JPS63256682A - Water-intercepting filler for watertight cable - Google Patents

Water-intercepting filler for watertight cable

Info

Publication number
JPS63256682A
JPS63256682A JP9058487A JP9058487A JPS63256682A JP S63256682 A JPS63256682 A JP S63256682A JP 9058487 A JP9058487 A JP 9058487A JP 9058487 A JP9058487 A JP 9058487A JP S63256682 A JPS63256682 A JP S63256682A
Authority
JP
Japan
Prior art keywords
ethylene
water
filler
propylene
hardness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9058487A
Other languages
Japanese (ja)
Other versions
JPH07116422B2 (en
Inventor
Kiyoshi Furukawa
古川 清志
Hiroshi Kobuchi
小渕 博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Cable Industries Ltd
Original Assignee
Mitsubishi Cable Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Cable Industries Ltd filed Critical Mitsubishi Cable Industries Ltd
Priority to JP9058487A priority Critical patent/JPH07116422B2/en
Publication of JPS63256682A publication Critical patent/JPS63256682A/en
Publication of JPH07116422B2 publication Critical patent/JPH07116422B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obtain the title filler which does not excessively adhere to an insulating core and bundled tapes, and has excellent watertightness, flexibility, filling characteristics, and workability, by mixing an ethylene/propylene/diene rubber with a non-halogenated polymer in a prescribed proportion. CONSTITUTION:70-30pts.wt. ethylene/propylene/diene rubber is mixed with 30-70pts.wt. non-halogenated polymer, such as an ethylene/butene copolymer, an ethylene/propylene copolymer or an ethylene/vinyl acetate copolymer, having a hardness (Shore A) of 75-90, and if necessary, Al(OH)3, ZnO, Sb2O3, clay, talc, stearic acid, etc., thus giving the title filler having a hardness (Shore A) of 50-80.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、絶縁コアや束ねテープなどと過度に接着しな
いようにした水蜜ケーブル用遮水充填剤に関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a water-shielding filler for water cables that prevents excessive adhesion to insulating cores, binding tapes, and the like.

従来の技術及び問題点 潜水艦などに用いられろ水密ケーブルは、一般に複数の
絶縁コアの撚線と、この撚線間に充填されると共に場合
によっては撚線の外周にも設けられた遮水充填剤と、こ
の遮水充填剤からなるカバ一層ないし撚線の外周に巻回
された束ねテープと、外層のシースからなる構造を有し
ており、かかる構造により高度な遮水性ないし水蜜性が
実現されている。
Conventional Technology and Problems Watertight cables used in submarines, etc. generally have a plurality of stranded wires with insulated cores, and a water-shielding filling that is filled between the strands and, in some cases, also around the outer periphery of the strands. It has a structure consisting of a cover made of this water-blocking filler or a binding tape wrapped around the outer circumference of the stranded wire, and an outer sheath, and this structure achieves a high level of water-blocking or water-retaining property. has been done.

従来、前記した遣水充填剤としては水密性や、得られる
ケーブルの可とう性などの点からパテ状態に近い未加硫
ゴムが用いられていた。
Conventionally, unvulcanized rubber, which is close to a putty state, has been used as the above-mentioned water-permeable filler in terms of watertightness and flexibility of the resulting cable.

しかしながら、シース層を押出成形して加硫処理する際
の熱で、その未加硫ゴムが絶縁コアや束ねテープと強く
接着し、ケーブル施工時における絶縁コアの取り出しが
困難になるという問題点があった。
However, the heat generated during extrusion molding and vulcanization of the sheath layer causes the unvulcanized rubber to strongly adhere to the insulating core and binding tape, making it difficult to remove the insulating core during cable construction. there were.

問題点を解決するための手段 本発明は、前記の問題点を克服した水蜜ケーブル用遮水
充填剤を提供するものである。
Means for Solving the Problems The present invention provides a water-shielding filler for water cables that overcomes the above-mentioned problems.

すなわち、本発明は、エチレン・プロピレン・ジエンゴ
ムと、硬度(ショアA)が75〜90の非ハロゲン系ポ
リマを、前者/後者の重量比で70/30〜30/70
の割合で配合してなり、その硬度(ショアA)が50〜
80であることを特徴とする水蜜ケーブル用遮水充填剤
を要旨とするものである。
That is, the present invention uses ethylene propylene diene rubber and a non-halogen polymer having a hardness (Shore A) of 75 to 90 in a weight ratio of 70/30 to 30/70.
The hardness (Shore A) is 50~
The main subject of the present invention is a water-shielding filler for a water-tight cable, which is characterized by having a hardness of 80%.

作用 前記構成により、非ハロゲン系ポリマに基づ(接着抑制
効果と共に、満足できる充填性、水蜜性を有する遣水充
填剤とすることができる。
Effects With the above structure, it is possible to obtain a water repellent filler based on a non-halogenated polymer (having an adhesion suppressing effect as well as satisfactory filling properties and water-repellent properties).

発明の構成要素の例示 本発明において用いられるエチレン・プロピレン・ジエ
ンゴムについては、成分の共重合割合やジエン成分の種
類などについて特に限定はな(、公知のものが用いられ
る。
Examples of Constituent Elements of the Invention Regarding the ethylene-propylene-diene rubber used in the present invention, there are no particular limitations on the copolymerization ratio of the components or the type of diene component (although known rubbers may be used).

本発明において用いられる非ハロゲン系ポリマは、ハロ
ゲンを含有しないものであり、硬度がショアA硬度で7
5〜90のものである。硬度が前記範囲にあるものは、
結晶性ポリマであっても用いつる。
The non-halogen-based polymer used in the present invention does not contain halogen and has a hardness of 7 on the Shore A scale.
5 to 90. Those whose hardness is within the above range,
Even crystalline polymers can be used.

好ましく用いつる非ハロゲン系ポリマとしては、エチレ
ン・ブテン共重合体、エチレン・プロピレン共重合体、
エチレン・酢酸ビニル共重合体などをあげることができ
る。
Preferably used non-halogenated polymers include ethylene/butene copolymer, ethylene/propylene copolymer,
Examples include ethylene/vinyl acetate copolymer.

本発明の遮水充填剤は、エチレン・プロピレン・ジエン
ゴムと非ハロゲン系ポリマの配合物からなるものである
。エチレン争プロピレン・ジエンゴムと非ハロゲン系ポ
リマの配合比としては、前者/後者の重量比でTo/3
0〜30/70の割合が適当である。その非ハロゲン系
ポリマの配合割合が30未満であると接着抑制効果に乏
しくなるし、70を超えると充填性に乏しくなり、水蜜
性や可とう性に優れるケーブルが得にくくなる。
The water-blocking filler of the present invention is composed of a blend of ethylene propylene diene rubber and a non-halogen polymer. The blending ratio of propylene/diene rubber to ethylene and non-halogenated polymer is To/3 in weight ratio of the former/latter.
A ratio of 0 to 30/70 is suitable. If the blending ratio of the non-halogenated polymer is less than 30, the adhesion suppressing effect will be poor, and if it exceeds 70, the filling property will be poor, making it difficult to obtain a cable with excellent water resistance and flexibility.

本発明の遮水充填剤はショアA硬度で50〜80、好ま
しくは55〜75の硬度を有するものである。その硬度
が50未満のものは接着抑制効果に乏しいし、80を超
えるものは充填性に乏しくて可とう性、水密性に優れる
ケーブルが得にくくなる。
The water-blocking filler of the present invention has a Shore A hardness of 50 to 80, preferably 55 to 75. If the hardness is less than 50, the adhesion suppressing effect is poor, and if it is more than 80, the filling property is poor, making it difficult to obtain a cable with excellent flexibility and watertightness.

本発明の遮水充填剤は前記の硬度を維持する範囲におい
て、ゴム組成物に通常配合されることのある添加剤、例
えば水酸化アルミニウム、水酸化マグネシウム、赤燐、
ホウ酸亜鉛、三酸化アンチモン、酸化亜鉛、クレー、タ
ルク、カーボンブラック、ステアリン酸、プロセス油、
ワックスなどの具体例で代表される難燃剤、充填剤、老
化防止剤、軟化剤などを通常量、含有していてもよい。
The water-blocking filler of the present invention may contain additives that are usually incorporated into rubber compositions, such as aluminum hydroxide, magnesium hydroxide, red phosphorus, etc., within the range that maintains the hardness described above.
Zinc borate, antimony trioxide, zinc oxide, clay, talc, carbon black, stearic acid, process oil,
It may contain a flame retardant exemplified by wax, a filler, an anti-aging agent, a softener, etc. in normal amounts.

本発明の遮水充填剤は、潜水艦などのように湿潤な雰囲
気となりやすいところに通例用いられろ水密ケーブルの
形成に用いられるもであり、特に絶縁コアの絶縁材がハ
ロゲンを含有しないものの場合に、有利に用いられる。
The water-blocking filler of the present invention is commonly used in places where the atmosphere is likely to be humid, such as submarines, and is used to form watertight cables, especially when the insulating material of the insulating core does not contain halogen. , used advantageously.

発明の効果 本発明の水密ケーブル用遮水充填剤は、水蜜性、可とう
性、充填性などに優れるほか、シース層を加硫処理する
際の熱によっても絶縁コアや束ねテープと強(接着しな
い特性を有している。その結果、絶縁コアを容易に取り
出すことができて、施工性に優れる水密ケーブルとする
ことができる。
Effects of the Invention The water-shielding filler for watertight cables of the present invention not only has excellent water-repellency, flexibility, and filling properties, but also has strong (adhesive) properties with the insulating core and binding tape due to the heat generated during vulcanization of the sheath layer. As a result, the insulating core can be easily taken out, making it possible to create a watertight cable with excellent workability.

実施例 実施例1 エチレン・プロピレン・ジエンゴム(EP21、日本合
成ゴム社製)50部(重量部、以下同様)と、エチレン
・ブテン共重合体(タフマーA4090、三片石油化学
社製〉50部と、酸化亜鉛5部と、ステアリン酸2部と
、水酸化アルミニウム(ハイシライト842M、昭和軽
金属社製)70部と、ナフテン系プロセス油(サンセン
4240.日本サンオイル社製)5部と、カーボンブラ
ック10部との混合物からなる遮水充填剤を得た。
Examples Example 1 Ethylene-propylene-diene rubber (EP21, manufactured by Japan Synthetic Rubber Co., Ltd.) 50 parts (by weight, the same applies hereinafter), ethylene-butene copolymer (Tafmer A4090, manufactured by Mikata Petrochemical Co., Ltd.) 50 parts , 5 parts of zinc oxide, 2 parts of stearic acid, 70 parts of aluminum hydroxide (Hisilite 842M, manufactured by Showa Light Metal Co., Ltd.), 5 parts of naphthenic process oil (Sansen 4240, manufactured by Nippon Sunoil Co., Ltd.), and 10 parts of carbon black. A water-blocking filler was obtained consisting of a mixture of

実施例2 エチレン・ブテン共重合体に代えて、エチレン・プロピ
レン共重合体(X−75、三片石油化学社製)を用いた
ほかは実施例1に準じて遮水充填剤を得た。
Example 2 A water-blocking filler was obtained according to Example 1, except that an ethylene-propylene copolymer (X-75, manufactured by Mikata Petrochemical Co., Ltd.) was used instead of the ethylene-butene copolymer.

実施例3 エチレン・プロピレン・ジエンゴムの配合量を70部と
すると共に、エチレン・ブテン共重合体に代えて、エチ
レン・酢酸ビニル共重合体くエバートに2010.三片
石油化学社製)30部を用いたほかは実施例1に準じて
遮水充填剤を得た。
Example 3 The blending amount of ethylene-propylene-diene rubber was 70 parts, and in place of the ethylene-butene copolymer, ethylene-vinyl acetate copolymer was used. A water-blocking filler was obtained according to Example 1, except that 30 parts of the filler (manufactured by Mikata Petrochemical Co., Ltd.) was used.

実施例4 赤燐(ノーバレット#120、燐化学社製)10部を追
加配合したほかは実施例2に準じて遮水充填剤を得た。
Example 4 A water-blocking filler was obtained according to Example 2, except that 10 parts of red phosphorus (Noballet #120, manufactured by Rin Kagaku Co., Ltd.) was additionally blended.

実施例S エチレン・プロピレン・ジエンゴムの配合量を30部と
すると共に、エチレン・プロピレン共重合体の配合量を
70部としたほかは実施例2に準じて遮水充填剤を得た
Example S A water-blocking filler was obtained according to Example 2, except that the amount of ethylene-propylene-diene rubber was 30 parts and the amount of ethylene-propylene copolymer was 70 parts.

実施例6 水酸化アルミニウムに代えて、水酸化マグネシウム(キ
スマー5B、協和化学社製)130部を用い、ナフテン
系プロセス油の配合量を8部としたほかは実施例4に準
じて遮水充填剤を得た。
Example 6 Waterproof filling was carried out according to Example 4, except that 130 parts of magnesium hydroxide (Kismer 5B, manufactured by Kyowa Kagaku Co., Ltd.) was used instead of aluminum hydroxide, and the amount of naphthenic process oil was 8 parts. obtained the drug.

比較例1 エチレン・プロピレン・ジエンゴムの配合量を100部
とし、エチレン・ブテン共重合体を配合しないほかは実
施例1に準じて遮水充填剤を得た。
Comparative Example 1 A water-blocking filler was obtained according to Example 1, except that the amount of ethylene-propylene-diene rubber was 100 parts and the ethylene-butene copolymer was not blended.

比較例2 エチレン・プロピレン共重合体の配合量を100部とし
、エチレン・プロピレン・ジエンゴムを配合しないほか
は実施例2に準じて遮水充填剤を得た。
Comparative Example 2 A water-blocking filler was obtained in accordance with Example 2, except that the amount of the ethylene-propylene copolymer was 100 parts, and the ethylene-propylene-diene rubber was not blended.

評価試験 [硬度] 実施例、比較例で得た遮水充填剤を70〜120℃の2
本ロールで混練し、これを120〜130℃で10分間
プレス成形して厚さ約3IIIImのシートとし、この
シートにつきJIS  K  6301に準拠して硬度
を測定した。
Evaluation test [Hardness] The water-blocking fillers obtained in Examples and Comparative Examples were
The mixture was kneaded using this roll, and then press-molded at 120 to 130°C for 10 minutes to form a sheet with a thickness of about 3IIIm, and the hardness of this sheet was measured in accordance with JIS K 6301.

[接着抑制性] エチレン・プロピレン・ジエンゴムで絶縁されたコアを
用いた3芯撚線を押出方式で得る際に、その中心の隙間
に紐状に成形した実施例又は比較例の遮水充填剤の混練
物を撚込みながら形成すると共に、各コア間に充填した
。その後、所定の厚さでハロゲンを含有しないゴムから
なるシース層を押出方式で形成し、そのシース層を15
0℃で60分間加硫処理して3×14−の水蜜ケーブル
を得た。
[Adhesion suppression property] Water-shielding filler of Examples or Comparative Examples formed into a string shape in the center gap when a three-core stranded wire using a core insulated with ethylene-propylene-diene rubber is obtained by extrusion method. The kneaded material was formed by twisting and filled between each core. Thereafter, a sheath layer made of halogen-free rubber is formed to a predetermined thickness using an extrusion method, and the sheath layer is
Vulcanization treatment was performed at 0° C. for 60 minutes to obtain a 3×14-sized water honey cable.

次に、得られた水密ケーブルを分解し、コアの絶縁層と
遮水充填剤との接着状態を調べ、引き剥がしが容易な場
合(密着していても接着していないもの、弱い接着で容
易に引き剥がせるものなど)を01引き剥がしが困難な
場合を×として評価した。
Next, the obtained watertight cable is disassembled and the adhesion state between the core insulation layer and the water-blocking filler is examined. (e.g. those that can be peeled off) were evaluated as 01, and those that were difficult to peel off were evaluated as ×.

[気密性1 水密性及び充填性並びに可とう性を評価する目的で、前
記で得た水蜜ケーブル3mをケーブル径の100倍に曲
げた状態で、その一端より窒素ガスを152mAq圧で
吹き込み、他端より流出した窒素ガスをメスシリンダ内
に集め、その採集量が50■となるまでの時間を調べ、
その時間が1時間を超える場合を○、1時間以下の場合
を×として評価した。
[Airtightness 1] For the purpose of evaluating watertightness, filling properties, and flexibility, the 3 m water cable obtained above was bent to 100 times the cable diameter, and nitrogen gas was blown into it at a pressure of 152 mAq from one end. Collect the nitrogen gas flowing out from the end into a measuring cylinder, and check the time it takes for the collected amount to reach 50μ.
A case where the time exceeded 1 hour was evaluated as ○, and a case where the time was 1 hour or less was evaluated as ×.

結果を表に示した。The results are shown in the table.

Claims (1)

【特許請求の範囲】[Claims] 1、エチレン・プロピレン・ジエンゴムと、硬度(ショ
アA)が75〜90の非ハロゲン系ポリマとを、前者/
後者の重量比で70/30〜30/70の割合で配合し
てなり、その硬度(ショアA)が50〜80であること
を特徴とする水密ケーブル用遮水充填剤。
1. Ethylene propylene diene rubber and a non-halogen polymer with a hardness (Shore A) of 75 to 90, the former /
A water-shielding filler for a watertight cable, characterized in that the latter is blended in a weight ratio of 70/30 to 30/70, and has a hardness (Shore A) of 50 to 80.
JP9058487A 1987-04-13 1987-04-13 Impermeable filler for watertight cable Expired - Fee Related JPH07116422B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9058487A JPH07116422B2 (en) 1987-04-13 1987-04-13 Impermeable filler for watertight cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9058487A JPH07116422B2 (en) 1987-04-13 1987-04-13 Impermeable filler for watertight cable

Publications (2)

Publication Number Publication Date
JPS63256682A true JPS63256682A (en) 1988-10-24
JPH07116422B2 JPH07116422B2 (en) 1995-12-13

Family

ID=14002494

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9058487A Expired - Fee Related JPH07116422B2 (en) 1987-04-13 1987-04-13 Impermeable filler for watertight cable

Country Status (1)

Country Link
JP (1) JPH07116422B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115395470A (en) * 2022-07-26 2022-11-25 沪东中华造船(集团)有限公司 Marine cable water-blocking ribbon device and water-blocking method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101486535B1 (en) * 2014-07-02 2015-01-27 (주)로이포스 Method for water-barrier tape for electric cable

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115395470A (en) * 2022-07-26 2022-11-25 沪东中华造船(集团)有限公司 Marine cable water-blocking ribbon device and water-blocking method

Also Published As

Publication number Publication date
JPH07116422B2 (en) 1995-12-13

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