JPS6336288A - Molecule model freely rotatable indicating position energy - Google Patents
Molecule model freely rotatable indicating position energyInfo
- Publication number
- JPS6336288A JPS6336288A JP17884986A JP17884986A JPS6336288A JP S6336288 A JPS6336288 A JP S6336288A JP 17884986 A JP17884986 A JP 17884986A JP 17884986 A JP17884986 A JP 17884986A JP S6336288 A JPS6336288 A JP S6336288A
- Authority
- JP
- Japan
- Prior art keywords
- freely rotatable
- indicating position
- position energy
- carbon
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005381 potential energy Methods 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 230000004660 morphological change Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 7
- 229920001195 polyisoprene Polymers 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 241000251730 Chondrichthyes Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Landscapes
- Toys (AREA)
- Radiation-Therapy Devices (AREA)
- Magnetic Bearings And Hydrostatic Bearings (AREA)
- Aerodynamic Tests, Hydrodynamic Tests, Wind Tunnels, And Water Tanks (AREA)
- Measurement Of Length, Angles, Or The Like Using Electric Or Magnetic Means (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、単結合が自由に回転で自る慣壇と水ＩＮ子に
磁石を使用して分子内ａ転によ墨形態数の確準ｉ数、位
置エネルギーＦ化及び水零轄合を寅鮪的に説明す石ため
の分子横型に聞するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention uses a magnet for a single bond to freely rotate and a water inlet to determine the definite i number of the ink morphological number and the potential energy F by intramolecular a-translation. This is similar to Ishime's molecular horizontal type, which explains the formation and water content in a tora-tuna-like manner.
周知のように、分子横型には骨格横型と電子雲構製があ
り、何れも手−力により色いろの形態に買えることが出
来る。しかし、これらの横１では、自然界で最も安定な
形態やゴム状弾性すなわちエンドロビー弾性を、わかり
易く１！明することは内畔である。ゴム状高分子は、分
子運−カにより、のたうち回る蛇のように、次から次へ
と形態を閲え、その形態数の確率の度数は分子の両端間
距離が蚊Ｉｆｆ首で小さい方が犬舎くなると言われてい
る。As is well known, there are two types of lateral molecular structures: skeletal lateral structures and electron cloud structures, both of which can be manufactured into various forms by hand. However, these horizontal 1's make it easy to understand the most stable form in nature, rubber-like elasticity, or endo-lobby elasticity! What I reveal is a secret. Due to molecular forces, rubber-like polymers take on forms one after another like a writhing snake, and the degree of probability of the number of forms is such that the distance between both ends of the molecule is smaller than that of a mosquito's neck if it is a dog's neck. It is said that it will become a building.
また、ゴムの威力ポリイソプレンにはシス製とトランス
製の二つの型があゐ。シスをポリイソプレンは、分子内
回転によ墨形態数の１車とイ装置エネルギーの影響で分
子の岡端聞距゛震がＩＩＩＩ鵞る傾向がある。そうして
側鎖のメチル基の公刊Ｉ力は、そのＩＩＩＩすることを
督促するＩＩＩＩをしている。トランス製ポリイソプレ
ンは、伸びた形態をとる傾向がある。In addition, there are two types of polyisoprene, which is the power of rubber: cis-made and trans-made. In cis-polyisoprene, there is a tendency for the molecular oscillations to increase due to intramolecular rotation and the influence of the device energy. Thus, the published I force of the methyl group on the side chain is doing the III that urges that III to do so. Trans-made polyisoprene tends to have an elongated morphology.
しかし、市販の分子横型では手−カでしか斐形できない
ため簡単に銃針的無作為ｙ形の１車や位置エネルギーが
分子内回転に及ぼす影響を確認することは出来ない。However, since the commercially available horizontal molecular type can only be shaped by hand, it is not possible to easily confirm the influence of a random Y-shaped wheel or potential energy on intramolecular rotation.
本発明は、このような欠京を解決するためになされたも
ので、その目的とするところは、簡単な攪作により迅速
にして、かつ正確に、しかもイー大差もｆよく形態数の
確率ｒＩＪ鮫すｆよりちエントロピーの程度を冥顛でき
るようにしたものである。The present invention has been made to solve this problem, and its purpose is to quickly and accurately calculate the probability rIJ of the number of forms by a simple agitation, and with a large difference f. This makes it possible to estimate the degree of entropy from the shark f.
以下、本発明を図示の実施例に基づいて説明する。Hereinafter, the present invention will be explained based on illustrated embodiments.
ｗ４１図は、本発明に（’Ｍ墨分子内回転による位置エ
ネルギー変化のカーブを示すエタンの分子ＩＩ型である
。１．２は正八面体の炭素原子、３．４．５、ｆ３，１
、ｓは磁石を使用した水素原子で結合手ｆ１１１１は全
て１ＰＩＩ掻である。９、ＩＥＩ、 １１．１２．１３
．１４は炭素と水素との結合手である。１５はａＳと炭
素との結合手で、そのＩＩＩＩＩｔｓは特にボールベア
リングを介して両Ｐ！Ｊ、！ＩＩ！原子と枢着して炭素
原子の回転をｌ！存にしてい石、その詳細は第３図で説
明する。Figure w41 is a molecule type II of ethane showing the curve of potential energy change due to intramolecular rotation (1.2 is a regular octahedral carbon atom, 3.4.5, f3,1
, s is a hydrogen atom using a magnet, and the bonds f1111 are all 1PII. 9, IEI, 11.12.13
．． 14 is a bond between carbon and hydrogen. 15 is a bond between aS and carbon, and its IIIts are particularly connected to both P! through a ball bearing. J,! II! Rotate the carbon atom by pivoting with the atom! The details of the existing stones are explained in Figure 3.
１Ｂはａｒｍ子１の回転が、重力の影響を受けないよう
に結合手１５をＩＩＩに保持するスタンド、１７はスタ
ンドの足に内定したロードセルで、水ｌ原子６と枢菅し
ている。炭ｌｌｌ原子１と炭素原子２とはそれぞれに結
合した水素原子の反発力で水１１１ｊｌｒ子が最も離れ
た位置で安定している。その関係は第２図下中央の通り
である。ここを基準にして炭素原子１を左右に回転して
、炭素原子２のトルク戻化をローＶセル１７で横比して
記賛すると、分子内回転による回転角と位置エネルギー
の関係がｊｌ’１２図中のように示される。！！１１２
１！！］土は位置エネルギーが最も高い不安定な重なり
型を示す。1B is a stand that holds the bond 15 in position III so that the rotation of the arm 1 is not affected by gravity; 17 is a load cell that is fixed to the leg of the stand, and is pivotally connected to the water l atom 6. Carbon atom 1 and carbon atom 2 are stabilized at the position where the water 111jlr child is the most distant due to the repulsive force of the hydrogen atoms bonded to each other. The relationship is shown in the bottom center of Figure 2. When carbon atom 1 is rotated left and right with this as a reference, and the torque return of carbon atom 2 is compared horizontally with low V cell 17, the relationship between the rotation angle due to intramolecular rotation and potential energy is jl' It is shown in Figure 12. ! ! 112
1! ! ] Soil exhibits an unstable overlap type with the highest potential energy.
第３図は炭素原子２をＡＢＣ面で切断しなｍ面図である
。炭素原子に結合した水１ｌＩｌ１１子は、互いの反発
力で互いに最も離れた位置で安定すゐのでそれらの轄合
轡は １［３９，５度で、８１！Ｉ合手は正八面体の辺
でｗＡ接しない四面の賃心にＩ［に存在する。FIG. 3 is an m-plane view of carbon atom 2 cut along the ABC plane. The water atoms bonded to carbon atoms are stable at the farthest positions due to mutual repulsion, so their sum is 1[39.5 degrees, 81! The I joint exists at the center of the four sides of the regular octahedron that are not in contact with wA.
１Ｂ、 １９．は結合手を枢菅すゐボールベアリングで
ある。1B, 19. is a ball bearing with a connecting arm.
第４図は２個の水分子ＩＩ型で水素結合の状態を示す。FIG. 4 shows the state of hydrogen bonding between two type II water molecules.
２８．２１はＭｌ原子、２２．２３．２４．２５は水素
原子である。この図は、上から見た図で１１２秦漂子の
真下には、１ｍ！１１１９１子が重力の影響を受けずに
回転自在な支持軸がある。この２償のｍ型の位置関係を
ＩＩｌ数変えて見ると、水素結合の状態を示す確率が大
である。28.21 is an Ml atom, and 22.23.24.25 is a hydrogen atom. This figure is a view from above, and there is a meter directly below 112 Hata Yuko! There is a support shaft that allows the child to rotate freely without being affected by gravity. If we look at the positional relationship of this two-compensated m-type by changing the IIl number, there is a high probability that it will show a hydrogen bond state.
ｌｌｌｂ図は骨格慣幇と電子雲横型（充実空間ｌＩ型）
との中間的横型のシス型ポリイソプレンの２単位であ不
、（ａ）は伸び切りの形態、（ｂ）はｎんだ形態である
。The lllb diagram shows skeletal customs and horizontal electron cloud type (full space II type)
2 units of cis-type polyisoprene with an intermediate horizontal type, (a) is a stretched form, and (b) is a n-shaped form.
（ａ）で、Ｃ１が重力の影響を受けずに回転が自由にず
よる位置で、隣の二重結合の炭１１１原子ＣＪ ＣＪを
図には無いがスタンドに固定する。次に、別の二重結合
の炭１１ｊ！Ｆ子を持ち分子内回転による多数の形ａＳ
化を起こさせて見ると、Ｃ７の結合手２６は分子の両端
間距離がｌｉする形態を取る確率が大である。トランス
型ポリイソプレンについてＩ！ＤＩに試問すると伸びる
形態を取る確Ｔが大である。In (a), at a position where C1 can freely rotate without being affected by gravity, the adjacent double-bonded carbon 111 atom CJ CJ is fixed to a stand (not shown in the figure). Next, another double bond charcoal 11j! Multiple forms aS with F-son and intramolecular rotation
When looking at the formation of C7, there is a high probability that the bond 26 of C7 takes a form in which the distance between both ends of the molecule is li. About trans polyisoprene! If you ask a DI, there is a high probability that the answer will be extended.
シス型ポリイソプレンの２単位横型をスタンドから取り
はずし、一端を持つで釣りさげると伸び切りの形態にな
る。この形態の１１大きめの積の底に情たえ、釉を捩る
と摸襲は飛んだり跳ねたりして多数の形態をとる。それ
らの形態のｒｉｍ聞Ｗｉ離は伸びた状態より綺んだ状態
の確率の方が大である。その詳細は、日本ゴム協会ｉＪ
、 １９８６年７月号３７５ページにある。If you remove the horizontal 2-unit cis-type polyisoprene from the stand and hang it by holding one end, it will become fully extended. Inspired by the 11-larger base of this form, when the glaze is twisted, the pieces fly and bounce, taking on many forms. The probability that the rim separation of these forms is in a neat state is greater than in an extended state. For details, please refer to the Japan Rubber Association iJ
, on page 375 of the July 1986 issue.
このように、本８明は炭素−炭素間の単結合が回転自在
で、水素原子に磁石を使用した分子横型に関するもので
、分子内回転による位置エネルギ一斐化の状態及び影響
、木秦轄台の状態、形態と分子の両端間距離を棚光的に
説明するためのものである。In this way, this book 8 is about a horizontal type of molecule in which the carbon-carbon single bond is rotatable and a magnet is used for the hydrogen atom, and the state and influence of potential energy monopolization due to intramolecular rotation, Kihata's author. It is used to explain the state of the platform, its morphology, and the distance between both ends of the molecule in terms of perspective.
４、＠閲の簡単な＠明
図面は、本発明の実施例を示したもので、第１図は分子
内回転による位置エネルギーＦ化を示すエタンの分子？
ｊｌ型、１２図はエタンの分子内回転による位置エネル
ギー変化と水素配位との関係、第３図は炭素−炭素轄合
の回転部の明細、Ｔ！！４４図は水１１！１合の状態、
第５図はシスをポリイソプレンの分子内回転において水
１１［子の反発力が形態に及ぼす影響を示す図であ不。4. The simple drawing @view shows an example of the present invention. Figure 1 shows an ethane molecule showing potential energy F change due to intramolecular rotation.
jl type, Figure 12 shows the relationship between potential energy changes due to intramolecular rotation of ethane and hydrogen coordination, Figure 3 shows details of the rotating part of the carbon-carbon junction, and T! ! Figure 44 shows the state of water 11!1 go,
FIG. 5 is a diagram showing the influence of the repulsive force of water 11 on the morphology of polyisoprene during intramolecular rotation of cis.
１．２、Ｃ−一一炭！ｔ［子
３．４．５．６．７．８−ｍ−水素原子９．１［］、
１１．１２．１３．１４．１５−−一轄合手１日−−−
スタンド
１７−−−ローＹセル
１日、１９−一一ボールベアリング
２［３，２１−ｍ−酸素原子
２２．２３．２４．２Ｂ−ｍ−水素原子２５．２７一−
−結合手
２日−一一接着用の９！起
Ｈ−ｍ−水素原子1.2, C-11 charcoal! t[child 3.4.5.6.7.8-m-hydrogen atom 9.1[],
11.12.13.14.15---1st day of first division---
Stand 17---Row Y cell 1st, 19-11 Ball bearing 2 [3,21-m-Oxygen atom 22.23.24.2B-m-Hydrogen atom 25.27-
- 2nd day of bonding hands - 9 for 11 gluing! H-m-hydrogen atom
Claims (1)
を使用して水素原子同士の斥力や引力による分子内回転
の位置エネルギー変化及び形態変化の確率度数を実験的
に説明できる分子模型1. A molecular model that has a structure in which single bonds can rotate freely and can experimentally explain the change in potential energy of intramolecular rotation due to repulsion and attraction between hydrogen atoms and the probability frequency of morphological changes using magnets for hydrogen atoms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61178849A JPH0687186B2 (en) | 1986-07-31 | 1986-07-31 | Molecular model using magnet for hydrogen atom |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61178849A JPH0687186B2 (en) | 1986-07-31 | 1986-07-31 | Molecular model using magnet for hydrogen atom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6336288A true JPS6336288A (en) | 1988-02-16 |
| JPH0687186B2 JPH0687186B2 (en) | 1994-11-02 |
Family
ID=16055747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61178849A Expired - Lifetime JPH0687186B2 (en) | 1986-07-31 | 1986-07-31 | Molecular model using magnet for hydrogen atom |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0687186B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02282286A (en) * | 1989-04-24 | 1990-11-19 | Jun Ui | Molecular model |
| JP2004233900A (en) * | 2003-01-31 | 2004-08-19 | Hinomoto Gosei Jushi Seisakusho:Kk | Molecule model |
| JP2009093204A (en) * | 2009-02-02 | 2009-04-30 | Hinomoto Gosei Jushi Seisakusho:Kk | Molecule model |
| JP2016031525A (en) * | 2014-07-30 | 2016-03-07 | 国立大学法人信州大学 | Molecular model and method for reproducing molecular structure |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59112274U (en) * | 1983-01-17 | 1984-07-28 | 中山 茂喜 | Atomic model with a magnet enclosed in a container |
-
1986
- 1986-07-31 JP JP61178849A patent/JPH0687186B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59112274U (en) * | 1983-01-17 | 1984-07-28 | 中山 茂喜 | Atomic model with a magnet enclosed in a container |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02282286A (en) * | 1989-04-24 | 1990-11-19 | Jun Ui | Molecular model |
| JP2004233900A (en) * | 2003-01-31 | 2004-08-19 | Hinomoto Gosei Jushi Seisakusho:Kk | Molecule model |
| JP2009093204A (en) * | 2009-02-02 | 2009-04-30 | Hinomoto Gosei Jushi Seisakusho:Kk | Molecule model |
| JP2016031525A (en) * | 2014-07-30 | 2016-03-07 | 国立大学法人信州大学 | Molecular model and method for reproducing molecular structure |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0687186B2 (en) | 1994-11-02 |
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