JPS63258689A - Method for making sterilized water - Google Patents
Method for making sterilized waterInfo
- Publication number
- JPS63258689A JPS63258689A JP9450087A JP9450087A JPS63258689A JP S63258689 A JPS63258689 A JP S63258689A JP 9450087 A JP9450087 A JP 9450087A JP 9450087 A JP9450087 A JP 9450087A JP S63258689 A JPS63258689 A JP S63258689A
- Authority
- JP
- Japan
- Prior art keywords
- water
- electrolytic cell
- producing sterilized
- organic compound
- voltage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 162
- 238000000034 method Methods 0.000 title abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 150000002894 organic compounds Chemical class 0.000 claims description 38
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 29
- 238000004519 manufacturing process Methods 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 25
- 235000019441 ethanol Nutrition 0.000 claims description 21
- 230000033116 oxidation-reduction process Effects 0.000 claims description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- 230000001954 sterilising effect Effects 0.000 abstract description 20
- -1 hydroxyl ions Chemical class 0.000 abstract description 18
- 150000002500 ions Chemical class 0.000 abstract description 18
- 239000007864 aqueous solution Substances 0.000 abstract description 16
- 230000002093 peripheral effect Effects 0.000 abstract description 9
- 238000003860 storage Methods 0.000 abstract description 9
- 239000001257 hydrogen Substances 0.000 abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 8
- 239000008399 tap water Substances 0.000 abstract description 6
- 235000020679 tap water Nutrition 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 2
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 33
- 230000000844 anti-bacterial effect Effects 0.000 description 13
- 235000013305 food Nutrition 0.000 description 12
- 238000004659 sterilization and disinfection Methods 0.000 description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 8
- 238000000605 extraction Methods 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 5
- 210000000170 cell membrane Anatomy 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- WQZGKKKJIJFFOK-SVZMEOIVSA-N (+)-Galactose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-SVZMEOIVSA-N 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000010865 sewage Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 235000013619 trace mineral Nutrition 0.000 description 4
- 239000011573 trace mineral Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000019640 taste Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000020681 well water Nutrition 0.000 description 3
- 239000002349 well water Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical class CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 206010067482 No adverse event Diseases 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000005283 ground state Effects 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000219051 Fagopyrum Species 0.000 description 1
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000003163 cell fusion method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000036210 malignancy Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004776 molecular orbital Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 210000001938 protoplast Anatomy 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
【発明の詳細な説明】
「技術分野」
本発明は、例えば食品、下水、コンポスト、土壌、植物
等においで、それらに含まれる細菌やかび等の微生物を
殺菌するために使用される殺菌水の製造法に関する。Detailed Description of the Invention [Technical Field] The present invention relates to the use of sterilized water used to sterilize microorganisms such as bacteria and mold contained in foods, sewage, compost, soil, plants, etc. Regarding manufacturing methods.
「従来技術およびその問題点Ｊ
食品加工、！！業、上下水処理、医療等の幅広い分野に
おいて、細菌、かび、ビールス等に対する静殺菌処理が
行なわれている。従来、このような静殺菌処理としては
、例えば、熱処理、アルコール処理、酸性処理、！！薬
、合成化学薬剤１こよる処理、抗性物質による処理など
多くの手段が用いられている。"Prior Art and its Problems J Static sterilization treatment against bacteria, mold, viruses, etc. is carried out in a wide range of fields such as food processing,!! industry, water and sewage treatment, and medicine. Conventionally, such static sterilization treatment Many methods are used for this purpose, such as heat treatment, alcohol treatment, acid treatment, treatment with drugs, synthetic chemical agents, and treatment with anti-inflammatory substances.
しかしながら、熱処理、アルコール処理、酸性処理など
は、適用分野が限られており、また、農業、合成化学薬
剤による処理、抗性物質による処理などは、人体に対す
る副作用などの問題点がある。このため、食品加工、農
業、上下水処理などの分野においては、より人体に対し
て安全な、がっ、低コストで行なえるようにした殺菌方
法の開発が望まれでいる。However, heat treatment, alcohol treatment, acid treatment, etc. have limited application fields, and agriculture, treatment with synthetic chemical agents, treatment with anti-biotics, etc. have problems such as side effects on the human body. Therefore, in the fields of food processing, agriculture, water and sewage treatment, etc., there is a desire to develop a sterilization method that is safer for the human body and can be carried out at a lower cost.
一方、近年、水を銀電極を有する電解槽で電気分解して
得られる銀イオン水を用いた静殺菌方法も提案されてい
る（例えば特開昭６０−９７０８８号参照）。On the other hand, in recent years, a static sterilization method using silver ion water obtained by electrolyzing water in an electrolytic cell having a silver electrode has also been proposed (see, for example, Japanese Patent Laid-Open No. 60-97088).
しかしながら、銀イオンは、人体に対して比較的安全で
あると（よいえ、金属であるから食品や上水道などに添
加するには問題がある。However, silver ions are relatively safe for the human body (although, since they are metals, there are problems with adding them to foods, water supplies, etc.).
「発明の目的」
本発明の目的は、優れた殺菌効果を有し、人体に対する
悪影響がなく、しがも低コストで得られるようにした殺
菌水の製造法を提供することにある。``Object of the Invention'' An object of the present invention is to provide a method for producing sterilizing water that has excellent sterilizing effects, has no adverse effects on the human body, and can be obtained at low cost.
ｒ発明の構成」
本発明による殺菌水の製造法は、陽極と陰極とを有する
電解槽に水を導入して電圧を印加し、この水に共鳴構造
を有する水溶性の有機化合物を添加することを特徴とす
る。``Structure of the Invention'' The method for producing sterilized water according to the present invention involves introducing water into an electrolytic cell having an anode and a cathode, applying a voltage, and adding a water-soluble organic compound having a resonance structure to the water. It is characterized by
また、本発明による別の殺菌水の製造法は、陽極と陰極
とを有し、両電極の間に隔膜が形成され、陽極室と陰極
室とに区画された電解槽の前記陽極室および前記陰極室
にそれぞれ水を導入して電圧を印加し、前記陽極室から
取出された水および／または前記陰極室から取出された
水に共鳴構造を有する水溶性の有機化合物を添加するこ
とを特徴とする。Another method for producing sterilized water according to the present invention provides an electrolytic cell having an anode and a cathode, a diaphragm being formed between both electrodes, and partitioned into an anode chamber and a cathode chamber. Water is introduced into each of the cathode chambers, a voltage is applied, and a water-soluble organic compound having a resonance structure is added to the water taken out from the anode chamber and/or the water taken out from the cathode chamber. do.
本発明により得られた殺菌水が、優れた殺菌効果を有す
る理由は、未た詳細には解明されていないが、本発明者
らの研究によれば次のように推測される。The reason why the sterilized water obtained by the present invention has an excellent sterilizing effect has not yet been elucidated in detail, but according to the research conducted by the present inventors, it is assumed as follows.
今回の研究は、生体内の機序における殺菌静菌作用の殆
どか生体内で生成される強力なラジカル種等の酸化作用
によって行なわれでいること、また、プロトプラストの
細胞融合の手法でみられるように微小電流ｉ＝Ｉ〜５０
ｕＡ、持続時間Δｔ＝０．２５〜５０止によってでも細
胞膜に孔が開き、ｉが著しく大きくなると細胞膜が破壊
されることに着眼し、これらの現象を人為的に複合的に
起こすことができれば、薬剤等を使用せずに殺菌が可能
であるとの判断に基いている。This research shows that most of the bactericidal and bacteriostatic effects in vivo are carried out by oxidative effects such as strong radical species generated in vivo, and that the protoplast cell fusion method So the minute current i=I~50
Focusing on the fact that pores open in the cell membrane even when uA and duration Δt = 0.25 to 50, and when i becomes significantly large, the cell membrane is destroyed, and if these phenomena can be artificially caused in combination, This is based on the judgment that sterilization is possible without the use of chemicals.
すなわち、本発明は、既に提案されでいる銀イオン水な
どの貴金属のもつ触媒機能による殺菌、静菌効果にたよ
らず、これらの研究をざらに一歩進めて、電気的エネル
ギーをもって意図的に選択した有機化合物の水溶液の分
子構造を変化させるという電子化学的手法において、殺
菌または静菌の機序そつくりだしたものである。That is, the present invention does not rely on the bactericidal and bacteriostatic effects due to the catalytic function of precious metals such as silver ion water, which have already been proposed, but rather takes these studies one step further and intentionally selects silver ionized water using electrical energy. It is an electrochemical method that changes the molecular structure of an aqueous solution of organic compounds to create a bactericidal or bacteriostatic mechanism.
具体的に説明すると、分子構造的に最も安定したものは
、基底状態といわれる二重結合をもつ分子構造であり、
Ｓ２２軌道とＳＰ２軌這がオーバーラツプしたう結合と
Ｐ軌道が重豊して生した■結合が重なったものである。To explain specifically, the most stable molecular structure is a molecular structure with a double bond called the ground state.
This is a combination of the S22 orbital and the SP2 orbital overlapping bond and the P orbital overlapping and the ■ bond created by the overlap.
これは、相似た構造が二つ以上集まって一つの化合物に
統一され、共鳴エネルギーによって安定しているといえ
る。この安定した分子にエネルギーを与えることにより
、分子が励起され、内部にエネルギーが貯蔵されて■結
合の準位が高まって、ついには■結合が分離してフリー
ラジカルとなる。このラジカルが安定を求めて細胞形質
膜の極性基と酸化反応を起こして水素を引き抜き形質膜
の機能を失活させ、ざらに接触と同時に含有する巨大な
エネルギーを与えることにより細胞膜と内容物に致命的
な破壊を行なわせる。This can be said to be a combination of two or more similar structures that are unified into a single compound and stabilized by resonance energy. By applying energy to this stable molecule, the molecule is excited, energy is stored internally, the level of the ■ bond increases, and finally the ■ bond separates and becomes a free radical. In search of stability, these radicals cause an oxidation reaction with the polar groups of the cell plasma membrane, extracting hydrogen and deactivating the plasma membrane function. cause fatal destruction.
この共鳴構造を有する有機化合物にエネルギーを与えて
分子を励起させる方法としで、一般水道水とか井戸水の
ように水中に微量元素を含む水を電気分解によって過電
圧を加えることにより、水中で水素結合をしでいる微量
元素の分子内に電子のエネルギーが充電される。この水
を取出し、例えば原子数が多く分子軌道の多い共鳴構造
を有する水溶性の有機化合物、例えばカルボン酸を溶解
させると、あらかじめ水中に貯蔵されたエネルギーがカ
ルボン酸の分子構造内に移行し、分子が励起される。そ
して、所定のエネルギーの移行がなされたとき、Ｔ［結
合が分離してカルボン酸ラジカルとなる。従来、電気分
解によるラジカル生成は、例えば酢酸の場合、次式のよ
うに水にとけてイオン化した酢酸アニオンが陽極に近づ
いて電子を失いアニオンのもつ陰電極が中和されてラジ
カルに変わり、この酢酸ラジカルが加電され、メチルラ
ジカルと炭酸ガスになるといわれでいる。A method of exciting molecules by giving energy to organic compounds with this resonance structure is to apply an overvoltage to water that contains trace elements, such as general tap water or well water, through electrolysis, thereby forming hydrogen bonds in the water. Electron energy is charged within the molecules of the trace elements. When this water is taken out and a water-soluble organic compound, such as carboxylic acid, which has a resonance structure with a large number of atoms and many molecular orbitals is dissolved, the energy previously stored in the water is transferred into the molecular structure of the carboxylic acid. molecules are excited. Then, when a predetermined energy transfer occurs, the T bond separates and becomes a carboxylic acid radical. Conventionally, in the case of acetic acid, for example, in the case of acetic acid, an acetate anion that has been dissolved in water and ionized approaches the anode, loses electrons, and the anion's negative electrode is neutralized and turns into radicals. It is said that acetic acid radicals are electrically charged and become methyl radicals and carbon dioxide gas.
ＣＨ３ＣＯ０Ｈ−１： ＣＨ３ＣＯＯ−＋ Ｈ◆ＣＨ３
ＣＯＯ−−＋ＣＨ３ＣＯＯ°＋ｅ−ＣＨ３ＣＯＯ°→Ｃ
Ｈ３＋ＣＯ□
しかし、今回の発明は、あらがじめ水溶液中に電子を充
電し、その後、共鳴構造体を有する何機化合物を一定時
間内に溶解させることにより、一定のエネルギーの移行
ができることを証明したものである。カルボン酸を例に
とって説明すると、水にカルボン酸が添加されると、水
溶液中では完全にイオン解離せず次式の共有結合体のま
ま存在する。CH3CO0H-1: CH3COO-+ H◆CH3
COO--+CH3COO°+e-CH3COO°→C
H3+CO□ However, this invention proves that a certain amount of energy can be transferred by first charging electrons in an aqueous solution and then dissolving a compound with a resonance structure within a certain period of time. This is what I did. Taking carboxylic acid as an example, when carboxylic acid is added to water, it does not completely dissociate into ions in an aqueous solution and remains as a covalent bond of the following formula.
通常、脂肪酸が２分子会合しでいるのは、鎖状環を形成
し、しかもＮＧ通して共鳴している鎖状結合による共口
烏体である。これに電解によるエネルギーを付加するわ
けであるが、物質もエネルギーもどんどん細分化してい
くと究極においで物質にもプロトン、電子、中性子とい
った限界があるように、エネルギーにもある大きざが定
まっていると推測される。この量子力学的観点からすれ
ば、■結合も例外ではなく、エネルギーが与えられると
分子か励起され、■結合の準位が高まってくる。しかし
、■結合のエネルギーは、順次に高まるのてはなく、あ
る水準から次の段階に飛び上がらなければならない仕組
かある。第３図に示すように、−格下のＮ状態は、基底
状態にある安定した分子構造の共鳴体である。これに電
気的にエネルギーを与えでいくと■結合のエネルギーは
■状態、次いで■状態に飛び上がる。■状態では二つの
Ｐ電子のスピンの方向で非配合型となり、■状態では逆
方向の配合型になる。■状態では■結合が解離してカル
ボン酸のフリーラジカルとなる。ざらに、電気的エネル
ギーが引き続き供給されると、■状態となり、分子間結
合が解離しでＲとＣＯ□になる。この■状態までくると
、原子数が減り、構造内に蓄積されたエネルギーが分散
減少し、殺菌を期待できない、■状態のラジカルがエネ
ルギーを内蔵した状態のままで不安定であるために安定
を求めて能動的になる。そこにタンパク貢の極性基を膜
表面に露出してカルボキシル基やアシル基などを結合し
やすい状態である細菌が投入されると、−挙に細菌の形
質膜に積極的にドツキングし、■状態の構造体がラジカ
ル反応を起こすと同時にエネルギーの伝達が行なわれ、
顕著な殺菌効果をみることができる。Normally, two molecules of fatty acids are associated to form a chain ring, and moreover, the chain bond resonates through the NG. Energy from electrolysis is added to this, but as matter and energy become more and more subdivided, in the same way that matter has limits such as protons, electrons, and neutrons, energy also has a certain size. It is assumed that there are. From this quantum mechanical perspective, ■bonds are no exception; when energy is given, molecules are excited, and the level of ■bonds increases. However, there is a mechanism in which the energy of bonding does not increase sequentially, but has to jump from one level to the next. As shown in FIG. 3, the - lower N state is a resonator with a stable molecular structure in the ground state. When electrical energy is given to this, the energy of the ■ bond jumps to the ■ state and then to the ■ state. In the ■ state, the spin direction of the two P electrons is non-combined, and in the ■ state, the spin direction is opposite. In the ■ state, the ■ bonds dissociate and become carboxylic acid free radicals. Roughly speaking, when electrical energy is continuously supplied, the state becomes ■ and the intermolecular bonds dissociate to form R and CO□. When this ■ state is reached, the number of atoms decreases, the energy accumulated in the structure is dispersed, and sterilization cannot be expected. Be active in seeking. When a bacterium is injected into this system, the polar groups of protein molecules are exposed on the membrane surface, making it easy to bond carboxyl groups and acyl groups. At the same time as the structure causes a radical reaction, energy is transferred,
A remarkable bactericidal effect can be seen.
細胞膜の電気抵抗の測定値は、およそ単位面積当り１０
２〜１０５Ωｃｍ２であり、これを比抵抗で表せば１０
８〜１０１１Ωｃｍ であるが、これは比較的絶縁性
のよい半導体の比抵抗と同じであるから、比抵抗を大き
く上回る電流が流れれば、それが相対的にみて微小な電
流であっても孔かあくことになる。まして、細菌のよう
な単細胞にとっては、巨大な電気エネルギーが伝達され
ることになれば、瞬時にして細胞破壊が行なわれること
になる。The measured electrical resistance of cell membranes is approximately 10
2 to 105Ωcm2, which is expressed as specific resistance 10
8 to 1011 Ωcm, which is the same as the resistivity of a semiconductor with relatively good insulation, so if a current that greatly exceeds the resistivity flows, even if it is a relatively small current, it will cause holes. It will be dark. Furthermore, for a single cell like a bacterium, if a huge amount of electrical energy were to be transmitted, the cell would be destroyed instantly.
そして、本発明の方法においては、ＰＨ、エネルギ１１
共鳴物質の濃度、酸化還元電位等を適宜組合せることに
より、静菌または殺菌の用途を自由にコントロールでき
る。In the method of the present invention, PH, energy 11
By appropriately combining the concentration of the resonant substance, redox potential, etc., the bacteriostatic or sterilizing application can be freely controlled.
次に、本発明を好ましい態様を挙げてざらに詳しく説明
する。Next, the present invention will be briefly described in detail by citing preferred embodiments.
本発明において、水としでは、通常の水道水、井戸水な
どいずれのものも使用できる。ただし、後の電解工程に
おいである程度の電流が流れることが必要であるため、
水中に若干の電解質が溶解しでいることが好ましく、蒸
留水などは適当でない、ざらに詳しくは、水の電気伝導
度が５０〜３５０ｕＵ／ｃｒｒｒであることが好ましい
０通常、水道水、井戸水なとは、殆ど上記範囲の電気伝
導度を有しているので、それらをそのまま使用すること
ができる。In the present invention, any water such as ordinary tap water or well water can be used. However, since it is necessary for a certain amount of current to flow in the subsequent electrolytic process,
It is preferable that some electrolyte is dissolved in the water, and distilled water is not suitable. More specifically, it is preferable that the electrical conductivity of water is 50 to 350 uU/crrr. Normally, tap water, well water, etc. have electrical conductivity within the above range, so they can be used as they are.
本発明の第１の発明によれば、上記水を、陽極と陰極と
を有する電解槽に導入し電圧を印加しで取出す、そして
、第１の発明においては、電解槽を通した後の水の酸化
還元電位が一１００〜亭４５０ｍＶとなるように電圧を
印加することが好ましい、この場合、上記範囲の酸化還
元電位とするために必要な電圧は、水の流量、水の電気
伝導度など応じで変化するため、それらに応しで定める
必要がある。電解槽を通した後の水の酸化還元電位が一
１００ｍＶ未満の場合には、殺菌効果が減少するという
問題が生し、また、電解槽を通した後の水の酸化還元電
位が４５０ ｍＶを超えると、殺菌効果が乏しくなると
いう問題が生じる。According to the first invention of the present invention, the water is introduced into an electrolytic cell having an anode and a cathode and taken out by applying a voltage, and in the first invention, the water after passing through the electrolytic cell is It is preferable to apply a voltage so that the oxidation-reduction potential of Since it changes depending on the situation, it is necessary to set it accordingly. If the oxidation-reduction potential of the water after passing through the electrolytic cell is less than 1100 mV, there will be a problem that the sterilizing effect will be reduced; If it exceeds this, a problem arises in that the bactericidal effect becomes poor.
また、本発明の第２の発明によれば、陽極と陰極とを有
し、両電極の間に隔膜が形成され、陽極室と陰極室とに
区画された電解槽の前記陽極室および前記陰極室にそれ
ぞれ水を導入して電圧を印加する。ここで、隔膜とは、
有機化合物などの分子−は通ざず、水酸イオン、水素イ
オンなどのイオンのみを通す性質を有する膜を意味する
。このような隔膜を有する電解槽に水を導入して電圧を
印加すると、陽極室からは酸性イオン水が取出され、陰
極室からはアルカリ性イオン水が取出される。Further, according to the second aspect of the present invention, the anode chamber and the cathode of an electrolytic cell have an anode and a cathode, a diaphragm is formed between both electrodes, and the electrolytic cell is partitioned into an anode chamber and a cathode chamber. Water is introduced into each chamber and a voltage is applied. Here, the diaphragm is
It refers to a membrane that allows only ions such as hydroxide ions and hydrogen ions to pass through, but not molecules such as organic compounds. When water is introduced into an electrolytic cell having such a diaphragm and a voltage is applied, acidic ionized water is taken out from the anode chamber and alkaline ionized water is taken out from the cathode chamber.
第２の発明においては、電解槽のＩＩｌ極室を通した復
の水の酸化還元電位が２００〜９００ ｍＶとなるよう
に電圧を印加することが好ましい、この場合にも、上記
範囲の酸化還元電位とするために必要な電圧は、水の流
量、水の電気伝導度などに応しで変化するため、それら
に応して定める必要がある。陽極室を通した後の水の酸
化還元電位が２００ｍＶ未溝の場８には、殺菌効果が低
下するという問題が生し、また、陽極室を通した後の水
の酸化還元電位が９００ ｍＶを超える場合も、殺菌効
果が低下するという問題が生じる。In the second invention, it is preferable to apply a voltage so that the redox potential of the aqueous water passing through the IIl electrode chamber of the electrolytic cell is 200 to 900 mV. The voltage required to set the potential changes depending on the flow rate of water, the electrical conductivity of water, etc., and therefore needs to be determined accordingly. The oxidation-reduction potential of the water after passing through the anode chamber is 200 mV In the field 8 without groove, there is a problem that the sterilizing effect is reduced, and the oxidation-reduction potential of the water after passing through the anode chamber is 900 mV. If it exceeds 20%, the problem also arises that the bactericidal effect decreases.
第２の発明においては、電解槽の陰極室を通した後の水
の酸化還元電位が２００〜−６００ｍＶとなるように電
圧を印加することが好ましい、この場合にも、上記範囲
の酸化還元電位とするために必要な電圧は、水の流量、
水の電気伝導度などに応しで変化するため、それらに応
じて定める必要がある。陰極Ｍを通した竣の水の酸化還
元電位が２００ｍＶを超える場合には、酸味と金属味を
生じるという問題が生し、また、陰極室を過した後の水
の酸化還元電位が一６００ｍＶ未溝の場合も、殺菌効果
が低下するという問題が主じる。In the second invention, it is preferable to apply a voltage so that the oxidation-reduction potential of the water after passing through the cathode chamber of the electrolytic cell is 200 to -600 mV. Also in this case, the oxidation-reduction potential within the above range The voltage required for is the water flow rate,
Since it changes depending on the electrical conductivity of water, etc., it is necessary to set it accordingly. If the oxidation-reduction potential of the water that has passed through the cathode M exceeds 200 mV, a problem arises in that the water tastes sour and metallic. In the case of grooves, the main problem is that the sterilizing effect is reduced.
また、第１；！３よび第２の発明（こあいで、電解槽を
通した後の水の電気伝導度が１００〜３０００ｕＬｌ／
ｃｍ３となるように、電圧を印加することが好ましい、
この場合、電気伝導度が１００ ｕ Ｕ／ｃｍ３未満の
場合には、殺菌効果か乏しく、３０００ ｕ Ｌｌ ／
ｃｍ３を超えると、Ｍ昧が強すぎて食用に適さない。Also, the first;! 3 and the second invention (in this case, the electrical conductivity of water after passing through the electrolytic cell is 100 to 3000 uL/
It is preferable to apply a voltage so that cm3,
In this case, if the electrical conductivity is less than 100 u Ll/cm3, the bactericidal effect is poor, and 3000 u Ll/cm3.
If it exceeds cm3, the malignancy will be too strong and it will not be suitable for consumption.
本発明の第１の発明においては、前記電解槽を過した木
に、共鳴構造を有する水溶性の有機化合物８添加する。In the first aspect of the present invention, a water-soluble organic compound 8 having a resonance structure is added to the wood that has passed through the electrolytic bath.
また、本発明の第２の発明においでは、前記電解槽の陽
極室に通したおよび／または前記陰極室に通した水に、
共鳴構造を有する水溶性の有機化合物を添加する。なお
、第２の発明においては、前記１１ｊ極室に通した水と
、前記陰極室に通した水とを混合し、この混合水に共鳴
構造を有する水溶性の有機化合物を添加しでもよい。Further, in the second aspect of the present invention, the water passed through the anode chamber and/or the cathode chamber of the electrolytic cell contains
A water-soluble organic compound having a resonance structure is added. In the second invention, the water passed through the 11j electrode chamber and the water passed through the cathode chamber may be mixed, and a water-soluble organic compound having a resonance structure may be added to the mixed water.
かかる有機化合物としては、カルボン酸系、アミノ基系
、アミン系など各種のものが挙げられるが、特にはカル
ボキシル基を有する化合物が好ましい、そして、カルボ
キシル基を有する化合物のうちでも、特に酢酸が好まし
い。Such organic compounds include various types such as carboxylic acid type, amino group type, and amine type, but compounds having a carboxyl group are particularly preferable, and among compounds having a carboxyl group, acetic acid is particularly preferable. .
上記有機化合物の水に対する添加量は、特に限定されな
いが、２００〜１００，０００ ｐｐｍが好ましい。The amount of the organic compound added to water is not particularly limited, but is preferably 200 to 100,000 ppm.
この添加量が２００ ｐｐｍ未満では、殺菌力が低下す
という問題が生し、この添加量が１００，０００ρｐｍ
を超えると、特（こ食品に使用した場合に味覚に悪影Ｗ
を与えるという問題が生しる。なお、これらの化合物は
、水中にそのままあるいは水溶液として添加されるが、
できるだけ高い濃度、好ましくは０．１５重量％以上の
濃度で添加することが好ましい、低濃度の水溶液として
添加した場合には、良好な殺菌効果が得られない。If the amount added is less than 200 ppm, there will be a problem that the bactericidal power will decrease.
Exceeding this may have a negative impact on the taste when used in special foods.
The problem arises in giving. Note that these compounds can be added to water as is or as an aqueous solution, but
It is preferable to add it at a concentration as high as possible, preferably at a concentration of 0.15% by weight or more; if it is added as a low concentration aqueous solution, a good bactericidal effect cannot be obtained.
本発明の好ましい態様によれば、水に上記有機化合物と
共にアルコールを添加する。アルコールとしては、エチ
ルアルコール、ブチルアルコール、プロピルアルコール
などの人体に悪影響のない低級アルコールが好ましく、
特にエチルアルコールが好ましい０食品中に添加する場
合、カルボン酸、例えば酢酸の濃度をある程度上げるこ
とにより、食味に変化を及ぼす場合がある。そこで、酢
酸の濃度を下げでいくと殺菌の効果が薄れること１こな
る。このような場合、カルボン酸にアルコールを混入す
ることによって、殺菌効果を高めることができる。アル
コールヲ添加することにより殺菌効果がより高められる
理由は、詳細には解明されていないが、本発明者らの研
究によれば次のように推測される。According to a preferred embodiment of the present invention, alcohol is added to water together with the above organic compound. As the alcohol, lower alcohols such as ethyl alcohol, butyl alcohol, and propyl alcohol, which have no adverse effects on the human body, are preferable.
Particularly when ethyl alcohol is preferred, when added to foods, increasing the concentration of carboxylic acids, such as acetic acid, to some extent may change the taste. Therefore, if the concentration of acetic acid is lowered, the sterilizing effect will be weakened. In such cases, the bactericidal effect can be enhanced by mixing alcohol with the carboxylic acid. The reason why the bactericidal effect is further enhanced by the addition of alcohol has not been elucidated in detail, but according to the research conducted by the present inventors, it is assumed as follows.
例えば酢酸にエチルアルコールを混合した水溶液で次の
式のようになる。For example, an aqueous solution of acetic acid and ethyl alcohol has the following formula.
Ｃ２Ｈ５０Ｈ＋ ＧＨ３ＣＯＯＨ→ＣＨ３ＣＯＯＣ２Ｈ
５＋ Ｈ２Ｏこの酢酸エチルエステルの構造式は、
のようになり、共鳴構造をとることにより、水溶液中に
既に印加された水素イオン、水酸イオン、微量元素イオ
ン等の蓄積されたエネルギーをこの共鳴体（こ転移させ
ることにより、エネルギー準位が上り、ついにはＴＴ結
合か解離して酢酸エステルのラジカルが生しる。また、
カルボン酸にアルコールを入れると、水溶液中でエステ
ル化し、原子数が増える。したかって、原子数が増える
とエネルギー準位の数だけ増えていくために、カルボン
Ｍ１４度を下げてもエネルギーの内蔵量が増加し、より
大きな電気的パルスを送ることができる。C2H50H+ GH3COOH→CH3COOC2H
5+ H2O The structural formula of this acetic acid ethyl ester is as follows, and by adopting a resonance structure, the accumulated energy of hydrogen ions, hydroxide ions, trace element ions, etc. that have already been applied in the aqueous solution is transferred to this resonance body. (By making this transition, the energy level rises, and finally the TT bond dissociates to generate an acetate radical. Also,
When an alcohol is added to a carboxylic acid, it esterifies in an aqueous solution and the number of atoms increases. Therefore, as the number of atoms increases, the number of energy levels increases, so even if the carbon M14 degree is lowered, the amount of built-in energy increases, making it possible to send a larger electrical pulse.
アルコールの添加量は、水に対して５００〜７００．０
００ ｐｐｍが好ましく、５００ ｐｐｍ未満では殺菌
効果か低下するという問題が生し、７００．０００ ｐ
ｐｍを超えると自然蒸発を起こし、変性を生しるという
問題が生しる。The amount of alcohol added is 500 to 700.0 per water.
00 ppm is preferable, and if it is less than 500 ppm, there is a problem that the bactericidal effect decreases, and 700.000 ppm is preferable.
If it exceeds pm, natural evaporation will occur, causing a problem of denaturation.
ところで、共鳴構造を有する水溶性の化合物またはその
化合物にアルコールを添加したものを水に混合して電気
エネルギーを供給する場合、その添加物が水中において
イオン解離しない状態で共有結合を完成する時間帯を設
定する必要がある。By the way, when supplying electrical energy by mixing a water-soluble compound with a resonance structure or a compound with alcohol added to water, there is a period of time during which the additive completes a covalent bond without ionic dissociation in water. need to be set.
これはＶａｎ’ｔ Ｈｏｆｆの理論にしたがって、溶液
中の湿質分子が一定の圧力をもつと仮定すると、溶媒に
接した物質もその分子溶液中に送りこもうとする膨張圧
かあると仮定できる。したがって、一定の濃度勾配に対
し、混入物質は限られた速さでしか拡散し得す、しかも
濃度がそれほど高くないところへ水中に貯Ｒされたエネ
ルギーを転移しで送り込んだ場合、電極界面へのイオン
の拡散が間に合わなくなり、電流が飽和値に達し、還元
波をみることができる。この状態をつくり出すためには
、エネルギーを内蔵した水に添加する有機化合物が拡散
する時間と水か必要エネルギーを保持する時間が重要と
なる。この状態をつくるためには、水に添加する時間８
１８０分以内に行なうのが好ましい、１８０分を超える
場合には、共有結合がくずれエネルギーの蓄積ができな
くなると共に、供給される水のエネルギー量も自然放電
のため減少して目的を達しえない。This is according to Van't Hoff's theory, and if we assume that the wet molecules in the solution have a constant pressure, we can also assume that the substance in contact with the solvent also has an expansion pressure that tries to push the molecules into the solution. . Therefore, for a given concentration gradient, contaminants can only diffuse at a limited rate, and if the energy stored in water is transferred to a place where the concentration is not very high, it will reach the electrode interface. The ions cannot diffuse in time, the current reaches its saturation value, and reduction waves can be seen. In order to create this state, the time required for the organic compound added to the energy-containing water to diffuse and the time required for the water to retain the necessary energy are important. To create this state, add it to the water for 8 hours.
It is preferable to carry out the heating within 180 minutes; if it exceeds 180 minutes, the covalent bonds will break down and energy cannot be stored, and the energy amount of the supplied water will also decrease due to natural discharge, making it impossible to achieve the purpose.
こうして得られた殺菌水は、各種の細菌、かびなどの微
堂物に対して優れた殺菌効果を有しでおり、水に共鳴構
造を有する水溶性の有機化合物を添加しただけなので、
人体に対して極めて安全である。また、水を電解槽に通
した後、有機化合物ヲ像量添加するという簡単な工程で
得られるので、低コストにで大量に製造することができ
る。The sterilized water obtained in this way has an excellent sterilizing effect against microorganisms such as various bacteria and molds, and because it is simply a water-soluble organic compound with a resonance structure added to the water,
Extremely safe for humans. Furthermore, since it can be obtained through a simple process of passing water through an electrolytic cell and then adding an image amount of an organic compound, it can be produced in large quantities at low cost.
したがっで、この殺菌水は、食品原料に添加したつ、噴
霧などの手段により食品の表面に付着させたつして、食
品の保存注を高めるのに好適である。また、食品取扱い
器具の洗浄水などとしで利用することもできる。ざらに
、医療用消毒とか、上下本道などに添加して殺菌を行な
ったり、土壌に散布して土壌中の有害量生物を除去し、
土壌の健全な菌生態を形成することにも適しでいる。ざ
らにまた、農作物に散布して、病害を防止するのにも適
しでいる。Therefore, this sterilized water is suitable for enhancing the preservation of food by adding it to food raw materials or adhering it to the surface of food by means such as spraying. It can also be used as cleaning water for food handling equipment. Roughly, it can be used for medical disinfection, added to up and down roads to sterilize, or sprayed on the soil to remove harmful amounts of living organisms in the soil.
It is also suitable for forming a healthy fungal ecology in the soil. It is also suitable for spraying on agricultural crops to prevent diseases.
「発明の実施例」
第１図には、本発明の第１の発明を実施するための装置
の一例か示されている。"Embodiment of the Invention" FIG. 1 shows an example of an apparatus for carrying out the first invention of the present invention.
この装置は、底板１、金属製の周壁２）上Ｍ３かうなる
電解槽４を有し、周壁２は陰電極を兼ねている。底板１
には、図示しない水道等の蛇口に接続された水の導入管
５が接続されでおり、途中に設けられたコツクロを開く
ことにより、水を電解槽４内に導入するようになってい
る。また、上Ｍ３には、電極支持棒７が挿通され、この
電極支持棒７の下部に陽電極８が取付けられている。そ
して、陽電極８は電極支持棒７を介して電源９の陽極に
接続され、一方、陰電極を兼ねた周壁２は電源９の陰極
に接続されている。ざらに、上Ｍ３には、取出し管１０
が接続されており、電解槽４を通した水がこの取出し管
１０から流出するようになっている。取出し管１０の途
中には、管１１の一端が接続されており、管１１の他端
は、ポンプ１２を介しで貯槽１３に挿入されている。貯
槽１３内には、共鳴構造を有する水溶性の有機化合物ま
たはその水溶液１４が貯留されている。This device has an electrolytic cell 4 consisting of a bottom plate 1, a metal peripheral wall 2) and an upper M3, and the peripheral wall 2 also serves as a negative electrode. Bottom plate 1
A water introduction pipe 5 connected to a faucet (not shown) such as a water supply is connected to the electrolytic cell 4, and water is introduced into the electrolytic cell 4 by opening a pipe provided in the middle. Further, an electrode support rod 7 is inserted through the upper M3, and a positive electrode 8 is attached to the lower part of the electrode support rod 7. The anode 8 is connected to the anode of the power source 9 via the electrode support rod 7, while the peripheral wall 2, which also serves as a cathode, is connected to the cathode of the power source 9. Roughly, the upper M3 has a take-out pipe 10.
is connected so that the water that has passed through the electrolytic cell 4 flows out from this extraction pipe 10. One end of a pipe 11 is connected to the middle of the extraction pipe 10, and the other end of the pipe 11 is inserted into a storage tank 13 via a pump 12. A water-soluble organic compound having a resonance structure or an aqueous solution 14 thereof is stored in the storage tank 13 .
次に、この装置を用いた本発明の第１の発明による殺菌
水の製造法について説明する。Next, a method for producing sterilized water according to the first aspect of the present invention using this apparatus will be explained.
まず、コツクロを開き、水道等の水を導入管５を通しで
電解槽４内に導入する。電解槽４においでは、電源９に
より予め陽電極８と陰電極をなす周壁２との間に直流電
圧を印加しておく、電解槽４にあいで、水は電解作用を
受１す、水酸イオン、水素イオン、微量元素イオンなど
のイオンが形成され、電気的エネルギーを付与される。First, the tank is opened and water such as tap water is introduced into the electrolytic cell 4 through the introduction pipe 5. In the electrolytic cell 4, a DC voltage is applied in advance between the positive electrode 8 and the peripheral wall 2 forming the negative electrode by a power source 9.In the electrolytic cell 4, water undergoes electrolytic action. Ions, such as ions, hydrogen ions, and trace element ions, are formed and imparted with electrical energy.
こうして電解槽４を通された水は、取出し管１０から流
出する。一方、貯槽１３に貯留された有機化合物または
その水溶液１４が、ポンプ１２により管１１８通して取
出し管１０ヲ流れる水に添加される。こうしで、本発明
による殺菌水が得られる。The water thus passed through the electrolytic cell 4 flows out from the take-out pipe 10. On the other hand, the organic compound or its aqueous solution 14 stored in the storage tank 13 is added by the pump 12 to the water flowing through the extraction pipe 10 through the pipe 118. In this way, sterilized water according to the invention is obtained.
第２図には、本発明の第２の発明を実施するための装置
の一例が示されている。FIG. 2 shows an example of an apparatus for implementing the second aspect of the present invention.
この装置は、底板１、金属製の周壁２）上蓋３からなる
電解槽４を有し、電解槽４の内部は、水酸イオン、水素
イオンなどのイオンのみを透過する隔膜１５が設けられ
、陽極室１６と陰極室１７とに区画されでいる。図示し
ない水道の蛇口等に接続された導入管５は、途中で管５
ａ、５ｂに分岐され、管５ａは底板１を通して陽極室１
６に接続され、管５ｂは底板１を通して陰極室１７に接
続されている。なあ、導入管５にはコツクロが設けられ
でいる。上蓋３には電極支持棒７が挿通され、電極支持
棒７の下部は、陽極室１６に挿入されると共に、陽電極
８が取付けられている。そして、陽電極８は、電極支持
棒７を介して電源９の陽極に接続され、陰電極を兼ねた
周壁２は、電源９の陰電極に接続されでいる。また、上
Ｍ３には、陽極室１６に連通する取出し管１８と、陰極
室１７に連通する取出し管１９とが取付けられている。This device has an electrolytic cell 4 consisting of a bottom plate 1, a metal peripheral wall 2) and an upper lid 3, and the inside of the electrolytic cell 4 is provided with a diaphragm 15 that allows only ions such as hydroxide ions and hydrogen ions to pass through. It is divided into an anode chamber 16 and a cathode chamber 17. The introduction pipe 5 connected to a water faucet (not shown), etc.
a and 5b, and the tube 5a passes through the bottom plate 1 to the anode chamber 1.
6, and the tube 5b is connected to the cathode chamber 17 through the bottom plate 1. Incidentally, the introduction pipe 5 is provided with a lock. An electrode support rod 7 is inserted through the upper lid 3, and the lower part of the electrode support rod 7 is inserted into the anode chamber 16, and an anode 8 is attached thereto. The positive electrode 8 is connected to the anode of the power source 9 via the electrode support rod 7, and the peripheral wall 2, which also serves as a negative electrode, is connected to the negative electrode of the power source 9. Further, an extraction tube 18 communicating with the anode chamber 16 and an extraction tube 19 communicating with the cathode chamber 17 are attached to the upper M3.
そして、取出し管１８の途中には、管１１の一端が接続
されであり、管１１の他端は、ポンプ１２ヲ介して貯槽
１３に挿入されている。貯槽１３内には、共鳴構造を有
する水溶性の有機化合物またはその水溶液１４が貯留さ
れでいる。One end of the pipe 11 is connected to the middle of the take-out pipe 18, and the other end of the pipe 11 is inserted into the storage tank 13 via the pump 12. A water-soluble organic compound having a resonance structure or an aqueous solution 14 thereof is stored in the storage tank 13 .
次に、この装置を用いた本発明の第２の発明による殺菌
水の製造法について説明する。Next, a method for producing sterilized water according to the second aspect of the present invention using this apparatus will be explained.
まず、コツクロを開き、水道等の水を導入管５を通して
導入する。水は、導入管５がら分岐した管５ａ、５ｂに
それぞれ流入し、管５ａがら電解槽４の陽極室１６内に
、また、管５ｂがら電解槽４の陰極室１７内にそれぞれ
流入する。電解槽４においでは、予め電源９により陽電
極８と陰電極を兼ねた周壁２との間に直流電圧が印加さ
れている。このため、水は電解作用を受け、水酸イオン
、水素イオンなどのイオンか形成され、電気的エネルギ
ーを付与される。そして、形成されたイオンが隔膜１５
を通しで移動することにより、陽極室１６には酸性イオ
ン本が、陰極室１７にはアルカリ性イオン水が形成され
る。酸性イオン水は、取出し管１８を通しで流出し、ア
ルカリ性イオン水は、取出し管１９ヲ通しで流出する。First, the pot is opened and water, such as tap water, is introduced through the introduction pipe 5. Water flows into pipes 5a and 5b branched from the introduction pipe 5, respectively, into the anode chamber 16 of the electrolytic cell 4 through the pipe 5a, and into the cathode chamber 17 of the electrolytic cell 4 through the pipe 5b. In the electrolytic cell 4, a DC voltage is applied in advance by a power source 9 between the positive electrode 8 and the peripheral wall 2 which also serves as a negative electrode. For this reason, water is subjected to electrolytic action, forming ions such as hydroxide ions and hydrogen ions, and is given electrical energy. Then, the formed ions are transferred to the diaphragm 15.
By moving through the water, acidic ion water is formed in the anode chamber 16 and alkaline ion water is formed in the cathode chamber 17. The acidic ion water flows out through the take-out pipe 18, and the alkaline ion water flows out through the take-out pipe 19.
そして、取出し管１８を通る酸性イオン水には、貯槽１
３の有機化合物またはその水溶液１４がポンプ１２によ
つ管１３ヲ通して添加される。こうして、取出し管１８
より本発明の殺菌水を得ることができる。なお、取出し
管１９がら取出されるアルカリ性イオン水に、有機化合
物またはその水溶液＋４１８：添加して本発明の殺菌水
を得ることもできる。ざらに、取出し管１８の酸性イオ
ン水と、取出し管１９のアルカリ性イオン水とを混合し
、この混合水に有機化合物またはその水溶液１４を添加
することにより、本発明の殺菌水を得ることもできる。The acidic ion water passing through the take-out pipe 18 is stored in a storage tank 1.
3 or an aqueous solution 14 thereof is added by pump 12 through line 13. In this way, the extraction pipe 18
The sterilized water of the present invention can thus be obtained. Note that the sterilized water of the present invention can also be obtained by adding an organic compound or an aqueous solution thereof+418: to the alkaline ionized water taken out from the takeout tube 19. Alternatively, the sterilized water of the present invention can also be obtained by mixing the acidic ion water in the take-out pipe 18 and the alkaline ion water in the take-out pipe 19, and adding the organic compound or its aqueous solution 14 to this mixed water. .
なお、第１図、第２図の装置においで、貯槽１３内に、
共鳴構造を有する水溶性の有機化合物の他に、アルコー
ルを所定濃度で混合しておけば、上記有機化合物と共に
アルコールも水に添加することができる。In addition, in the apparatus shown in FIGS. 1 and 2, in the storage tank 13,
If alcohol is mixed at a predetermined concentration in addition to the water-soluble organic compound having a resonance structure, the alcohol can be added to water together with the organic compound.
実施例１
第１図の装置Ｆを用い、第１表に示すような条件、すな
わち添加物およびその濃度、印加電圧、電流、水の流量
で水を処理し、Ｎ０１１〜８の殺菌水を得た。得られた
殺菌水は、第１表に示すようなｐＨ１酸化酸化型位、酸
素溶存■、電気伝導度を有しでいた。Example 1 Using the apparatus F shown in Figure 1, water was treated under the conditions shown in Table 1, i.e., additives and their concentrations, applied voltage, current, and water flow rate, to obtain sterilized water of N011-8. Ta. The obtained sterilized water had a pH of 1, an oxidation level of 1, dissolved oxygen, and an electrical conductivity as shown in Table 1.
（以下、余白）
次に、これらの殺菌水を用いて殺菌試験を行なった。す
なわち、大腸菌を１０８個となるように水に分散した懸
濁液、ソバ粉より培養した一般雑菌を１０’個／ｃｒｎ
’となるように水に分散させた懸濁液に、それぞれ殺菌
水を同量加え、これらの混合液をフードプレート培地（
Ｂ旧培地、ＤＨＬ培地、日本製薬■製）に入れて、３５
℃で２４時間放言した後の生菌数を測定した。この結果
を第２表に示す。(Hereinafter, blank space) Next, a sterilization test was conducted using these sterilized waters. That is, a suspension of Escherichia coli dispersed in water at 108 cells, and 10' cells/crn of general bacteria cultured from buckwheat flour.
' Add the same amount of sterilized water to each suspension in water, and add these mixtures to the food plate medium (
B old medium, DHL medium, manufactured by Nippon Pharmaceutical ■), 35
The number of viable bacteria was measured after leaving the mixture at ℃ for 24 hours. The results are shown in Table 2.
（以下、余白）
第２表
実施例２
第２図の装置を用い、第３表に示すような条件、すなわ
ち添加物およびその濃度、印加電圧、電流、水の流量で
水を処理し、Ｎｏ、 ９〜１７の殺菌水を得た。得られ
た殺菌水は、第３表に示すようなｐＨ，酸化還元電位、
酸素溶存量、電気伝導度を有していた。(Hereinafter, blank spaces) Table 2 Example 2 Using the apparatus shown in Figure 2, water was treated under the conditions shown in Table 3, that is, additives and their concentrations, applied voltage, current, and water flow rate. , 9 to 17 sterilized water was obtained. The obtained sterilized water has pH, oxidation-reduction potential, and
It had a high amount of dissolved oxygen and electrical conductivity.
（以下、余白）
次に、こうして得られた殺菌水を用いて、実施例１と同
様にして殺菌試９を行なった。この結果をＭ４表に示す
。(Hereinafter, blank space) Next, sterilization test 9 was conducted in the same manner as in Example 1 using the sterilized water thus obtained. The results are shown in Table M4.
第４表
実施例３
第１図の装Ｍを用い、水を電圧２４ Ｖ、電流６００ｍ
Ａ、水の流１２１２／分で処理した後、共鳴構造を有す
る有機化合物として、グルコース、Ｄ−ガラクトース、
乳酸、どルどンＶＷそれぞれ１５００ｐｐｍとなるよう
に添加して殺菌水を得た。Table 4 Example 3 Using the device M shown in Figure 1, water was heated at a voltage of 24 V and a current of 600 m.
A. After treatment with a water flow of 1212/min, organic compounds with resonance structures include glucose, D-galactose,
Sterilized water was obtained by adding lactic acid and Dorudon VW at 1500 ppm each.
これらの殺菌水を用いて、実施例１と同様な殺菌試験を
行なったところ、第５表に示すような結果が得られた。When the same sterilization test as in Example 1 was conducted using these sterilized waters, the results shown in Table 5 were obtained.
第５表
第５表から、酢酸に限らず、グルコース、Ｄ−ガラクト
ース、乳酸、ビルどン酸などの他の共鳴構造を倚する有
機化合物を添加した場合にも、同様な殺菌効果か得られ
ることがわかる。Table 5 From Table 5, similar bactericidal effects can be obtained not only when acetic acid is added, but also when organic compounds with other resonance structures such as glucose, D-galactose, lactic acid, and bildonic acid are added. I understand that.
「発明の効果」
以上説明したように、本発明によれば、水を電解槽に導
入して電圧を印加し、この水に共鳴構造を有する水溶性
の有機化合物を添加するという簡単な工程で、侵れた殺
菌効果を有する殺菌水を得ることができる。この殺菌水
は、共Ｏａ構造を有する水溶性の有機化合物か添加され
ているだけなので、人体に対しても全く安全であり、ま
た、低コストで製造することができる。したかつて、食
品、上下水道、ａ業などの広い分野で利用することがで
きる。"Effects of the Invention" As explained above, according to the present invention, water is introduced into an electrolytic cell, a voltage is applied, and a water-soluble organic compound having a resonance structure is added to the water. , it is possible to obtain sterilized water with a strong sterilizing effect. Since this sterilized water only contains a water-soluble organic compound having a co-Oa structure, it is completely safe for the human body and can be produced at low cost. Since then, it can be used in a wide range of fields such as food, water supply and sewage, and a-industry.
第１図は本発明を実施するための装置の一例を示す概略
断面図、第２図は本発明を実施するための装置の他の例
を示す概略断面図、第３図は■結合のエネルギー準位を
示す説明図である。
図中、２は陰電極を兼ねた周壁、４は電解槽、５は導入
管、５ａ、５ｂは管、７は電極支持棒、８は陽電極、９
は電源、１０は取出し管、１１は管、１２はポンプ、１
３は貯槽、１４は有機化合物またはその水溶液、１５は
隔膜、１６は陽極室、１７は陰極室、１日、１９は取出
し管である。
第２図
■壮′飢（−−）５．５ｅＶFig. 1 is a schematic sectional view showing an example of an apparatus for carrying out the present invention, Fig. 2 is a schematic sectional view showing another example of an apparatus for carrying out the present invention, and Fig. 3 is a schematic sectional view showing an example of an apparatus for carrying out the present invention. FIG. 3 is an explanatory diagram showing levels. In the figure, 2 is a peripheral wall that also serves as a negative electrode, 4 is an electrolytic cell, 5 is an introduction tube, 5a, 5b are tubes, 7 is an electrode support rod, 8 is a positive electrode, 9
is a power supply, 10 is an extraction pipe, 11 is a pipe, 12 is a pump, 1
3 is a storage tank, 14 is an organic compound or its aqueous solution, 15 is a diaphragm, 16 is an anode chamber, 17 is a cathode chamber, and 19 is an extraction tube. Fig. 2 ■ Energy starvation (--) 5.5eV
Claims (20)
を印加し、この水に共鳴構造を有する水溶性の有機化合
物を添加することを特徴とする殺菌水の製造法。(1) A method for producing sterilized water, which comprises introducing water into an electrolytic cell having an anode and a cathode, applying a voltage, and adding a water-soluble organic compound having a resonance structure to the water.
有する水溶性の有機化合物が、カルボキシル基を有する
化合物である殺菌水の製造法。(2) The method for producing sterilized water according to claim 1, wherein the water-soluble organic compound having a resonance structure is a compound having a carboxyl group.
ル基を有する化合物が、酢酸である殺菌水の製造法。(3) The method for producing sterilized water according to claim 2, wherein the compound having a carboxyl group is acetic acid.
前記共鳴構造を有する水溶性の有機化合物の添加量が、
前記水に対して２００〜１００，０００ｐｐｍである殺
菌水の製造法。(4) In any one of claims 1 to 3,
The amount of the water-soluble organic compound having the resonance structure added is
A method for producing sterilized water having a concentration of 200 to 100,000 ppm based on the water.
前記電解槽に通した後の水の酸化還元電位が−１００〜
＋４５０ｍＶとなるように、前記電解槽に電圧を印加す
る殺菌水の製造法。(5) In any one of claims 1 to 4,
The oxidation-reduction potential of the water after passing through the electrolytic cell is -100 ~
A method for producing sterilized water, in which a voltage is applied to the electrolytic cell so that the voltage is +450 mV.
前記水に、前記共鳴構造を有する水溶性の有機化合物と
共に、アルコールを添加する殺菌水の製造法。(6) In any one of claims 1 to 5,
A method for producing sterilized water, comprising adding alcohol to the water together with a water-soluble organic compound having the resonance structure.
がエチルアルコールである殺菌水の製造法。(7) A method for producing sterilized water according to claim 6, wherein the alcohol is ethyl alcohol.
前記電解槽に水を通した後、前記共鳴構造を有する水溶
性の有機化合物を１８０分以内に添加する殺菌水の製造
法。(8) In any one of claims 1 to 7,
A method for producing sterilized water, which comprises adding a water-soluble organic compound having the resonance structure within 180 minutes after passing the water through the electrolytic cell.
前記電解槽に通した後の水の電気伝導度が１００〜３０
００μ■／ｃｍ＾３となるように前記電解槽に電圧を印
加する殺菌水の製造法。(9) In any one of claims 1 to 8,
The electrical conductivity of the water after passing through the electrolytic cell is 100 to 30.
A method for producing sterilized water in which a voltage is applied to the electrolytic cell so that the voltage becomes 00μ/cm^3.
され、陽極室と陰極室とに区画された電解槽の前記陽極
室および前記陰極室にそれぞれ水を導入して電圧を印加
し、前記陽極室から取出された水および／または前記陰
極室から取出された水に共鳴構造を有する水溶性の有機
化合物を添加することを特徴とする殺菌水の製造法。(10) Water is introduced into the anode chamber and the cathode chamber of the electrolytic cell, which has an anode and a cathode, a diaphragm is formed between the two electrodes, and is divided into an anode chamber and a cathode chamber to apply a voltage. A method for producing sterilized water, which comprises applying a water-soluble organic compound having a resonance structure to the water taken out from the anode chamber and/or the water taken out from the cathode chamber.
から取出された水と、前記陰極室から取出された水とを
混合し、この混合水に前記共鳴構造を有する水溶性の有
機化合物を添加する殺菌水の製造法。(11) In claim 10, the water taken out from the anode chamber and the water taken out from the cathode chamber are mixed, and the water-soluble organic compound having the resonance structure is added to the mixed water. Method for producing sterilized water to be added.
て、前記共鳴構造を有する水溶性の有機化合物が、カル
ボキシル基を有する化合物である殺菌水の製造法。(12) The method for producing sterilized water according to claim 10 or 11, wherein the water-soluble organic compound having a resonance structure is a compound having a carboxyl group.
キシル基を有する化合物が、酢酸である殺菌水の製造法
。(13) The method for producing sterilized water according to claim 12, wherein the carboxyl group-containing compound is acetic acid.
いて、前記共鳴構造を有する水溶性の有機化合物の添加
量が、前記水に対して２００〜１００，０００ｐｐｍで
ある殺菌水の製造法。(14) The method for producing sterilized water according to any one of claims 10 to 13, wherein the amount of the water-soluble organic compound having the resonance structure added is 200 to 100,000 ppm based on the water.
いて、前記電解槽の陽極室に通した後の水の酸化還元電
位が２００〜９００ｍＶとなるように、前記電解槽に電
圧を印加する殺菌水の製造法。(15) In any one of claims 10 to 14, a voltage is applied to the electrolytic cell so that the oxidation-reduction potential of water after passing through the anode chamber of the electrolytic cell is 200 to 900 mV. Method for producing sterilized water.
いて、前記電解槽の陰極室を通した後の水の酸化還元電
位が＋２００〜−６００ｍＶとなるように、前記電解槽
に電圧を印加する殺菌水の製造法。(16) In any one of claims 10 to 15, a voltage is applied to the electrolytic cell so that the oxidation-reduction potential of water after passing through the cathode chamber of the electrolytic cell is +200 to -600 mV. A method for producing sterilized water.
いて、前記水に、前記共鳴構造を有する水溶性の有機化
合物と共に、アルコールを添加する殺菌水の製造法。(17) A method for producing sterilized water according to any one of claims 10 to 16, wherein alcohol is added to the water together with the water-soluble organic compound having the resonance structure.
ールがエチルアルコールである殺菌水の製造法。(18) The method for producing sterilized water according to claim 17, wherein the alcohol is ethyl alcohol.
いて、前記電解槽に水を通した後、前記共鳴構造を有す
る水溶性の有機化合物を１８０分以内に添加する殺菌水
の製造法。(19) The method for producing sterilized water according to any one of claims 10 to 18, wherein the water-soluble organic compound having the resonance structure is added within 180 minutes after the water is passed through the electrolytic cell.
いて、前記電解槽を通した後の水の電気伝導度が１００
〜３０００μ■／ｃｍ＾３となるように前記電解槽に電
圧を印加する殺菌水の製造法。(20) In any one of claims 10 to 19, the electrical conductivity of water after passing through the electrolytic cell is 100.
A method for producing sterilized water in which a voltage is applied to the electrolytic cell so that the voltage is ~3000μ/cm^3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9450087A JPS63258689A (en) | 1987-04-17 | 1987-04-17 | Method for making sterilized water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9450087A JPS63258689A (en) | 1987-04-17 | 1987-04-17 | Method for making sterilized water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63258689A true JPS63258689A (en) | 1988-10-26 |
Family
ID=14112029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9450087A Pending JPS63258689A (en) | 1987-04-17 | 1987-04-17 | Method for making sterilized water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63258689A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305988A (en) * | 1987-06-08 | 1988-12-13 | Yoshiaki Matsuo | Apparatus for producing sterilized water |
| EP0647594A3 (en) * | 1993-10-09 | 1995-06-07 | Brochier Fa Hans | Electrostatic water sterilizer. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5966392A (en) * | 1982-10-04 | 1984-04-14 | Tdk Corp | Method and apparatus for manufacturing pasteurized ion water |
| JPS6119497B2 (en) * | 1978-03-20 | 1986-05-17 | Nippon Electric Co | |
| JPS61283391A (en) * | 1985-05-23 | 1986-12-13 | Sanyo Electric Co Ltd | Method for sterilizing drinking water of beverage feeder |
-
1987
- 1987-04-17 JP JP9450087A patent/JPS63258689A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6119497B2 (en) * | 1978-03-20 | 1986-05-17 | Nippon Electric Co | |
| JPS5966392A (en) * | 1982-10-04 | 1984-04-14 | Tdk Corp | Method and apparatus for manufacturing pasteurized ion water |
| JPS61283391A (en) * | 1985-05-23 | 1986-12-13 | Sanyo Electric Co Ltd | Method for sterilizing drinking water of beverage feeder |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305988A (en) * | 1987-06-08 | 1988-12-13 | Yoshiaki Matsuo | Apparatus for producing sterilized water |
| EP0647594A3 (en) * | 1993-10-09 | 1995-06-07 | Brochier Fa Hans | Electrostatic water sterilizer. |
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