JPS63294760A - Powdered tocopherol composition - Google Patents
Powdered tocopherol compositionInfo
- Publication number
- JPS63294760A JPS63294760A JP62130774A JP13077487A JPS63294760A JP S63294760 A JPS63294760 A JP S63294760A JP 62130774 A JP62130774 A JP 62130774A JP 13077487 A JP13077487 A JP 13077487A JP S63294760 A JPS63294760 A JP S63294760A
- Authority
- JP
- Japan
- Prior art keywords
- tocopherol
- powdered
- composition
- fatty acid
- gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 title claims abstract description 69
- 239000011732 tocopherol Substances 0.000 title claims abstract description 65
- 229930003799 tocopherol Natural products 0.000 title claims abstract description 63
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 229960001295 tocopherol Drugs 0.000 title claims abstract description 59
- 235000010384 tocopherol Nutrition 0.000 title claims abstract description 57
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 19
- 229930195729 fatty acid Natural products 0.000 claims abstract description 19
- 239000000194 fatty acid Substances 0.000 claims abstract description 19
- 229920002472 Starch Polymers 0.000 claims abstract description 17
- 229930006000 Sucrose Natural products 0.000 claims abstract description 17
- 239000005720 sucrose Substances 0.000 claims abstract description 17
- -1 sucrose ester Chemical class 0.000 claims abstract description 17
- 235000019698 starch Nutrition 0.000 claims abstract description 16
- 239000008107 starch Substances 0.000 claims abstract description 16
- 244000215068 Acacia senegal Species 0.000 claims abstract description 9
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 9
- 239000000205 acacia gum Substances 0.000 claims abstract description 9
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 9
- 240000004584 Tamarindus indica Species 0.000 claims abstract description 4
- 235000004298 Tamarindus indica Nutrition 0.000 claims abstract description 4
- 150000004676 glycans Chemical class 0.000 claims abstract description 4
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 4
- 239000005017 polysaccharide Substances 0.000 claims abstract description 4
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 3
- 239000000230 xanthan gum Substances 0.000 claims abstract description 3
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 3
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 3
- 229920002907 Guar gum Polymers 0.000 claims abstract 2
- 239000000665 guar gum Substances 0.000 claims abstract 2
- 235000010417 guar gum Nutrition 0.000 claims abstract 2
- 229960002154 guar gum Drugs 0.000 claims abstract 2
- ORYOIBJWFDNIPD-UHFFFAOYSA-N diacetyl 2,3-dihydroxybutanedioate Chemical compound CC(=O)OC(=O)C(O)C(O)C(=O)OC(C)=O ORYOIBJWFDNIPD-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 27
- DNISEZBAYYIQFB-PHDIDXHHSA-N (2r,3r)-2,3-diacetyloxybutanedioic acid Chemical compound CC(=O)O[C@@H](C(O)=O)[C@H](C(O)=O)OC(C)=O DNISEZBAYYIQFB-PHDIDXHHSA-N 0.000 abstract description 5
- 150000004665 fatty acids Chemical class 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 15
- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 description 12
- 235000013305 food Nutrition 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- GZIFEOYASATJEH-UHFFFAOYSA-N D-delta tocopherol Natural products OC1=CC(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-UHFFFAOYSA-N 0.000 description 6
- 229940087168 alpha tocopherol Drugs 0.000 description 6
- 235000010389 delta-tocopherol Nutrition 0.000 description 6
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 6
- 229960000984 tocofersolan Drugs 0.000 description 6
- 235000019149 tocopherols Nutrition 0.000 description 6
- 235000004835 α-tocopherol Nutrition 0.000 description 6
- 239000002076 α-tocopherol Substances 0.000 description 6
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 6
- 239000002446 δ-tocopherol Substances 0.000 description 6
- 235000010382 gamma-tocopherol Nutrition 0.000 description 5
- 239000002478 γ-tocopherol Substances 0.000 description 5
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 5
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 4
- 235000011613 Pinus brutia Nutrition 0.000 description 4
- 241000018646 Pinus brutia Species 0.000 description 4
- 229940088594 vitamin Drugs 0.000 description 4
- 229930003231 vitamin Natural products 0.000 description 4
- 235000013343 vitamin Nutrition 0.000 description 4
- 239000011782 vitamin Substances 0.000 description 4
- 150000003722 vitamin derivatives Chemical class 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940066595 beta tocopherol Drugs 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- RGKHAQKSWFKIQQ-UHFFFAOYSA-N diacetyl 2,3-dihydroxybutanedioate;octadecanoic acid Chemical compound CC(=O)OC(=O)C(O)C(O)C(=O)OC(C)=O.CCCCCCCCCCCCCCCCCC(O)=O RGKHAQKSWFKIQQ-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Grain Derivatives (AREA)
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は水に容易に分散する粉末トコフェロール組成物
に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to powdered tocopherol compositions that are easily dispersible in water.
トコフェロールはビタミンＥとして知られ、α−トコフ
ェロール、β−トコフェロール、γ−トコフェロール、
δ−トコフェロールの４種類の同族体がある。従来トコ
フェロールは酸化防止の目的で食品、医薬品、化粧品な
どの分野で使用されてきた。ところが最近になってトコ
フェロールの栄養・生理効果を目的とした利用が目立っ
てきており、なかでも健康の維持増進のため、動物性・
植物性油脂食品をはじめ乳製品、飲料、インスタント食
品など各種食品において栄養強化のために使用される場
合が多くなってきた。Tocopherol is known as vitamin E and includes α-tocopherol, β-tocopherol, γ-tocopherol,
There are four congeners of δ-tocopherol. Traditionally, tocopherols have been used in the fields of food, medicine, cosmetics, etc. for the purpose of antioxidant. However, recently, the use of tocopherol for nutritional and physiological effects has become prominent, and in particular, animal-derived and
It is increasingly being used for nutritional enrichment in various foods such as vegetable oil and fat foods, dairy products, beverages, and instant foods.
トコフェロールは油溶性の物質であるため、添加対象が
油性のものである場合には、その添加は容易であるが、
対象が水性のものである場合には、それに添加して均一
に混合分散することは難しい。そのため、おのずとトコ
フェロールの添加できる対象は限定されていた。これら
の問題を解決するためにトコフェロールを水溶性の乳剤
となし、食品に添加する試みもなされているが、乳剤自
体が水性のため、その保存・取扱い中に腐敗菌の増殖す
る危険性が高く、長期保存に耐えられないなどの問題点
があり、十分普及するには至っていない。かかる事情か
ら取り扱いが容易で、かつ保存性が高く、水性の対象へ
の添加・配合が可能な形態としてトコフェロールを粉末
化する技術が特開昭５１−７９７４６号、特開昭５８−
１８７１７４号、特開昭６０−６４９１９号および特開
昭６１−６０６１９号に開示されている。しかし、いず
れも水分散性において十分に問題点が解決されていると
は言えない。Since tocopherol is an oil-soluble substance, it is easy to add it when the target is oil-based.
If the target is aqueous, it is difficult to add it to it and mix and disperse it uniformly. Therefore, the targets to which tocopherol can be added are naturally limited. To solve these problems, attempts have been made to make tocopherol into a water-soluble emulsion and add it to foods, but since the emulsion itself is water-based, there is a high risk of spoilage bacteria growing during storage and handling. However, it has not been widely used due to problems such as not being able to withstand long-term storage. Under these circumstances, a technology for powderizing tocopherol in a form that is easy to handle, has a high shelf life, and can be added to and blended into aqueous substances has been proposed in JP-A-51-79746 and JP-A-58-
No. 187174, JP-A-60-64919, and JP-A-61-60619. However, none of them can be said to have sufficiently solved the problems in water dispersibility.
従来技術にもとづいて得られる粉末トコフェロール組成
物は水性の対象に添加した場合、（１）粉末がママコに
なり十分な分散が困難である。When a powdered tocopherol composition obtained according to the prior art is added to an aqueous solution, (1) the powder becomes lumpy and it is difficult to sufficiently disperse it;
（２）食品など、塩類を多く含むものやｐＨの低いもの
に添加した場合、分散した粉末中の油分が凝集分離する
。(2) When added to foods that contain a lot of salt or have a low pH, the oil in the dispersed powder will coagulate and separate.
などの問題点があり、いずれも十分な対策がとられてい
るとは言えない。There are several problems, and it cannot be said that sufficient countermeasures have been taken for all of them.
本発明は上記の従来の粉末トコフェロール組成物の短所
を解消し、水に対する粉末の分散性がいちじるしく良好
な粉末トコフェロール組成物を提供するものである。The present invention overcomes the disadvantages of the conventional powdered tocopherol compositions and provides a powdered tocopherol composition that has extremely good dispersibility in water.
（問題点を解決するための手段）
本発明者らは水に容易に分散する粉末トコフェロール組
成物に関して鋭意検討した結果、トコフェロール、ガム
質、デンプン加水分解物からなる粉末トコフェロールを
製造するにあたって、該粉末にシヨ糖脂肪酸エステルと
ジアセチル酒石酸モノグリセリドをそれぞれ０．１〜５
重量部配合することにより水分散性にいちじるしくすぐ
れた粉末トコフェロール組成物が得られることを見い出
し、本発明にいたった。すなわち本発明はトコフェロー
ル、ガム質、デンプン加水分解物、シヨ糖脂肪酸エステ
ルおよびジアセチル酒石酸モノグリセリドを必須成分と
し、該シヨ糖脂肪酸エステルおよびジアセチル酒石酸モ
ノグリセリドがそれぞれ０．１〜５重量部であることを
特徴とする、水分散性がいちじるしくすぐれた粉末トコ
フェロール組成物を提示するものである。(Means for Solving the Problems) As a result of extensive research into powdered tocopherol compositions that are easily dispersed in water, the present inventors found that in producing powdered tocopherol consisting of tocopherol, gum, and starch hydrolyzate, Add 0.1 to 5 sucrose fatty acid ester and diacetyl tartrate monoglyceride to the powder.
It has been found that a powdered tocopherol composition with particularly excellent water dispersibility can be obtained by incorporating these parts by weight, leading to the present invention. That is, the present invention is characterized in that tocopherol, gum, starch hydrolyzate, sucrose fatty acid ester, and diacetyl tartrate monoglyceride are essential components, and each of the sucrose fatty acid ester and diacetyl tartrate monoglyceride is 0.1 to 5 parts by weight. The present invention provides a powdered tocopherol composition with extremely excellent water dispersibility.
本発明でいうトコフェロールとはトコフェロールの同族
体単独または混合物を言い、必要に応じて他の油脂類、
例えば牛脂、肝脂、大豆油。Tocopherol as used in the present invention refers to tocopherol homologs alone or as a mixture, and if necessary, other oils and fats,
For example, beef tallow, liver fat, and soybean oil.
コーン油、パーム油等で希釈してもよく、その粉末中の
組成量は限定されない。It may be diluted with corn oil, palm oil, etc., and the composition amount in the powder is not limited.
本発明においてデンプン加水分解物は小麦デンプン、バ
レイシヨデンプン、コーンスターチなどを加水分解した
ものであり、そのＤＥ値は２〜２０であることが好まし
い。ＤＥ値が下限未満のものを使用すると粉末の水への
溶解性が悪化する。またＤＥ値が上限を越えるものを使
用すると粉末の吸湿性が強くなり、ブロッキングを発生
し、水分散性が低下する。デンプン加水分解物が粉末中
に占める割合は限定されない。In the present invention, the starch hydrolyzate is obtained by hydrolyzing wheat starch, potato starch, corn starch, etc., and preferably has a DE value of 2 to 20. If a powder with a DE value below the lower limit is used, the solubility of the powder in water will deteriorate. Furthermore, if a powder with a DE value exceeding the upper limit is used, the powder becomes highly hygroscopic, causing blocking and decreasing water dispersibility. The proportion of the starch hydrolyzate in the powder is not limited.
本発明に使用するシヨ糖脂肪酸エステルは、とくにＨＬ
Ｂ値や付加脂肪酸の種類、エステル化度によって限定さ
れないが、親水性のものが好ましい。ジアセチル酒石酸
モノグリセリドは付加脂肪酸の種類によって限定される
ものではないが、通常はオレイン酸あるいはステアリン
酸付加のモノグリセライドまたはそれらの混合物が使用
可能である。The sucrose fatty acid ester used in the present invention is particularly suitable for HL
Although not limited by B value, type of added fatty acid, or degree of esterification, hydrophilic ones are preferred. The diacetyl tartaric acid monoglyceride is not limited by the type of added fatty acid, but monoglyceride added with oleic acid or stearic acid, or a mixture thereof can usually be used.
本発明における、シヨ糖脂肪酸エステルおよびジアセチ
ル酒石酸モノグリセリドは粉末仝珊に対しそれぞれ０．
１〜５重量部であることが必要であり、０．１重量部未
満の使用量では満足な水分散性は得られず、また５重Φ
部を越える配合量では分散性の効果は変らず不経済であ
る。In the present invention, sucrose fatty acid ester and diacetyl tartrate monoglyceride are each 0.0% relative to powdered silicone.
It is necessary that the amount is 1 to 5 parts by weight, and if the amount used is less than 0.1 part by weight, satisfactory water dispersibility cannot be obtained, and 5-fold Φ
If the amount exceeds 1 part, the dispersibility effect will not change and it will be uneconomical.
本発明粉末トコフェロール組成物の製造に当り、シヨ糖
脂肪酸エステルおよびジアセチル酒石酸モノグリセリド
は粉末中に均一に分散されればよく、添加方法はとくに
限定されないが、例えばガム質、デンプン加水分解物、
シヨ糖脂肪酸エステルを水に溶解し、加温したのちトコ
フェロールとジアセチル酒石酸モノグリセリドを加え、
ホモゲナイザーで均質乳化させ、スプレードライヤーで
粉末化して本発明粉末トコフェロール組成物を得ること
ができる。In producing the powdered tocopherol composition of the present invention, the sucrose fatty acid ester and diacetyl tartaric acid monoglyceride need only be uniformly dispersed in the powder, and the method of addition is not particularly limited.
Dissolve sucrose fatty acid ester in water, heat it, add tocopherol and diacetyl tartrate monoglyceride,
The powdered tocopherol composition of the present invention can be obtained by uniformly emulsifying it with a homogenizer and powdering it with a spray dryer.
（実施例〕 以下に実施例を示し本発明を具体的に説明する。(Example〕 EXAMPLES The present invention will be specifically explained below with reference to Examples.
実施例−１
アラビアガム１２．５Ｋｇ、デンプン加水分解物（松谷
化学ｋｋ製、パインデツクス＃１００．ＤＥ２．３ ＞
１６４．７５ＮＬシヨ糖脂肪酸エステル（三菱化成食
品ｋｋ製、リョートーシュガーエステルＳ−１１７０）
１２．５Ｎ５Ｆを水２５０１に６０〜７０℃で溶解し
た。これに天然ミックストコフェロール（総トコフェロ
ール９４９．６ ｍｆｌ／ ’ｊ、トコフェロール組成
：α−トコフェロール１７．８１ＲＩ／ｇ、β、γ−ト
コフェロール６８０．２ ｆｆ１ｇ／ ｇ、δ−トコフ
ェロール２５１．６ ｒｌｔｇ／ ｇ＞ ６ＯＮ！９と
ジアセチル酒石酸モノグリセリド（理研ビタミンｋｋ製
、ポエムＷ−１４、ジアセチル酒ＥＷｔオレイン酸モノ
グリセリド）２５０ｇを７０℃で混合したものを加えホ
モミキサーにて撹拌混合した。この混合液をピストンホ
モゲナイザーで乳化処理し、次いで、この乳化液を噴霧
屹燥して２６４．８ Ｋ’Ｊの粉末トコフェロール組成
物を１ｑだ。粉末中の水分含有率は５．６％であった。Example-1 Gum arabic 12.5Kg, starch hydrolyzate (manufactured by Matsutani Chemical KK, Pinedex #100.DE2.3>
164.75NL sucrose fatty acid ester (manufactured by Mitsubishi Kasei Foods KK, Ryoto Sugar Ester S-1170)
12.5N5F was dissolved in water 2501 at 60-70°C. This is supplemented with natural mixed tocopherols (total tocopherol 949.6 mfl/'j, tocopherol composition: α-tocopherol 17.81 RI/g, β, γ-tocopherol 680.2 ff1g/g, δ-tocopherol 251.6 rltg/g> A mixture of 250 g of 6ON!9 and diacetyl tartaric acid monoglyceride (manufactured by Riken Vitamin KK, Poem W-14, diacetyl sake EWt oleic acid monoglyceride) at 70°C was added and mixed with stirring using a homomixer.This mixture was mixed using a piston homogenizer. Emulsification was carried out, and the emulsion was then spray-dried to obtain 1 q of a powdered tocopherol composition with a weight of 264.8 K'J.The water content in the powder was 5.6%.
実施例−２
アラビアガム４００ｇ、デンプン加水分解物（松谷化学
ｋｋ製、パインデックス＃４．ＤＥ１９．５） ９４８
ｇとシヨ糖脂肪酸エステル（第一工業製薬ｋｋ製、Ｄ
ＫエステルＦ−７０）２ｇを水２１に５０〜６０℃で溶
解した。これに天然ミックストコフェロール（総トコフ
ェロール９２８．４η／ｇ、トコフェロール組成：α−
トコフェロール７．０η／９．β、γ−トコフェロール
６４４．６ ｑ／ ！？ 、δ−トコフェロール２７６
゜８ｒＩｔｇ／９）４５０ｇ、大豆油１００ｇ、ジアセ
チル酒石酸モノグリセリド（理研ビタミンｋｋ製、ボエ
ムＷ−１０，ジアセチル酒石酸ステアリン酸モノグリセ
リド）１００ｇを７０℃にて混合したものを加え、以下
実施例−１と同様に処理して粉末トコフェロール組成物
（水分含有率６．１％） ２１３０ｇを得た。Example-2 400 g of gum arabic, starch hydrolyzate (manufactured by Matsutani Chemical KK, Pine Index #4.DE19.5) 948
g and sucrose fatty acid ester (manufactured by Daiichi Kogyo Seiyaku KK, D
2 g of K ester F-70) was dissolved in water 21 at 50-60°C. This is combined with natural mixed tocopherol (total tocopherol 928.4η/g, tocopherol composition: α-
Tocopherol 7.0η/9. β, γ-tocopherol 644.6 q/! ? , δ-tocopherol 276
A mixture of 450 g of ゜8rItg/9), 100 g of soybean oil, and 100 g of diacetyl tartrate monoglyceride (manufactured by Riken Vitamin KK, Boheme W-10, diacetyl tartrate stearate monoglyceride) at 70°C was added, and the following was the same as in Example-1. 2130 g of a powdered tocopherol composition (water content 6.1%) was obtained.
実施例−３
アラビアガム５６０ｇ、タマリンド種子多糖類４０９、
デンプン加水分解物（松谷化学ｋｋｌ、パインデックス
＃ ２ 、 Ｄ Ｅ １０） ２３４０ｇとシヨ糖脂肪
酸エステル（三菱化成食品ｋｋ製、リョートーシュガー
エステルＳ−１５７０） １２０ （ｊを水４１に６０
〜７０℃で溶解した。これに天然ミックストコノエロー
ル（総トコフェロール９４７．８ ｍｌ／ ｇ。Example-3 Gum arabic 560g, tamarind seed polysaccharide 409,
2340 g of starch hydrolyzate (Matsutani Chemical KKL, Pine Index #2, DE 10) and 120 g of sucrose fatty acid ester (Mitsubishi Kasei Foods KK, Ryoto Sugar Ester S-1570) (j to 41 to 60
Dissolved at ~70°C. This is supplemented with natural mixed toconoeols (947.8 ml/g total tocopherols).
トコフェロール組成：α−トコフェロール２２．７Ｑ／
ｇｅβ、γ−トコフェロール６６５．７ ｍ’ｊ／
ｇ。Tocopherol composition: α-tocopherol 22.7Q/
geβ, γ-tocopherol 665.7 m'j/
g.
δ−トコフェロール２５９．４η／９’）９２０ｇにジ
アセチル酒石酸モノグリセリド（理研ビタミンｋｋ製、
ポエムＷ−１０） ２０ｇを５０℃で混合したものを加
え、以下実施例−１と同様にして水分含有率５．１％の
粉末トコフェロール組成物４２１５９を１ｑた。920 g of δ-tocopherol 259.4η/9') and diacetyl tartrate monoglyceride (manufactured by Riken Vitamin KK,
20g of Poem W-10) were mixed at 50°C, and 1q of powdered tocopherol composition 42159 with a water content of 5.1% was prepared in the same manner as in Example-1.
実施例−４
タマリンド種子多糖類５Ｋｇ、キサンタンガム５００ｇ
、デンプン加水分解物（松谷化学ｋｋ製。Example-4 Tamarind seed polysaccharide 5Kg, xanthan gum 500g
, starch hydrolyzate (manufactured by Matsutani Chemical KK).
パインデックス＃ １ 、 Ｄ Ｅ ８．５ ） ６３
．４に９とシヨ糖脂肪酸エステル（三菱化成食品ｋｋ製
、リョートーシュガーエステルＰ−１６７０＞ １ Ｋ
ｇを水１００１に６０〜７０℃で溶解した。これに天然
ミックストコフェロール（Ｐトコフェロール７５８．３
η／９、トコフェロール組成：α−トコフェロール１８
．２η／ｇ、β、γ−トコフェロール５３２．６ ＪＩ
ｙ／９．δ−トコフェロール２０７．５η／ ｇ） ３
０Ｋｙとジアセチル酒石酸モノグリセリド（理研ビタミ
ンｋｋ製、ポエムＷ−１４＞ １００ ｇを６０℃で混
合−して加え、以下実施例−１と同様に処理して粉末ト
コフェロール１０７．９Ｎｙを得た。この粉末の水分含
有率は７．３％であった。Pine index #1, DE 8.5) 63
．． 4 to 9 and sucrose fatty acid ester (manufactured by Mitsubishi Kasei Foods KK, Ryoto Sugar Ester P-1670> 1K
g was dissolved in water 1001 at 60-70°C. This includes natural mixed tocopherols (P-tocopherol 758.3
η/9, tocopherol composition: α-tocopherol 18
．． 2η/g, β, γ-tocopherol 532.6 JI
y/9. δ-tocopherol 207.5η/g) 3
0Ky and diacetyl tartrate monoglyceride (manufactured by Riken Vitamin KK, Poem W-14> 100 g were mixed at 60°C and then treated in the same manner as in Example 1 to obtain powdered tocopherol 107.9 Ny. This powder The moisture content was 7.3%.
比較例−１
アラビアガム４００９．デンプン加水分解物（松谷化学
ｋｋ製、パインデックス＃ ２ ） １１４０ｇを水２
１に６０〜７０℃で溶解した。これに天然ミックストコ
フェロール（総トコフェロール９１５．７！Ｉｔｇ／ｇ
、 トコフェロール組成：α−トコフェロール１６．５
Ｉｎ！ｊ／ ９ 、β、ｒ−トコフェロール４０１．６
ＩＱ／ ９ 、δ−トコフエＯ−ル４９７．６Ｒ１／
ｇ＞ ４６０ ｇを７０℃に加温して加え、以下実施
例−１と同様にして粉末トコフェロール組成物（水分含
有率５．５％＞ ２１１６ｇを得た。Comparative Example-1 Gum Arabic 4009. 1140g of starch hydrolyzate (manufactured by Matsutani Chemical KK, Pine Index #2) in 2 parts water
1 at 60-70°C. This is combined with natural mixed tocopherols (total tocopherols 915.7!Itg/g)
, Tocopherol composition: α-tocopherol 16.5
In! j/9, β, r-tocopherol 401.6
IQ/9, δ-tocopherol 497.6R1/
g > 460 g was heated to 70°C and added thereto, and the same procedure as in Example 1 was carried out to obtain 2116 g of a powdered tocopherol composition (moisture content > 5.5%).
比較例−２
アラビアガム４００９．デンプン加水分解物（パインデ
ックス＃ ２ ） １０４０ｇ、マルトース１００ ｅ
ｊを水２１に６０〜７０℃で溶解した。これに比較例−
１で用いたトコフェロール４６０ ｇを７０℃に加温し
て加え、以下実施例−１と同様に処理して粉末トコフェ
ロール組成物２１５７ｇを得た。Comparative Example-2 Gum Arabic 4009. Starch hydrolyzate (Paindex #2) 1040g, maltose 100e
j was dissolved in water 21 at 60-70°C. Comparative example to this
460 g of the tocopherol used in Example 1 was heated to 70° C. and then treated in the same manner as in Example 1 to obtain 2157 g of a powdered tocopherol composition.
粉末の水分含有率は７．３％であった。The moisture content of the powder was 7.3%.
比較例−３
アラビアガム４００ｇ、デンプン加水分解物（パインデ
ックス＃ ２ ＞ １０８０ｇとシヨ糖脂肪酸エステル
（Ｓ−１５７０＞ ６０ｇを水２１に６０〜７０℃で溶
解した。これに比較例−１で使用した天然ミックストコ
フェロール４６０ ｇを７０℃に加温して加え、以下実
施例−１と同様に処理して粉末トコフェロール組成物（
水分含有率６．４％）２１３７ｇを得た。Comparative Example-3 400 g of gum arabic, starch hydrolyzate (Paindex #2 > 1080 g, and sucrose fatty acid ester (S-1570 > 60 g) were dissolved in water 21 at 60 to 70°C. Used in Comparative Example-1 460 g of natural mixed tocopherol was heated to 70°C and then treated in the same manner as in Example 1 to obtain a powdered tocopherol composition (
2137 g of water content (6.4%) was obtained.
比較例−４
アラビアガム４００ｇ、デンプン加水分解物（パインデ
ックス＃ ２ ＞ １０８０ｇを水２１に６０〜７０℃
で溶解した。これに比較例−１で用いたトコフェロール
４６０ ｇとジアセチル酒石酸モノグリセリド（ポエム
Ｗ−１４）６０ｇを７０℃で混合したものを加え、以下
実施例−１同様にして水分含有率５．７％の粉末トコフ
ェロール組成物２１２１９を得た。Comparative Example-4 400 g of gum arabic and starch hydrolyzate (Paindex #2 > 1080 g were added to 21 g of water at 60-70°C.
It was dissolved in To this was added a mixture of 460 g of tocopherol used in Comparative Example-1 and 60 g of diacetyl tartrate monoglyceride (Poem W-14) at 70°C, and the same procedure as in Example-1 was made to prepare a powder with a water content of 5.7%. Tocopherol composition 21219 was obtained.
実施例−１〜４および比較例−１〜４で得た粉末トコフ
ェロール組成物の水分散性を試験するため、２５℃の蒸
溜水、１０％食塩水、５％クエン酸水溶液（１）Ｈ２，
３＞を各２００ ｍｌ、ご−カー（直径８ ｃｍ ）に
入れ、マグネチックスターラー（撹拌子の長さ３ ｃｍ
＞によりｓｏｏｒｐｍの回転数で撹拌しておき、これ
に各粉末トコフェロール組成物４．０ｇを入れ、全てが
分散するのに要する時間を調べた。結果を表−１〜表−
３に示す。In order to test the water dispersibility of the powdered tocopherol compositions obtained in Examples 1 to 4 and Comparative Examples 1 to 4, 25°C distilled water, 10% saline, 5% citric acid aqueous solution (1) H2,
Put 200 ml of each of 3> into a stirrer (diameter 8 cm) and use a magnetic stirrer (stirring bar length 3 cm).
4.0 g of each powdered tocopherol composition was added to the mixture, and the time required for all of the tocopherol compositions to be dispersed was determined. The results are shown in Table-1 to Table-
Shown in 3.
これらの結果から本発明の効果が明確になる。These results clearly demonstrate the effects of the present invention.
表−１〜表−３の結果から明らかなように、トコフェロ
ール、ガム質、デンプン加水分解物からなる粉末トコフ
ェロール組成物を製造するにあたって、その粉末中にシ
ヨ糖脂肪酸エステルおよびジアセチル酒石酸モノグリセ
リドをそれぞれ０．１〜５重量部配合することによって
、いちじるしく水分散性にすぐれた粉末トコフェロール
組成物を得ることができる。また本発明により得られる
粉末トコフェロール組成物は塩類溶液中や酸性溶液中で
も分散性がすぐれているので、従来の技術で得られる粉
末トコフェロール組成物よりもその添加対象を拡大する
ことができる。As is clear from the results in Tables 1 to 3, when producing a powdered tocopherol composition consisting of tocopherol, gum, and starch hydrolyzate, sucrose fatty acid ester and diacetyl tartrate monoglyceride were added to the powder at zero concentrations, respectively. By blending .1 to 5 parts by weight, a powdered tocopherol composition with particularly excellent water dispersibility can be obtained. Furthermore, since the powdered tocopherol composition obtained by the present invention has excellent dispersibility even in salt solutions and acidic solutions, it can be added to a wider range of objects than powdered tocopherol compositions obtained by conventional techniques.
Claims (3)
シヨ糖脂肪酸エステルおよびジアセチル酒石酸モノグリ
セリドを必須成分とし、該シヨ糖脂肪酸エステルおよび
ジアセチル酒石酸モノグリセリドが夫々０．１〜５重量
部配合されていることを特徴とする粉末トコフェロール
組成物。(1) Tocopherol, gum, starch hydrolyzate,
1. A powdered tocopherol composition comprising sucrose fatty acid ester and diacetyl tartrate monoglyceride as essential components, and containing 0.1 to 5 parts by weight of each of the sucrose fatty acid ester and diacetyl tartrate monoglyceride.
キサンタンガム、グアーガムの１種または２種以上であ
る特許請求の範囲第１項記載の粉末トコフェロール組成
物。(2) Gum quality is gum arabic, tamarind seed polysaccharide,
The powdered tocopherol composition according to claim 1, which is one or more of xanthan gum and guar gum.
請求の範囲第１項記載の粉末トコフェロール組成物。(3) The powdered tocopherol composition according to claim 1, wherein the starch hydrolyzate has a DE value of 2 to 20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62130774A JPS63294760A (en) | 1987-05-27 | 1987-05-27 | Powdered tocopherol composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62130774A JPS63294760A (en) | 1987-05-27 | 1987-05-27 | Powdered tocopherol composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63294760A true JPS63294760A (en) | 1988-12-01 |
| JPH0473985B2 JPH0473985B2 (en) | 1992-11-25 |
Family
ID=15042346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62130774A Granted JPS63294760A (en) | 1987-05-27 | 1987-05-27 | Powdered tocopherol composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63294760A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0792585A1 (en) * | 1996-03-01 | 1997-09-03 | Kraft Foods, Inc. | Mouthfeel and lubricity enhancing composition |
| JP2010046002A (en) * | 2008-08-20 | 2010-03-04 | Ishikawa Prefecture | Oil-and-fat/carbohydrate powdery raw material comprising lipid soluble vitamin or lipid soluble vitamin-like substance, and method for producing the same |
-
1987
- 1987-05-27 JP JP62130774A patent/JPS63294760A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0792585A1 (en) * | 1996-03-01 | 1997-09-03 | Kraft Foods, Inc. | Mouthfeel and lubricity enhancing composition |
| JP2010046002A (en) * | 2008-08-20 | 2010-03-04 | Ishikawa Prefecture | Oil-and-fat/carbohydrate powdery raw material comprising lipid soluble vitamin or lipid soluble vitamin-like substance, and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0473985B2 (en) | 1992-11-25 |
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