JPS63271893A - Driving of electrochromic element - Google Patents

Driving of electrochromic element

Info

Publication number
JPS63271893A
JPS63271893A JP62105420A JP10542087A JPS63271893A JP S63271893 A JPS63271893 A JP S63271893A JP 62105420 A JP62105420 A JP 62105420A JP 10542087 A JP10542087 A JP 10542087A JP S63271893 A JPS63271893 A JP S63271893A
Authority
JP
Japan
Prior art keywords
coloring
voltage
gradually
discoloring
decreasing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62105420A
Other languages
Japanese (ja)
Inventor
Atsushi Minoura
淳 箕浦
Nariyuki Takahashi
高橋 成幸
Toshiyasu Ito
伊藤 敏安
Hisayoshi Kato
久喜 加藤
Katsuaki Okabayashi
岡林 克明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyoda Gosei Co Ltd
Toyota Central R&D Labs Inc
Original Assignee
Toyoda Gosei Co Ltd
Toyota Central R&D Labs Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyoda Gosei Co Ltd, Toyota Central R&D Labs Inc filed Critical Toyoda Gosei Co Ltd
Priority to JP62105420A priority Critical patent/JPS63271893A/en
Priority to US07/176,708 priority patent/US5007718A/en
Publication of JPS63271893A publication Critical patent/JPS63271893A/en
Pending legal-status Critical Current

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  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

PURPOSE:To improve uniformity of coloring and discoloring, and to lengthen life of an electrochromic element as well as to prevent spotting, irregular coloring, and peeling of the element by gradually increasing or decreasing an impressed voltage to the element. CONSTITUTION:When coloring, a voltage gradually increasing action with a voltage gradually increasing and decreasing circuit 16 is made to start with a transfer switch 17 switched to the coloring side, and an impressed voltage to an electrochromic element 3 is made to gradually increase. When discoloring, a voltage gradually decreasing action of the circuit 16 is made to start with the switch 17 switched to the discoloring side, and the impressed voltage to the element 3 is made to gradually decrease. A coloring and discoloring speeds in the peripheral and center parts can be uniformalized, and life is lengthened with spotting and irregular coloring of the element eliminated and peeling of the peripheral part prevented even in the large size electrochromic element by relaxing flowing of an excess electricity quantity to the peripheral part of the element 3 by such voltage impressing method.

Description

【発明の詳細な説明】 発明の目的 (産業上の利用分野) 本発明はエレクトロクロミック素子の駆動方法に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION Object of the Invention (Field of Industrial Application) The present invention relates to a method for driving an electrochromic device.

(従来の技術及び発明が解決しようとする問題点)エレ
クトロクロミック(以下、ECという。)素子の通常の
駆動方法は、第3図に示すように着色時に所定の定電圧
を急に印加し、潤色時に逆の定電圧を急に印加するとい
うものであるから、結局EC素子は矩形状の定電圧によ
って駆動されているといえる。面積の小さいEC素子(
例えば、100cffl以下)はこの方法によって良好
に駆動することができる。
(Prior art and problems to be solved by the invention) A normal method for driving an electrochromic (hereinafter referred to as EC) element is to suddenly apply a predetermined constant voltage during coloring, as shown in FIG. Since a reverse constant voltage is suddenly applied during color embellishment, it can be said that the EC element is driven by a rectangular constant voltage. Small area EC element (
For example, 100 cffl or less) can be favorably driven by this method.

ところが、面積の大きいEC素子(例えば、100Cd
以上)を上記方法によって駆動すると、第3図に光透過
事変化を比較して示すように、着色時にEC素子の周辺
部が急に濃く着色してから中央部が徐々に着色してゆく
という問題が顕在化する。なぜなら、EC素子は容口性
を持っているため、第3図に示すように矩形状の電圧の
立上がり時には過大なラッシュカレントが流れることに
なり、ざらにEC素子に用いられている透明電極は面抵
抗が大きいので、その電極取出し部でおる周辺部に前記
ラッシュカレントが集中して過剰な電気量が注入される
からである。
However, EC elements with large areas (for example, 100Cd
When the above) is driven by the above method, as shown in Figure 3 for comparison of light transmission, the peripheral part of the EC element suddenly becomes darkly colored during coloring, and then the central part gradually becomes colored. A problem becomes apparent. This is because EC elements have porosity, so when a rectangular voltage rises, an excessive rush current flows, as shown in Figure 3, and the transparent electrodes used in EC elements This is because, since the sheet resistance is large, the rush current is concentrated in the periphery of the electrode lead-out portion, and an excessive amount of electricity is injected.

また、潤色時にはEC素子の周辺部から急に消色してゆ
くという同様の問題が起こる。
Further, when coloring is applied, a similar problem occurs in that the color suddenly disappears from the periphery of the EC element.

ざらに、前記周辺部への過剰電気損の注入が繰り返され
ると、同周辺部にじみや色むらが残ったり、同周辺部が
剥離したりして、EC素子の寿命が短くなるという不具
合もある。
Furthermore, if excessive electrical loss is repeatedly injected into the peripheral area, bleeding or uneven coloring may remain in the peripheral area, or the peripheral area may peel off, resulting in problems such as shortening the life of the EC element. .

発明の構成 (問題点を解決するための手段) そこで、本発明は前記問題点を解決するために、EC素
子への印加電圧を漸増又は漸減させて同EC素子を着色
又は消色するという技術的手段をとった。
Structure of the Invention (Means for Solving the Problems) Therefore, in order to solve the above-mentioned problems, the present invention provides a technique for coloring or decolorizing the EC elements by gradually increasing or decreasing the voltage applied to the EC elements. I took appropriate measures.

(作用) まず、EC素子を着色さけるには、同EC素子への印加
電圧を漸増させる。すると、印加電圧は徐々に増加する
から、EC素子は容a性負荷であるにも拘らず、同EC
素子への電流も徐々に増加することとなり、ラッシュカ
レントが防止される。
(Function) First, in order to avoid coloring the EC element, the voltage applied to the EC element is gradually increased. Then, since the applied voltage gradually increases, even though the EC element is a capacitive load, the same EC
The current to the element also increases gradually, and rush current is prevented.

従って、EC素子の周辺部への過剰な電気量の注入が緩
和され、EC素子の周辺部はその着色速度が減少して中
央部とともに徐々に着色する。
Therefore, injection of an excessive amount of electricity to the peripheral portion of the EC element is alleviated, and the coloring speed of the peripheral portion of the EC element decreases, and the peripheral portion of the EC element is gradually colored together with the central portion.

次に、EC素子を消色させるには、同EC素子への印加
電圧を漸減させる。すると、印加電圧は徐々に減少する
から、着色時と同様、ラッシュカレントが防止される。
Next, in order to decolor the EC element, the voltage applied to the EC element is gradually decreased. Then, since the applied voltage gradually decreases, rush current is prevented as in the case of coloring.

従って、EC素子の周辺部への過剰な電気量の注入が緩
和され、EC素子の周辺部はその消色速度が減少して中
央部とともに徐々に消色する。
Therefore, injection of an excessive amount of electricity into the periphery of the EC element is alleviated, and the decoloring speed of the periphery of the EC element decreases, and the color gradually disappears along with the central part.

(実施例) 以下、本発明を自動車のサンルーフ用のEC素子に具体
化した実施例を第1図及び第2図に従って説明する。
(Example) Hereinafter, an example in which the present invention is embodied in an EC element for an automobile sunroof will be described with reference to FIGS. 1 and 2.

第1図に示すように、本実施例のEC調光板としてのサ
ンルーフ1は寸法700mX 500mX2.5Mの強
化無機ガラス板よりなる上部及び下部の基板2a、 2
bと、それらの間に形成され透過モードで使用される電
極間寸法400mX400m(セル面積1600cff
l)のEC素子3とにより構成されている。
As shown in FIG. 1, a sunroof 1 as an EC dimming plate of this embodiment has upper and lower substrates 2a and 2 made of reinforced inorganic glass plates with dimensions of 700m x 500m x 2.5M.
b, and the interelectrode size 400m x 400m formed between them and used in transmission mode (cell area 1600cff
The EC element 3 shown in FIG.

前記EC素子3は、 ■ 上部基板2aの下面に形成された厚さ約2000A
のITO(インジウムスズ酸化物)膜よりなる上部透明
電極4、 ■ 同上部透明電極4の下面に電解重合により形成され
た厚さ約6000Aのポリアニリン膜よりなる酸化発色
層5、 ■ 下部基板2bの上面に形成された厚さ約2000A
のITO膜よりなる下部透明電極8、■ 同下部透明電
極8の上面に積層された厚さ約6000Aの酸化タング
ステン膜よりなる還元発色層7、及び、 ■ 両基板2a、2b間を一定間隔に支持するスペー+
J 9 aと前記酸化発色層5と還元発色層7との間に
満たされた、ポリエチレンオキサイドと1M  LiC
lO4/プロピレンカーボネイトとが1:6で配合され
てなるゲル状電解質のイオン供与体層6 の積層物からなり、同EC素子3の周囲はエポキシ樹脂
よりなる硬質の封止材9bによって封止されている。前
記上部及び下部の基板2a、2b上の透明電極4,8は
約200/口の面抵抗を有し、それらの−側部には導電
ペースト10.11が塗布され、同導電ペースト10.
11に駆動電圧印加用のリード線12.13がはんだ付
けされている。
The EC element 3 has a thickness of approximately 2000 Å formed on the lower surface of the upper substrate 2a.
an upper transparent electrode 4 made of an ITO (indium tin oxide) film, ■ an oxidized coloring layer 5 made of a polyaniline film with a thickness of about 6000 A formed by electrolytic polymerization on the lower surface of the upper transparent electrode 4, and ■ a lower substrate 2b. Approximately 2000A thick formed on the top surface
A lower transparent electrode 8 made of an ITO film, ■ A reduction coloring layer 7 made of a tungsten oxide film with a thickness of about 6000 A laminated on the upper surface of the lower transparent electrode 8, and ■ A constant interval between both substrates 2a and 2b. Supporting space+
J 9 a, polyethylene oxide and 1M LiC filled between the oxidation coloring layer 5 and the reduction coloring layer 7
It consists of a laminate of an ion donor layer 6 made of a gel electrolyte with a ratio of lO4/propylene carbonate in a ratio of 1:6, and the EC element 3 is surrounded by a hard sealing material 9b made of epoxy resin. ing. The transparent electrodes 4, 8 on the upper and lower substrates 2a, 2b have a sheet resistance of about 200/hole and are coated with a conductive paste 10.11 on their negative sides.
Lead wires 12 and 13 for applying a driving voltage are soldered to 11.

次に、EC素子3を駆動するための電源14について説
明すると、第1図に示すように同電源14はバッテリ、
オルタネータ、ダイナモ等(交流源による場合は変圧ト
ランス、整流回路、平滑回路等も含む)の電力供給源1
5と、EC素子3への印加電圧を所定電圧から別の所定
電圧まで漸増させ、ざらに同じく漸減させるための電圧
漸増漸減回路16と、同回路16における電圧漸増(着
色側)と電圧漸減(潤色側)を切替えるための切替スイ
ッチ17とを備えている。前記電圧漸増漸減回路16に
は例えば長周期三角波発娠回路を利用することができる
Next, the power source 14 for driving the EC element 3 will be explained. As shown in FIG. 1, the power source 14 is a battery,
Power supply source 1 for alternators, dynamos, etc. (including transformers, rectifier circuits, smoothing circuits, etc. when using AC sources)
5, a voltage gradual increase/decrease circuit 16 for gradually increasing the voltage applied to the EC element 3 from a predetermined voltage to another predetermined voltage, and roughly decreasing the voltage in the same way; It is equipped with a changeover switch 17 for changing over the embellished color side. For example, a long-period triangular wave generation circuit can be used as the voltage gradual increase/decrease circuit 16.

本実施例の電源14は、着色時に印加電圧をO■から1
.4vまで約20秒間で直線的に漸増させた後、1.4
Vで一定化させる一方、潤色時にO■から−2,1vま
で約20秒で直線的に漸減させた後、−2,1Vで一定
化させるように調整・設定されており、一旦EC素子3
が所定の濃度に達した後は電源を開放状態として、EC
素子3のメモリ性によりその濃度を一定に保持する。
The power supply 14 of this embodiment changes the applied voltage from O to 1 during coloring.
.. After increasing linearly to 4v in about 20 seconds, 1.4
While keeping it constant at V, it is adjusted and set so that it gradually decreases linearly from O to -2.1V in about 20 seconds during embellishment, and then becomes constant at -2.1V, and once the EC element 3
After reaching the predetermined concentration, the power supply is opened and the EC
The memory property of the element 3 keeps its concentration constant.

そして、電源14の出力端子にリード線12゜13を介
してEC素子3の上部及び下部の透明電極4.8が接続
されている。
The upper and lower transparent electrodes 4.8 of the EC element 3 are connected to the output terminal of the power source 14 via lead wires 12.about.13.

続いて、前記電源14によるEC素子3の駆動方法につ
いて説明する。
Next, a method of driving the EC element 3 using the power source 14 will be explained.

■ 着色時 まず、切替スイッチ17を着色側に投入して、電源14
の電圧漸増漸減回路16による電圧漸増作用を開始させ
、EC素子3への印加電圧を漸増させる。
■ When coloring, first turn on the selector switch 17 to the coloring side and turn on the power supply 14.
The voltage gradual increase/decrease circuit 16 starts the voltage gradual increase action, and the voltage applied to the EC element 3 is gradually increased.

すると、第2図に示すように印加電圧はOVから1.4
■まで約20秒かけて徐々に増加するから、EC素子3
は各回性負荷であるにも拘らず、同EC素子3への電流
も第2図に示すように徐々に増加することとなり、ラッ
シュカレントが防止される。
Then, as shown in Figure 2, the applied voltage increases from OV to 1.4
EC element 3 increases gradually over about 20 seconds until ■.
Although is a circular load, the current to the EC element 3 also gradually increases as shown in FIG. 2, and rush current is prevented.

従って、前述したようなEC素子3の周辺部への過剰な
電気量の注入が緩和され、第2図に光透通事変化を比較
して示すように、EC素子3の周辺部はその着色速度が
減少して中央部とともに徐々に着色する。
Therefore, the injection of an excessive amount of electricity into the periphery of the EC element 3 as described above is alleviated, and as shown in FIG. The speed decreases and the color gradually increases along with the center.

着色電圧印加時から約20秒が経過するとEC素子3へ
の印加電圧は1.4■で一定になり、やがてEC素子3
における酸化還元反応が飽和するため、光透過率は周辺
部でも中央部でも約20%まで低下して着色度がほぼ定
常状態となる。
When about 20 seconds have passed since the coloring voltage was applied, the voltage applied to the EC element 3 becomes constant at 1.4■, and soon the EC element 3
Since the redox reaction in the area is saturated, the light transmittance decreases to about 20% in both the peripheral and central areas, and the degree of coloring becomes almost steady.

■ 潤色時 前記切替スイッチ17投入から約30秒経過したとき、
同切替スイッチ17を潤色側に切替えて、電源14の電
圧漸増漸減回路16による電圧漸減作用を開始させ、E
C素子3への印加電圧を漸減させる。
■ When about 30 seconds have passed since the changeover switch 17 was turned on during embellishment,
Switch the changeover switch 17 to the embellishing side to start the voltage gradual decrease action by the voltage gradual increase gradual decrease circuit 16 of the power supply 14,
The voltage applied to the C element 3 is gradually decreased.

すると、第2図に示すように印加電圧はOVから−2,
1vまで約20秒かけて徐々に減少するから、着色時と
同様、ラッシュカレントが防止される。
Then, as shown in Figure 2, the applied voltage decreases from OV to -2,
Since the voltage gradually decreases to 1 V over about 20 seconds, rush current is prevented as in the case of coloring.

従って、前述したようなEC素子3の周辺部への過剰な
電気量の注入が緩和され、第2図に比較して示すように
、EC素子3の周辺部はその潤色速度が減少して中央部
とともに徐々に消色する。
Therefore, the excessive amount of electricity injected into the peripheral part of the EC element 3 as described above is alleviated, and as shown in comparison with FIG. The color gradually fades over time.

着色電圧印加時から約20秒が経過するとEC素子3へ
の印加電圧は“−2,1Vで一定になり、やがてEC素
子3における酸化還元反応が飽和するため、光透過率は
周辺部でも中央部でも約78%まで増加して潤色度がほ
ぼ定常状態となる。
After approximately 20 seconds have elapsed since the application of the coloring voltage, the voltage applied to the EC element 3 becomes constant at -2.1V, and the redox reaction in the EC element 3 eventually becomes saturated, so that the light transmittance changes even in the periphery as well as in the center. %, it increases to about 78%, and the degree of embellishment becomes almost steady state.

上記の通り、本実施例によればEC素子3周辺部への過
剰な電気量の注入が防止され、これにより同周辺部の過
剰な酸化還元反応による着消色が防止されるので、着色
又は潤色が進んで定常状態になったときの着色度又は潤
色度の均一性が向上する。
As described above, according to this embodiment, injection of an excessive amount of electricity into the peripheral area of the EC element 3 is prevented, and thereby coloring or decoloring due to excessive redox reaction in the peripheral area is prevented. The degree of coloring or the uniformity of the degree of embellishment improves when the embellishment progresses and reaches a steady state.

また、着色及び消色が繰り返されても、同周辺部にじみ
や色むらが残ったり、同周辺部が劣化して剥離したりす
ることがなく、EC素子の野命を延ばすこともできる。
Further, even if coloring and decoloring are repeated, bleeding or uneven coloring will not remain in the peripheral area, nor will the peripheral area deteriorate and peel, thereby extending the life of the EC element.

なお、本発明は前記実施例の構成に限定されるものでは
なく、例えば以下のように発明の趣旨から逸脱しない範
囲で任意に変更して具体化することもできる。
It should be noted that the present invention is not limited to the configuration of the above-mentioned embodiments, and may be modified and embodied as desired without departing from the spirit of the invention, for example, as described below.

(1) 本発明は特に100CId以上の面積のEC素
子の駆動方法とじてに具体化するとその効果が著しいが
、勿論それ以下の面積のEC素子に具体化することもで
きる。
(1) The present invention is particularly effective when embodied as a method for driving an EC element with an area of 100 CId or more, but it can of course be embodied in an EC element with an area smaller than that.

(2)  EC素子3への印加電圧の漸増又は漸減は時
間に対して曲線的に変化するものでもよい。
(2) The voltage applied to the EC element 3 may be gradually increased or decreased in a curved manner with respect to time.

(3) 液体タイプ又は全固体タイプのEC素子に具体
化したり、反射モードのEC素子に具体化したりするこ
ともできる。
(3) It can be implemented as a liquid type or all solid type EC element, or as a reflection mode EC element.

発明の効果 以上詳述したように、本発明はEC素子の着色度及び潤
色度の均一性を向上させることができるばかりでなく、
EC素子のしみ、色むら及び剥離を防止して寿命を延ば
すこともできるという優れた効果を奏する。
Effects of the Invention As detailed above, the present invention not only improves the uniformity of the degree of coloring and embellishment of the EC element, but also
It has the excellent effect of preventing stains, color unevenness, and peeling of the EC element and extending its life.

【図面の簡単な説明】[Brief explanation of the drawing]

第1.2図は本発明を具体化した実施例を示し、第1図
はEC素子とその駆動方法に使用する電源を示す全体概
略図、第2図は同電源によりEC素子に印加される電圧
、EC素子に流れる電流、及び、EC素子の周辺部及び
中央部の光透過率の時間的変化を示すタイムチャート図
である。また、第3図は従来例における電圧、電流及び
光透過率の時間的変化を示すタイムチャート図でおる。 3・・・エレクトロクロミック(EC’)素子、14・
・・電源、16・・・電圧漸増漸減回路。 特許出願人     豊田合成 株式会社株式会社 豊
田中央研究所 代 理 人   弁理士  恩1)博宣2m 口■5d手棒売辛市正豐十 1.事イ1切翫 昭和62年ネ話γ願第105420−号2、発明の名称 エレクトロクロミック素子の駆動方法 3、7+It+Iiをする者 事件との関係: 特許出願人 住 所   愛美1県西春[J井郡春日村大字落合字長
畑1番地氏 名   嗣田合成株式会社 (名 称)   代表者根本 正夫 住 所   愛知県愛別11り長久手町大字長漱字横道
41番地の1氏名  株式会社ff、lII中央研究所
(名称)   代表者小松登 4、代理人 住所 〒500  岐阜市端詰町2番装置、  058
2 (65) −1810(イ夫ΣI乏)ファックス専
用 0582 (66)−1339第2図
Figure 1.2 shows an embodiment embodying the present invention, Figure 1 is an overall schematic diagram showing the EC element and the power source used for its driving method, and Figure 2 shows the power applied to the EC element by the same power source. FIG. 3 is a time chart showing temporal changes in voltage, current flowing through the EC element, and light transmittance at the peripheral and central parts of the EC element. Further, FIG. 3 is a time chart showing temporal changes in voltage, current, and light transmittance in the conventional example. 3... Electrochromic (EC') element, 14.
...Power supply, 16...voltage gradual increase gradual decrease circuit. Patent Applicant Toyoda Gosei Co., Ltd. Toyota Central Research Institute Co., Ltd. Agent Patent Attorney On 1) Hironobu 2m Mouth ■ 5d Tebo Selling Shinichi Masafyo 11. Matter 1: 1986 Application No. 105420-2 Name of the invention: Method of driving an electrochromic device 3, 7 + It + Ii Relationship with the case: Patent applicant address Nishiharu, Aimi 1 prefecture [Ji] 1, Nagahata, Ochiai, Kasuga Village, Kasuga Village Name: Tsuguta Gosei Co., Ltd. (Name) Representative: Masao Nemoto Address: 1, 41, Yokomichi, Nagato, Nagakute-machi, Aibetsu, Aichi Prefecture ff, lII Central Research Co., Ltd. Place (name) Representative Noboru Komatsu 4, Agent address 058, No. 2 Hatazume-cho, Gifu City, 500
2 (65) -1810 (Ifu ΣI poor) Fax only 0582 (66) -1339 Figure 2

Claims (1)

【特許請求の範囲】[Claims] 1.エレクトロクロミック素子への印加電圧を漸増又は
漸減させて同エレクトロクロミック素子を着色又は消色
することを特徴とするエレクトロクロミック素子の駆動
方法。
1. 1. A method for driving an electrochromic device, which comprises gradually increasing or decreasing a voltage applied to the electrochromic device to color or decolor the electrochromic device.
JP62105420A 1987-04-02 1987-04-28 Driving of electrochromic element Pending JPS63271893A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP62105420A JPS63271893A (en) 1987-04-28 1987-04-28 Driving of electrochromic element
US07/176,708 US5007718A (en) 1987-04-02 1988-04-01 Electrochromic elements and methods of manufacturing and driving the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62105420A JPS63271893A (en) 1987-04-28 1987-04-28 Driving of electrochromic element

Publications (1)

Publication Number Publication Date
JPS63271893A true JPS63271893A (en) 1988-11-09

Family

ID=14407107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62105420A Pending JPS63271893A (en) 1987-04-02 1987-04-28 Driving of electrochromic element

Country Status (1)

Country Link
JP (1) JPS63271893A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007139899A (en) * 2005-11-15 2007-06-07 Toshiba Corp Display device and display element driving method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007139899A (en) * 2005-11-15 2007-06-07 Toshiba Corp Display device and display element driving method

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