JPS6339022B2 - - Google Patents
Info
- Publication number
- JPS6339022B2 JPS6339022B2 JP4278281A JP4278281A JPS6339022B2 JP S6339022 B2 JPS6339022 B2 JP S6339022B2 JP 4278281 A JP4278281 A JP 4278281A JP 4278281 A JP4278281 A JP 4278281A JP S6339022 B2 JPS6339022 B2 JP S6339022B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- wax
- alkali metal
- melting point
- alkanolamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 claims description 15
- 239000001993 wax Substances 0.000 claims description 13
- 239000012188 paraffin wax Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004200 microcrystalline wax Substances 0.000 claims description 7
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 7
- 239000003208 petroleum Substances 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000000123 paper Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- -1 Alkali metal salts Chemical class 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920006174 synthetic rubber latex Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paper (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は、新聞紙等の包装用紙に適用されてそ
の防湿性能を十分に発揮し、且従来より解消の望
まれてきた欠点的な低いすべり摩擦を改良したワ
ツクス系エマルジヨン組成液に関する。
従来、ワツクス系エマルジヨン組成液は、その
撥発性、防水性、防湿性の優れていることが着目
され、各種分野で使用されている。しかしなが
ら、この組成液の使用面での上述の長所は、すべ
り易いという欠点により帳消しされ易いという欠
点がある。従つて、このすべり易いことを改良す
るため、すべり防止剤の併用が各方面で研究され
てきている。しかし、これら防止剤は、その性能
面又はワツクス系エマルジヨン組成液に対する相
溶性などにおいて欠くるところがあつたり、価格
の点などからその目的を達成する上で十分である
とは云い難いのが現状であると云つた不利点があ
る。
本発明の目的は上述の欠点や不利点を解消した
優れた撥水性や防湿性をもち、且つすべり難い即
ちすべり摩擦の大なる防湿紙を作成するに役立つ
ワツクス系エマルジヨン組成液を提供することに
ある。
本発明によれば、融点40〜70℃の固型パラフイ
ンワツクス50〜90部に融点66〜94℃のマイクロク
リスタリンワツクス10〜50部を加え、更にこれに
炭素数８〜18の直鎖又は側鎖のある飽和又は不飽
和の脂肪酸をアルカリ金属水酸化物又はジエチノ
ールアミンの如きアルカノールアミンでケン化し
て得たもの５〜20部を添加し、尚更にこれに軟化
点50〜100℃のマレイン化石油樹脂をアルカリ金
属水酸化物でケン化して得たもの50〜150部を加
え混合して得られた物質を常法により加温し、一
般式（）なる乳化剤を用いて乳化すると優れた
防湿性をもち、すべり摩擦性の改良された防湿紙
を製造しうる有用なるワツクス系エマルジヨン組
成液が得られる。
更に本発明においては、上記のパラフインワツ
クスとマイクロクリスタリンワツクスとの量比に
従う混合物質を、パルミチン酸、ステアリン酸、
オレイン酸、トール油脂肪酸、ロジン酸などのア
ルカリ金属塩又はアルカノールアミン塩、及びマ
レイン化石油樹脂のアルカリ金属塩又はアルカノ
ールアミン塩の添加下に混合し、同時に一般式
（Ｉ）の乳化剤を添混併用して常法により加温下
系物質を乳化する。かくして得られた乳化液は、
それを使用することにより良好な防湿性を有し、
すべり摩擦の十分改良されたる防湿性用紙を与え
ることができる。尚本発明においては、上記乳化
において保護コロイド剤を併用し、その乳化安定
性を高めることができる。
本発明においては、パラフインワツクスとして
は、融点40〜70℃を有するｎ―パラフインワツク
スが主として使用でき、マイクロクリスタリンワ
ツクスとしては、融点66〜94℃、好ましくは66〜
84℃を持つ粘着性又は非粘着性のものが使用でき
る（この非粘着性のものの例としては、日本精ロ
ウ製Hi―Mic―1080、同3080、同1043などがあ
る）。又、エマルジヨンの安定性を高める目的で
用いられる保護コロイド剤としては、ニカワ、ゼ
ラチン、ポリビニルアルコール、及びステアリン
アルコールの如き高級アルコールなどがある。
次に本発明の詳細を実施例によつて説明する。
実施例 １
１ 〔60℃〕ｎ―パラフイン 30部
２ マイクロクリスタリンワツクス 8
（Hi―Mic―1045日本精ロウ製）
３ トール脂肪酸 7
４ マレイン化石油樹脂 53
５ 高級アルコール 3
（NAA―48日本油脂製）
６ 乳化剤Ａ―103 6
（日本サイアナミツド製の一般式
（Ｉ）に相当する剤）
７ 48％ KOH 6
８ 水 235
１の４つ口フラスコ（温度計、滴下ロート、
玉型冷却管、撹拌棒を備えたフラスコ）に上記１
〜６の物質を順次仕込み、マントルヒーターにて
混合加熱溶解し、95〜100℃で７の48％KOHを滴
下し、その後80〜90℃に保ち、よく混合し、滴下
ロートより70〜90℃の熱水を滴下混合し、相転換
を行い、その後希釈水を入れて固形分30％のワツ
クスエマルジヨンを得た。
実施例 ２
１ 〔52℃〕ｎ―パラフイン 30部
２ マイクロクリスタリンワツクス 8
（Hi―Mic―3080日本精ロウ製）
３ トール脂肪酸 5
４ マレイン化石油樹脂 53
５ 高級アルコール 3
（NAA―48日本油脂製）
６ 乳化剤Ａ―103 6
（日本サイアナミツド製の一般式
（）に相当する剤）
７ 48％ KOH 5.3
８ 水 230
なる物質を用い、実施例１に準じ30％のワツクス
エマルジヨンを得た。
実施例 ３
１ 〔49℃〕ｎ―パラフイン 28.5部
２ マイクロクリスタリンワツクス 9.5
（Hi―Mic―1080日本精ロウ製）
３ トール脂肪酸 7
４ マレイン化石油樹脂 53
５ 高級アルコール 1
６ 乳化剤Ａ―103 3
（日本サイアナミツド製の一般式
（）に相当する剤）
７ 48％ KOH 6
８ 水 232
なる物質を用い、実施例１に準じ30％のワツクス
エマルジヨンを得た。
参考例
１ 〔60℃〕ｎ―パラフイン 38部
２ トールロジン 5
３ マレイン化石油樹脂 53
４ 高級アルコール 3
（NAA―48日本油脂製）
５ 乳化剤NS―204.5 2
（日本油脂製）
６ ジエタノールアミン 1
７ 48％ KOH 4
８ 水 230
なる物質を用い、実施例１に準じ30％のワツクス
エマルジヨンを得た。
実施例１〜３で得たワツクスエマルジヨン及び
参考例で得たワツクスエマルジヨン各100部と合
成ゴム系ラテツクス（三井東圧製MBRラテツク
ス；商品名ポリラツク＃717）100部をそれぞれ混
合し、市販の両更クラフト紙（坪量70gr/m2）の
裏面にバーコーター等を用いて均一に塗工し、そ
の塗工紙を用いて防湿性及びすべり摩擦の実験を
行つた。
塗工量： 7gr/m2
乾燥温度：熱風乾燥器で110℃／２分
透湿度：カツプ法（JIS Ｚ―0208―1976）
40℃／90％で24時間測定
すべり摩擦：水平法（J.Tappi No.30、ｍ―
74）ストログラフＲ型（東洋精器）
にて測定
得られた結果を表１に示す。
The present invention relates to a wax-based emulsion composition that is applied to packaging papers such as newspapers, fully exhibits its moisture-proofing properties, and improves the disadvantageous low sliding friction that has been desired to be overcome. Conventionally, wax-based emulsion compositions have attracted attention for their excellent repellency, waterproofness, and moisture-proofing properties, and have been used in various fields. However, the above-mentioned advantages of this liquid composition in terms of use are easily offset by the disadvantage of slipperiness. Therefore, in order to improve this slipperiness, the combined use of anti-slip agents has been studied in various fields. However, it is currently difficult to say that these inhibitors are sufficient to achieve their objectives due to their lack of performance or compatibility with wax-based emulsion compositions, and their cost. There are some disadvantages. The object of the present invention is to provide a wax-based emulsion composition liquid that eliminates the above-mentioned drawbacks and disadvantages and has excellent water repellency and moisture-proofing properties, and is useful for producing moisture-proof paper that is difficult to slip, that is, has a large sliding friction. be. According to the present invention, 10 to 50 parts of microcrystalline wax with a melting point of 66 to 94°C is added to 50 to 90 parts of solid paraffin wax with a melting point of 40 to 70°C, and further a linear wax having a carbon number of 8 to 18 Alternatively, 5 to 20 parts of a saturated or unsaturated fatty acid with a side chain is saponified with an alkali metal hydroxide or an alkanolamine such as diethynolamine, and the softening point is 50 to 100°C. When 50 to 150 parts of maleated petroleum resin obtained by saponification with an alkali metal hydroxide are added and mixed, the resulting substance is heated in a conventional manner and emulsified using an emulsifier of the general formula (). A wax-based emulsion composition is obtained which is useful for producing moisture-proof paper having excellent moisture-proof properties and improved sliding friction properties. Furthermore, in the present invention, a mixed substance according to the above quantitative ratio of paraffin wax and microcrystalline wax is mixed with palmitic acid, stearic acid,
Alkali metal salts or alkanolamine salts such as oleic acid, tall oil fatty acids, rosin acid, and alkali metal salts or alkanolamine salts of maleated petroleum resin are added and mixed, and at the same time, an emulsifier of general formula (I) is added. When used in combination, the substance under heating is emulsified using a conventional method. The emulsion thus obtained is
It has good moisture resistance by using it,
A moisture-proof paper with sufficiently improved sliding friction can be provided. In the present invention, a protective colloid agent can be used in conjunction with the emulsification to enhance the emulsion stability. In the present invention, n-paraffin wax having a melting point of 40 to 70°C can be mainly used as the paraffin wax, and n-paraffin wax having a melting point of 66 to 94°C, preferably 66 to 94°C, can be used as the microcrystalline wax.
Adhesive or non-adhesive products with a temperature of 84°C can be used (examples of non-adhesive products include Nippon Seiro Hi-Mic-1080, Hi-Mic-3080, and Hi-Mic-1043). Protective colloid agents used for the purpose of increasing the stability of emulsions include glue, gelatin, polyvinyl alcohol, and higher alcohols such as stearin alcohol. Next, the details of the present invention will be explained by referring to examples. Example 1 1 [60°C] N-paraffin 30 parts 2 Microcrystalline wax 8 (Hi-Mic-1045 Nippon Seiro) 3 Tall fatty acid 7 4 Maleated petroleum resin 53 5 Higher alcohol 3 (NAA-48 Nippon Oil & Fats) ) 6 Emulsifier A-103 6 (Agent corresponding to general formula (I) manufactured by Nippon Cyanamid) 7 48% KOH 6 8 Water 235 1 4-necked flask (thermometer, dropping funnel,
Add the above 1 to a flask equipped with a ball-shaped cooling tube and a stirring bar).
- 6 substances are prepared one after another, mixed and heated using a mantle heater to dissolve, then 48% KOH from 7 is added dropwise at 95-100℃, then kept at 80-90℃, mixed well, and heated to 70-90℃ from a dropping funnel. of hot water was added dropwise to perform phase inversion, and then dilution water was added to obtain a wax emulsion with a solid content of 30%. Example 2 1 [52°C] N-paraffin 30 parts 2 Microcrystalline wax 8 (Hi-Mic-3080 manufactured by Nippon Seiro) 3 Tall fatty acid 5 4 Maleated petroleum resin 53 5 Higher alcohol 3 (NAA-48 Nippon Oil & Fats) Emulsifier A-103 6 (manufactured by Nippon Cyanamid Co., Ltd., corresponding to the general formula ()) 7 48% KOH 5.3 8 Water 230 A 30% wax emulsion was obtained according to Example 1. . Example 3 1 [49°C] N-paraffin 28.5 parts 2 Microcrystalline wax 9.5 (Hi-Mic-1080 manufactured by Nippon Seiro) 3 Tall fatty acid 7 4 Maleated petroleum resin 53 5 Higher alcohol 1 6 Emulsifier A-103 3 A 30% wax emulsion was obtained according to Example 1 using a substance (agent corresponding to the general formula () manufactured by Nippon Cyanamid): 7 48% KOH 6 8 Water 232. Reference example 1 [60℃] n-paraffin 38 parts 2 Tall rosin 5 3 Maleated petroleum resin 53 4 Higher alcohol 3 (NAA-48 manufactured by NOF) 5 Emulsifier NS-204.5 2 (Made by NOF) 6 Diethanolamine 1 7 48% A 30% wax emulsion was obtained according to Example 1 using the following substances: KOH 4 8 Water 230 . 100 parts each of the wax emulsion obtained in Examples 1 to 3 and the wax emulsion obtained in Reference Example were mixed with 100 parts of a synthetic rubber latex (MBR Latex manufactured by Mitsui Toatsu Co., Ltd.; trade name Polylac #717). The coated paper was coated uniformly on the back side of commercially available double-grained kraft paper (basis weight 70gr/m 2 ) using a bar coater, etc., and experiments on moisture resistance and sliding friction were conducted using the coated paper. Coating amount: 7gr/ m2 Drying temperature: Hot air dryer at 110℃/2 minutes Moisture permeability: Cup method (JIS Z-0208-1976) Measured at 40℃/90% for 24 hours Sliding friction: Horizontal method (J. Tappi No.30, m-
74) Strograph R type (Toyo Seiki)
The results obtained are shown in Table 1.
【表】
表１より本発明の組成液による塗工紙は実用上
の透湿度を損ずることなく、すべり摩擦性の改良
がなし得られおることが判る。[Table] From Table 1, it can be seen that the coated paper using the composition of the present invention has improved sliding friction properties without impairing its practical moisture permeability.
Claims (1)
ス50〜90部（以下「部」はすべて「重量部」と
する）に融点66〜94℃なるマイクロクリスタリ
ンワツクス10〜50部； (ロ) 炭素数８〜18を有する直鎖又は側鎖のある飽
和又は不飽和の脂肪酸を、アルカリ金属の水酸
化物又はジエチノールアミン等のアルカノール
アミンでケン化したもの５〜20部； (ハ) 軟化点50〜100℃なるマレイン化石油樹脂を
アルカリ金属の水酸化物又はアルカノールアミ
ンでケン化したもの50〜150部； なる(イ)、(ロ)、(ハ)の物質を加温下に混合し、得られ
た混合物を、一般式 （たゞし、Ｒは炭素数１〜９のアルキル基；ｎは
１〜10の整数とする。）にて示される乳化剤を用
い、常法により加温下に乳化して得られるものな
ることを特徴とするワツクス系エマルジヨン組成
液。[Scope of Claims] 1 (a) 50 to 90 parts of solid paraffin wax with a melting point of 40 to 70°C (hereinafter all "parts" are "parts by weight") and microcrystalline wax with a melting point of 66 to 94°C. 10 to 50 parts; (b) A saturated or unsaturated fatty acid with a straight chain or side chain having 8 to 18 carbon atoms, saponified with an alkali metal hydroxide or an alkanolamine such as diethynolamine5 ~20 parts; (c) 50 to 150 parts of maleated petroleum resin with a softening point of 50 to 100°C saponified with an alkali metal hydroxide or alkanolamine; (a), (b), (c) The following substances are mixed under heating, and the resulting mixture is expressed by the general formula (wherein, R is an alkyl group having 1 to 9 carbon atoms; n is an integer of 1 to 10). A wax-based emulsion composition liquid characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4278281A JPS57155253A (en) | 1981-03-23 | 1981-03-23 | Wax-type emulsion liquid composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4278281A JPS57155253A (en) | 1981-03-23 | 1981-03-23 | Wax-type emulsion liquid composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57155253A JPS57155253A (en) | 1982-09-25 |
| JPS6339022B2 true JPS6339022B2 (en) | 1988-08-03 |
Family
ID=12645535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4278281A Granted JPS57155253A (en) | 1981-03-23 | 1981-03-23 | Wax-type emulsion liquid composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57155253A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5539035A (en) * | 1994-10-12 | 1996-07-23 | The Mead Corporation | Recyclable wax-coated containers |
-
1981
- 1981-03-23 JP JP4278281A patent/JPS57155253A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57155253A (en) | 1982-09-25 |
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