JPS63319191A - Transfer material for thermal recording - Google Patents
Transfer material for thermal recordingInfo
- Publication number
- JPS63319191A JPS63319191A JP62154311A JP15431187A JPS63319191A JP S63319191 A JPS63319191 A JP S63319191A JP 62154311 A JP62154311 A JP 62154311A JP 15431187 A JP15431187 A JP 15431187A JP S63319191 A JPS63319191 A JP S63319191A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- dye
- transfer material
- irradiated
- laser radiation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000000975 dye Substances 0.000 abstract description 22
- 238000004040 coloring Methods 0.000 abstract description 7
- 239000004065 semiconductor Substances 0.000 abstract description 4
- 229920000877 Melamine resin Polymers 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000001000 anthraquinone dye Substances 0.000 abstract description 2
- 239000011230 binding agent Substances 0.000 abstract description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract 4
- 239000004640 Melamine resin Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920001721 polyimide Polymers 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229930192627 Naphthoquinone Natural products 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002791 naphthoquinones Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3852—Anthraquinone or naphthoquinone dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3854—Dyes containing one or more acyclic carbon-to-carbon double bonds, e.g., di- or tri-cyanovinyl, methine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、感熱記録用転写材料に関する。さらに詳しく
述べるならば、本発明は、レーザ光照射により染料を昇
華させて、転写体に文字や画像を記録するための昇華型
感熱記録用転写材料に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a transfer material for thermal recording. More specifically, the present invention relates to a sublimation-type heat-sensitive recording transfer material for recording characters or images on a transfer body by sublimating a dye by laser beam irradiation.
従来、この分野の記録方法としては、染料を担持した支
持体（転写材料）と受像体（転写体）とを対向させ、サ
ーマルヘッド等の、電気信号により制御される熱源を圧
着して、文字もしくは画像を転写記録する方法がある。Conventionally, the recording method in this field has been to place a dye-supported support (transfer material) and an image receptor (transfer material) facing each other, and press a heat source controlled by an electric signal, such as a thermal head, to print characters. Alternatively, there is a method of transferring and recording the image.
しかし、この方法では、転写に際して一般に高温を必要
とするため、サーマルヘッドを用いた場合に放熱時間等
の制約から、記録速度が遅くなるという問題点がある。However, this method generally requires a high temperature for transfer, so when a thermal head is used, there is a problem that the recording speed becomes slow due to restrictions such as heat dissipation time.
本発明の目的は、従って、サーマルヘッドの代りにレー
ザ光を用いた、高速でしかも解像度の良好な転写画像を
得ることのできる、昇華型感熱記録用転写材料を提供す
ることにある。Therefore, an object of the present invention is to provide a transfer material for sublimation type heat-sensitive recording, which uses a laser beam instead of a thermal head and can obtain transferred images at high speed and with good resolution.
本発明によれば、支持フィルム上にレーザ光の照射によ
り発熱する物質を含む層と昇華性染料を含む層とを設け
てなる、感熱記録用転写材料が提供される。According to the present invention, there is provided a transfer material for heat-sensitive recording, which comprises a support film provided with a layer containing a substance that generates heat when irradiated with laser light and a layer containing a sublimable dye.
本発明の転写材料においては、通常、レーザ光の照射に
より発熱する物質を含む層（発熱層）と昇華性染料を含
む層（色材層）とは、この順に支持フィルム上に積層さ
れている。この転写材料、好ましくはシート状の材料、
の色材層側に受像シートを密着させ、転写シートの支持
フィルム側からレーザ光を照射すると、色材層中の染料
が昇華して受像シート上に転写される。In the transfer material of the present invention, a layer containing a substance that generates heat when irradiated with laser light (heat generation layer) and a layer containing a sublimable dye (coloring material layer) are usually laminated in this order on a support film. . This transfer material, preferably a sheet material,
When an image-receiving sheet is brought into close contact with the coloring material layer side of the image-receiving sheet and a laser beam is irradiated from the support film side of the transfer sheet, the dye in the coloring material layer is sublimated and transferred onto the image-receiving sheet.
照射されたレーザ光を吸収して発熱する物質は任意に選
ぶことが可能であるが、近年普及の著しい半導体レーザ
を用いる場合は、特に、近赤外領域に特性吸収を持つ物
質が適当である。例としては、シアニン系色素、スクワ
リリウム系色素、ナフトキノン系色素、アントラキノン
系色素等があり、具体的には下記表１に示す化合物を挙
げることができる。Any substance that absorbs the irradiated laser light and generates heat can be selected arbitrarily, but when using semiconductor lasers, which have become popular in recent years, a substance that has characteristic absorption in the near-infrared region is especially suitable. . Examples include cyanine dyes, squarylium dyes, naphthoquinone dyes, and anthraquinone dyes, and specific examples include compounds shown in Table 1 below.
以下余白
これらの近赤外線吸収色素は、直接塗布して適用しても
よく、または尿素−メラミン樹脂、尿素−ホルマリン樹
脂、エポキシ樹脂、ウレタン樹脂、アクリル樹脂、ポリ
エステル樹脂、ポリイミド樹脂、ポリエーテル樹脂、ポ
リスルホン樹脂等をバインダーとして用いて適用しても
よい。These near-infrared absorbing dyes may be applied by direct coating, or may be applied using urea-melamine resins, urea-formalin resins, epoxy resins, urethane resins, acrylic resins, polyester resins, polyimide resins, polyether resins, A polysulfone resin or the like may be used as a binder.
色材層を構成する昇華性染料としては、通常のポリエス
テル繊維材料の転写捺染用染料、昇華性の高いカラーフ
ォーマ−を含むイオン系染料、または特に昇華型転写用
に開発された染料等が用いられる。これら染料を融点ま
たは軟化点の高い樹脂と溶剤又は水等の溶媒と混合する
ことにより、色材層を構成するインクを調製することが
できる。As the sublimable dye constituting the color material layer, dyes for transfer printing of ordinary polyester fiber materials, ionic dyes containing highly sublimable color formers, or dyes developed especially for sublimation transfer are used. It will be done. By mixing these dyes with a resin having a high melting point or a high softening point, a solvent, or a solvent such as water, an ink constituting the color material layer can be prepared.
また、色材層には、非昇華性の粒子、界面活性剤等を添
加して用いることもできる。Furthermore, non-sublimable particles, surfactants, etc. can also be added to the coloring material layer.
上記インクを調製するための樹脂は通常の印刷インキに
使用されるものであってよく、例えばロジン系、フェノ
ール系、キシレン系、石油系、ビニル系、ポリイミド系
、アルキッド系、ニトロセルロース系、アルキルセルロ
ース系、エーテル系、エステル系などの油性系の樹脂、
またはマレイン酸系、アクリル酸系、カゼイン、シェラ
ツク、ニカワ等の水性系樹脂を使用することができる。The resin for preparing the above ink may be one used in ordinary printing inks, such as rosin-based, phenol-based, xylene-based, petroleum-based, vinyl-based, polyimide-based, alkyd-based, nitrocellulose-based, alkyl-based, etc. Oil-based resins such as cellulose, ether, and ester,
Alternatively, aqueous resins such as maleic acid, acrylic acid, casein, shellac, and glue can be used.
より具体的には、融点または軟化点の高いポリカーボネ
ート、ポリスルホン、ポリフェニレンオキサイド、ポリ
アクリレート、セルロース誘導体等を挙げることができ
る。More specifically, polycarbonates, polysulfones, polyphenylene oxides, polyacrylates, cellulose derivatives and the like having high melting points or softening points can be mentioned.
これらの光−熱変換物質および昇華性染料は、通常、プ
ラスチックフィルム上に、光−熱変換物質から昇華性染
料の順に塗布される。用いられるプラスチックフィルム
としては、例えば、ポリエステル、ポリイミド、ポリ塩
化ビニル、ポリエチレン、ポリプロピレン等のフィルム
を挙げることができるが、半導体レーザ光を透過するフ
ィルムであれば、上記のものに限らず用いることが可能
である。These light-to-heat conversion substances and sublimable dyes are usually applied onto a plastic film in the order of the light-to-heat conversion substance and the sublimable dye. Examples of plastic films that can be used include films made of polyester, polyimide, polyvinyl chloride, polyethylene, polypropylene, etc., but any film that transmits semiconductor laser light can be used without being limited to the above. It is possible.
転写体、特に受像シートとしては、紙、合成紙、プラス
チックフィルム等を挙げることができる。Examples of the transfer body, particularly the image-receiving sheet, include paper, synthetic paper, and plastic film.
以下に、実施例を挙げて、本発明をさらに説明する。例
中、「部」は重量部を示す。The present invention will be further explained below with reference to Examples. In the examples, "parts" indicate parts by weight.
実施例１
フタロシアニンｐｂ錯体２０部をポリイミドワニス８０
部に分散させ、ワイヤーバーコーティングによりポリエ
ステルフィルムにコートし、乾燥した。加熱硬化した後
、得られる色剤層は５ＩＩＴＩｌの厚みを有していた。Example 1 20 parts of phthalocyanine pb complex was added to 80 parts of polyimide varnish.
It was coated onto a polyester film by wire bar coating and dried. After heat curing, the resulting colorant layer had a thickness of 5IITIl.
この後、さらにこの上にナフトキノン系の昇華性分散染
料５部、ポリカーボネート５部、ジクロルメタン１００
部およびシリカ粒子（平均粒径５Ｉ１ｍ）１０部からな
る分散液を塗布して、厚み３／／ｌＴｌとなる様にした
。After this, 5 parts of naphthoquinone-based sublimable disperse dye, 5 parts of polycarbonate, and 100 parts of dichloromethane were added on top of this.
A dispersion consisting of 10 parts and 10 parts of silica particles (average particle size 5I1m) was applied to give a thickness of 3//1Tl.
この転写フィルムとポリエステルラミネート紙とを重ね
合せ、フィルム側より半導体レーザ（波長８３０ｎｍ、
出力５０ｍＷ）を光学系を通して２５＊径のスポット状
として照射し、良好な転写像を得た。This transfer film and polyester laminated paper are overlapped, and a semiconductor laser (wavelength 830 nm,
A good transferred image was obtained by irradiating a spot with an output of 50 mW through an optical system with a diameter of 25*.
結果を表２に示す。The results are shown in Table 2.
実施例２
フタロシアニンｐｂ錯体に代えて、下記式のポリメチン
系色素
２０部を用いた以外は、実施例１と同様な方法で、転写
材料を調製し、良好な転写像を得た。Example 2 A transfer material was prepared in the same manner as in Example 1, except that 20 parts of a polymethine dye of the following formula was used in place of the phthalocyanine pb complex, and a good transferred image was obtained.
結果を表２に示す。The results are shown in Table 2.
実施例３
フタロシアニンｐｂ錯体の代りに、下記式、のレーザ光
吸収色素を用いた以外は、実施例１と同様の方法で、転
写材料を作成し、良好な転写像を得た。Example 3 A transfer material was prepared in the same manner as in Example 1, except that a laser light absorbing dye of the following formula was used instead of the phthalocyanine pb complex, and a good transferred image was obtained.
結果を表２に示す。The results are shown in Table 2.
比較例
実施例１において、フタロシアニンＰｂ層を設けなかっ
た以外は、同様にして、転写フィルムを作成し、ポリエ
ステルラミネート紙と重ね合せて、サーマルヘッド（１
２ｄｏｔ／ｍ、０．７ｍＷ／ｄｏｔのラインヘッド）を
用いて、転写記録を行った。Comparative Example A transfer film was prepared in the same manner as in Example 1, except that the phthalocyanine Pb layer was not provided, and it was laminated with polyester laminated paper and transferred to a thermal head (1
Transfer recording was performed using a 2 dot/m, 0.7 mW/dot line head).
結果を表２に示す。The results are shown in Table 2.
較例
マル
ト
Ｊ／ｄ
二／１＝
〔発明の効果〕
本発明によれば、レーザ光を照射することにより転写印
字することのできる感熱記録用転写材料が提供され、解
像度の良好な転写画像を高速で得ることかできる。Comparative Example Malt J/d 2/1= [Effects of the Invention] According to the present invention, a transfer material for thermal recording that can be transferred and printed by irradiation with laser light is provided, and a transferred image with good resolution can be produced. You can get it fast.
Claims (1)
質を含む層と昇華性染料を含む層とを設けてなる、感熱
記録用転写材料。1. A transfer material for heat-sensitive recording, comprising a support film provided with a layer containing a substance that generates heat when irradiated with laser light and a layer containing a sublimable dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62154311A JPS63319191A (en) | 1987-06-23 | 1987-06-23 | Transfer material for thermal recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62154311A JPS63319191A (en) | 1987-06-23 | 1987-06-23 | Transfer material for thermal recording |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63319191A true JPS63319191A (en) | 1988-12-27 |
Family
ID=15581341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62154311A Pending JPS63319191A (en) | 1987-06-23 | 1987-06-23 | Transfer material for thermal recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63319191A (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4942141A (en) * | 1989-06-16 | 1990-07-17 | Eastman Kodak Company | Infrared absorbing squarylium dyes for dye-donor element used in laser-induced thermal dye transfer |
| US4948777A (en) * | 1989-06-16 | 1990-08-14 | Eastman Kodak Company | Infrared absorbing bis(chalcogenopyrylo)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer |
| US4950639A (en) * | 1989-06-16 | 1990-08-21 | Eastman Kodak Company | Infrared absorbing bis(aminoaryl)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer |
| US4973572A (en) * | 1987-12-21 | 1990-11-27 | Eastman Kodak Company | Infrared absorbing cyanine dyes for dye-donor element used in laser-induced thermal dye transfer |
| JPH0330991A (en) * | 1989-06-16 | 1991-02-08 | Eastman Kodak Co | Infrared ray absorbing merocyanine dye for dye donating element which is used for laser induction dye heat transfer |
| JPH0330992A (en) * | 1989-06-16 | 1991-02-08 | Eastman Kodak Co | Infrared ray absorbing oxonol dye for dye donating element which is used for laser induction dye heat transfer |
| JPH0336094A (en) * | 1989-06-20 | 1991-02-15 | Eastman Kodak Co | Infrared ray absorbing quinoid dye for dye donating element which is used for laser induction dye heat transfer |
| JPH0363185A (en) * | 1989-06-20 | 1991-03-19 | Eastman Kodak Co | Infrared absorption nickel-dithiolene dye complex for dye donor element for use in laser induced dye thermal transfer |
| EP0482595A1 (en) * | 1990-10-25 | 1992-04-29 | E.I. Du Pont De Nemours And Company | Donor element for thermal imaging containing infra-red absorbing squarlium compound |
| EP0542544A2 (en) * | 1991-11-13 | 1993-05-19 | Imperial Chemical Industries Plc | Laser printer and thermal transfer printing method |
| EP0568267A2 (en) * | 1992-04-27 | 1993-11-03 | Minnesota Mining And Manufacturing Company | Thermal transfer materials |
| US5840463A (en) * | 1997-07-14 | 1998-11-24 | E. I. Du Pont De Nemours And Company | Photosensitive donor element assemblages and associated process for laser-induced thermal transfer |
| US5843617A (en) * | 1996-08-20 | 1998-12-01 | Minnesota Mining & Manufacturing Company | Thermal bleaching of infrared dyes |
| US5856061A (en) * | 1997-08-14 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Production of color proofs and printing plates |
| US5863860A (en) * | 1995-01-26 | 1999-01-26 | Minnesota Mining And Manufacturing Company | Thermal transfer imaging |
| US6143451A (en) * | 1996-11-26 | 2000-11-07 | E. I. Du Pont De Nemours And Company | Imaged laserable assemblages and associated processes with high speed and durable image-transfer characteristics for laser-induced thermal transfer |
| EP1063231A1 (en) * | 1999-06-21 | 2000-12-27 | Yamamoto Chemicals, Inc. | Polymethine compounds, method of producing the same, and use thereof |
| US6855474B1 (en) | 2004-05-03 | 2005-02-15 | Kodak Polychrome Graphics Llc | Laser thermal color donors with improved aging characteristics |
| US6899988B2 (en) | 2003-06-13 | 2005-05-31 | Kodak Polychrome Graphics Llc | Laser thermal metallic donors |
| USRE39105E1 (en) | 1999-06-21 | 2006-05-23 | Yamamoto Chemicals, Inc. | Polymethine compounds, method of producing same, and use thereof |
| DE102012017010A1 (en) | 2012-08-28 | 2012-10-31 | Heidelberger Druckmaschinen Ag | Treating printing material printed with an ink comprises exposing printing material to laser radiation and absorbing laser radiation by tris-aryl-immonium absorber compounds and/or tetrakis-aryl-immonium absorber compounds |
-
1987
- 1987-06-23 JP JP62154311A patent/JPS63319191A/en active Pending
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973572A (en) * | 1987-12-21 | 1990-11-27 | Eastman Kodak Company | Infrared absorbing cyanine dyes for dye-donor element used in laser-induced thermal dye transfer |
| JPH0512159B2 (en) * | 1989-06-16 | 1993-02-17 | Eastman Kodak Co | |
| US4948777A (en) * | 1989-06-16 | 1990-08-14 | Eastman Kodak Company | Infrared absorbing bis(chalcogenopyrylo)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer |
| US4950639A (en) * | 1989-06-16 | 1990-08-21 | Eastman Kodak Company | Infrared absorbing bis(aminoaryl)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer |
| JPH0330991A (en) * | 1989-06-16 | 1991-02-08 | Eastman Kodak Co | Infrared ray absorbing merocyanine dye for dye donating element which is used for laser induction dye heat transfer |
| JPH0330992A (en) * | 1989-06-16 | 1991-02-08 | Eastman Kodak Co | Infrared ray absorbing oxonol dye for dye donating element which is used for laser induction dye heat transfer |
| US4942141A (en) * | 1989-06-16 | 1990-07-17 | Eastman Kodak Company | Infrared absorbing squarylium dyes for dye-donor element used in laser-induced thermal dye transfer |
| JPH0512157B2 (en) * | 1989-06-16 | 1993-02-17 | Eastman Kodak Co | |
| JPH0336094A (en) * | 1989-06-20 | 1991-02-15 | Eastman Kodak Co | Infrared ray absorbing quinoid dye for dye donating element which is used for laser induction dye heat transfer |
| US5036040A (en) * | 1989-06-20 | 1991-07-30 | Eastman Kodak Company | Infrared absorbing nickel-dithiolene dye complexes for dye-donor element used in laser-induced thermal dye transfer |
| JPH0363185A (en) * | 1989-06-20 | 1991-03-19 | Eastman Kodak Co | Infrared absorption nickel-dithiolene dye complex for dye donor element for use in laser induced dye thermal transfer |
| JPH0541438B2 (en) * | 1989-06-20 | 1993-06-23 | Eastman Kodak Co | |
| EP0482595A1 (en) * | 1990-10-25 | 1992-04-29 | E.I. Du Pont De Nemours And Company | Donor element for thermal imaging containing infra-red absorbing squarlium compound |
| EP0542544A2 (en) * | 1991-11-13 | 1993-05-19 | Imperial Chemical Industries Plc | Laser printer and thermal transfer printing method |
| EP0542544A3 (en) * | 1991-11-13 | 1994-03-23 | Ici Plc | |
| EP0568267A3 (en) * | 1992-04-27 | 1993-12-01 | Minnesota Mining & Mfg | Thermal transfer materials |
| EP0568267A2 (en) * | 1992-04-27 | 1993-11-03 | Minnesota Mining And Manufacturing Company | Thermal transfer materials |
| US5863860A (en) * | 1995-01-26 | 1999-01-26 | Minnesota Mining And Manufacturing Company | Thermal transfer imaging |
| US5843617A (en) * | 1996-08-20 | 1998-12-01 | Minnesota Mining & Manufacturing Company | Thermal bleaching of infrared dyes |
| US6143451A (en) * | 1996-11-26 | 2000-11-07 | E. I. Du Pont De Nemours And Company | Imaged laserable assemblages and associated processes with high speed and durable image-transfer characteristics for laser-induced thermal transfer |
| US5840463A (en) * | 1997-07-14 | 1998-11-24 | E. I. Du Pont De Nemours And Company | Photosensitive donor element assemblages and associated process for laser-induced thermal transfer |
| US5856061A (en) * | 1997-08-14 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Production of color proofs and printing plates |
| EP1063231A1 (en) * | 1999-06-21 | 2000-12-27 | Yamamoto Chemicals, Inc. | Polymethine compounds, method of producing the same, and use thereof |
| USRE39105E1 (en) | 1999-06-21 | 2006-05-23 | Yamamoto Chemicals, Inc. | Polymethine compounds, method of producing same, and use thereof |
| US6899988B2 (en) | 2003-06-13 | 2005-05-31 | Kodak Polychrome Graphics Llc | Laser thermal metallic donors |
| US6855474B1 (en) | 2004-05-03 | 2005-02-15 | Kodak Polychrome Graphics Llc | Laser thermal color donors with improved aging characteristics |
| DE102012017010A1 (en) | 2012-08-28 | 2012-10-31 | Heidelberger Druckmaschinen Ag | Treating printing material printed with an ink comprises exposing printing material to laser radiation and absorbing laser radiation by tris-aryl-immonium absorber compounds and/or tetrakis-aryl-immonium absorber compounds |
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