JPS6337169A - Uv-curable binder composition - Google Patents
Uv-curable binder compositionInfo
- Publication number
- JPS6337169A JPS6337169A JP17892786A JP17892786A JPS6337169A JP S6337169 A JPS6337169 A JP S6337169A JP 17892786 A JP17892786 A JP 17892786A JP 17892786 A JP17892786 A JP 17892786A JP S6337169 A JPS6337169 A JP S6337169A
- Authority
- JP
- Japan
- Prior art keywords
- ester
- binder composition
- curable binder
- parts
- acrylamide methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 239000011230 binding agent Substances 0.000 title claims abstract description 12
- -1 acrylamide methyl cellulose ester Chemical class 0.000 claims abstract description 11
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 9
- 239000001923 methylcellulose Substances 0.000 claims abstract description 9
- 235000010981 methylcellulose Nutrition 0.000 claims abstract description 9
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 6
- 229960002900 methylcellulose Drugs 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 125000005396 acrylic acid ester group Chemical class 0.000 abstract description 3
- 239000002966 varnish Substances 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000002383 tung oil Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業−にの利用分野）
この発明は、紫外線硬化型バインダー組成物の改良に関
する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) This invention relates to improvements in ultraviolet curable binder compositions.
（従来の技術）
従来紫外線硬化型バインダー組成物としては、セルロー
ズアセチイトブチレイ） （ＣＢＡ）、エトキシエトキ
シアリレイト、Ｎ−ビニルピロリドン、トリプロピレン
グリコールデイアクリレート、紫外線吸収剤等を配合し
たものが知られている。(Prior art) Conventional UV-curable binder compositions include those containing cellulose acetate butylene (CBA), ethoxyethoxyarylate, N-vinylpyrrolidone, tripropylene glycol diacrylate, UV absorbers, etc. Are known.
（発明が解決しようとする問題点）
しかし、以ヒの従来知られている紫外線硬化型バインダ
ーについては処理基板の表面との接着性が悪く、また硬
化速度が遅く、しかも表面？Ａ膜が弱い上に、光沢がな
いなどの難点がある。(Problems to be Solved by the Invention) However, the conventionally known ultraviolet curable binders have poor adhesion to the surface of the processed substrate, slow curing speed, and are difficult to cure on the surface. There are drawbacks such as the A film is weak and lacks luster.
この発す１は上記実情に鑑み、紫外線硬化型バインダー
における上述の難点を改良することを目的とする。In view of the above-mentioned circumstances, the purpose of this invention is to improve the above-mentioned difficulties in ultraviolet curable binders.
（問題点を解決するための手段）
本願発１１名等は」：記問題点を解決するため、鋭意研
究の結果、紫外線硬化型バインダー組成物中、セルロー
ズアセテートエステル、例えばＣＡＢに替えてアクリル
酸エステルとアクリルアミドメチル−セルローズエステ
ルとの反応生成物であるアクリルアミドメチルセルロー
ズエステル変性アクリル酸エステルを使用することによ
り、所期の目的を達成することを見出したものである。(Means for Solving the Problems) In order to solve the problems mentioned above, the 11 authors of this application and others conducted extensive research and found that acrylic acid was added to cellulose acetate ester, such as CAB, in the ultraviolet curable binder composition. It has been discovered that the desired object can be achieved by using acrylamide methyl cellulose ester-modified acrylic ester, which is a reaction product of an ester and an acrylamide methyl cellulose ester.
この発明で使用するアクリル酸エステルとアクリルアミ
ドメチル−セルローズエステルとの反応生成物の一例を
示す構造式は以下の通りである。The structural formula showing an example of the reaction product of acrylic acid ester and acrylamide methyl cellulose ester used in this invention is as follows.
０ＣＨ２Ｃ）ＩＧＯＯＲ
ＯＨ，ＣＨｆ１：ＯＯＲ
ここで、アクリルアミドメチル−セルローズエステルに
よって変性されるアクリル酸エステルの種類としては、
メチルアクリレート、エチルアクリレート等を挙げるこ
とができる。0CH2C)IGOOR OH, CHf1:OOR Here, the types of acrylic esters modified by acrylamide methyl-cellulose ester are:
Examples include methyl acrylate and ethyl acrylate.
（発明の効果）
μＬのように、この発明によれば紫外線硬化型バインダ
ー組成中に含まれる例えばＣＡＢ等のセルローズアセテ
ートエステルに科えてアクリルアミドメチル−セルロー
ズエステル変性アクリル酸エステルを使用すると、従来
の組成に比べてバインダーの接着性が改良され、また紫
外線による硬化速度が速められる。(Effects of the Invention) As shown in μL, according to the present invention, when an acrylamide methyl-cellulose ester-modified acrylic ester is used in addition to a cellulose acetate ester such as CAB contained in an ultraviolet curable binder composition, the conventional composition The adhesion of the binder is improved compared to the conventional method, and the curing speed by ultraviolet light is accelerated.
更に、この発明による紫外線硬化型バインダー組成によ
れば、光沢が良く、しかも強度の高い表面塗膜が得られ
る０例えば、ＩＣカードや磁気カーＦのような塩化ビニ
ール又は塩ビニールアクリル共重合体の成形板表面をよ
り強度のある塗膜にすることができる。Furthermore, according to the ultraviolet curable binder composition according to the present invention, a surface coating film with good gloss and high strength can be obtained. A stronger coating film can be formed on the surface of the molded plate.
（実施例） 以下、この発明の実施例を示す。(Example) Examples of this invention will be shown below.
実施例１
セルローズエステル変性アクリルアミドメチル０Ｗｔｌ
ヒドロキシエチルメタアクリレート ３０ＷｔＸトリ
プロピレングリコールデイアクリレート！８．５１１１
ｔｌ
エトキシエトキシアクリレート ＋８．５Ｗｔ＄表
面滑剤 ０．５讐ｔＸ紫外線
吸収剤（イルガレル ＋８４） ３．ＯＷｔ＄以上
の組成をビニールタイル表面に３０ｐＬの厚さで塗布し
、この上からマーキュリ−ランプを使用して４０Ｗ／ｃ
層 の強さの紫外線を７．５ｍ／分の速さで照射した。Example 1 Cellulose ester modified acrylamide methyl 0Wtl hydroxyethyl methacrylate 30WtX tripropylene glycol diacrylate! 8.5111
tl Ethoxyethoxy acrylate +8.5Wt$ surface lubricant 0.5tX ultraviolet absorber (Ilgarel +84) 3. Apply a composition of OWt$ or more to the surface of the vinyl tile at a thickness of 30 pL, and then use a Mercury lamp to apply 40 W/c on top of this.
The ultraviolet rays were irradiated at a speed of 7.5 m/min.
この結果、ビニルタイル表面には光沢があり、しかも強
度のある塗膜が形成された。As a result, a glossy and strong coating film was formed on the vinyl tile surface.
実施例２
Ａワニス
精製亜麻仁油 ７８９重量部桐油
１９５＠呈部これを１８０℃に
加熱してグリセリン１５１．５重量部を加えて２００℃
まで加熱する。更に２４５℃まで加熱してから水酸化リ
チウム０．７重量部を加える。Example 2 A varnish refined linseed oil 789 parts by weight tung oil
195 @ Presentation part Heat this to 180°C, add 151.5 parts by weight of glycerin, and heat to 200°C.
Heat until. After further heating to 245° C., 0.7 parts by weight of lithium hydroxide is added.
これを１８０℃に冷却してからインフタレート３１８
屯埴部を加え、２４６℃にして２時間保つ。After cooling this to 180℃, inphthalate 318
Add the tunban and keep at 246°C for 2 hours.
常温にしてこれから精製物を２５０重量部を採り、１０
０℃で１．５時間加熱した後、バラベンゾキノン０．４
重品８部、２−メチルイミダゾール０．４毛早一部、グ
リシデルメタアクリレート７．２重量部、アクリルアミ
ドメチルセルロースエステル７．２重量部を加え、３０
分間保ってから８０℃に冷却し、デブチルチンディアセ
テートを点滴してよく攪拌してＡワニスを調整する。At room temperature, take 250 parts by weight of the purified product and add 10 parts by weight.
After heating at 0°C for 1.5 hours, rosebenzoquinone 0.4
Add 8 parts of heavy duty, 0.4 parts of 2-methylimidazole, 7.2 parts of glycidel methacrylate, and 7.2 parts of acrylamide methylcellulose ester,
After keeping it for a minute, it was cooled to 80°C, and debutyltin diacetate was added dropwise and stirred well to prepare varnish A.
Ｂワニス
ａ）ロジンペンタエリスリトール
エステル ４０屯１．１部ｂ）
桐油 １０重量部Ｃ）軽油
４０玉量部上記を配合し
て１８０±５℃に加熱し、溶解させる。冷却後、アルミ
ニウムオクトエート１ｆｆｉ星部を加え、攪拌して軽油
１３重量部を加えて３０分で１５０±５℃になるように
加熱してＢワニスを調整する。B varnish a) Rosin pentaerythritol ester 40 tons 1.1 parts b)
Tung oil 10 parts by weight C) Light oil 40 parts by weight The above ingredients were blended and heated to 180±5°C to dissolve. After cooling, add 1ffi part of aluminum octoate, stir, add 13 parts by weight of light oil, and heat to 150±5°C in 30 minutes to prepare B varnish.
インキ処方ink formulation
Claims (1)
ステルに替えてアクリルアミドメチル−セルローズエス
テル変性アクリル酸エステルを使用することを特徴とす
る紫外線硬化型バインダー組成物。An ultraviolet curable binder composition characterized in that an acrylamide methyl-cellulose ester modified acrylic ester is used in place of cellulose acetate ester in the ultraviolet curable ink composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17892786A JPS6337169A (en) | 1986-07-31 | 1986-07-31 | Uv-curable binder composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17892786A JPS6337169A (en) | 1986-07-31 | 1986-07-31 | Uv-curable binder composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6337169A true JPS6337169A (en) | 1988-02-17 |
Family
ID=16057072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17892786A Pending JPS6337169A (en) | 1986-07-31 | 1986-07-31 | Uv-curable binder composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6337169A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1884959A1 (en) * | 2006-07-31 | 2008-02-06 | Agfa HealthCare NV | Topcoat layers for phosphor or scintillator screens or panels. |
| EP1884958A1 (en) | 2006-07-31 | 2008-02-06 | Agfa HealthCare NV | Polymer compositions and use thereof as topcoat layers for phosphor or scintillator screens or panels. |
-
1986
- 1986-07-31 JP JP17892786A patent/JPS6337169A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1884959A1 (en) * | 2006-07-31 | 2008-02-06 | Agfa HealthCare NV | Topcoat layers for phosphor or scintillator screens or panels. |
| EP1884958A1 (en) | 2006-07-31 | 2008-02-06 | Agfa HealthCare NV | Polymer compositions and use thereof as topcoat layers for phosphor or scintillator screens or panels. |
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