JPS6325656B2 - - Google Patents

Info

Publication number
JPS6325656B2
JPS6325656B2 JP1951880A JP1951880A JPS6325656B2 JP S6325656 B2 JPS6325656 B2 JP S6325656B2 JP 1951880 A JP1951880 A JP 1951880A JP 1951880 A JP1951880 A JP 1951880A JP S6325656 B2 JPS6325656 B2 JP S6325656B2
Authority
JP
Japan
Prior art keywords
processing
rinsing
color photographic
substituted
silver halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP1951880A
Other languages
Japanese (ja)
Other versions
JPS56116031A (en
Inventor
Kazuhiro Kobayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Konica Minolta Inc
Original Assignee
Konica Minolta Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc
Priority to JP1951880A priority Critical patent/JPS56116031A/en
Publication of JPS56116031A publication Critical patent/JPS56116031A/en
Publication of JPS6325656B2 publication Critical patent/JPS6325656B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3046Processing baths not provided for elsewhere, e.g. final or intermediate washings

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明はハロゲン化銀カラー写真感光材料の処
理方法に関する。更に詳しくはハロゲン化銀カラ
ー写真感光材料の物理的性質を改良する方法に関
する。 通常のカラー写真感光材料の処理工程、特に乾
燥工程や処理後の巻き取り作業中にしばしば静電
気が発生することはよく知られているが、こうし
た静電気の発生は、例えばゴミやホコリの付着を
容易にし、現像所の作業性に重大な障害を与える
ばかりか、場合によつては著しく低下させること
になる。こうした静電気の発生は、家庭での写真
感材の保存および取り扱い中にも発生する。また
一方、現像所の作業中、家庭での写真感材の保存
および取り扱い中にすり傷が発生することも知ら
れているが、こうしたすり傷の発生も物理的故障
として無視できない。 処理後の写真感光材料の物理的性質の低下を防
止する方法として、種々の界面活性剤を含有する
最終仕上げ液で処理する方法が知られている。例
えばN−ラウリル−β−イミノジプロピオン酸の
如きN,N−ジ置換−β−アミノ−プロピオン酸
塩を含有する水溶液に浸漬する方法(特開昭51−
103429号公報)等が知られている。しかしなが
ら、これら多くの界面活性剤は、処理後の写真感
光材料に於ける静電気の発生とすり傷の発生を同
時に防止することはできず、しかも静電気の発生
を有効に防止する界面活性剤の多くはカラー写真
画像の保存安定性を著しく損うという重大な欠点
を有している。 従つて、本発明の目的は、カラー写真画像の保
存安定性を損うことなく、処理後の写真感光材料
の帯電性を下げ、静電気の発生を防止するハロゲ
ン化銀カラー写真感光材料の処理方法を提供する
ことにある。 更に本発明の他の目的は、カラー写真画像の保
存安定性を損うことなく、処理後の写真感光材料
の摩擦抵抗を下げ、すり傷の発生を防止するハロ
ゲン化銀カラー写真感光材料の処理方法を提供す
ることにある。 本発明者は種々検討の結果、ハロゲン化銀カラ
ー写真感光材料の発色現像処理工程に於いて、脱
銀処理後、下記一般式()で示される化合物を
少なくとも一種含有する浴で処理することによ
り、これらの目的が達成されることを見出した。 一般式() 式中、R1は炭素原子数8〜20の置換・未置換
の飽和ないしは不飽和アルキル基、R2,R3およ
びR4はそれぞれ水素原子または置換・未置換の
低級アルキル基(例えばメチル基、エチル基、プ
ロピル基、ブチル基、ヒドロキシエチル基等)
Xは、アニオン(水酸イオン、硝酸イオン、ハ
ロゲンイオン、メチル硫酸イオン、リン酸二水素
イオン等)を表わす。mおよびnは1〜6の整数
である。また、R1,R2,R3およびR4の置換アル
キル基としては、種々のものが選べるが、特にヒ
ドロキシアルキル基が好ましい。 次に本発明に用いる一般式()で示される化
合物の代表的具体例を示すが、これらに限定され
るものではない。 これら化合物は、処理液1当り0.01〜20g、
望ましくは0.05g〜10g添加した時良好な効果が
得られる。 また、これらの化合物は、粉状または水溶液あ
るいはイソプロパノールなど有機溶媒に溶かされ
た液として調合処理剤組成物中に内蔵させても良
い。さらに粉状または水溶液あるいはイソプロパ
ノールなど有機溶媒に溶かされた液として処理液
調製の過程あるいは調製された処理液等のいずれ
の段階で加えられても良い結果が得られる。 脱銀処理後、一般式()の化合物を少なくと
も1種含有するリンス浴で処理すること以外、本
発明の実施態様には特に制限はなく、あらゆる処
理方法が適用出来るが、たとえばその代表的なも
のとしては、定着または漂白定着後、リンス、水
洗を行なう方式、定着または漂白定着後、リン
ス、水洗、安定処理を行なう方式、定着または漂
白定着後、水洗、リンス処理を行なう方式、漂白
または漂白定着後、水洗、リンス、安定処理を行
なう方式、漂白または漂白定着後、水洗、リン
ス、水洗、安定処理を行なう方式が考えられる。 また本発明のリンス浴は、他の浴(例えば安定
浴)を兼ねてもよい。 リンス浴は一般式()で示される化合物を少
なくとも1種含有するが、また更に他の界面活性
剤、退色防止剤、硬膜剤、増白剤、柔軟剤、或い
はPH調整剤等と適宜組み合わせて使用することが
できる。有用な界面活性剤としては、パーフロロ
アルキルカルボン酸塩(例えば旭硝子製サーフロ
ンS−111,S−113)、パーフロロアルキル燐酸
エステル(例えば旭硝子製サーフロンS−112)、
パーフロロアルキルトリメチルアンモニウム塩
(例えは旭硝子製サーフロンS−121)、パーフロ
ロアルキルベタイン(例えば旭硝子製サーフロン
S−131,S−132,S−133)、パーフロロアルキ
ルEO付加物(例えば旭硝子製サーフロンS−
145)、ノニオン系有機シリコーンサーフアクタン
ト(例えばユニオンカーバイド社製ユニオンカー
バイドL−75,L−76,L−77,L−78)、カチ
オン系有機シリコーンサーフアクタント(例えば
ユニオンカーバイド社製ユニオンカーバイドL−
79)、ポリオキシエチレンアルキルエーテル(例
えば花王アトラス製エマルゲン810、エマルゲン
910)等がある。 本発明のリンス浴はカラーネガフイルム、カラ
ーペーパー、カラーポジフイルム、スライド用カ
ラー反転フイルム、映画用カラー反転フイルム、
TV用カラー反転フイルム、反転カラーペーパー
などの一般のハロゲン化銀カラー写真感光材料の
いずれの処理にも適用できる。 以下実施例によつて本発明のリンス浴を用いた
場合のハロゲン化銀カラー写真感光材料の物理的
性能の改良効果、画像安定性に関する結果を代表
的な実施例について示すが、本発明は以下の実施
例に限られるものではない。 実施例 1 サクラクローム100プロフエツシヨナル(小西
六写真工業〓製カラーリバーサルフイルム)をウ
エツジ露光後、下記の処理工程に従い現像処理を
行なつた。 処理工程(38℃) 処理時間 第一現像 …6分00秒 水 洗 …2分00秒 反 転 …2分00秒 発色現像 …6分00秒 漂白調整 …2分00秒 漂 白 …6分00秒 定 着 …4分00秒 水 洗 …4分00秒 安 定 …2分00秒 次いで同様にウエツジ露光した感材を上記の処
理工程に従い定着、水洗処理迄処理した後、本発
明の化合物を含有するリンス浴で38℃2分処理し
た後、水洗、安定処理を行なつた。 使用したリンス浴の内容と試験結果を表1に示
す。引掻強度の測定は16milの針を使用し、写真
感材裏面に傷が発生する荷重を測定することによ
つて行なつた。帯電量の測定は、写真感材の一端
に500gの錘を吊し、表面をポリエステル加工し
た円形の圧板と写真感材の裏面を接触させ、他端
を40mm/secで引つ張ることによつて生じたフイ
ルム裏面の帯電量をフアラデーケージによつて測
定することによつて行なつた。 なお、引掻強度、帯電量の測定は共に23℃20%
RHで行なつた。カラー写真画像の保存安定性の
測定は、70℃80%RHで2週間経時した時の濃度
1.5の濃度変化率を測定することによつて行なつ
た。
The present invention relates to a method for processing silver halide color photographic materials. More specifically, the present invention relates to a method for improving the physical properties of silver halide color photographic materials. It is well known that static electricity is often generated during the processing of ordinary color photographic materials, especially during the drying process and the winding operation after processing. This not only seriously impedes the workability of the photofinishing laboratory, but also significantly reduces it in some cases. Such static electricity is also generated during the storage and handling of photographic materials at home. On the other hand, it is known that scratches occur during work in a photo lab or during storage and handling of photographic materials at home, and the occurrence of such scratches cannot be ignored as a physical failure. As a method for preventing deterioration of the physical properties of photographic materials after processing, methods of processing with final finishing liquids containing various surfactants are known. For example, a method of immersion in an aqueous solution containing an N,N-disubstituted-β-amino-propionate such as N-lauryl-β-iminodipropionic acid (Japanese Unexamined Patent Application Publication No. 51-197)
103429) etc. are known. However, many of these surfactants cannot simultaneously prevent the generation of static electricity and the generation of scratches in photographic materials after processing, and many of the surfactants that can effectively prevent the generation of static electricity has the serious drawback of significantly impairing the storage stability of color photographic images. Therefore, an object of the present invention is to provide a method for processing a silver halide color photographic material, which reduces the chargeability of the photographic material after processing and prevents the generation of static electricity, without impairing the storage stability of color photographic images. Our goal is to provide the following. Still another object of the present invention is to process a silver halide color photographic material to reduce the frictional resistance of the photographic material after processing and prevent the occurrence of scratches without impairing the storage stability of color photographic images. The purpose is to provide a method. As a result of various studies, the present inventor discovered that in the color development process of silver halide color photographic light-sensitive materials, after desilvering treatment, by treating with a bath containing at least one compound represented by the following general formula (). , found that these objectives were achieved. General formula () In the formula, R 1 is a substituted or unsubstituted saturated or unsaturated alkyl group having 8 to 20 carbon atoms, and R 2 , R 3 and R 4 are each a hydrogen atom or a substituted or unsubstituted lower alkyl group (for example, a methyl group). , ethyl group, propyl group, butyl group, hydroxyethyl group, etc.)
X represents an anion (hydroxide ion, nitrate ion, halogen ion, methyl sulfate ion, dihydrogen phosphate ion, etc.). m and n are integers of 1-6. Furthermore, various substituted alkyl groups can be selected as the substituted alkyl groups for R 1 , R 2 , R 3 and R 4 , but hydroxyalkyl groups are particularly preferred. Next, typical examples of the compound represented by the general formula () used in the present invention will be shown, but the invention is not limited thereto. These compounds are 0.01 to 20g per 1 treatment liquid,
Good effects can be obtained preferably when 0.05g to 10g is added. Further, these compounds may be incorporated into the formulated treatment composition as a powder, an aqueous solution, or a liquid dissolved in an organic solvent such as isopropanol. Furthermore, good results can be obtained even if it is added in the form of a powder, an aqueous solution, or a liquid dissolved in an organic solvent such as isopropanol at any stage of the preparation of the processing solution or the prepared processing solution. After the desilvering treatment, there are no particular limitations on the embodiments of the present invention, other than treatment with a rinsing bath containing at least one compound of the general formula (), and any treatment method can be applied. Methods include rinsing and rinsing after fixing or bleach-fixing, rinsing, rinsing and stabilization after fixing or bleach-fixing, rinsing and rinsing after fixing or bleach-fixing, and bleaching or bleaching. Possible methods include washing with water, rinsing, and stabilizing treatment after fixing, and washing with water, rinsing, rinsing, and stabilizing treatment after bleaching or bleach-fixing. Further, the rinsing bath of the present invention may also serve as another bath (for example, a stabilizing bath). The rinsing bath contains at least one compound represented by the general formula (), and may also be appropriately combined with other surfactants, anti-fading agents, hardeners, brighteners, softeners, PH adjusters, etc. can be used. Useful surfactants include perfluoroalkyl carboxylates (e.g. Surflon S-111, S-113 manufactured by Asahi Glass), perfluoroalkyl phosphates (e.g. Surflon S-112 manufactured by Asahi Glass),
Perfluoroalkyltrimethylammonium salts (e.g. Asahi Glass Surflon S-121), perfluoroalkyl betaines (e.g. Asahi Glass Surflon S-131, S-132, S-133), perfluoroalkyl EO adducts (e.g. Asahi Glass Surflon) S-
145), nonionic organic silicone surfactants (e.g. Union Carbide L-75, L-76, L-77, L-78 manufactured by Union Carbide), cationic organic silicone surfactants (e.g. Union Carbide manufactured by Union Carbide) L-
79), polyoxyethylene alkyl ether (e.g. Kao Atlas Emulgen 810, Emulgen
910) etc. The rinsing bath of the present invention is suitable for color negative film, color paper, color positive film, color reversal film for slides, color reversal film for movies,
It can be applied to any processing of general silver halide color photographic materials such as TV color reversal film and reversal color paper. In the following Examples, the effects of improving the physical performance of silver halide color photographic materials and the results regarding image stability when using the rinsing bath of the present invention will be shown with respect to typical examples. The present invention is not limited to this embodiment. Example 1 Sakura Chrome 100 Professional (color reversal film manufactured by Konishi Roku Photo Industries) was exposed to light using a wedge and then developed according to the following process steps. Processing process (38℃) Processing time First development...6 minutes 00 seconds Water washing...2 minutes 00 seconds Reversing...2 minutes 00 seconds Color development...6 minutes 00 seconds Bleaching adjustment...2 minutes 00 seconds Bleaching...6 minutes 00 seconds Seconds Fixation...4 minutes 00 seconds Water washing...4 minutes 00 seconds Stability...2 minutes 00 seconds Next, the wet-exposed photosensitive material was processed in the same manner as described above until it was fixed and washed with water, and then the compound of the present invention was applied. After treatment at 38°C for 2 minutes in a rinsing bath containing water, washing with water and stabilization treatment were performed. Table 1 shows the contents of the rinse bath used and the test results. The scratch strength was measured using a 16 mil needle and measuring the load at which scratches occurred on the back side of the photographic material. The amount of charge can be measured by suspending a 500 g weight from one end of the photosensitive material, bringing the back side of the photosensitive material into contact with a circular pressure plate whose surface is treated with polyester, and pulling the other end at a rate of 40 mm/sec. The amount of charge generated on the back side of the film was measured using a Faraday cage. The scratch strength and charge amount were both measured at 23°C and 20%.
It was done at RH. The storage stability of color photographic images is measured by the density after 2 weeks at 70°C and 80%RH.
This was done by measuring the concentration change rate of 1.5.

【表】 以上の結果から、本発明のリンス浴で処理する
ことにより静電気の発生と、すり傷の発生を共に
有効に防止することができ、しかもカラー画像の
保存安定性に何ら悪影響を及ぼさないことが明ら
かであろう。 また、定着処理後、水洗処理することなしに同
じ組成のリンス浴で38℃2分処理した後、水洗、
安定処理しても良い結果が得られる。 実施例 2 実施例1で使用したものと同じ感光材料をウエ
ツジ露光した後、実施例1と同一の処理工程で現
像処理した。ここで使用した安定浴の組成は次の
通りである。 ホルマリン(37%) 6g エマルゲン810(花王アトラス製) 0.5g サーフロンS−113(旭硝子製) 0.5g 水を加えて 1 次いで同様にウエツジ露光した感材を同一の処
理工程に従い定着、水洗処理まで処理した後、上
記安定浴に本発明の化合物を添加した安定−リン
ス浴で38℃2分処理した。 使用した化合物とテスト結果を表2に示す。引
掻強度、帯電量およびカラー写真画像の保存安定
性の測定は、実施例1と同様に行なつた。
[Table] From the above results, treatment with the rinsing bath of the present invention can effectively prevent both the generation of static electricity and the generation of scratches, and has no adverse effect on the storage stability of color images. That should be obvious. In addition, after the fixing process, without washing with water, process in a rinse bath with the same composition for 2 minutes at 38°C, then wash with water,
Good results can be obtained even with stable processing. Example 2 The same photosensitive material used in Example 1 was subjected to wedge exposure and then developed in the same processing steps as in Example 1. The composition of the stabilizing bath used here is as follows. Formalin (37%) 6g Emulgen 810 (manufactured by Kao Atlas) 0.5g Surflon S-113 (manufactured by Asahi Glass) 0.5g Add water 1 Then, the same process was carried out using the same process to fix and wash the wet-exposed sensitive material. After that, the sample was treated in a stable rinsing bath at 38°C for 2 minutes, in which the compound of the present invention was added to the above-mentioned stable bath. Table 2 shows the compounds used and the test results. The scratch strength, charge amount, and storage stability of color photographic images were measured in the same manner as in Example 1.

【表】【table】

【表】 以上の結果から、本発明の化合物を添加した安
定−リンス浴で処理することによつても静電気の
発生と、すり傷の発生を共に有効に防止すること
ができ、しかもカラー画像の保存安定性に何ら悪
影響を及ぼさないことが明らかであろう。
[Table] From the above results, treatment with a stable rinsing bath containing the compound of the present invention can effectively prevent both the generation of static electricity and the generation of scratches. It will be clear that there is no adverse effect on storage stability.

Claims (1)

【特許請求の範囲】 1 ハロゲン化銀カラー写真感光材料の発色現像
処理工程に於いて、脱銀処理後、下記一般式
()で示される化合物を少なくとも一種含有す
る浴で処理することを特徴とするハロゲン化銀カ
ラー写真感光材料の処理方法。 一般式() 〔式中、R1は炭素原子数8〜20の置換・未置換
の飽和ないしは不飽和アルキル基、R2,R3およ
びR4はそれぞれ水素原子または置換・未置換の
低級アルキル基、Xはアニオン、mおよびnは
1〜6の整数を表わす。〕
[Scope of Claims] 1. In the color development process of a silver halide color photographic light-sensitive material, after desilvering treatment, the material is treated with a bath containing at least one compound represented by the following general formula (). A method for processing silver halide color photographic materials. General formula () [In the formula, R 1 is a substituted or unsubstituted saturated or unsaturated alkyl group having 8 to 20 carbon atoms, R 2 , R 3 and R 4 are each a hydrogen atom or a substituted or unsubstituted lower alkyl group, and X is a substituted or unsubstituted lower alkyl group. The anion, m and n represent integers of 1 to 6. ]
JP1951880A 1980-02-18 1980-02-18 Processing method for silver halide color photographic sensitive material Granted JPS56116031A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1951880A JPS56116031A (en) 1980-02-18 1980-02-18 Processing method for silver halide color photographic sensitive material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1951880A JPS56116031A (en) 1980-02-18 1980-02-18 Processing method for silver halide color photographic sensitive material

Publications (2)

Publication Number Publication Date
JPS56116031A JPS56116031A (en) 1981-09-11
JPS6325656B2 true JPS6325656B2 (en) 1988-05-26

Family

ID=12001561

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1951880A Granted JPS56116031A (en) 1980-02-18 1980-02-18 Processing method for silver halide color photographic sensitive material

Country Status (1)

Country Link
JP (1) JPS56116031A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0234807U (en) * 1988-08-30 1990-03-06
JPH04133947U (en) * 1991-06-01 1992-12-14 愛知機械工業株式会社 Rear under mirror mounting structure
JPH0593993U (en) * 1992-06-01 1993-12-21 日産ディーゼル工業株式会社 Outside mirror body mounting structure

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3674202B2 (en) * 1996-12-04 2005-07-20 日本エクスラン工業株式会社 Antibacterial acrylonitrile fiber and method for producing the same
US7119047B1 (en) 2001-02-26 2006-10-10 C And T Company, Inc. Modified activated carbon for capacitor electrodes and method of fabrication thereof
DE10113334A1 (en) * 2001-03-20 2002-09-26 Cognis Deutschland Gmbh Novel quaternary surfactants, with amphoteric betaine or cationic quaternary amide structure, are useful in cosmetic, pharmaceutical, detergent, rinsing or revivifying compositions and have good storage stability

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0234807U (en) * 1988-08-30 1990-03-06
JPH04133947U (en) * 1991-06-01 1992-12-14 愛知機械工業株式会社 Rear under mirror mounting structure
JPH0593993U (en) * 1992-06-01 1993-12-21 日産ディーゼル工業株式会社 Outside mirror body mounting structure

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JPS56116031A (en) 1981-09-11

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