JPS6326962A - Stop and storing method for fuel cell - Google Patents
Stop and storing method for fuel cellInfo
- Publication number
- JPS6326962A JPS6326962A JP60184979A JP18497985A JPS6326962A JP S6326962 A JPS6326962 A JP S6326962A JP 60184979 A JP60184979 A JP 60184979A JP 18497985 A JP18497985 A JP 18497985A JP S6326962 A JPS6326962 A JP S6326962A
- Authority
- JP
- Japan
- Prior art keywords
- air
- line
- fuel
- cell
- battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims description 9
- 238000001816 cooling Methods 0.000 claims abstract description 15
- 239000002737 fuel gas Substances 0.000 claims abstract description 15
- 238000007789 sealing Methods 0.000 claims abstract 2
- 239000003792 electrolyte Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005273 aeration Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04228—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
- H01M8/04303—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during shut-down
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04097—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
Description
【発明の詳細な説明】
本発明は、燐酸電解質を用いる燃料電池特に可搬用小型
電池の停止保存方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for shutting down and storing a fuel cell, particularly a small portable battery, using a phosphoric acid electrolyte.
燃料電池の運転停止に際し、従来は外気の強制流通によ
り電池温度を下げてから、電池及び経路内の各反応ガス
を窒素ガスで置換するため窒素パージを行なうと共に電
気ヒータにより110℃〜120°C程度に保温し、保
存状態に入っていた。このように保存時窒素パージ及び
保温を行なう目的は、電池の安全性確保と電解質の変質
防止のためである。When shutting down a fuel cell, conventionally, the cell temperature is lowered by forced circulation of outside air, and then a nitrogen purge is performed to replace the cell and each reaction gas in the path with nitrogen gas, and an electric heater is used to lower the cell temperature to 110°C to 120°C. It was kept warm and preserved. The purpose of nitrogen purging and heat retention during storage is to ensure the safety of the battery and to prevent deterioration of the electrolyte.
しかしながら、可搬用電池(数KW〜数10KW出力)
の使用場所は、商用′Wt、/lX及び窒素ガスがない
場であり、従来のような窒素パージを行ないつつ電気で
保温することは不可能となる。However, portable batteries (several KW to several tens of KW output)
The place where this is used is where commercial 'Wt, /lX and nitrogen gas are not available, and it is impossible to keep it warm by electricity while performing the conventional nitrogen purge.
この発明は、燃料電池の保存時、電気による保温及び窒
素ガスによるパージを行なうことなく、保存・を可能と
する方法を提供するものである。The present invention provides a method that allows fuel cells to be stored without having to be kept warm by electricity or purged with nitrogen gas.
この発明は、電池停止に際し、反応空気系及び冷却空気
系に外部新鮮空気を7.を通しつつ、燃料ガスの供給を
遮断した状態で、放電反応により燃料ガス中の水素分圧
を低下させて後負荷を遮断し、ついで燃料系にも外部新
鮮空気を流通させ、電池が所定温度に低下した時点で、
燃料系・反応空気系及び冷却空気系の各給排バルブを閉
じて電池内の前記各県に新鮮空気を封入し、この状態で
保存を行なうものである。This invention provides external fresh air to the reaction air system and cooling air system when the battery is stopped. With the supply of fuel gas cut off, the hydrogen partial pressure in the fuel gas is lowered by a discharge reaction to cut off the afterload, and fresh air is then passed through the fuel system, allowing the battery to reach a predetermined temperature. When it drops to
The supply/exhaust valves of the fuel system, reaction air system, and cooling air system are closed to fill each prefecture in the battery with fresh air, and the battery is stored in this state.
この発明では燃料ガスの供給遮断後、その燃料成分(H
2)を低下きせるまで放電して後負荷を遮断し、この燃
料系にも反応空気系及び冷却系と同様に外部新鮮空気を
流通させて後電池内の各県に外部新鮮空気を封入するも
ので、従来のような窒素ガスバージを行なう必要がない
と共に、電池が外気温まで低下しても、限られた封入空
気中の水分が電解液に吸収されるだけで、電池に大きな
支障をきたすことなく、窒素パージや電気ヒータによる
保温も不用となり、商用電源や窒素源のない所でも可搬
用燃料電池の保存が可能となる。In this invention, after cutting off the supply of fuel gas, the fuel component (H
2) The afterload is cut off by discharging the battery until it drops, and external fresh air is circulated through this fuel system in the same way as the reaction air system and cooling system, and external fresh air is sealed in each prefecture in the rear battery. This eliminates the need to perform a nitrogen gas purge as in the past, and even if the temperature of the battery drops to the outside temperature, only a limited amount of moisture in the enclosed air will be absorbed by the electrolyte, causing major damage to the battery. This eliminates the need for nitrogen purge or heat insulation using electric heaters, making it possible to store portable fuel cells even in locations without commercial power or nitrogen sources.
本発明の実施例を第1図につい工説明する。An embodiment of the present invention will be explained with reference to FIG.
電池(1)に供給きれる燃料ガスは、リホーマ=(2)
でメタノールを改質した水素リッチガス(8280%、
CO220%)を用い、酸化剤としての反応空気との間
で電池反応にあうかり、電力を発生する。この際燃料ガ
ス及び反応空気の供給・琲気各弁(3)(3’)及び(
4)(4’)は開いている。The fuel gas that can be supplied to the battery (1) is reformed = (2)
Hydrogen-rich gas (8280%,
Using CO2 (20%), a battery reaction occurs with reaction air as an oxidizing agent to generate electricity. At this time, the fuel gas and reaction air supply and aeration valves (3) (3') and (
4) (4') is open.
電池(1)の作動温度は180℃〜190℃で、反応熱
により昇温する電池を作動温度に維持するため、ブロワ
(5)で循環する空気により冷却きれる。電池(1)を
冷却した高温排ガスの一部は、反応空気として電池(1
)に供給きれ、その排ガスは燃料ガスの排ガスと共にリ
ホーマ−(2)のバーナー熱源として利用される。The operating temperature of the battery (1) is 180° C. to 190° C., and in order to maintain the battery at the operating temperature, the temperature of which rises due to reaction heat, can be cooled down by air circulated by a blower (5). A part of the high-temperature exhaust gas that cooled the battery (1) is transferred to the battery (1) as reaction air.
), and the exhaust gas is used as a burner heat source for the reformer (2) together with the exhaust gas of the fuel gas.
冷却空気の循環経路(6)(6’)には、供給・排気6
弁(7)(7’)の他に外気導入弁く8)及び外部排出
弁(9)を有し、電池運転中外部排出弁(9)は閉じて
いるが、外気導入弁(8)を開いて、この弁(8)より
導入される低温の新鮮空気により、反応空気として排出
きれる空気を補うと共に、電池を循環する冷却空気の温
度を下げる。The cooling air circulation path (6) (6') includes a supply/exhaust 6
In addition to the valves (7) and (7'), it has an outside air intake valve (8) and an external exhaust valve (9).The external exhaust valve (9) is closed during battery operation, but when the outside air intake valve (8) is closed. When opened, the low-temperature fresh air introduced through this valve (8) supplements the air that can be exhausted as reaction air and lowers the temperature of the cooling air circulating through the battery.
次に電池の運転停止及び保存法について説明する。Next, methods for stopping and preserving the battery will be explained.
運転停止に際し、リホーマ−(2)へのメタノール供給
を停止すると共に、燃料ガスの供給・排気6弁(3)(
3’)が閉じられる。同時に外部排出弁(9)を開いて
、外気導入弁く8)より取入れた外部新鮮空気が、オー
ブン経路で冷却系に流通して電池(1)を冷却すると共
に、反応空気系にも流通して電池内の湿った空気を系外
に送り出す、弁く3)(3′)間に封入された燃料ガス
中の水素分圧は、反応空気との反応により低下し、これ
が所定値に低下したことを電池T圧により検出して負荷
(10〉を遮断する。ついで分岐弁(11)及び排気弁
(3′)を開いて、燃料系にも外部空気を流通させ、水
素分圧の低い燃料ガスを直かに系外に排出する。When the operation is stopped, the methanol supply to the reformer (2) is stopped, and the six fuel gas supply/exhaust valves (3) (
3') is closed. At the same time, the external exhaust valve (9) is opened, and the external fresh air taken in from the outside air intake valve (8) flows through the oven path to the cooling system to cool the battery (1), and also flows to the reaction air system. The hydrogen partial pressure in the fuel gas sealed between valve 3) (3'), which sends the moist air inside the battery out of the system, decreases due to the reaction with the reaction air, and this drops to a predetermined value. This is detected by the battery T pressure and the load (10) is cut off.Then, the branch valve (11) and the exhaust valve (3') are opened to allow external air to flow through the fuel system as well, allowing fuel with low hydrogen partial pressure to flow through the fuel system. Exhaust the gas directly out of the system.
かくして燃料系、反応空気系及び冷却系にオーブン経路
で流通ずる外気により電池温度が低下し5.ある一定値
(約120℃)まで降下した時点で、ブロワ(5)を停
止すると共に、前記各県の供給・排気6弁(11ン(3
′)、(4>(4’)及び(7)(7’)を閉じること
により、電池(1)内の各県に外部空気を封入する。Thus, the outside air flowing through the oven path through the fuel system, reaction air system, and cooling system lowers the cell temperature.5. When the temperature drops to a certain level (approximately 120°C), the blower (5) is stopped and the six supply/exhaust valves (11 valves (3
'), (4>(4') and (7) By closing (7'), external air is sealed in each prefecture in the battery (1).
この状態で保存が行なわれるが、電池温度は外気温まで
序々に降下し、電解質の燐酸が吸湿性のため燃料系と反
応空気系では封入空気中の水分を吸収して燐酸濃度が低
下するけれども、封入空気量が少ないので濃度低下もし
くは電解質の増量はわずかである。Storage is carried out in this state, but the battery temperature gradually drops to the outside temperature, and since the phosphoric acid in the electrolyte is hygroscopic, the fuel system and reaction air system absorb moisture from the enclosed air and the phosphoric acid concentration decreases. Since the amount of air enclosed is small, there is only a slight decrease in concentration or increase in the amount of electrolyte.
尚前述のように放電による封入燃料ガス中の水素分圧の
低下は、燃料極(N)と空気極(P)との間に差圧をも
たらす、又、保存中の電池温度降下は電解質の増量及び
場合により氷結をもたらす。これらに耐えうるよう、第
2図に示すように、電解質マトリックス(M)は強度の
大きいカーボンマトリックス層(mI)(ml)をSi
Cマトリックス層(m2)の両面に配置して三層構成と
した1図中(12〉はカーボンプレートで、燃料ガス及
び反応空気の各流通溝(13)及び(14)を有する。As mentioned above, the decrease in the partial pressure of hydrogen in the enclosed fuel gas due to discharge causes a pressure difference between the fuel electrode (N) and the air electrode (P), and the drop in battery temperature during storage causes the electrolyte to drop. Resulting in bulk increase and possibly freezing. In order to withstand these conditions, as shown in Figure 2, the electrolyte matrix (M) is made of a strong carbon matrix layer (mI) (ml) made of Si.
A carbon plate (12>) is arranged on both sides of the C matrix layer (m2) to form a three-layer structure, and has flow grooves (13) and (14) for the fuel gas and reaction air.
前記電池停止過程における負荷遮断後のブロワく5)の
運転は、電池スタートアップ用に備えている補助蓄電池
を用いて行なう。The blower 5) is operated after the load is cut off in the battery stop process using an auxiliary storage battery provided for battery startup.
本発明゛によれば、を池の停止に際し、外部空気をオー
ブン経路で反応空気系及び冷却空気系に流通しつつ、燃
料ガス系の水素分圧を低下させて後負荷を遮断し、燃料
ガス系にも外部空気を流通し、電池温度が所定値に降下
した時点で、電池内の各県に外部空気を封入して保存状
態とするもので、従来のように電池保存時窒素ガスを各
系内に連続供給すること及び、温度保持用ヒータへの継
続通電を行なうことを不必要とし、商用電源や窒・電源
のない所でも電池に支障をきたすこ、となく、停止保存
が可能となるなど、可搬用燃料電池に極めて有効である
。According to the present invention, when the oven is stopped, the hydrogen partial pressure in the fuel gas system is reduced to cut off the afterload while the external air is flowing through the oven path to the reaction air system and the cooling air system. External air is also circulated through the system, and when the battery temperature drops to a predetermined value, external air is sealed in each part of the battery to preserve it. It eliminates the need for continuous supply into the system and continuous energization of temperature-maintaining heaters, making it possible to stop and store the battery without causing any trouble to the battery even in places where there is no commercial power supply or nitrogen/power supply. It is extremely effective for portable fuel cells.
第1′CIAは本発明法を説明するための燃料電池シス
テム図、第2図は本発明法による単位セルの概要断面図
である。
1・・・電池、2・・・リホーマ−13,3’・・・燃
料ガスの給・排各弁、4,4′・・・反応空気の給・排
各弁、5,5′・・・冷却空気の給・排各弁、6,6′
・・・冷却空気の循環経路(運転時)、8・・・外気導
入弁、9・・・外部排出弁、11・・・分岐弁。
N・・・燃料極、P・・・空気極、M・・・マトリック
ス(三層構成)。1'CIA is a fuel cell system diagram for explaining the method of the present invention, and FIG. 2 is a schematic sectional view of a unit cell according to the method of the present invention. 1...Battery, 2...Reformer 13, 3'...Fuel gas supply/discharge valves, 4,4'...Reaction air supply/discharge valves, 5,5'...・Cooling air supply/discharge valves, 6, 6'
. . . Cooling air circulation path (during operation), 8. Outside air intake valve, 9. External discharge valve, 11. Branch valve. N: fuel electrode, P: air electrode, M: matrix (three-layer structure).
Claims (2)
オーブン経路で外部空気を流通しつつ、燃料ガスの供給
を遮断した状態で、放電により前記燃料ガス中の水素分
圧を低下させて後負荷を遮断し、ついで燃料系にも前記
外部空気を流通させ、電池が所定温度に低下した時点で
燃料系、反応空気系及び冷却空気系の各給排バルブを閉
じて電池内の前記各系に外部空気を封入し、この状態で
保存を行なうことを特徴とする燃料電池の停止保存法。(1) When the battery is stopped, the hydrogen partial pressure in the fuel gas is lowered by discharging while the supply of fuel gas is cut off while external air is passed through the reaction air system and the cooling air system through the oven path. After the afterload is cut off, the external air is also allowed to flow through the fuel system, and when the temperature of the battery drops to a predetermined temperature, the supply and exhaust valves of the fuel system, reaction air system, and cooling air system are closed to release each of the above-mentioned air inside the battery. A fuel cell shutdown preservation method characterized by sealing external air into the system and preserving it in this state.
質マトリックスが、SiCマトリックス層の両面に強度
の大きいカーボンマトリックス層を配置した三層構成で
あることを特徴とする特許請求の範囲第1項記載の燃料
電池の停止保存法。(2) Claims characterized in that the electrolyte matrix interposed between the fuel electrode and the air electrode of the battery has a three-layer structure in which strong carbon matrix layers are arranged on both sides of a SiC matrix layer. 1. A method for shutting down and preserving a fuel cell as described in paragraph 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60184979A JPS6326962A (en) | 1985-08-22 | 1985-08-22 | Stop and storing method for fuel cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60184979A JPS6326962A (en) | 1985-08-22 | 1985-08-22 | Stop and storing method for fuel cell |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6326962A true JPS6326962A (en) | 1988-02-04 |
JPH0433112B2 JPH0433112B2 (en) | 1992-06-02 |
Family
ID=16162677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60184979A Granted JPS6326962A (en) | 1985-08-22 | 1985-08-22 | Stop and storing method for fuel cell |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6326962A (en) |
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JP2005183197A (en) * | 2003-12-19 | 2005-07-07 | Honda Motor Co Ltd | Stopping method of fuel cell |
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JP2010080176A (en) * | 2008-09-25 | 2010-04-08 | Casio Computer Co Ltd | Reactive equipment, and controlling portion thereof |
US7867661B2 (en) | 2005-07-28 | 2011-01-11 | Honda Motor Co., Ltd. | Fuel cell system and method |
US7883811B2 (en) | 2002-09-18 | 2011-02-08 | Honda Giken Koygo Kabushiki Kaisha | Control apparatus for fuel cell stack |
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1985
- 1985-08-22 JP JP60184979A patent/JPS6326962A/en active Granted
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JP2009087954A (en) * | 1997-12-22 | 2009-04-23 | Equos Research Co Ltd | Fuel cell system |
JP2002324564A (en) * | 2001-04-26 | 2002-11-08 | Equos Research Co Ltd | Fuel cell device and control method therefor |
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JP2003157875A (en) * | 2001-11-21 | 2003-05-30 | Nissan Motor Co Ltd | Fuel cell system |
US7883811B2 (en) | 2002-09-18 | 2011-02-08 | Honda Giken Koygo Kabushiki Kaisha | Control apparatus for fuel cell stack |
US7943261B2 (en) | 2002-10-31 | 2011-05-17 | Panasonic Corporation | Method of operating fuel cell system and fuel cell system |
JP2004206898A (en) * | 2002-12-24 | 2004-07-22 | Equos Research Co Ltd | Fuel cell system |
JP4599796B2 (en) * | 2002-12-24 | 2010-12-15 | 株式会社エクォス・リサーチ | Fuel cell system |
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JP2005183197A (en) * | 2003-12-19 | 2005-07-07 | Honda Motor Co Ltd | Stopping method of fuel cell |
JP4681250B2 (en) * | 2004-04-14 | 2011-05-11 | 本田技研工業株式会社 | Fuel cell system |
JP2005302609A (en) * | 2004-04-14 | 2005-10-27 | Honda Motor Co Ltd | Fuel cell system |
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US7846596B2 (en) | 2004-11-09 | 2010-12-07 | Honda Motor Co., Ltd. | Fuel cell system and method of discharging a reaction gas from the fuel cell system |
JP4699010B2 (en) * | 2004-11-09 | 2011-06-08 | 本田技研工業株式会社 | Fuel cell system |
JP2006134807A (en) * | 2004-11-09 | 2006-05-25 | Honda Motor Co Ltd | Fuel cell system |
JP2006202520A (en) * | 2005-01-18 | 2006-08-03 | Honda Motor Co Ltd | Shutdown method of fuel cell system, and fuel cell system |
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JP2010080176A (en) * | 2008-09-25 | 2010-04-08 | Casio Computer Co Ltd | Reactive equipment, and controlling portion thereof |
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