JPS63280010A - Plaster for preventing armpit odor - Google Patents

Plaster for preventing armpit odor

Info

Publication number
JPS63280010A
JPS63280010A JP11558187A JP11558187A JPS63280010A JP S63280010 A JPS63280010 A JP S63280010A JP 11558187 A JP11558187 A JP 11558187A JP 11558187 A JP11558187 A JP 11558187A JP S63280010 A JPS63280010 A JP S63280010A
Authority
JP
Japan
Prior art keywords
plaster
odor
armpit
preventing
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11558187A
Other languages
Japanese (ja)
Inventor
Takashi Kishi
岸 高司
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP11558187A priority Critical patent/JPS63280010A/en
Publication of JPS63280010A publication Critical patent/JPS63280010A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain the titled plaster easily applicable to human body and effective in continuously preventing armpit odor, by applying a tacky adhesive layer containing cyclodextrins to at least one surface of a substrate consisting of a specific nonwoven cloth composed mainly of polyurethane fiber. CONSTITUTION:The objective plaster for preventing armpit odor is composed of a substrate having a tacky adhesive layer on at least one surface of the substrate, wherein said substrate is composed of a nonwoven cloth having an elongation of >=100%, preferably >=150% and composed mainly of polyurethane fiber and said tacky adhesive layer contains >=3wt.%, preferably >=5wt.% of cyclodextrin and/or its derivative. Armpit odor can be eliminated continuously over a long period by applying the plaster to the armpit of human body. The plaster is resistant to peeling off and is applicable without causing disagreeable feeling or paint to the skin nor causing stuffing of the skin because the substrate is stretchable according to the stretching of the skin and has moisture permeability. Furthermore, the plaster can be easily applied to and peeled off from the skin as necessary.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は9人体に簡単5適用され得、かつわきが臭の防
止が持続的になされ得るわきが臭防止用貼付剤に関する
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a patch for preventing armpit odor that can be easily applied to the human body and that can continuously prevent armpit odor.

(従来の技術) 人体の一部から発生する臭気の除去方法には。(Conventional technology) How to remove odors from parts of the human body.

入浴、清拭の他には、香料などによる臭気のマスキング
や中和がある。マスキングとは、除去すべき臭気に対し
1人間の嗅覚に比較的快く感じる奥を加え、そのことに
より臭気を目立たなくすることである。臭気の中和とは
、ある臭気に対して。
In addition to bathing and cleaning, there is also masking and neutralization of odors using fragrances. Masking is the process of adding depth to the odor to be removed that is relatively pleasant to the human sense of smell, thereby making the odor less noticeable. Odor neutralization refers to a certain odor.

他の種の臭気を加え、固有の臭気を弱めることである。The idea is to add odors from other species and weaken their own odors.

このような香料には9例えばバニラ、ジャスミン、Il
香等がある。しかし、これら臭気の除去方法は、臭気の
発生源を根本的に取り除くものではなく、一定時間を経
ると再び臭気が発生する。
Such fragrances include 9 e.g. vanilla, jasmine, Il.
There are scents etc. However, these odor removal methods do not fundamentally remove the source of the odor, and the odor will occur again after a certain period of time.

臭気物質をある種の物質と反応させて、無臭あるいは臭
気の弱い他の物質に変える方法もあるものの、この方法
でも長時間にわたる臭気除去はなされない、特に、わき
が臭のような他人に不快感を与える臭気については、持
続的な臭気除去(8〜10時間またはそれ以上)が望ま
れている。
Although there is a method of reacting odorous substances with certain substances to change them into odorless or weak odor substances, this method does not eliminate odors for a long time, especially when it causes discomfort to others such as armpit odor. For odors that provide odors, sustained odor removal (8-10 hours or more) is desired.

(発明が解決しようとする問題点) 本発明は、上記従来の問題点を解決するものであり、そ
の目的とするところは、わきが臭の除去が持続的になさ
れ得るわきが臭防止用貼付剤を提供することにある。本
発明の他の目的は、皮膚の屈伸に応じた伸縮性を有する
わきが臭防止用貼付剤を提供することにある。本発明の
さらに他の目的は、簡単に適用され得るわきが臭防止用
貼付剤を提供することにある0本発明のさらに他の目的
は、蒸れを生じないわきが臭防止用貼付剤を提供するこ
とにある。
(Problems to be Solved by the Invention) The present invention solves the above conventional problems, and its purpose is to provide a patch for preventing armpit odor that can continuously remove armpit odor. It is about providing. Another object of the present invention is to provide a patch for preventing armpit odor that has elasticity according to the bending and stretching of the skin. Still another object of the present invention is to provide a patch for preventing armpit odor that can be easily applied.A further object of the present invention is to provide a patch for preventing armpit odor that does not cause stuffiness. It is in.

(問題点を解決するための手段) 本発明は、香料などを用いる臭気のマスキングや中和と
いった従来のわきが臭除去方法に代えて。
(Means for Solving the Problems) The present invention replaces conventional methods of removing armpit odor, such as masking and neutralizing odor using fragrances.

わきが臭の臭気成分をシクロデキストリンに取り込ませ
ることにより、わきが臭が長時間にわたって持続的に除
去され得る。との発明者の知見にもとづいて完成された
By incorporating odor components of armpit odor into cyclodextrin, armpit odor can be continuously removed over a long period of time. It was completed based on the inventor's knowledge.

本発明のわきが臭防止用貼付剤は、基材および。The patch for preventing armpit odor of the present invention comprises a base material and a base material.

該基材の少なくとも片面に粘着剤層を有する貼付剤であ
って、該基材が、ポリウレタン繊維を主体としかつ10
0%以上の伸長性を有する不織布からなり、そして該粘
着剤層がシクロデキストリンおよび/またはその誘導体
を含有し、そのことにより上記目的が達成される。
A patch having an adhesive layer on at least one side of the base material, wherein the base material is mainly composed of polyurethane fibers and
It is made of a nonwoven fabric having an elongation of 0% or more, and the adhesive layer contains cyclodextrin and/or a derivative thereof, thereby achieving the above object.

シクロデキストリンは、6〜8個のD−グルコースがα
−1,4グルコシド結合したオリゴ糖である。シクロデ
キストリンはドーナツ状の分子であって、環状構造の中
心に空洞を有する。環の内側は疎水性であり、親油基を
有する化合物を取り込んで包接化合物を形成する0本発
明の発明者は。
Cyclodextrin has 6 to 8 D-glucose α
- It is an oligosaccharide with 1,4 glucosidic bonds. Cyclodextrin is a donut-shaped molecule with a cavity in the center of the cyclic structure. The inside of the ring is hydrophobic and incorporates a compound having a lipophilic group to form an clathrate.

シクロデキストリンのこのような性質を利用し。Taking advantage of these properties of cyclodextrin.

わきが臭の臭気成分を包接させて臭気を除去することを
考えた。
We thought of removing odor by including the odor components of armpit odor.

シクロデキストリンやシクロデキストリン製造過程は、
粘着剤層において、3重量%以上、好ましくは5重量%
以上の範囲で含有される。3重量%を下まわると、わき
が臭の除去が効果的になされない。シクロデキストリン
には、これを構成するグルコースの数により、α、β、
γ−シクロデキストリンの3種類の化合物がある0本発
明に用いられるシクロデキストリンは、上記化合物のい
ずれでもよく、またそれらの混合物でもよい。混合物と
しては、シクロデキストリン製造過程において、各タイ
プのシクロデキストリンに単離される前の混合物が挙げ
られる。この混合物の混合比は。
Cyclodextrin and the cyclodextrin manufacturing process are
In the adhesive layer, 3% by weight or more, preferably 5% by weight
It is contained within the above range. If it is less than 3% by weight, armpit odor will not be effectively removed. Cyclodextrin has α, β,
There are three types of γ-cyclodextrin compounds. The cyclodextrin used in the present invention may be any of the above compounds or may be a mixture thereof. The mixture includes a mixture before being isolated into each type of cyclodextrin in the cyclodextrin manufacturing process. What is the mixing ratio of this mixture?

α:β:γ−約fi:3:1 (重量比)である、しか
し、各タイプのシクロデキストリンを任意の比率で混合
した混合物も使用可能である。シクロデキストリン誘導
体には9例えば、シクロデキストリン骨格にマルトース
分子が1個〜数個で導入された化合物がある。
α:β:γ - about fi:3:1 (weight ratio), but mixtures of each type of cyclodextrin in any ratio can also be used. Examples of cyclodextrin derivatives include compounds in which one to several maltose molecules are introduced into a cyclodextrin skeleton.

基材に用いられる不織布の伸長性は、100%以上、好
ましくは150%以上の範囲とされる。伸長性が100
%を下まわると、得られた貼付剤が患部に応じた伸縮性
を有しな(なる、ここで、伸長性とは2弾性的に伸縮し
得る範囲内での1伸び率”(弾性的伸び率)を示す0弾
性的に伸縮し得る範囲とは、材料を伸ばした後、外力を
除くと完全に元の長さにまで回復し得る範囲を意味する
。ただし、材料により回復時間が異なるため9本発明で
は、伸長性を以下の方法により定義する。
The extensibility of the nonwoven fabric used for the base material is in the range of 100% or more, preferably 150% or more. Stretchability is 100
%, the obtained patch will not have the elasticity appropriate to the affected area (here, extensibility is defined as 1 elongation within the range where it can be elastically expanded or contracted). The elastically stretchable range means the range in which a material can completely recover to its original length after being stretched and the external force is removed.However, the recovery time varies depending on the material. Therefore, in the present invention, extensibility is defined by the following method.

幅20鶴で長さが80m以上の試験片を作製する。A test piece with a width of 20 squares and a length of 80 m or more is prepared.

この試験片の中央部分に50tm幅の標線を2本描く。Draw two marked lines with a width of 50 tm in the center of this test piece.

試験片を80m間隔の2点を支点として、それぞれ30
C11/分の速さで反対方向に引き伸ばす、あらかじめ
定めた長さにて引き伸ばしを停止し9次いで。
The test piece was placed at two points 80m apart as fulcrums, each with 30
Stretch in the opposite direction at a speed of C11/min, stop stretching at a predetermined length, and repeat 9 times.

30a1/分の速さで試験片を元に戻す。試験片が最初
の長さに戻った時点で停止し、外力を加えない状態で1
0分間放置する。放置後、試験片の標線の長さを測定す
る。引き伸ばし長を変えて、繰り返し試験を行い、標線
の伸び率が5%以内である最大の引き伸ばし長を求める
。この最大引き伸ばし長を元の試験片の長さと比較して
、試験片の伸び率を測定し、これをその材料の伸長性と
定義する。
Return the specimen at a rate of 30a1/min. Stop when the test piece returns to its initial length, and continue for 1 time without applying any external force.
Leave for 0 minutes. After standing, measure the length of the marked line of the test piece. Repeat the test by changing the stretching length, and find the maximum stretching length for which the elongation rate of the marked line is within 5%. This maximum stretched length is compared to the length of the original specimen to determine the elongation rate of the specimen, which is defined as the extensibility of the material.

粘着剤層に含有される粘着剤には0通常の感圧性接着剤
が用いられる。この感圧性接着剤は、粘着と再剥離とが
複数回にわたって可能な組成物とされる。この組成物の
Tgは、  −110〜10℃の範囲に含まれる。好ま
しい粘着剤には1例えば、 (メタ)アクリル酸エステ
ル(共)重合体系および。
An ordinary pressure-sensitive adhesive is used as the adhesive contained in the adhesive layer. This pressure-sensitive adhesive is a composition that can be adhered and re-peeled multiple times. The Tg of this composition is in the range of -110 to 10°C. Preferred adhesives include, for example, (meth)acrylate (co)polymer systems and.

天然ゴム、合成ゴム(IR,IIR,SBR,SISブ
ロックコポリマー、 SBSブロックコポリマーおよび
それらの混合物)、ポリビニルエーテル系組成物。
Natural rubber, synthetic rubber (IR, IIR, SBR, SIS block copolymers, SBS block copolymers and mixtures thereof), polyvinyl ether compositions.

水溶゛性高分子等を主成分とした系等がある。これらの
粘着剤には、必要に応じて、粘着性発現剤(軟化剤など
)が含有される。この粘着剤に水溶性高分子を添加すれ
ば8汗などの水分が吸収されるため、湿った表面への粘
着が可能となる。水溶性高分子には1例えば、グアーガ
ム、トラガントガム、カラヤガム、ペクチン、ポリビニ
ルピロリドン、ポリビニルアルコール、ポリアクリル酸
ナトリウム、カルボキシメチルセルロニスナトリウム。
There are systems whose main components are water-soluble polymers, etc. These adhesives contain a tackifier (such as a softener) as necessary. If a water-soluble polymer is added to this adhesive, moisture such as sweat will be absorbed, making it possible to adhere to damp surfaces. Examples of water-soluble polymers include guar gum, gum tragacanth, gum karaya, pectin, polyvinylpyrrolidone, polyvinyl alcohol, sodium polyacrylate, and sodium carboxymethylcellulonis.

カルボキシメチル化デンプンがある。There is carboxymethylated starch.

本発明のわきが臭防止用貼付剤は、使用前において、シ
クロデキストリンが大気中の他の臭気成分を包接しない
ように1通常、粘着剤層の表面に剥離性の保護紙または
フィルムが積層される。
Before using the patch for preventing armpit odor of the present invention, a removable protective paper or film is usually laminated on the surface of the adhesive layer to prevent the cyclodextrin from including other odor components in the atmosphere. Ru.

(実施例) 以下に本発明の実施例について述べる。(Example) Examples of the present invention will be described below.

実施班土 (1)粘着剤溶液の調製 アクリル酸2−エチルヘキシル、メタクリル酸イソブチ
ルおよびメタクリル酸を酢酸エチルに溶解し、溶液重合
させて下記組成のアクリル酸エステル系共重合体を調製
した。このアクリル酸エステル系共重合体は、酢酸エチ
ル中に30重量%の濃度で粘着剤溶液として提供された
Example 1: Preparation of adhesive solution 2-ethylhexyl acrylate, isobutyl methacrylate and methacrylic acid were dissolved in ethyl acetate and solution polymerized to prepare an acrylic ester copolymer having the following composition. This acrylic ester-based copolymer was provided as an adhesive solution in ethyl acetate at a concentration of 30% by weight.

アクリル酸2−エチルヘキシル   80重量%メタク
リル酸イソブチル      17重量%メタクリル酸
           3重量%この粘着剤溶液100
重量部に対し、シクロデキストリン混合物を3重量部で
加えた。このシクロデキストリン混合物中において、各
タイプのシクロデキストリンの混合比は、α:β:γ=
約6=3:1 (重量比)である。
2-Ethylhexyl acrylate 80% by weight Isobutyl methacrylate 17% by weight Methacrylic acid 3% by weight This adhesive solution 100
The cyclodextrin mixture was added in an amount of 3 parts by weight based on the weight part. In this cyclodextrin mixture, the mixing ratio of each type of cyclodextrin is α:β:γ=
The ratio is approximately 6=3:1 (weight ratio).

(2)貼付剤の作製 基材として、繊維の平均直径約150μ鋼、平均長約2
5鶴のポリエステル系ポリウレタン繊維からなる不織布
を用いた。この不織布の目付は約60g/ばであり、そ
の伸び率は約600%であった。
(2) As a base material for the preparation of the patch, the average diameter of the fibers is approximately 150μ, and the average length is approximately 2.
A nonwoven fabric made of 5 Tsuru polyester polyurethane fibers was used. The basis weight of this nonwoven fabric was approximately 60 g/ba, and its elongation rate was approximately 600%.

この基材に、イソプレン−メタクリル酸メチル(7:3
重量比)から成るグラフト重合体を約8g1rdの層厚
で塗工し、アンカー処理を行った。このアンカー処理層
に、(1)項で得た粘着剤溶液を。
Isoprene-methyl methacrylate (7:3
A graft polymer consisting of (weight ratio) was coated to a layer thickness of about 8g1rd, and anchor treatment was performed. Apply the adhesive solution obtained in section (1) to this anchor treatment layer.

シリコーン剥離紙を用いた転写塗工法により塗工し、約
60μs+厚の粘着剤r層を形成した。得られた貼付剤
は9例えば、lQaaX5cmの大きさに切断され、使
用に供される。使用時には、シリコーン剥離紙が剥離さ
れる。この貼付剤を1人体の腋窩部に貼付したところ、
30時間以上にわたってわきが臭の除去がなされた。し
かも、この貼付剤は、皮膚の屈伸に応じて伸縮し、剥離
することはなかった。貼付剤による蒸れも生じなかった
Coating was performed by a transfer coating method using silicone release paper to form an adhesive R layer with a thickness of approximately 60 μs. The obtained patch is cut into a size of, for example, 1QaaX5cm, and used. In use, the silicone release paper is peeled off. When this patch was applied to the axillary region of a human body,
Underarm odor was removed for over 30 hours. Furthermore, this patch expanded and contracted in accordance with the bending and stretching of the skin, and did not peel off. There was no stuffiness caused by the patch.

裏1貫主 (1)粘着剤溶液の調製 合成ポリイソプレンゴム(IR,IR−2200,日本
合成ゴム社製)90重量部 スチレン−イソプレン−スチレンブロック共重合体(S
IS、 E−2359、住友化学社製)10重量部ポリ
−β−ピネン樹脂(軟化点110℃)70重量部 スクワラン            25重量部2.6
−ジ(t−ブチル)クレゾール 1重量部1グリチルレ
チン         0.5重量部上記処方を混合し
た後、シクロヘキサンに溶解して、18%の粘着剤溶液
を調製した。この粘着剤溶液100重量部に対し、実施
例1と同じシクロデキストリン混合物を2.5重量部の
割合で加えた。
Back 1 Main (1) Preparation of adhesive solution Synthetic polyisoprene rubber (IR, IR-2200, manufactured by Japan Synthetic Rubber Co., Ltd.) 90 parts by weight Styrene-isoprene-styrene block copolymer (S
IS, E-2359, manufactured by Sumitomo Chemical Co., Ltd.) 10 parts by weight Poly-β-pinene resin (softening point 110°C) 70 parts by weight Squalane 25 parts by weight 2.6
- Di(t-butyl)cresol 1 part by weight 1 Glycyrrhetinn 0.5 part by weight The above formulations were mixed and then dissolved in cyclohexane to prepare an 18% adhesive solution. To 100 parts by weight of this adhesive solution, 2.5 parts by weight of the same cyclodextrin mixture as in Example 1 was added.

(2)貼付剤の作製 実施例1と同様の基材を用いた。この基材上に。(2) Preparation of patch The same base material as in Example 1 was used. on this base material.

(1)項で得た粘着剤溶液を、実施例1と同様の方法に
より塗工して、約70μ鋼厚の粘着剤層を形成した。得
られた貼付剤は9例えば、lQcmX5amの大きさに
切断され、使用に供される。使用時には。
The adhesive solution obtained in section (1) was applied in the same manner as in Example 1 to form an adhesive layer with a thickness of approximately 70 μm. The obtained patch is cut into a size of 9, for example, 1Qcm x 5am, and is ready for use. when in use.

シリコーン剥離紙が剥離される。この貼付剤を。The silicone release paper is peeled off. This patch.

人体の腋窩部に貼付したところ、30時間以上にわたっ
てわきが臭の除去がなされた。しかも、この貼付剤は、
皮膚の屈伸に応じて伸縮し、剥離することはなかった。
When applied to the armpits of the human body, armpit odor was removed for over 30 hours. Moreover, this patch
It expanded and contracted according to the bending and stretching of the skin, and did not peel off.

貼付剤による蒸れも生じなかった。There was no stuffiness caused by the patch.

(発明の効果) 本発明のわきが臭防止用貼付剤は、このように。(Effect of the invention) The patch for preventing armpit odor of the present invention is as follows.

粘着剤層にシクロデキストリンを含有するため。Because the adhesive layer contains cyclodextrin.

これを人体の腋窩部に貼付すれば、わきが臭の臭気除去
が持続的になされる。わきが臭は0例えば。
If this is applied to the armpit area of the human body, armpit odor will be removed continuously. For example, my armpit odor is 0.

30時間以上の長時間にわたって除去され得る。しかも
、この貼付剤は、基材が伸長性を有するポリウレタン繊
維でなるため、皮膚の屈伸に応じて伸縮し、容易に剥離
しない、貼付した皮膚に異和感や痛みを与えることもな
い、貼付剤の基材が水分を透過させ得るため、蒸れも生
じない、この貼付剤は、簡単に適用され、必要に応じて
容易に剥離し得る。その結果9本発明のわきが臭防止用
貼付剤によれば、わきが臭の除去が効果的になされる。
It can be removed for long periods of time, such as 30 hours or more. Moreover, since the base material of this patch is made of stretchable polyurethane fibers, it expands and contracts according to the bending and stretching of the skin, does not peel off easily, and does not cause any discomfort or pain to the skin to which it is applied. The patch, which also does not cause stuffiness because the agent's base is permeable to moisture, is easy to apply and can be easily removed if necessary. As a result, according to the patch for preventing armpit odor of the present invention, armpit odor can be effectively removed.

以上that's all

Claims (1)

【特許請求の範囲】 1、基材および、該基材の少なくとも片面に粘着剤層を
有する貼付剤であって、 該基材が、ポリウレタン繊維を主体としかつ100%以
上の伸長性を有する不織布からなり、そして、該粘着剤
層が、シクロデキストリンおよび/またはその誘導体を
含有するわきが臭防止用貼付剤。 2、前記シクロデキストリンおよび/またはその誘導体
が、前記粘着剤層にて3重量%以上の割合で含有された
特許請求の範囲第1項に記載のわきが臭防止用貼付剤。
[Scope of Claims] 1. A patch having a base material and an adhesive layer on at least one side of the base material, wherein the base material is a nonwoven fabric mainly composed of polyurethane fibers and having elongation of 100% or more. A patch for preventing armpit odor, wherein the adhesive layer contains cyclodextrin and/or a derivative thereof. 2. The patch for preventing armpit odor according to claim 1, wherein the cyclodextrin and/or its derivative is contained in the adhesive layer in a proportion of 3% by weight or more.
JP11558187A 1987-05-12 1987-05-12 Plaster for preventing armpit odor Pending JPS63280010A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11558187A JPS63280010A (en) 1987-05-12 1987-05-12 Plaster for preventing armpit odor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11558187A JPS63280010A (en) 1987-05-12 1987-05-12 Plaster for preventing armpit odor

Publications (1)

Publication Number Publication Date
JPS63280010A true JPS63280010A (en) 1988-11-17

Family

ID=14666131

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11558187A Pending JPS63280010A (en) 1987-05-12 1987-05-12 Plaster for preventing armpit odor

Country Status (1)

Country Link
JP (1) JPS63280010A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0474107A (en) * 1990-05-15 1992-03-09 Sunstar Inc Cosmetic composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0474107A (en) * 1990-05-15 1992-03-09 Sunstar Inc Cosmetic composition

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