JPS6339620A - Reformer for fuel cell - Google Patents
Reformer for fuel cellInfo
- Publication number
- JPS6339620A JPS6339620A JP61180082A JP18008286A JPS6339620A JP S6339620 A JPS6339620 A JP S6339620A JP 61180082 A JP61180082 A JP 61180082A JP 18008286 A JP18008286 A JP 18008286A JP S6339620 A JPS6339620 A JP S6339620A
- Authority
- JP
- Japan
- Prior art keywords
- fuel
- passage
- evaporator
- heating
- reformer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 40
- 239000007789 gas Substances 0.000 abstract description 10
- 238000010438 heat treatment Methods 0.000 abstract description 10
- 238000001704 evaporation Methods 0.000 abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 4
- 230000008020 evaporation Effects 0.000 abstract description 4
- 239000002737 fuel gas Substances 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- 238000013021 overheating Methods 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
- H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
Description
【発明の詳細な説明】
〔発明の技術分野〕
本発明は燃料電池における燃料改質装置に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a fuel reformer in a fuel cell.
燃料電池は、主として燃料を水素に変換する改質装置と
、この改質装置で発生した水素を空気(酸素)と反応さ
せて水と電気に変える燃料電池本体とからなっている。A fuel cell mainly consists of a reformer that converts fuel into hydrogen, and a fuel cell main body that reacts the hydrogen generated in the reformer with air (oxygen) and converts it into water and electricity.
改質装置は蒸発器によって燃料(例えばメタノールと水
との混合液)を気化し、その気化した燃料ガスを反応管
の触媒層に通して水素ガス主体の改質ガスに変化させ、
それを燃料電池本体へ送るようになっている。The reformer vaporizes fuel (for example, a mixture of methanol and water) using an evaporator, passes the vaporized fuel gas through a catalyst layer in a reaction tube, and converts it into a reformed gas consisting mainly of hydrogen gas.
It is designed to send it to the fuel cell itself.
一般に、上記改質装置の蒸発器に対する燃料の供給路に
は、蒸発効率を高めるために予熱器が接続されており、
この予熱器で予熱された燃料が蒸発器に供給されるよう
になっている。しかし、この予熱器は燃料供給部を大型
化すると共に、組立てにあたり部品点数を増加する原因
になっている。Generally, a preheater is connected to the fuel supply path to the evaporator of the reformer to increase evaporation efficiency.
Fuel preheated by this preheater is supplied to the evaporator. However, this preheater increases the size of the fuel supply section and increases the number of parts during assembly.
本発明の目的は、上述した従来装置で特別に設けていた
予熱器を省略しながら燃料の予熱を可能にし、部品点数
の低減および装置のコンパクト化を可能にする燃料電池
用改質装置を提供することにある。An object of the present invention is to provide a fuel cell reforming device that enables preheating of fuel while omitting the preheater specially provided in the conventional device described above, and which enables a reduction in the number of parts and a compact device. It's about doing.
上記目的を達成する本発明の燃料電池用改質装置は、分
配管から分岐させた複数の燃料吐出管を、ケース内に収
納した蒸発器に開口させた改質装置において、前記分配
管を前記ケース内に収納したことを特徴とするものであ
る。A fuel cell reformer of the present invention that achieves the above object is a reformer in which a plurality of fuel discharge pipes branched from a distribution pipe are opened to an evaporator housed in a case. It is characterized by being housed in a case.
図に示す実施例において、1は燃料を気化するための蒸
発器で、その下部にはバーナ2が加熱器として配置され
、そのバーナ2の外側を囲むケースにはファン26から
燃焼用空気が強制送風されるようになっている。蒸発器
1は環状に形成され、その内部は燃料液体を気化するた
めの蒸発部1aと、その気化された燃料ガスをスーパー
ヒートさせる過熱部1bとの二つに区分されている。In the embodiment shown in the figure, 1 is an evaporator for vaporizing fuel, a burner 2 is arranged below it as a heater, and a fan 26 forces combustion air into a case surrounding the outside of the burner 2. It is designed to be ventilated. The evaporator 1 is formed into an annular shape, and its interior is divided into two parts: an evaporating section 1a for vaporizing fuel liquid and a superheating section 1b for superheating the vaporized fuel gas.
上記蒸発器1上面の外周には、環状の分配管4が接触又
は近接するように配置されている。An annular distribution pipe 4 is arranged on the outer periphery of the upper surface of the evaporator 1 so as to be in contact with or close to it.
この分配管4には外部から燃料供給管3が接続され、ま
たこの分配管4からは複数の燃料吐出管5.・−・、5
が円周に沿って所定間隔に分岐され、それぞれの端部を
蒸発部la内に貫通させて、メタノールと水との混合燃
料を吐出するようになっている。A fuel supply pipe 3 is connected to this distribution pipe 4 from the outside, and a plurality of fuel discharge pipes 5.・-・、5
is branched at predetermined intervals along the circumference, and each end is penetrated into the evaporator section la to discharge a mixed fuel of methanol and water.
蒸発器1は外殻となるケース6の中に収納され、その上
方には加熱空間7が形成され、さらにその上方に隔壁1
0を介して、反応後の改質ガスを集める集合室11が設
けられている。加熱空間7には環状をした反応器8が設
置され、その反応器内部には触媒層9が充填されている
。The evaporator 1 is housed in a case 6 serving as an outer shell, a heating space 7 is formed above the case 6, and a partition wall 1 is further formed above the case 6.
A collecting chamber 11 is provided through the reactor 0 to collect the reformed gas after the reaction. A ring-shaped reactor 8 is installed in the heating space 7, and a catalyst layer 9 is filled inside the reactor.
この反応器8は下端を接続部12を介して蒸発器1に連
通し、また上端を集合室11に直接連通させている。This reactor 8 has a lower end in communication with the evaporator 1 via a connection 12 and an upper end in direct communication with the collecting chamber 11 .
反応器8には、内周側から外周側へ抜ける多数の貫通孔
16.−・、16が上下方向に多段にわたると共に、円
周方向に並んで設けられている。各段の貫通孔16は、
図に示すように平面視で重なるようにしてもよ(、また
オフセットさせた位置関係にしてもよい。このような貫
通孔16を存する反応器8の外周壁とケース6との間は
隔壁13によって内外二つに区分され、それぞれ環状の
加熱通路14と排気通路15を形成している。この両道
路14.15は、隔壁13の上端部に設けた多数の連通
口17、−。The reactor 8 has a large number of through holes 16 extending from the inner circumferential side to the outer circumferential side. -., 16 are provided in multiple stages in the vertical direction and are arranged in parallel in the circumferential direction. The through holes 16 at each stage are
As shown in the figure, they may overlap in plan view (or they may be offset). A partition wall 13 is located between the outer circumferential wall of the reactor 8 and the case 6 in which such a through hole 16 is present. It is divided into two parts, an inner and an outer part, and forms an annular heating passage 14 and an annular exhaust passage 15, respectively.
17によって互いに連通している。また、ケース6の下
部には排気口18が設けられ、排気通路15を外部に連
通させている。17 and communicate with each other. Further, an exhaust port 18 is provided in the lower part of the case 6, and the exhaust passage 15 is communicated with the outside.
上記構成において、蒸発器1の蒸発部1bで気化した燃
料ガスは、過熱部1bを通過する際にスーパーヒートさ
れて反応器8に入り、触媒層9において水素主体の改質
ガスに変化したのち上方の集合室11に入り、次いで図
示しない燃料電池本体に送られる。一方、バーナ2で発
生した加熱ガスは、蒸発器1で燃料の気化およびスーパ
ーヒートを行ったのち、中央通路20から加熱空間7の
中央部に入り、そこを上昇する間に反応器8を加熱しな
がら順次多段の貫通孔16を加熱通路14に通り抜け、
そこを上昇して上端の連通口17を折り返し、次いで排
気通路15を下降して排気口18から外部へ排気される
。In the above configuration, the fuel gas vaporized in the evaporation section 1b of the evaporator 1 is superheated when passing through the superheating section 1b, enters the reactor 8, and changes into a reformed gas mainly consisting of hydrogen in the catalyst layer 9. The fuel enters the upper gathering chamber 11 and is then sent to the fuel cell main body (not shown). On the other hand, the heated gas generated in the burner 2 vaporizes the fuel in the evaporator 1 and superheats it, then enters the center of the heating space 7 from the central passage 20 and heats the reactor 8 while rising there. while sequentially passing through the multistage through holes 16 into the heating passage 14,
It ascends there, turns around the communication port 17 at the upper end, then descends through the exhaust passage 15 and is exhausted to the outside through the exhaust port 18.
上述した燃料改質装置によると、燃料の分配管4がケー
ス6の内側に設けられているため、分配管4に供給され
た燃料は排気通路15を下降する加熱ガスによって加熱
され、また蒸発器1の外壁に接触または近接することに
より、その蒸発器1からも加熱される。すなわち、燃料
供給管3から分配管4に供給された燃料はここで予熱さ
れ、その予熱ののち複数の燃料吐出管5に分配されて蒸
発部1aへ吐出される。According to the fuel reformer described above, since the fuel distribution pipe 4 is provided inside the case 6, the fuel supplied to the distribution pipe 4 is heated by the heated gas flowing down the exhaust passage 15, and the fuel is heated by the heated gas flowing down the exhaust passage 15. By contacting or being close to the outer wall of the evaporator 1, heat is also generated from the evaporator 1. That is, the fuel supplied from the fuel supply pipe 3 to the distribution pipe 4 is preheated here, and after preheating, it is distributed to a plurality of fuel discharge pipes 5 and discharged to the evaporation section 1a.
したがって、上記改質装置では、分配管4自体が予熱器
として作用するため、従来のような特別の予熱器を設け
ることが不要になる。そのため部品点数を低減し、かつ
装置をコンパクトにすることができる。Therefore, in the above-mentioned reformer, the distribution pipe 4 itself acts as a preheater, making it unnecessary to provide a special preheater as in the prior art. Therefore, the number of parts can be reduced and the device can be made more compact.
上述したように本発明の燃料電池用改質装置は、燃料吐
出管に対する分配管を、蒸発器を収納しているケース内
に収納したので、この分配管自体が予熱器として作用し
、従来設けていたような特別の予熱器を不要にする。そ
のため、それによって部品点数を低減し、かつ装置のコ
ンパクト化を可能にする。As mentioned above, in the fuel cell reformer of the present invention, the distribution pipe for the fuel discharge pipe is housed in the case that houses the evaporator, so this distribution pipe itself acts as a preheater, and is different from the conventional one. This eliminates the need for a special preheater. Therefore, the number of parts can be reduced and the device can be made more compact.
第1図は本発明の実施例による燃料電池用改質装置であ
り、第2図は第1図のn−u矢視図である。
1・・・蒸発器、 2・・・バーナ、 4・・・分配器
、5・・・燃料吐出管、 6・・・ケース、 8・・
・反応器。FIG. 1 shows a fuel cell reformer according to an embodiment of the present invention, and FIG. 2 is a view taken along arrow nu in FIG. DESCRIPTION OF SYMBOLS 1... Evaporator, 2... Burner, 4... Distributor, 5... Fuel discharge pipe, 6... Case, 8...
・Reactor.
Claims (2)
ス内に収納した蒸発器に開口させた改質装置において、
前記分配管を前記ケース内に収納したことを特徴とする
燃料電池用改質装置。(1) In a reformer in which a plurality of fuel discharge pipes branched from a distribution pipe are opened to an evaporator housed in a case,
A reformer for a fuel cell, characterized in that the distribution pipe is housed in the case.
許請求の範囲第1項記載の燃料電池用改質装置。(2) The fuel cell reformer according to claim 1, wherein the distribution pipe is in contact with or close to the outer wall of the evaporator.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61180082A JPS6339620A (en) | 1986-08-01 | 1986-08-01 | Reformer for fuel cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61180082A JPS6339620A (en) | 1986-08-01 | 1986-08-01 | Reformer for fuel cell |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6339620A true JPS6339620A (en) | 1988-02-20 |
Family
ID=16077138
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61180082A Pending JPS6339620A (en) | 1986-08-01 | 1986-08-01 | Reformer for fuel cell |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6339620A (en) |
-
1986
- 1986-08-01 JP JP61180082A patent/JPS6339620A/en active Pending
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