JPS6341754B2 - - Google Patents
Info
- Publication number
- JPS6341754B2 JPS6341754B2 JP55171029A JP17102980A JPS6341754B2 JP S6341754 B2 JPS6341754 B2 JP S6341754B2 JP 55171029 A JP55171029 A JP 55171029A JP 17102980 A JP17102980 A JP 17102980A JP S6341754 B2 JPS6341754 B2 JP S6341754B2
- Authority
- JP
- Japan
- Prior art keywords
- printing
- desensitizer
- printed
- paper
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229940090898 Desensitizer Drugs 0.000 claims description 25
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 238000007639 printing Methods 0.000 description 30
- 230000000694 effects Effects 0.000 description 14
- 239000000976 ink Substances 0.000 description 14
- 238000007645 offset printing Methods 0.000 description 11
- 238000007644 letterpress printing Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000000586 desensitisation Methods 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- -1 attapulgide Substances 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011973 solid acid Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000000269 nucleophilic effect Effects 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- JPIYZTWMUGTEHX-UHFFFAOYSA-N auramine O free base Chemical compound C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 JPIYZTWMUGTEHX-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- YLZSIUVOIFJGQZ-UHFFFAOYSA-N bis[4-(dimethylamino)phenyl]methanol Chemical compound C1=CC(N(C)C)=CC=C1C(O)C1=CC=C(N(C)C)C=C1 YLZSIUVOIFJGQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011981 development test Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 229910002055 micronized silica Inorganic materials 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010971 suitability test Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/128—Desensitisers; Compositions for fault correction, detection or identification of the layers
Landscapes
- Color Printing (AREA)
Description
本発明は減感剤に関する。さらに詳細には無色
の発色剤を呈色させるための電子受容性化合物ま
たは固体酸によるノーカーボン感圧複写紙におい
て、呈色機能を抑制するか阻止するための減感剤
に関する。
一般に感圧複写紙は、電子供与性のロイコ染料
が微細なカプセル中に包含されて塗布された紙と
電子受容性物質または固体酸を塗布された紙から
なり、両紙を相対して重ね合わせ、加圧すると加
圧部分のカプセルが破壊されてロイコ染料が発色
する。減感剤は、電子受容性物質または電子供与
性物質を塗布した面のどちらか一方の面の発色不
要部分に予め塗布して呈色を抑制するか阻止する
目的で使用される。
電子受容性物質および電子供与性物質を含んだ
カプセルは紙に全面に均一に塗布されるので、不
要部分は、印刷機などによつて減感剤をどちらか
の面に塗布する方法が広く行なわれている。
電子受容性の固体酸としては粘土鉱物質、例え
ば酸性白土、ベントナイト、アタパルガイド、ゼ
オライト、カオリンなどが知られている。また電
子供与性の発色剤としては、クリスタルバイオレ
ツトラクトン、ローダミンアニリノラクトン、マ
ラカイトグリーンラクトン、ベンゾイルロイコメ
チレンブルー、ミヒラーヒドロール、N−アリル
ロイコオーラミンなどが知られている。
従来公知の減感剤としては、特公昭46−29546、
特公昭49−19647、特開昭48−6805などにみられ
るようなポリヒドロキシ化合物、特公昭44−
27255、特公昭45−21448などにみられるようなア
ミン系化合物、特公昭33−3921、特開昭49−
15513などにみられるようなヘテロ化合物、特開
昭52−156010、特開昭53−97511などにみられる
ようポリエーテル化合物などがある。
これらの減感剤の大部分は、強い親水性物質で
あるため、凸版印刷機によつて印刷されており、
凸版印刷機以外の印刷機を使用することは困難で
あつた。減感剤を凸版印刷機以外の印刷機で印刷
できるようになると種々の利点を生じる。例え
ば、オフセツト平版印刷機で印刷できるようにな
れば、従来の凸版印刷機で印刷する場合に比べ
て、(1)オフセツトされるのでインキの盛りが均一
である(2)印圧が版全面に均一にかかるので、中葉
紙マイクロカプセルの破壊が少ない(3)製版が簡単
である(4)印刷速度が大である(5)印刷の仕上りが美
しい(6)印刷機が広く一般に普及しているので需要
が大であるなどの利点が期待できる。
減感剤を湿式オフセツト印刷機によつて印刷す
る試みは、例えば減感剤としてアルコキシル求核
化合物を用いてなされてきたが、従来の減感剤で
は、印刷適性、耐ブリード性が劣り、その減感効
果も十分なものではなかつた。
また、最近、減感剤を水なし平版印刷で印刷す
る試みもなされているが、従来から広く普及して
いる湿式オフセツト印刷機で印刷できる減感剤の
出現は強く望まれるところであつた。
本発明者らは、凸版印刷機のみならず凸版印刷
機以外の印刷機でも印刷可能な減感剤を鋭意研究
した結果、本発明の減感効果のすぐれた減感剤を
発明するに至つたものである。
すなわち、本発明は、樹脂酸還元アルコール
に、アルキレンオキシドまたはスチレンオキシド
を付加せしめた生成物を含んでなる減感剤であ
る。
本発明は、ノーカーボン複写紙などの感圧複写
紙にすぐれた減感効果を有し、減感剤の印刷され
ていない部分へのブリードがなく、凸版印刷のみ
ならず凸版印刷以外の印刷方法とりわけ湿式オフ
セツト印刷での印刷時の印刷適性にすぐれ、従来
の減感剤の欠点である黄変や臭気の問題がなく、
合成も容易な減感剤を提供するものである。
本発明による減感剤を用いた印刷インキは、従
来の凸版印刷の他種々の印刷方法例えばオフセツ
ト印刷、フレキソ印刷などでも印刷できるので、
従来の凸版印刷用減感インキでは得られなかつた
種々の利点を有する。例えば、本発明による減感
剤を使用して作つた印刷インキを湿式オフセツト
印刷機によつて印刷した場合には、印刷効果もす
ぐれ、乾燥性も特にすぐれているので、印刷の高
速化が可能であり、製版も容易で、多大の省力化
ができる。
本発明により減感剤を用いて作つてインキによ
り印刷した場合には、筆記性がよく、印刷されて
いるのが目立たない印刷物が得られる。
本発明にかかわる樹脂酸還元アルコールとは、
天然樹脂の成分である樹脂酸を還元して得られ、
ロジンアルコールとよばれているロジンから得ら
れる樹脂酸還元アルコールなどがよく知られてい
る。ロジンは、アビエチン酸を主成分とする樹脂
を主成分とするので、ロジンから得られる樹脂酸
アルコールの主成分はヒドロアビエチルアルコー
ルであることが知られている。
本発明において用いられるアルキレンオキシド
には、エチレンオキシド、プロピレンオキシド、
ブチレンオキシド、またはこれらの混合物などが
あるが、減感効果の上からは、エチレンオキシ
ド、プロピレンオキシド、またはこれらの混合物
が好ましい。アルキレンオキシドもしくはスチレ
ンオキシドの付加モル数は樹脂酸還元アルコール
の水酸基1モルに対し、エチレンオキシド、プロ
ピレンオキシドの場合には1〜100モル、スチレ
ンオキシドでは1〜20モルが最も好ましく、この
モル数以上または未満では印刷効果および減感効
果が悪くなる傾向がある。
本発明の減感剤を用いた印刷インキには、目的
に応じて、減感効果を阻害しない程度において乾
燥促進剤、他のワニス、溶剤、顔料など所望の添
加剤を適宜加えることができる。
以下、実施例により本発明を説明する。
実施例 1
アビトール(米国ハーキユレス社製 樹脂酸還
元アルコール)100g(水酸基約0.28モル含有)
とプロピレンオキシド163g(2.8モル)の付加反
応生成物60重量部に、酸化チタン(ルチル)20重
量部および鉱油10重量部を混合し、三本ロールミ
ルにて混練して減感インキを調製した。得られた
減感インキを、オフセツト印刷試験機を用いて市
販のノーカーボン感圧複写紙中葉紙に塗布量がそ
れぞれ5.0g/m2になるように印刷した。以下同
様に下記の付加反応生成物を含む減感インキを調
製し印刷した。
The present invention relates to desensitizers. More particularly, the present invention relates to a desensitizer for suppressing or blocking the coloring function in carbonless pressure-sensitive copying paper using an electron-accepting compound or solid acid for coloring a colorless coloring agent. Generally, pressure-sensitive copying paper consists of paper coated with an electron-donating leuco dye encapsulated in fine capsules and paper coated with an electron-accepting substance or solid acid. When pressurized, the capsule in the pressurized area is destroyed and the leuco dye develops color. The desensitizer is used for the purpose of suppressing or preventing color development by applying it in advance to areas where color development is not required on either the surface coated with the electron-accepting substance or the electron-donating substance. Capsules containing electron-accepting substances and electron-donating substances are uniformly applied to the entire surface of the paper, so it is widely used to apply a desensitizer to either side of the paper using a printing machine to remove unnecessary areas. It is. Clay minerals such as acid clay, bentonite, attapulgide, zeolite, and kaolin are known as electron-accepting solid acids. Also, known electron-donating color formers include crystal violet lactone, rhodamine anilinolactone, malachite green lactone, benzoyl leucomethylene blue, Michler's hydrol, and N-allyl leuco auramine. Conventionally known desensitizers include Japanese Patent Publication No. 46-29546;
Polyhydroxy compounds such as those found in JP-A-1964-19647, JP-A-48-6805, etc.;
27255, amine compounds such as those found in Japanese Patent Publication No. 1972-21448, Japanese Patent Publication No. 33-3921, Japanese Patent Publication No. 1973-
These include hetero compounds as seen in JP-A No. 15513, and polyether compounds as shown in JP-A-156010-1983 and JP-A-97511-A. Most of these desensitizers are strongly hydrophilic substances and are therefore printed by letterpress printing presses.
It was difficult to use printing machines other than letterpress printing machines. The ability to print desensitizers on printing presses other than letterpress printing presses provides various advantages. For example, if it became possible to print with an offset lithographic printing machine, compared to printing with a conventional letterpress printing machine, (1) the ink would be evenly distributed because it is offset, and (2) the printing pressure would be applied to the entire surface of the plate. Because it applies evenly, there is less destruction of paper microcapsules (3) Plate making is easy (4) Printing speed is high (5) Printing has a beautiful finish (6) Printing machines are widely used by the general public Therefore, advantages such as high demand can be expected. Attempts have been made to print desensitizers using wet offset printing machines, for example, using alkoxyl nucleophilic compounds as desensitizers, but conventional desensitizers have poor printability and bleed resistance, and The desensitization effect was also not sufficient. Although attempts have recently been made to print desensitizers by waterless lithographic printing, there has been a strong desire for a desensitizer that can be printed using conventional wet offset printing machines. As a result of intensive research into desensitizers that can be printed not only on letterpress printing machines but also on printing machines other than letterpress printing machines, the present inventors came to invent the desensitizer with excellent desensitizing effects of the present invention. It is something. That is, the present invention is a desensitizer comprising a product obtained by adding alkylene oxide or styrene oxide to a resin acid-reduced alcohol. The present invention has an excellent desensitizing effect on pressure-sensitive copying paper such as carbonless copying paper, and there is no bleeding of desensitizer into unprinted areas, and the present invention is applicable to printing methods other than letterpress printing as well as letterpress printing. In particular, it has excellent printability during wet offset printing, and does not have the problems of yellowing and odor that are the drawbacks of conventional desensitizers.
The present invention provides a desensitizer that is easy to synthesize. The printing ink using the desensitizer according to the present invention can be printed by various printing methods such as offset printing and flexographic printing in addition to conventional letterpress printing.
It has various advantages not available with conventional desensitized inks for letterpress printing. For example, when a printing ink made using the desensitizer according to the present invention is printed using a wet offset printing machine, the printing effect is excellent and the drying properties are also particularly excellent, making it possible to speed up printing. Therefore, plate making is easy and a large amount of labor can be saved. When a desensitizer is used in accordance with the present invention and printed with ink, a printed matter with good writability and inconspicuous printing can be obtained. The resin acid-reduced alcohol related to the present invention is
Obtained by reducing resin acid, which is a component of natural resin,
Resin acid-reduced alcohol obtained from rosin, called rosin alcohol, is well known. Since rosin has a resin containing abietic acid as its main component, it is known that the main component of resin acid alcohol obtained from rosin is hydroabiethyl alcohol. The alkylene oxides used in the present invention include ethylene oxide, propylene oxide,
Examples include butylene oxide and mixtures thereof, but ethylene oxide, propylene oxide, or mixtures thereof are preferred from the viewpoint of desensitizing effect. The number of moles of alkylene oxide or styrene oxide added is most preferably 1 to 100 moles in the case of ethylene oxide and propylene oxide, and 1 to 20 moles in the case of styrene oxide, and more than this number of moles or If it is less than that, the printing effect and desensitization effect tend to deteriorate. Depending on the purpose, desired additives such as a drying accelerator, other varnishes, solvents, pigments, etc. can be appropriately added to the printing ink using the desensitizer of the present invention to an extent that does not inhibit the desensitizing effect. The present invention will be explained below with reference to Examples. Example 1 100 g of Avitol (resin acid-reduced alcohol manufactured by Hercules, USA) (contains about 0.28 mole of hydroxyl group)
20 parts by weight of titanium oxide (rutile) and 10 parts by weight of mineral oil were mixed with 60 parts by weight of an addition reaction product of 163 g (2.8 moles) of propylene oxide and propylene oxide, and the mixture was kneaded in a three-roll mill to prepare a desensitizing ink. The obtained desensitized inks were printed on commercially available carbonless pressure-sensitive copy paper using an offset printing tester so that the coating amount was 5.0 g/m 2 . Desensitizing inks containing the following addition reaction products were prepared and printed in the same manner.
【表】
比較例 1
ポリエチレングリコール(分子量約400)
(PEG400、三洋化成工業(株)製、水酸基価250)30
重量部、アマニ油変性アルキド樹脂30重量部、鉱
油10重量部および酸化チタン(ルチル)30重量部
を3本ローラーミルで均一に練肉混合し、減感イ
ンキを調製した。
得られた減感インキを、オフセツト印刷試験機
を用いて、市販のノーカーボン感圧複写紙の中葉
紙に、塗布量が5.0g/m2になるように印刷した。
比較例 2
アルコキシル化求核化合物の1種であるエトキ
シル化ノニルフエノール(減感剤)60重量%、グ
リセリンでエステル化したロジン40重量%からな
るワニス80重量部に、微粒子化シリカ3重量部、
炭酸カルシウム12重量部および酸化チタン(ルチ
ル)5重量部を三本ロールミルにて混練して減感
インキを調製した。
得られた減感インキを、比較例1と同様にし
て、市販のノーカーボン感圧複写紙の中葉紙に印
刷した。
次に減感効果、耐ブリード性およびオフセツト
印刷適性についての試験法を示す。
〔試験法〕
減感効果試験
上記の印刷紙を用いて、直径0.8mmの球に100
gの荷重をかけ、1分間に5mの速度で移動さ
せ複写(発色)操作をし、減感効果試験した。
試験の結果は表1の通りで、数値はミクロデン
シトメーターで測定した反射視覚度値(ビジア
ルデンシテイの略号Vis、D)を示す。[Table] Comparative example 1 Polyethylene glycol (molecular weight approximately 400)
(PEG400, manufactured by Sanyo Chemical Industries, Ltd., hydroxyl value 250) 30
A desensitizing ink was prepared by uniformly mixing 30 parts by weight of linseed oil-modified alkyd resin, 10 parts by weight of mineral oil, and 30 parts by weight of titanium oxide (rutile) using a three-roller mill. The obtained desensitized ink was printed using an offset printing tester on the inner sheet of commercially available carbonless pressure-sensitive copying paper so that the coating amount was 5.0 g/m 2 . Comparative Example 2 To 80 parts by weight of a varnish consisting of 60% by weight of ethoxylated nonylphenol (desensitizer), which is a type of alkoxylated nucleophilic compound, and 40% by weight of rosin esterified with glycerin, 3 parts by weight of micronized silica,
A desensitizing ink was prepared by kneading 12 parts by weight of calcium carbonate and 5 parts by weight of titanium oxide (rutile) in a three-roll mill. The obtained desensitized ink was printed in the same manner as in Comparative Example 1 on the inner sheet of commercially available carbonless pressure-sensitive copying paper. Next, test methods for desensitization effect, bleed resistance and offset printing suitability will be shown. [Test method] Desensitization effect test Using the above printing paper, 100
The desensitizing effect was tested by applying a load of 1.5 g and moving at a speed of 5 m per minute for copying (color development).
The results of the test are shown in Table 1, and the numerical values indicate the reflective visibility values (visual density abbreviation: Vis, D) measured with a microdensitometer.
【表】【table】
【表】
耐ブリード性試験
上記印刷物と減感しないノーカーボン感圧複
写紙とを重ねあわせて、10g/cm2の荷重をか
け、相対湿度90%、温度20℃の恒温恒湿室の中
に1ケ月間放置した後、上記印刷物および減感
しないノーカーボン感圧複写紙についてそれぞ
れ発色試験をした。その結果を表2に示す。[Table] Bleed resistance test The above printed material and non-desensitized carbonless pressure-sensitive copying paper were stacked together, a load of 10 g/cm 2 was applied, and the paper was placed in a constant temperature and humidity room at a relative humidity of 90% and a temperature of 20°C. After being left for one month, a color development test was conducted on the printed matter and the non-desensitized carbonless pressure-sensitive copying paper. The results are shown in Table 2.
【表】【table】
【表】
オフセツト印刷適性試験
印刷適性は、オフセツト印刷試験機による印
刷時の印刷し易さを総合的に判定した。結果を
表3に示す。[Table] Offset printing suitability test Printing suitability was comprehensively judged by ease of printing using an offset printing tester. The results are shown in Table 3.
【表】【table】
実施例19、20および比較例3によつて得られた
減感インキを、フレキソ印刷試験機を用いて、市
販のノーカーボン感圧複写紙の中葉紙に、塗布量
がそれぞれ4.0g/m2になるように印刷した。
〔試験法〕
得られた印刷紙を用いて、実施例1〜18、およ
び比較例1および2について行なつた試験法と同
一の方法により、減感効果および耐ブリード性を
試験した。また、フレキソ印刷適性については、
フレキソ印刷試験機による印刷のし易さを総合的
に判定した。
減感効果試験の結果を表4に、耐ブリード性試
験の結果を表5に、また、フレキソ印刷適性試験
の結果を表6に、それぞれ示す。
The desensitizing inks obtained in Examples 19 and 20 and Comparative Example 3 were applied to inner sheets of commercially available carbonless pressure-sensitive copying paper using a flexographic printing tester at a coating amount of 4.0 g/m 2 , respectively. I printed it to look like this. [Test Method] Using the obtained printed paper, desensitization effect and bleed resistance were tested by the same method as that used in Examples 1 to 18 and Comparative Examples 1 and 2. Regarding suitability for flexographic printing,
The ease of printing was comprehensively judged using a flexographic printing tester. The results of the desensitization effect test are shown in Table 4, the results of the bleed resistance test are shown in Table 5, and the results of the flexo printing aptitude test are shown in Table 6.
【表】【table】
【表】【table】
【表】
○:良好 △:やや劣る
表1ないし表6に示した結果から、本発明によ
る減感剤が、減感効果、耐ブリード性、オフセツ
ト印刷適性およびフレキソ印刷適性においてすぐ
れていることがわかる。[Table] ○: Good △: Slightly poor
The results shown in Tables 1 to 6 show that the desensitizer according to the present invention is excellent in desensitizing effect, bleed resistance, suitability for offset printing, and suitability for flexographic printing.
Claims (1)
ドまたはスチレンオキシドを付加せしめた生成物
を含んでなる減感剤。1. A desensitizer comprising a product obtained by adding alkylene oxide or styrene oxide to a resin acid-reduced alcohol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55171029A JPS5795493A (en) | 1980-12-05 | 1980-12-05 | Sensitivity reducing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55171029A JPS5795493A (en) | 1980-12-05 | 1980-12-05 | Sensitivity reducing agent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5795493A JPS5795493A (en) | 1982-06-14 |
JPS6341754B2 true JPS6341754B2 (en) | 1988-08-18 |
Family
ID=15915759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55171029A Granted JPS5795493A (en) | 1980-12-05 | 1980-12-05 | Sensitivity reducing agent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5795493A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0453609U (en) * | 1990-09-13 | 1992-05-07 |
-
1980
- 1980-12-05 JP JP55171029A patent/JPS5795493A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0453609U (en) * | 1990-09-13 | 1992-05-07 |
Also Published As
Publication number | Publication date |
---|---|
JPS5795493A (en) | 1982-06-14 |
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