JPS6341132Y2 - - Google Patents
Info
- Publication number
- JPS6341132Y2 JPS6341132Y2 JP1984097180U JP9718084U JPS6341132Y2 JP S6341132 Y2 JPS6341132 Y2 JP S6341132Y2 JP 1984097180 U JP1984097180 U JP 1984097180U JP 9718084 U JP9718084 U JP 9718084U JP S6341132 Y2 JPS6341132 Y2 JP S6341132Y2
- Authority
- JP
- Japan
- Prior art keywords
- resin liquid
- injection
- injection head
- stirring blade
- shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002347 injection Methods 0.000 claims description 84
- 239000007924 injection Substances 0.000 claims description 84
- 239000007788 liquid Substances 0.000 claims description 78
- 229920005989 resin Polymers 0.000 claims description 77
- 239000011347 resin Substances 0.000 claims description 77
- 238000003756 stirring Methods 0.000 claims description 23
- 238000007599 discharging Methods 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000020169 heat generation Effects 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005007 epoxy-phenolic resin Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Description
【考案の詳細な説明】
〔技術分野〕
本考案は反応性樹脂液を内部で混合して下部の
ノズル部より吐出させる混合注入装置に関するも
のである。[Detailed Description of the Invention] [Technical Field] The present invention relates to a mixing injection device that mixes a reactive resin liquid internally and discharges the mixture from a lower nozzle portion.
従来、例えば硬質ウレタンフオーム等のように
二種以上の樹脂液を混合して反応硬化させるタイ
プの発泡プラスチツクを製造するにあたつては、
第2図に示すような混合注入装置が用いられてい
る。図中2は注入ヘツドで、注入ヘツド2内には
撹拌羽根1が回転自在に配設してある。注入ヘツ
ド2の上部両側には反応性樹脂液が注入ヘツド2
内に注入される樹脂液注入口6,6がそれぞれ設
けてあり、また注入ヘツド2の下端部には内部で
混合された混合樹脂液を吐出するノズル部5が設
けてある。また7は注入ヘツド2の上面板で、こ
の上面板7には撹拌羽根1のシヤフト8を通す軸
孔9が設けてあり、軸孔9にはオイルシール10
が装着してある。各樹脂液注入口6,6より注入
ヘツド2内に注入された反応性樹脂液は撹拌羽根
1の撹拌により混合され、そして撹拌羽根1と注
入ヘツド2の内壁面との間に形成される混合室1
1を流下して注入ヘツド2のノズル部5より吐出
され、そしてこの混合樹脂液は成形板などの基板
裏面に注入充填されて硬化するのである。ところ
が、各樹脂液注入口6より注入ヘツド2内に注入
された反応性樹脂液は全量が注入ヘツド2の樹脂
混合室11を通つて流下するのではなくて、樹脂
液の一部は注入口6より上側の混合室11内にも
入つて残留するという問題がある。このように反
応性樹脂液が注入ヘツド2の混合室11内の上部
に停滞すると反応性樹脂液がその部分で反応硬化
して注入ヘツド2内壁面に付着硬化し、その結果
長時間運転を続けると硬化物Aが図のように堆積
して撹拌羽根1の抵抗となり、発熱、焼き付けを
起こして運転ができなくなるものであつた。しか
も、樹脂液の一部はシヤフト8表面及びオイルシ
ール10にも固着して発熱、焼き付けし、オイル
シール10が破損するおそれがあるという問題が
あつた。
Conventionally, when manufacturing foamed plastics such as hard urethane foam, in which two or more resin liquids are mixed and cured by reaction,
A mixing injection device as shown in FIG. 2 is used. In the figure, reference numeral 2 denotes an injection head, and within the injection head 2, a stirring blade 1 is rotatably disposed. The reactive resin liquid is placed on both sides of the upper part of the injection head 2.
Injection ports 6, 6 for injecting a resin liquid into the injection head 2 are respectively provided, and a nozzle portion 5 is provided at the lower end of the injection head 2 for discharging the mixed resin liquid mixed inside. Reference numeral 7 designates the upper surface plate of the injection head 2, and this upper surface plate 7 is provided with a shaft hole 9 through which the shaft 8 of the stirring blade 1 passes.
is installed. The reactive resin liquid injected into the injection head 2 from each resin liquid injection port 6, 6 is mixed by stirring by the stirring blade 1, and the mixture is formed between the stirring blade 1 and the inner wall surface of the injection head 2. Room 1
1 flows down and is discharged from the nozzle portion 5 of the injection head 2, and this mixed resin liquid is injected and filled into the back surface of a substrate such as a molded plate and hardened. However, the entire amount of the reactive resin liquid injected into the injection head 2 from each resin liquid injection port 6 does not flow down through the resin mixing chamber 11 of the injection head 2, but a portion of the resin liquid flows through the injection port. There is a problem that the mixture also enters the mixing chamber 11 above the mixing chamber 6 and remains there. When the reactive resin liquid stagnates in the upper part of the mixing chamber 11 of the injection head 2 in this way, the reactive resin liquid reacts and hardens in that area and adheres to the inner wall surface of the injection head 2, resulting in continued operation for a long time. The hardened material A was deposited as shown in the figure and became a resistance to the stirring blade 1, causing heat generation and seizure, making it impossible to operate. In addition, a portion of the resin liquid adheres to the surface of the shaft 8 and the oil seal 10, causing heat generation and burning, which may cause damage to the oil seal 10.
〔考案の目的〕
本考案は上記の点に鑑みて成されたものであつ
て、注入ヘツド内に注入された二種以上の反応性
樹脂液の一部が注入ヘツドの上部内に残留して反
応硬化するということがなく、長時間運転するこ
とも可能であると共にまたオイルシール等が破損
することもない混合注入装置を提供することを目
的とするものである。[Purpose of the invention] The present invention has been made in view of the above points, and is intended to prevent a part of two or more reactive resin liquids injected into the injection head from remaining in the upper part of the injection head. It is an object of the present invention to provide a mixing injection device that does not undergo reaction hardening, can be operated for a long time, and does not damage oil seals or the like.
すなわち、本考案の混合注入装置は、内部に撹
拌羽根1が配設された注入ヘツド2の上部両側に
反応性樹脂液が注入される樹脂液注入口3,4を
それぞれ設けると共に一方の樹脂液注入口3を他
方の樹脂液注入口4よりも上方位置に形成し、注
入ヘツド2の下端部に混合樹脂液を吐出するノズ
ル部5を設け、上記撹拌羽根1のシヤフト8を注
入ヘツド2の上面板7に形成した軸孔9に通し、
シヤフト8の周囲にて撹拌羽根1と注入ヘツド2
の上面板7との間にOリング12を介在せしめて
成るもので、一方の樹脂液注入口3を他方の樹脂
液注入口4よりも上方位置に形成することによつ
て注入ヘツド2の混合室11の上部内には一方の
樹脂液のみが残留するようにして上記目的を達成
したものである。
That is, the mixing injection device of the present invention is provided with resin liquid injection ports 3 and 4 on both sides of the upper part of the injection head 2 in which the stirring blade 1 is disposed, and in which the reactive resin liquid is injected. The injection port 3 is formed above the other resin liquid injection port 4, a nozzle part 5 for discharging the mixed resin liquid is provided at the lower end of the injection head 2, and the shaft 8 of the stirring blade 1 is connected to the injection head 2. Pass through the shaft hole 9 formed in the top plate 7,
Stirring blade 1 and injection head 2 around shaft 8
An O-ring 12 is interposed between it and the top plate 7, and one resin liquid injection port 3 is formed above the other resin liquid injection port 4, thereby making it possible to mix the injection head 2. The above object is achieved by leaving only one of the resin liquids in the upper part of the chamber 11.
以下本考案を実施例に基づいて詳述する。第1
図に示すように注入ヘツド2内にはシヤフト8の
回転駆動によつて回転する撹拌羽根1が配設して
ある。注入ヘツド2の上面に取り付けられた上面
板7にはシヤフト8を通す軸孔9が設けてあり、
上面板7とシヤフト8との間にはオイルシール1
0が装着してある。また、この上面板7と撹拌羽
根1との間にはシヤフト8の周囲にてOリング1
2が介装してある。注入ヘツド2の上部両側には
それぞれ反応性樹脂液を注入ヘツド2内に注入す
る樹脂液注入口3,4が設けてあり、この樹脂液
注入口3,4は一方の樹脂液注入口3が他方の樹
脂液注入口4よりも上方位置に形成してあつて、
両樹脂液注入口3,4に上下レベル差を設けてあ
る。両樹脂液注入口3,4のレベル差は本考案の
実施例では10mm程度としてある。また、注入ヘツ
ド2の下端部には内部で混合された混合樹脂液を
吐出するノズル部5が設けてある。 The present invention will be described in detail below based on examples. 1st
As shown in the figure, a stirring blade 1 is disposed within the injection head 2 and is rotated by the rotation of a shaft 8. As shown in FIG. A top plate 7 attached to the top of the injection head 2 is provided with a shaft hole 9 through which a shaft 8 passes.
An oil seal 1 is installed between the top plate 7 and the shaft 8.
0 is installed. Additionally, an O-ring 1 is installed around the shaft 8 between the top plate 7 and the stirring blade 1.
2 is interposed. Resin liquid injection ports 3 and 4 are provided on both sides of the upper part of the injection head 2, respectively, for injecting reactive resin liquid into the injection head 2. It is formed at a position above the other resin liquid injection port 4, and
A difference in upper and lower levels is provided between both resin liquid injection ports 3 and 4. In the embodiment of the present invention, the level difference between the resin liquid injection ports 3 and 4 is approximately 10 mm. Furthermore, a nozzle portion 5 is provided at the lower end of the injection head 2 for discharging the mixed resin liquid mixed inside.
しかして、上部樹脂液注入口3と下部樹脂液注
入口4からそれぞれ反応性樹脂液が注入ヘツド2
の混合室11内に注入されると、両樹脂液は撹拌
羽根1の撹拌によつて混合室11内で混合され、
同時に自重により各樹脂液は混合室11内を流下
してノズル部5より吐出されるものである。その
際、各樹脂液は注入時の圧力や撹拌羽根1の回転
力によつて注入口3,4部分よりも上側の混合室
11内にも入り込む場合があるが、上部樹脂液注
入口3と下部樹脂液注入口4には上記のように上
下のレベル差を設けているために、混合室11の
上部には上部樹脂液注入口3から注入された樹脂
液のみが優先して入ることになり、そして混合室
11の上部には上部樹脂液注入口3からの樹脂液
のみが溜まることになつて混合室11の上部には
下部樹脂液注入口4から注入された樹脂液が混入
することがないものである。従つて、混合室11
の上部では反応が起こらず、混合室11上部及び
オイルシール10への硬化物の硬化付着を防止す
ることができて、長時間の運転においても加熱、
焼き付けを起こすということがないものである。
従つて、このことは運転停止時において混合室1
1内部の洗浄も容易に行えるという利点がある。
つまり、洗浄する場合には従来では、両樹脂液の
注入を停止した後、混合室11内に洗浄溶剤を注
入して内壁面を洗浄し、その後空気を吹き込んで
洗浄溶剤を揮発させるという方法で行つているの
であるが、上部樹脂液注入口3から注入した樹脂
液だけを混合室11内に注入して内部の混合樹脂
液を追い出すことによつて、運転停止後も内壁面
に硬化物が発生することがなく、従つて洗浄溶剤
による洗浄が極めて容易に行えるのである。ま
た、撹拌羽根1の上部と注入ヘツド2の上面板7
との間にOリング12を介在させることにより、
撹拌羽根1と上面板7との間隙を塞いでオイルシ
ール10側へ樹脂液が流入するのを防ぎ、上記効
果をさらに増加することができると共に、また上
部樹脂液注入口3から注入された樹脂液のみが混
合室11の上部に溜まるために、混合液の侵入を
防止することができるものである。 Thus, the reactive resin liquid is supplied to the injection head 2 from the upper resin liquid injection port 3 and the lower resin liquid injection port 4, respectively.
When injected into the mixing chamber 11, both resin liquids are mixed in the mixing chamber 11 by stirring by the stirring blade 1.
At the same time, each resin liquid flows down in the mixing chamber 11 due to its own weight and is discharged from the nozzle portion 5. At that time, each resin liquid may enter the mixing chamber 11 above the injection ports 3 and 4 due to the pressure at the time of injection and the rotational force of the stirring blade 1, but the upper resin liquid injection port 3 Since the lower resin liquid inlet 4 is provided with a level difference between the upper and lower sides as described above, only the resin liquid injected from the upper resin liquid inlet 3 enters the upper part of the mixing chamber 11 with priority. Then, only the resin liquid from the upper resin liquid injection port 3 is accumulated in the upper part of the mixing chamber 11, and the resin liquid injected from the lower resin liquid injection port 4 is mixed into the upper part of the mixing chamber 11. There is no such thing. Therefore, the mixing chamber 11
No reaction occurs in the upper part of the mixing chamber 11 and the oil seal 10 can be prevented from hardening and adhesion of the cured product, and even during long-term operation, heating and
It does not cause burn-in.
Therefore, this means that when the operation is stopped, the mixing chamber 1
1 has the advantage that the inside can be easily cleaned.
In other words, when cleaning, conventionally, after stopping the injection of both resin liquids, the cleaning solvent is injected into the mixing chamber 11 to clean the inner wall surface, and then air is blown in to volatilize the cleaning solvent. However, by injecting only the resin liquid injected from the upper resin liquid inlet 3 into the mixing chamber 11 and expelling the mixed resin liquid inside, the cured product can be kept on the inner wall surface even after the operation is stopped. Therefore, cleaning with a cleaning solvent can be performed extremely easily. In addition, the upper part of the stirring blade 1 and the upper surface plate 7 of the injection head 2
By interposing the O-ring 12 between
Closing the gap between the stirring blade 1 and the upper plate 7 prevents the resin liquid from flowing into the oil seal 10 side, further increasing the above effect, and also preventing the resin injected from the upper resin liquid injection port 3. Since only the liquid accumulates in the upper part of the mixing chamber 11, it is possible to prevent the mixed liquid from entering.
なお、上記で使用する反応性樹脂液としては例
えば硬質ウレタンフオームの製造にあつては、ポ
リオール成分とイソシアネート成分を用いること
ができる。ここで、両成分のうち比重が軽い成
分、例えばポリオール成分を上部樹脂液注入口3
から注入ヘツド2内部に注入するのが良い。すな
わち、上部樹脂液注入口3と下部樹脂液注入口4
に上下レベルの差を付けることによつて、混合室
11の上部内には優先的に上部樹脂液注入口3か
らの樹脂液のみを充填させるようにしたが、さら
に比重の軽い方の樹脂液を上部樹脂液注入口3か
ら注入することによつて混合室11の上部内にこ
の樹脂液のみが確実に混合することなく溜まるよ
うにしたものである。また、両成分のうちポリオ
ール成分を上部樹脂液注入口3から混合室11内
に注入すれば運転停止時においてもトラブルを発
生することがないものである。すなわち、イソシ
アネート成分は空気中の水分と反応して硬化する
という性質があるのであるが、ポリオール成分は
イソシアネート成分と混合されない限り空気中の
水分とは反応しないために混合室11の上部にポ
リオール成分を注入充填したままラインを停止し
たとしても硬化することがないからである。ま
た、この混合注入装置にあつては、硬質ウレタン
フオームの製造に限定するものではなく、二種以
上の反応性樹脂液を混合して反応させるタイプの
樹脂、例えばエポキシ樹脂、フエノール樹脂、ユ
リア樹脂、アルキド樹脂等の混合にも適用するこ
とができる。 In addition, as the reactive resin liquid used above, for example, in the production of rigid urethane foam, a polyol component and an isocyanate component can be used. Here, a component with a lighter specific gravity among both components, for example, a polyol component, is added to the upper resin liquid injection port 3.
It is preferable to inject into the injection head 2 from the inside. That is, the upper resin liquid injection port 3 and the lower resin liquid injection port 4
By creating a difference in the upper and lower levels of the mixing chamber 11, only the resin liquid from the upper resin liquid inlet 3 is preferentially filled into the upper part of the mixing chamber 11. By injecting the resin liquid from the upper resin liquid injection port 3, only this resin liquid is ensured to accumulate in the upper part of the mixing chamber 11 without being mixed. Moreover, if the polyol component of both components is injected into the mixing chamber 11 from the upper resin liquid injection port 3, no trouble will occur even when the operation is stopped. That is, the isocyanate component has the property of curing by reacting with moisture in the air, but the polyol component does not react with moisture in the air unless mixed with the isocyanate component, so the polyol component is placed in the upper part of the mixing chamber 11. This is because even if the line is stopped while it is injected and filled, it will not harden. In addition, this mixing injection device is not limited to the production of hard urethane foam, but can also be used to mix and react two or more types of reactive resin liquids, such as epoxy resins, phenolic resins, and urea resins. It can also be applied to mixing of alkyd resins, etc.
上記のように本考案は、内部に撹拌羽根が配設
された注入ヘツドの上部両側に反応性樹脂液が注
入される樹脂液注入口をそれぞれ設ける共に、一
方の樹脂液注入口を他方の樹脂液注入口よりも上
方位置に形成したので、上部の樹脂液注入口より
注入ヘツド内に注入された樹脂液だけが優先して
混合室の上部内に入つて溜まることになり、混合
室の上部では反応性樹脂液が混合して硬化すると
いうことがなく、長時間の運転を可能とし、また
オイルシール等が破損する心配もないものであ
る。更に、硬質ウレタンフオームを製造する場合
においては、ポリオール成分を上部の樹脂液注入
口より注入ヘツド内に注入するようにすれば、前
述した効果によりライン停止時には混合室の内部
が自動的にポリオール成分で洗浄されるために、
ライン停止時においていちいち内部を洗浄する必
要もないものである。また撹拌羽根のシヤフトを
注入ヘツドの上面板に形成した軸孔に通し、シヤ
フトの周囲にて撹拌羽根と注入ヘツドの上面板と
の間にOリングを介在せしめてあるので、撹拌羽
根と上面板との間隙を塞いでオイルシール側へ樹
脂液が流入するのを防ぎ、反応液の一部がオイル
シールに侵入してここで硬化して焼き付けを起こ
すのを防止する効果をよりいつそう確実にできる
という利点がある。
As described above, the present invention provides resin liquid injection ports into which the reactive resin liquid is injected on both sides of the upper part of the injection head in which stirring blades are disposed inside, and connects one resin liquid injection port to the other resin liquid injection port. Since it is formed above the liquid injection port, only the resin liquid injected into the injection head from the upper resin liquid injection port will preferentially enter and accumulate in the upper part of the mixing chamber. In this case, the reactive resin liquid does not mix and harden, allowing long-time operation, and there is no fear of damage to oil seals or the like. Furthermore, when manufacturing rigid urethane foam, if the polyol component is injected into the injection head from the upper resin liquid injection port, the interior of the mixing chamber will automatically fill with the polyol component when the line is stopped due to the above-mentioned effect. To be washed with
There is no need to clean the inside every time the line is stopped. In addition, the shaft of the stirring blade is passed through the shaft hole formed in the top plate of the injection head, and an O-ring is interposed between the stirring blade and the top plate of the injection head around the shaft. This prevents the resin liquid from flowing into the oil seal side by blocking the gap between the oil seal and the oil seal, thereby ensuring the effect of preventing a portion of the reaction liquid from entering the oil seal and hardening there, causing seizure. It has the advantage of being possible.
第1図は本考案一実施例の混合注入装置の断面
図、第2図は従来例の混合注入装置の断面図であ
る。
1は撹拌羽根、2は注入ヘツド、3は上部樹脂
液注入口、4は下部樹脂液注入口、5はノズル
部、7は上面板、8はシヤフト、12はOリング
である。
FIG. 1 is a sectional view of a mixing injection device according to an embodiment of the present invention, and FIG. 2 is a sectional view of a conventional mixing injection device. 1 is a stirring blade, 2 is an injection head, 3 is an upper resin liquid injection port, 4 is a lower resin liquid injection port, 5 is a nozzle portion, 7 is a top plate, 8 is a shaft, and 12 is an O-ring.
Claims (1)
両側に反応性樹脂液が注入される樹脂液注入口を
それぞれ設けると共に一方の樹脂液注入口を他方
の樹脂液注入口よりも上方位置に形成し、注入ヘ
ツドの下端部に混合樹脂液を吐出するノズル部を
設け、上記撹拌羽根のシヤフトを注入ヘツドの上
面板に形成した軸孔に通し、シヤフトの周囲にて
撹拌羽根と注入ヘツドの上面板との間にOリング
を介在せしめて成る混合注入装置。 Resin liquid injection ports into which the reactive resin liquid is injected are provided on both sides of the upper part of the injection head, which has a stirring blade inside, and one resin liquid injection port is formed at a position higher than the other resin liquid injection port. A nozzle part for discharging the mixed resin liquid is provided at the lower end of the injection head, and the shaft of the stirring blade is passed through the shaft hole formed in the top plate of the injection head, and the shaft of the stirring blade is inserted around the shaft and above the injection head. A mixing injection device with an O-ring interposed between the face plate and the face plate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9718084U JPS6112707U (en) | 1984-06-28 | 1984-06-28 | Mixing injection device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9718084U JPS6112707U (en) | 1984-06-28 | 1984-06-28 | Mixing injection device |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6112707U JPS6112707U (en) | 1986-01-25 |
JPS6341132Y2 true JPS6341132Y2 (en) | 1988-10-27 |
Family
ID=30656707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9718084U Granted JPS6112707U (en) | 1984-06-28 | 1984-06-28 | Mixing injection device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6112707U (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5422802B2 (en) * | 2010-03-18 | 2014-02-19 | 洋 岡井 | Coating device for two-component mixed fast-curing composition and fast-curing composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5829725A (en) * | 1981-08-14 | 1983-02-22 | Kureha Chem Ind Co Ltd | 1-(3,3,3-trifluoropropyl)-4-(alpha-methylbenzyl)benzene |
-
1984
- 1984-06-28 JP JP9718084U patent/JPS6112707U/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5829725A (en) * | 1981-08-14 | 1983-02-22 | Kureha Chem Ind Co Ltd | 1-(3,3,3-trifluoropropyl)-4-(alpha-methylbenzyl)benzene |
Also Published As
Publication number | Publication date |
---|---|
JPS6112707U (en) | 1986-01-25 |
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