオン性の１ヒ合物であるか、あるい
は第三アミン、第三アミンオキサイド、エトキシル化ア
ミン、ベタイン、スルホベタイン等である。具体的には
、ココナツジメチルアミンオキ−サイ′ド、ココナツ１
−リメチル第四アンモニウムクロライド及びココナツス
ルホベタイン等が挙げられる。Detergent active compounds which are cationic under acidic conditions in the composition are permanently cationic compounds, such as quaternary ammonium and imidazoline compounds, or tertiary amines, tertiary amines, etc. These include oxides, ethoxylated amines, betaines, sulfobetaines, and the like. Specifically, coconut dimethylamine oxide, coconut 1
-remethyl quaternary ammonium chloride, coconut sulfobetaine, and the like.
通常、本発明組成物は陽イオン性の洗浄活性化合物を０
．１〜１０重量％含有する。幾っがの陽イオン桂洗浄剤
の混合物、゛並υに陽イオン性洗浄剤と非イオン性洗浄
剤との混合物も使用可能である。Typically, the compositions of the present invention contain zero cationic cleaning active compounds.
．． Contains 1 to 10% by weight. Mixtures of several cationic detergents, as well as mixtures of cationic and nonionic detergents, can be used.
本発明への使用に適した゛染料は、酸のａｌｌ範囲内で
、即ち本発明の場合′水溶液量１１１ｏｚ〜６の範囲内
゛でｐＨに依存して変色する染料である。′上記のよう
な染料め典型例は、゛アシッドプル−１’（Ｃｒ ４
２０４５）、アシッドブルニ９’（ＣＩ゛４２０９０）
、アシッドバイオレッ？−’１７（ＣＩ ４２６５０
）及び主ルダントブル−１（ＣＩ ４３８３０）とい
つ外トリアリー□ルメタン系の染料である０本発明の組
成物は通常、０．０ＯＱ１〜１重量％の染料を含有する
。所望の色への変化を実現すべく、ｐＨに依存して変色
しない池の染料を付加的に含有させることも任意に可能
である。Dyes suitable for use in the present invention are dyes that change color depending on pH within the all range of acids, that is, in the case of the present invention, within the range of 111 oz to 6 oz of aqueous solution. 'A typical example of such a dye is 'Acidpur-1' (Cr4
2045), Acid Bruni 9' (CI゛42090)
, acid violet? -'17 (CI 42650
) and the main redundant blue-1 (CI 43830) and triarylmethane-based dyes. The compositions of the present invention usually contain 0.0OQ 1 to 1% by weight of the dye. Optionally, it is possible to additionally include a pH-dependent dye that does not change color in order to achieve the desired color change.
強酸としては、塩酸、硫酸、硝酸及びスルフーミン酸の
ような無機酸が適当であり、本発明の組成物はこのよう
な酸’５０．５〜２５重量％含有する。Suitable strong acids are inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid and sulfumic acid; the compositions of the invention contain from 50.5 to 25% by weight of such acids.
本発明の組成物のｐＨは２以下であり、きわめて有。The pH of the composition of the present invention is 2 or less, which is extremely high.
用な場合においては１以下である。 ゛香料、腐食
防止剤、粘度調節剤、電解質塩、少量の陰イオン性洗浄
剤、溶剤、内水性物質等のよ。In appropriate cases, it is less than or equal to 1. ``Fragrances, corrosion inhibitors, viscosity modifiers, electrolyte salts, small amounts of anionic detergents, solvents, aqueous substances, etc.
うなその他の任慧成分ち本発明組成物に含有させ得る。Other beneficial ingredients may be included in the composition of the present invention.
増粘した組成物は、便器の垂直面及び傾斜面と比較的長
時間接触し続けることができ、より良好な洗浄を実現す
るので特に望ましい。本発明の組成物は、界面活性剤で
、キサンタンゴム、ボ′リアクリレートなどのポリマー
物質で、並びにシリカ及び粘土のようを無機増粘剤で増
粘することができる。Thickened compositions are particularly desirable because they can remain in contact with the vertical and inclined surfaces of the toilet bowl for a relatively long period of time, resulting in better cleaning. The compositions of the present invention can be thickened with surfactants, polymeric materials such as xanthan gum, polyacrylates, and inorganic thickeners such as silicas and clays.
叉１」Ｌ二二邦−
次の表Ｉに、水で稀釈すると変色する幾つかの本発明組
成物を示す。数値の単位は重量％である。Table I below shows some compositions of the invention that change color when diluted with water. The numerical unit is weight %.
Claims (4)
して変色する染料とを含有するｐＨ１２以下の水性の酸
性液体洗剤組成物であつて、洗浄活性化合物が組成物中
に陽イオンの形態で存在し、染料は酸のｐＨ（範囲内で
ｐＨに依存して変色することを特徴とする洗剤組成物。(1) An aqueous acidic liquid detergent composition having a pH of 12 or less containing an aqueous solution of a strong acid, a detersive active compound, and a dye that changes color depending on pH, wherein the detergent active compound contains cations in the composition. Detergent composition, characterized in that the dye changes color depending on the pH (within an acidic pH range).
ミダゾリン化合物から成るグループから選択された常時
陽イオン性の洗浄活性化合物であることを特徴とする特
許請求の範囲第１項に記載の組成物。(2) The composition according to claim 1, wherein the cleaning active compound is a permanently cationic cleaning active compound selected from the group consisting of quaternary ammonium and imidazoline compounds. .
ン性であり、第三アミン、第三アミンオキサイド、エト
キシル化アミン、ベタイン及びスルホベタインから成る
グループから選択されることを特徴とする特許請求の範
囲第１項に記載の組成物。(3) the cleaning active compound is cationic only within the acid pH range and is selected from the group consisting of tertiary amines, tertiary amine oxides, ethoxylated amines, betaines and sulfobetaines; A composition according to claim 1.
特徴とする特許請求の範囲第１項から第３項のいずれか
に記載の組成物。(4) The composition according to any one of claims 1 to 3, which is thickened by containing a thickener.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8619391 | 1986-08-08 | ||
| GB868619391A GB8619391D0 (en) | 1986-08-08 | 1986-08-08 | Acidic liquid cleaning composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6343999A true JPS6343999A (en) | 1988-02-25 |
Family
ID=10602444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62195144A Pending JPS6343999A (en) | 1986-08-08 | 1987-08-04 | Acidic liquid detergent composition |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0255978A3 (en) |
| JP (1) | JPS6343999A (en) |
| AU (1) | AU607708B2 (en) |
| BR (1) | BR8703992A (en) |
| CA (1) | CA1329751C (en) |
| GB (1) | GB8619391D0 (en) |
| ZA (1) | ZA875848B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01240600A (en) * | 1988-03-18 | 1989-09-26 | Seiwa Kogyo Kk | Cleaning agent for toilet |
| JP2007177121A (en) * | 2005-12-28 | 2007-07-12 | Kao Corp | Detergent for hard surface |
| JP2010521572A (en) * | 2007-03-26 | 2010-06-24 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition system for changing visual indication |
| JP2010521573A (en) * | 2007-03-26 | 2010-06-24 | ザ プロクター アンド ギャンブル カンパニー | Liquid composition system to change the visual display |
| JP2015518918A (en) * | 2012-06-08 | 2015-07-06 | エス．シー． ジョンソン アンド サン、インコーポレイテッド | Adhesive detergent composition having color change system |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743395A (en) * | 1986-09-12 | 1988-05-10 | The Drackett Company | Thickened acid cleaner compositions containing quaternary ammonium germicides and having improved thermal stability |
| GB9000028D0 (en) * | 1990-01-02 | 1990-03-07 | Shell Int Research | Cleaning of equipment used in a liquid phase oxidation process |
| FR2717108B1 (en) * | 1994-03-14 | 1996-04-26 | Sgb | Cleaning process, range of cleaning products and products used in the process. |
| US5691291A (en) * | 1994-10-28 | 1997-11-25 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
| EP0788536A1 (en) * | 1994-10-28 | 1997-08-13 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
| EP0754749A1 (en) * | 1995-07-20 | 1997-01-22 | The Procter & Gamble Company | Fabric softeners containing water soluble dyes for reduced staining |
| US5965514A (en) * | 1996-12-04 | 1999-10-12 | The Procter & Gamble Company | Compositions for and methods of cleaning and disinfecting hard surfaces |
| US6331515B1 (en) * | 2001-08-06 | 2001-12-18 | Colgate-Palmolive Co. | Color changing liquid cleaning composition comprising red dyes |
| GB0305010D0 (en) * | 2003-03-05 | 2003-04-09 | Unilever Plc | Changing colours |
| GB0314211D0 (en) * | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
| US7651989B2 (en) | 2003-08-29 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
| ES2324676T3 (en) * | 2004-10-04 | 2009-08-12 | The Procter And Gamble Company | COMPOSITION WITH A COMPLEX FORMER DYE WITH METALS AND A TENSIOACTIVE. |
| US8067350B2 (en) | 2005-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Color changing cleansing composition |
| US9688946B2 (en) * | 2012-12-10 | 2017-06-27 | Milliken & Company | Cleaning composition and method for using the same |
| WO2017200496A1 (en) | 2016-05-18 | 2017-11-23 | Hayat Kimya Sanayi Anonim Sirketi | Dual purpose cleaning composition for limescale removal |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1313180A (en) * | 1970-09-23 | 1973-04-11 | Unilever Ltd | Surface active liquids |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4016089A (en) * | 1974-11-11 | 1977-04-05 | Regan Glen B | Denture cleaning concentrate |
| US4302253A (en) * | 1980-02-19 | 1981-11-24 | R. T. Vanderbilt Company, Inc. | Thickeners for acid cleaning compositions |
-
1986
- 1986-08-08 GB GB868619391A patent/GB8619391D0/en active Pending
-
1987
- 1987-07-30 CA CA000543417A patent/CA1329751C/en not_active Expired - Fee Related
- 1987-07-30 EP EP87201455A patent/EP0255978A3/en not_active Ceased
- 1987-08-04 AU AU76549/87A patent/AU607708B2/en not_active Ceased
- 1987-08-04 JP JP62195144A patent/JPS6343999A/en active Pending
- 1987-08-06 BR BR8703992A patent/BR8703992A/en not_active Application Discontinuation
- 1987-08-07 ZA ZA875848A patent/ZA875848B/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1313180A (en) * | 1970-09-23 | 1973-04-11 | Unilever Ltd | Surface active liquids |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01240600A (en) * | 1988-03-18 | 1989-09-26 | Seiwa Kogyo Kk | Cleaning agent for toilet |
| JP2007177121A (en) * | 2005-12-28 | 2007-07-12 | Kao Corp | Detergent for hard surface |
| JP2010521572A (en) * | 2007-03-26 | 2010-06-24 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition system for changing visual indication |
| JP2010521573A (en) * | 2007-03-26 | 2010-06-24 | ザ プロクター アンド ギャンブル カンパニー | Liquid composition system to change the visual display |
| JP2015518918A (en) * | 2012-06-08 | 2015-07-06 | エス．シー． ジョンソン アンド サン、インコーポレイテッド | Adhesive detergent composition having color change system |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8619391D0 (en) | 1986-09-17 |
| CA1329751C (en) | 1994-05-24 |
| AU607708B2 (en) | 1991-03-14 |
| ZA875848B (en) | 1989-04-26 |
| AU7654987A (en) | 1988-02-11 |
| BR8703992A (en) | 1988-04-05 |
| EP0255978A3 (en) | 1989-03-08 |
| EP0255978A2 (en) | 1988-02-17 |
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