JPS6343936A - Antibacterial and antifungal agent - Google Patents
Antibacterial and antifungal agentInfo
- Publication number
- JPS6343936A JPS6343936A JP61187376A JP18737686A JPS6343936A JP S6343936 A JPS6343936 A JP S6343936A JP 61187376 A JP61187376 A JP 61187376A JP 18737686 A JP18737686 A JP 18737686A JP S6343936 A JPS6343936 A JP S6343936A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- thiocyanomethylthio
- benzothiazole
- active ingredient
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 25
- 239000003242 anti bacterial agent Substances 0.000 title claims abstract description 16
- 229940121375 antifungal agent Drugs 0.000 title claims abstract description 12
- 239000003429 antifungal agent Substances 0.000 title claims abstract description 8
- TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001971 elastomer Polymers 0.000 claims abstract description 15
- 239000005060 rubber Substances 0.000 claims abstract description 15
- 239000004480 active ingredient Substances 0.000 claims abstract description 11
- 239000004033 plastic Substances 0.000 claims abstract description 9
- 229920003023 plastic Polymers 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
- 239000000194 fatty acid Substances 0.000 claims abstract description 5
- 229930195729 fatty acid Natural products 0.000 claims abstract description 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000417 fungicide Substances 0.000 claims description 8
- 230000001804 emulsifying effect Effects 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 230000000843 anti-fungal effect Effects 0.000 abstract description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- 235000021314 Palmitic acid Nutrition 0.000 abstract description 2
- 235000021355 Stearic acid Nutrition 0.000 abstract description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract description 2
- 239000001095 magnesium carbonate Substances 0.000 abstract description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 2
- 239000008117 stearic acid Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 1
- 244000043261 Hevea brasiliensis Species 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 229920003052 natural elastomer Polymers 0.000 description 5
- 229920001194 natural rubber Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- -1 diene compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 150000001845 chromium compounds Chemical class 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- CUXYLFPMQMFGPL-FWSDQLJQSA-N alpha-Eleostearic acid Natural products CCCCC=CC=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-FWSDQLJQSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- IXLCRBHDOFCYRY-UHFFFAOYSA-N dioxido(dioxo)chromium;mercury(2+) Chemical compound [Hg+2].[O-][Cr]([O-])(=O)=O IXLCRBHDOFCYRY-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000004503 fine granule Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 229940093920 gynecological arsenic compound Drugs 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000005608 naphthenic acid group Chemical class 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の目的〕
本発明は、ゴム用及び／またはプラスチック用防菌防黴
剤に関するものである。更に述べれば２−（チオシアノ
メチルチオ）ベンゾチアゾールを有効成分とするゴム用
及び／またはプラスチック用の防菌防黴剤に関するもの
である。DETAILED DESCRIPTION OF THE INVENTION [Object of the Invention] The present invention relates to an antibacterial and antifungal agent for rubber and/or plastics. More specifically, the present invention relates to an antibacterial and antifungal agent for rubber and/or plastics containing 2-(thiocyanomethylthio)benzothiazole as an active ingredient.
近年、高分子技術の進歩にともなりて、菌黴Ｃてよるこ
れら高分子の劣化が問題となっており、広範囲の工業製
品が変質分解するなど、損害もまだ莫大なものがある。In recent years, with the progress of polymer technology, the deterioration of these polymers due to fungi and mold C has become a problem, and a wide range of industrial products have been altered and decomposed, resulting in enormous damage.
特に高温多湿の梅雨期が危険である。It is especially dangerous during the hot and humid rainy season.
ゴム用及び／またはプラスチック用の菌徽の生育抑制全
目的として多くの防菌防黴剤（フェノール系化合物、有
機ハロゲン系化合物、有Ｒｔ錫系化合物、ナフテン酸系
（ヒ合物、タール系化合物等の有機系薬剤やＣＣＡ系（
銅］ヒ合物、クロム化合物の混合物）、タオルマン基糸
（フッ素化合物、クロム化合物及びフェノール類の混合
物）等の無機系薬剤）が使用されてＶ３るが、防菌防黴
剤を添加することによって加硫条件が変わったり、物理
化学的特性や電気特性に変化音きたすような物質は使用
することはできず、また直接２間接Ｃ−て人体に毒性を
与えるような防菌防黴剤は使用できない。Many antibacterial and fungicidal agents (phenolic compounds, organic halogen compounds, Rt tin compounds, naphthenic acid compounds, tar compounds, Organic drugs such as
Inorganic agents such as copper (a mixture of arsenic compounds, chromium compounds) and Taulmann base yarn (a mixture of fluorine compounds, chromium compounds, and phenols) are used, but antibacterial and fungicidal agents are added. Do not use substances that may cause changes in the vulcanization conditions, physicochemical properties, or electrical properties, and do not use antibacterial or antifungal agents that may cause toxicity to the human body through direct or indirect C-. cannot be used.
その点からも適切な防菌防黴剤の出現が強く望まれてＶ
３た。From this point of view, the emergence of an appropriate antibacterial and fungicidal agent is strongly desired.
3.
本発明者らは、ゴム用及び／またはプラスチック用Ｃで
有用な防菌防黴剤を開発するべく鋭意研究を行りた結果
、２−（チオシアノメチルチオ）ベンゾチアゾールを有
効成分とする殺菌剤が、極めて少量でゴム用及び／また
はプラスチック用の防菌防黴活性を有する優れた薬剤で
あることを見出し、本発明を完成するに至った。The present inventors conducted intensive research to develop a useful antibacterial and fungicidal agent for use in rubber and/or plastics. The present inventors have discovered that it is an excellent agent having antibacterial and antifungal activity for rubber and/or plastics in extremely small amounts, and have completed the present invention.
本発明の基体となる高分子材料としては、天然ゴム（Ｎ
Ｒ）、イソプレンゴム（ＩＲ）、ブタジェンゴム（ＢＲ
）、クロロプレンゴム（ＣＲ）。Natural rubber (N
R), isoprene rubber (IR), butadiene rubber (BR)
), chloroprene rubber (CR).
エチレンプロピレンゴム（ＥＰＤＭまたＨＥＰＭ）、ス
チレン−ブタジェンゴム（ＳＢＲ）、７クリロニトリル
ーブタジエンゴム（ＮＢＲ） 等の合成ゴム、またはそ
れらのブレンドゴム、更にジエン化合物、変性ポリオレ
フィン、アクリロニトリル樹脂、マレイン酸エステル樹
脂、アクリロニトリル−ブタジェン−スチレン樹脂（Ａ
ＢＳ）、ポリ塩化ビニル（ＰＶＣ）等の合成樹脂が挙げ
られる。Synthetic rubbers such as ethylene propylene rubber (EPDM or HEPM), styrene-butadiene rubber (SBR), 7-crylonitrile-butadiene rubber (NBR), or blend rubbers thereof, as well as diene compounds, modified polyolefins, acrylonitrile resins, maleic acid ester resins , acrylonitrile-butadiene-styrene resin (A
BS), polyvinyl chloride (PVC), and other synthetic resins.
本発明において２−（チオシアノメチルチオ）ベンゾチ
アゾールの添加量としては上記高分子製品中の高分子材
料１００重量部当たりＱ、０００１〜１．０重量部、好
ましくは０．００１〜０．５重量部でありて、この範囲
の２−（チオシアノメチルチオ）ベンゾチアゾールを添
加使用することによって、防菌防黴に優れた効果が得ら
れる。In the present invention, the amount of 2-(thiocyanomethylthio)benzothiazole added is Q, 0001 to 1.0 parts by weight, preferably 0.001 to 0.5 parts by weight, per 100 parts by weight of the polymer material in the polymer product. By adding and using 2-(thiocyanomethylthio)benzothiazole in this range, excellent antibacterial and antifungal effects can be obtained.
本発明の防菌防黴剤は粉剤、水和剤、乳剤２粒剤、微粒
剤及びその他の一般に行われる形態の薬剤として使用す
ることが可能である。本発明に使用される担体は、液体
、固体の何れでもよく、特定の担体に限定されるもので
はない。固体担体としてはゴム用防着剤として使用され
る炭酸塩、つまり炭酸カルシウム、炭酸亜鉛、炭酸カリ
ウム。The antibacterial and antifungal agent of the present invention can be used as a powder, a wettable powder, two emulsion tablets, a fine granule, and other commonly used pharmaceutical forms. The carrier used in the present invention may be either liquid or solid, and is not limited to a specific carrier. Solid carriers include carbonates used as anti-stick agents for rubber, namely calcium carbonate, zinc carbonate and potassium carbonate.
炭酸マグネシウム、炭酸ナトリウム、炭酸鉛等が挙げら
れ、高級脂肪酸としては通常炭素数１２〜３゜の飽和ま
たは不飽和の高級脂肪酸であシ、ラフリン酸、ミリスチ
ン酸、パルミチン酸、マルガリン酸、ステアリン酸、ベ
ヘニン酸、オレイン酸、リルイン酸、α−エレオステア
リン酸、β−エレオステアリン酸、α−リルイン酸等が
例示できる。また本発明の高級脂肪酸の塩としては、上
記高級脂肪酸のナトリウム塩、カリウム塩、マグネシウ
ム塩、カルシウム塩、亜鉛塩、アルミニウム塩、鉄塩、
リチウム塩等が挙げられ、液体担体としては本発明に係
る有効成分化合物または、有効成分化合物に対して、溶
媒となるもの及び、非溶媒であっても補助剤により有効
成分化合物を分散または、溶解し得るものならば使用で
きる。例えばベンゼン、キンレン、トルエン、ケロシン
、アルコール類、ケトン類、ｉ７メチルスルホキシド。Examples include magnesium carbonate, sodium carbonate, lead carbonate, etc. Higher fatty acids are usually saturated or unsaturated higher fatty acids having 12 to 3 carbon atoms, lafric acid, myristic acid, palmitic acid, margaric acid, and stearic acid. , behenic acid, oleic acid, liluic acid, α-eleostearic acid, β-eleostearic acid, α-lylunic acid, and the like. Further, the salts of higher fatty acids of the present invention include sodium salts, potassium salts, magnesium salts, calcium salts, zinc salts, aluminum salts, iron salts,
Examples of liquid carriers include lithium salts, etc., and examples of the liquid carrier include the active ingredient compound according to the present invention or a solvent for the active ingredient compound, and even if it is a non-solvent, the active ingredient compound can be dispersed or dissolved with an auxiliary agent. You can use it if you can. For example, benzene, quinolene, toluene, kerosene, alcohols, ketones, i7 methyl sulfoxide.
ジメチルホルムアミド等が挙げられる。これに適当な界
面活性剤その他の補助剤例えば展着剤、固着剤等を混合
し、水溶剤あるいは乳剤として使用できる。また本発明
に係る２−（チオシアノメチルチオ）ベンゾチアゾール
の防菌防黴効果を確実にするために、処理方法は適宜選
択することができる。Examples include dimethylformamide. It can be used as an aqueous solution or emulsion by mixing a suitable surfactant and other auxiliary agents such as a spreading agent and a fixing agent. Further, in order to ensure the antibacterial and antifungal effect of 2-(thiocyanomethylthio)benzothiazole according to the present invention, the treatment method can be appropriately selected.
次に本発明の実施例を示してこの発明の効果を更に、詳
細に説明するが、この発明はこれらに限定されるもので
はない。Next, the effects of the present invention will be explained in more detail by showing examples of the present invention, but the present invention is not limited thereto.
実施例 １
（粉剤）
２−（チオシアノメチルチオ）ベンゾチアゾールを２重
量部及び炭酸亜鉛９８重量部を均一に混合粉砕すれば有
効成分２％を含有する粉剤を得る。Example 1 (Powder) 2 parts by weight of 2-(thiocyanomethylthio)benzothiazole and 98 parts by weight of zinc carbonate are uniformly mixed and ground to obtain a powder containing 2% of the active ingredient.
実施例 ２
（乳剤）
２−（チオシアノメチルチオ）ベンゾチアゾールをω重
量部、メチルエチルケトン２３重量部及びポリオキシエ
チレンノニルフェニルエーテル１７重量部を混合して溶
解すれば有効成分６０％を含有する乳剤を得る。このも
のを使用する場合は水で６００〜１００（賠に希釈して
ゴム及びプラスチックに散布する。Example 2 (Emulsion) By mixing and dissolving ω parts by weight of 2-(thiocyanomethylthio)benzothiazole, 23 parts by weight of methyl ethyl ketone and 17 parts by weight of polyoxyethylene nonylphenyl ether, an emulsion containing 60% of the active ingredient can be obtained. obtain. When using this product, dilute it to 600-100% with water and spray it on rubber and plastic.
次に本発明に係るゴム用及び／またはプラスチック用防
菌防黴剤の生育抑制効果を試験例により具体的に説明す
る。Next, the growth inhibiting effect of the antibacterial and fungicidal agent for rubber and/or plastics according to the present invention will be specifically explained using test examples.
試験例 １
ゴムの防菌防黴試験
第１表に示す配合処方に従りて天然ゴムマスターバッチ
を作製した。この天然ゴムマスターバッチに本発明に係
る２−（チオシアノメチルチオ）ベンゾチアゾールを添
加混練り後、厚さが５．Ｑ ｍｍのシート状だロールか
ら切り出した。次に恒温検音３０±２℃、相対温度８５
％の条件下で自然放置して防菌防黴の試験に供した。Test Example 1 Antibacterial and antifungal test of rubber A natural rubber masterbatch was prepared according to the formulation shown in Table 1. After adding and kneading the 2-(thiocyanomethylthio)benzothiazole according to the present invention to this natural rubber masterbatch, the thickness was 5.5 mm. It was cut out from a roll of Q mm sheet. Next, constant temperature measurement 30±2℃, relative temperature 85
% and subjected to an antibacterial and antifungal test.
所定時間後試料を取り出し、ゴム生地表面上に菌黴が生
育してＶｈるか否かを目視で観察した。その結果を第２
表に示す。After a predetermined period of time, the sample was taken out and visually observed to see if fungi had grown on the surface of the rubber fabric and reached Vh. The result is the second
Shown in the table.
第 １ 表
第 ２ 表
防菌防黴効果の有無の表示：○：有、×：無（１）三新
化学工業株式会社製２−（チオシアノメチルチオ）ベン
ゾチアゾールの商品名
試験例 ２
第１表の天然ゴムマスターバッチに、粉剤をペルジャー
ダスターを用いて均一に塗布した後、試験例１に準じ防
菌防黴試験を行った。その結果を第３表に示す。Table 1 Table 2 Indication of presence or absence of antibacterial and antifungal effect: ○: Yes, ×: No (1) Product name of 2-(thiocyanomethylthio)benzothiazole manufactured by Sanshin Chemical Industry Co., Ltd. Test example 2 After uniformly applying the powder to the natural rubber masterbatch shown in the table using a Pelger duster, an antibacterial and antifungal test was conducted in accordance with Test Example 1. The results are shown in Table 3.
試験例 ３
第１表の天然ゴムマスターパッチを乳剤（希釈第
３ 表
〔発明の効果〕
試験例１〜３で明らかなごとく、本発明に係る２−（チ
オシアノメチルチオ）ベンゾチアゾールを有効成分とし
た防菌防黴剤は、少量の添加で未加硫ゴム生地の防菌防
黴効果が優れていることが明らかであり、本発明の産業
的利用価値は大なるものであることがわかる。Test Example 3 The natural rubber master patch shown in Table 1 was mixed into an emulsion (diluted
3 Table [Effects of the Invention] As is clear from Test Examples 1 to 3, the antibacterial and fungicidal agent containing 2-(thiocyanomethylthio)benzothiazole as an active ingredient according to the present invention can be used to cure unvulcanized rubber with the addition of a small amount. It is clear that the antibacterial and antifungal effect of the fabric is excellent, and it can be seen that the industrial utility value of the present invention is great.
Claims (3)
を有効成分とするゴム用及び／またはプラスチック用防
菌防黴剤。(1) An antibacterial and antifungal agent for rubber and/or plastics containing 2-(thiocyanomethylthio)benzothiazole as an active ingredient.
を炭酸塩、高級脂肪酸またはその塩の一種または二種以
上とを混合してなる特許請求の範囲第一項記載の防菌防
黴剤。(2) The antibacterial and fungicidal agent according to claim 1, which is obtained by mixing 2-(thiocyanomethylthio)benzothiazole with one or more of carbonates, higher fatty acids, or salts thereof.
を有機溶媒に混合または水に乳化分散してなる特許請求
の範囲第１項記載の防菌防黴剤。(3) The antibacterial and fungicidal agent according to claim 1, which is obtained by mixing 2-(thiocyanomethylthio)benzothiazole in an organic solvent or emulsifying and dispersing it in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61187376A JPH0615636B2 (en) | 1986-08-08 | 1986-08-08 | Antibacterial and antifungal method for rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61187376A JPH0615636B2 (en) | 1986-08-08 | 1986-08-08 | Antibacterial and antifungal method for rubber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6343936A true JPS6343936A (en) | 1988-02-25 |
| JPH0615636B2 JPH0615636B2 (en) | 1994-03-02 |
Family
ID=16204927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61187376A Expired - Lifetime JPH0615636B2 (en) | 1986-08-08 | 1986-08-08 | Antibacterial and antifungal method for rubber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0615636B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995008267A1 (en) * | 1993-09-24 | 1995-03-30 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing 2-(thiocyanomethylthio)benzothiazole and an organic acid |
-
1986
- 1986-08-08 JP JP61187376A patent/JPH0615636B2/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995008267A1 (en) * | 1993-09-24 | 1995-03-30 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing 2-(thiocyanomethylthio)benzothiazole and an organic acid |
| US5494904A (en) * | 1993-09-24 | 1996-02-27 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing 2-(thiocyanomethylthio)benzothiazole and an organic acid |
| US5604250A (en) * | 1993-09-24 | 1997-02-18 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing 2-(thiocyanomethylthio) benzothiazole and an organic acid |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0615636B2 (en) | 1994-03-02 |
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