JPS63250325A - Antimicrobial composition for spray - Google Patents
Antimicrobial composition for sprayInfo
- Publication number
- JPS63250325A JPS63250325A JP8535587A JP8535587A JPS63250325A JP S63250325 A JPS63250325 A JP S63250325A JP 8535587 A JP8535587 A JP 8535587A JP 8535587 A JP8535587 A JP 8535587A JP S63250325 A JPS63250325 A JP S63250325A
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- antibacterial
- ion
- spray
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000007921 spray Substances 0.000 title claims abstract description 20
- 230000000845 anti-microbial effect Effects 0.000 title abstract description 10
- 239000010457 zeolite Substances 0.000 claims abstract description 69
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 67
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 64
- -1 woods Substances 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003380 propellant Substances 0.000 claims abstract description 10
- 238000005342 ion exchange Methods 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 9
- 239000004332 silver Substances 0.000 claims abstract description 9
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000001273 butane Substances 0.000 claims abstract description 4
- 239000003915 liquefied petroleum gas Substances 0.000 claims abstract description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 239000010949 copper Substances 0.000 claims abstract description 3
- 239000001294 propane Substances 0.000 claims abstract description 3
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229940029284 trichlorofluoromethane Drugs 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 239000011701 zinc Substances 0.000 claims abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 58
- 150000002500 ions Chemical class 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 4
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 3
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 claims description 2
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 claims description 2
- 229940099364 dichlorofluoromethane Drugs 0.000 claims description 2
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 claims description 2
- 229910052675 erionite Inorganic materials 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 5
- 239000002781 deodorant agent Substances 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- 241000894006 Bacteria Species 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 12
- 239000000123 paper Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000002609 medium Substances 0.000 description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 7
- 229910001431 copper ion Inorganic materials 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 7
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 241000233866 Fungi Species 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- 239000008272 agar Substances 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 241000193755 Bacillus cereus Species 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000012149 noodles Nutrition 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 239000002504 physiological saline solution Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000222120 Candida <Saccharomycetales> Species 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000012136 culture method Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000002953 phosphate buffered saline Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000001965 potato dextrose agar Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は抗菌性スプレーに関し、更に詳しくは、抗菌性
ゼオライトを含有する抗菌性スプレーに関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an antibacterial spray, and more particularly to an antibacterial spray containing an antibacterial zeolite.
従来から、抗菌性ゼオライトを用いて高分子体に殺菌性
(抗菌性)を付与することは知られている〔特開昭59
−133235号公報〕。特開昭59−133235号
公報には、抗菌性ゼオライトと有機高分子とからなるゼ
オライト粒子含を高分子体が開示されている。ところが
、該高分子体の抗菌性は、高分子体の表面近傍に存在す
る抗菌性ゼオライトの作用によるものであり、高分子体
内部に存在する抗菌性ゼオライトは、高分子体の抗菌性
にはほとんど寄与しない。従って、抗菌性ゼオライトの
利用率を高めるという観点からは、抗菌性ゼオライトは
高分子体の表面付近のみに存在することが好ましい。It has been known for some time that antibacterial zeolites can be used to impart bactericidal properties (antibacterial properties) to polymers [Japanese Patent Application Laid-Open No. 59-19902]
-133235 Publication]. JP-A-59-133235 discloses a polymer containing zeolite particles consisting of antibacterial zeolite and an organic polymer. However, the antibacterial properties of the polymer are due to the action of antibacterial zeolite present near the surface of the polymer, and the antibacterial zeolite present inside the polymer has no effect on the antibacterial properties of the polymer. contributes little. Therefore, from the viewpoint of increasing the utilization rate of the antibacterial zeolite, it is preferable that the antibacterial zeolite exists only near the surface of the polymer.
又、前記特開昭59−133235号公報に記載の抗菌
性を有する高分子体を得るには、高分子体中に抗菌性ゼ
オライトを混合する必要がある。Furthermore, in order to obtain the antibacterial polymer described in JP-A-59-133235, it is necessary to mix antibacterial zeolite into the polymer.
ところが、該方法は、既にフィルム、板、容器、繊維等
に成型されている高分子体には適用できず、又高分子体
に限らず、例えば壁の防カビ等には全く応用できない。However, this method cannot be applied to polymers that have already been molded into films, plates, containers, fibers, etc., and it cannot be applied not only to polymers but also to mold-proofing walls, etc. at all.
そこで本発明の目的は、抗菌性を付与したい物品に、簡
単にかつその物品の表面にのみ抗菌性(殺菌性)を付与
できる抗菌性スプレー用組成物及び該組成物を用いたス
プレーを提供することにある。Therefore, an object of the present invention is to provide an antibacterial spray composition that can easily impart antibacterial properties (sterilizing properties) only to the surface of an article to which it is desired to impart antibacterial properties, and a spray using the composition. There is a particular thing.
本発明は、抗菌性ゼオライト、アルコール及び噴射剤を
含む抗菌性スプレー用組成物に関する。The present invention relates to an antimicrobial spray composition comprising an antimicrobial zeolite, an alcohol and a propellant.
以下本発明について説明する。The present invention will be explained below.
本発明の組成物は「抗菌性ゼオライト」を含有するもの
である。ここで抗菌性ゼオライトとは、ゼオライト中の
イオン交換可能なイオンの一部又は全部を抗菌性金属イ
オンでイオン交換したちのである。抗菌性ゼオライトに
含まれる抗菌性金属イオンとしては、例えば銀、銅及び
亜鉛からなる群から選ばれる少なくとも一種の金属のイ
オンを挙げることができる。さらに、本発明に用いる抗
菌性ゼオライト中のイオン交換可能なイオンの一部は、
さらにアンモ、ニウムイオンでイオン交換されているも
のであることができる。アンモニウムイオンを含む抗菌
性ゼオライトを含有する組成物は、それを適用したポリ
マーを経時的に変色させることが少ないことから特に好
ましい。The composition of the present invention contains "antibacterial zeolite". Here, the antibacterial zeolite is one in which some or all of the ion-exchangeable ions in the zeolite have been ion-exchanged with antibacterial metal ions. Examples of the antibacterial metal ion contained in the antibacterial zeolite include ions of at least one metal selected from the group consisting of silver, copper, and zinc. Furthermore, some of the ion-exchangeable ions in the antibacterial zeolite used in the present invention are
Furthermore, it can be ion-exchanged with ammonium or nium ions. Compositions containing antibacterial zeolites containing ammonium ions are particularly preferred because the polymers to which they are applied are less likely to discolor over time.
すなわち本発明に用いる抗菌性ゼオライトは、ゼオライ
ト中のイオン交換可能なイオン、例えばナトリウムイオ
ン、カルシウムイオン、カリウムイオン、マグネシウム
イオン、鉄イオン等のその一部又は全部を前記抗菌性金
属イオン及びさらに必要によりアンモニウムイオンで1
換したものである。ゼオライト中の銀イオンの含有量は
0.1〜15%、好ましくは0.1〜5%とすることが
優れた抗菌力を示すという観点から適当である。又銅イ
オン及び亜鉛イオンの含有量は、いずれも0.1〜8%
とすることが好ましい。さらにゼオライト中のアンモニ
ウムイオンの含有量は0.5〜5%、好ましくは0.5
〜2%とすることが、該ゼオライトによるポリマー等の
変色を有効に防止するという観点から適当である。尚、
本明細書において、%とは110℃乾燥基準の重量%を
いう。That is, the antibacterial zeolite used in the present invention replaces some or all of the ion-exchangeable ions in the zeolite, such as sodium ions, calcium ions, potassium ions, magnesium ions, iron ions, etc. with the antibacterial metal ions and further necessary 1 for ammonium ion by
It has been replaced. The content of silver ions in the zeolite is suitably from 0.1 to 15%, preferably from 0.1 to 5%, from the viewpoint of exhibiting excellent antibacterial activity. In addition, the content of copper ions and zinc ions is both 0.1 to 8%.
It is preferable that Furthermore, the ammonium ion content in the zeolite is 0.5 to 5%, preferably 0.5%.
From the viewpoint of effectively preventing discoloration of polymers and the like caused by the zeolite, it is appropriate to set the content to 2%. still,
In this specification, % refers to % by weight on a dry basis at 110°C.
本発明において抗菌性ゼオライトに用いる「ゼオライト
」としては、天然ゼオライト及び合成ゼオライトのいず
れも用いることができる。ゼオライトは、一般に三次元
骨格構造を有するアルミノシリケートであり、一般式と
してはXM2/n O・虞20.・YS102・2H,
Oで表示される。ここでMはイオン交換可能なイオンを
表わし通常は1又は2価の金属のイオンである。nは(
金属)イオンの原子価である。XおよびYはそれぞれの
金属酸化物、シリカ係数、Zは結晶水の数を表示してい
る。ゼオライトの具体例としては例えばA型ゼオライト
、X型ゼオライト、Y型ゼオライト、モルデナイト、ク
リノプチロライト、チャバサイト、エリ・オナイト等を
挙げることができる。ただしこれらに限定されるもので
はない。これら例示ゼオライトのイオン交換容量は、A
型ゼオライト?meq/g % X型ゼオライト6、4
meq/g 、 Y型ゼオライト5 meq/g 。As the "zeolite" used for the antibacterial zeolite in the present invention, both natural zeolite and synthetic zeolite can be used. Zeolites are generally aluminosilicates with a three-dimensional skeleton structure, and have a general formula of XM2/nO.・YS102・2H,
Displayed as O. Here, M represents an ion exchangeable ion, and is usually a monovalent or divalent metal ion. n is (
(metal) ion valence. X and Y represent the respective metal oxide and silica coefficients, and Z represents the number of water of crystallization. Specific examples of zeolites include A-type zeolite, X-type zeolite, Y-type zeolite, mordenite, clinoptilolite, chabasite, and eri-onite. However, it is not limited to these. The ion exchange capacity of these exemplary zeolites is A
type zeolite? meq/g % X-type zeolite 6, 4
meq/g, Y-type zeolite 5 meq/g.
モルデナイト2.6meq/g 、クリノプチロライト
2.13 meq/g 、チャバサイト5 meq/g
、エリオナイ) 3.3meq/g であり、いずれ
もアンモニウムイオン及び銀イオンでイオン交換するに
充分の容量を有している。mordenite 2.6 meq/g, clinoptilolite 2.13 meq/g, chabasite 5 meq/g
, Erionai) 3.3 meq/g, and both have sufficient capacity for ion exchange with ammonium ions and silver ions.
又、合成ゼオライトは平均粒径が0.2〜10μm1好
ましくは0.6〜6μmであり、最大粒径が10μm以
下、好ましくは6μm以下のものであることが、スプレ
ーとしたときの噴霧が良好であることから好ましい。In addition, the synthetic zeolite should have an average particle size of 0.2 to 10 μm, preferably 0.6 to 6 μm, and a maximum particle size of 10 μm or less, preferably 6 μm or less, to ensure good atomization when sprayed. This is preferable.
以下本発明に用いる抗菌性ゼオライトの製造方法につい
て説明する。The method for producing the antibacterial zeolite used in the present invention will be explained below.
本発明の抗菌性ゼオライトは、予め調製した抗菌性イオ
ン(銀イオン、銅イオン、亜鉛イオン)さらに必要によ
りアンモニウムイオンを含有する(混合)水溶液にゼオ
ライトを接触させて、ゼオライト中のイオン交換可能な
イオンと上記イオンとを置換させる。接触は、10〜7
0℃、好ましくは40〜60℃で3〜24時間、好まし
くは10〜24時間バッチ式又は連続式(例えばカラム
法)によって行うことができる。尚上記混合水溶液のp
)Iは3〜10、好ましくは5〜7に調整する。該調整
により、銀の酸化物等のゼオライト表面又は細孔内への
析出を防止できるので好ましい。The antibacterial zeolite of the present invention is produced by contacting the zeolite with an aqueous solution containing (mixed) antibacterial ions (silver ions, copper ions, zinc ions) and, if necessary, ammonium ions, prepared in advance, so that the ions in the zeolite can be exchanged. The ion is replaced with the above ion. Contact is 10-7
It can be carried out at 0°C, preferably 40 to 60°C, for 3 to 24 hours, preferably 10 to 24 hours, by a batch method or a continuous method (for example, a column method). In addition, p of the above mixed aqueous solution
) I is adjusted to 3-10, preferably 5-7. This adjustment is preferable because it can prevent silver oxides and the like from being deposited on the zeolite surface or into the pores.
又、(混合)水溶液中の各イオンは、通常いずれも塩と
して供給される。例えば銀イオンは、硝酸銀、硫酸銀等
、銅イオンは硝酸銅(■)、硫酸銅等、亜鉛イオンは硝
酸亜鉛(■)、硫酸亜鉛等、アンモニウムイオンは、硝
酸アンモニウム、硫酸アンモニウム、酢酸アンモニウム
等、を用いることができる。Further, each ion in the (mixed) aqueous solution is usually supplied as a salt. For example, silver ions include silver nitrate, silver sulfate, etc., copper ions include copper nitrate (■), copper sulfate, etc., zinc ions include zinc nitrate (■), zinc sulfate, etc., and ammonium ions include ammonium nitrate, ammonium sulfate, ammonium acetate, etc. Can be used.
ゼオライト中の抗菌性金属イオン等の含有量は前記混合
水溶液中の各イオン(塩)a度を調節することによって
、適宜制御することができる。例えば抗菌性ゼオライト
が銀イオン及びアンモニウムイオンを含有する場合、前
記混合水溶液中のアンモニウムイオン濃度を0.85M
/l〜3.1M/β、銀イオン濃度を0.(10)2M
/42〜0.15M/!とすることによって、適宜、ア
ンモニウムイオン含有量0.5〜5%、銀イオン含有量
0.1〜5%の抗菌性ゼオライトを得ることができる。The content of antibacterial metal ions, etc. in the zeolite can be appropriately controlled by adjusting the a degree of each ion (salt) in the mixed aqueous solution. For example, when the antibacterial zeolite contains silver ions and ammonium ions, the ammonium ion concentration in the mixed aqueous solution is 0.85M.
/l~3.1M/β, silver ion concentration 0. (10) 2M
/42~0.15M/! By doing so, an antibacterial zeolite having an ammonium ion content of 0.5 to 5% and a silver ion content of 0.1 to 5% can be obtained as appropriate.
又、抗菌性ゼオライトが銅イオン、亜鉛イオンを含有す
る場合、前記混合水溶液中の銅イオン濃度は0.1M/
1〜0.85M/β、亜鉛イオン濃度は0.15M/β
〜1..2M/Ilとすることによって、適宜銅イオン
含有量0.1〜8%、亜鉛イオン含有量0.1〜8%の
抗菌性ゼオライトを得ることができる。In addition, when the antibacterial zeolite contains copper ions and zinc ions, the copper ion concentration in the mixed aqueous solution is 0.1M/
1 to 0.85M/β, zinc ion concentration is 0.15M/β
~1. .. By adjusting the ratio to 2M/Il, an antibacterial zeolite having an appropriate copper ion content of 0.1 to 8% and a zinc ion content of 0.1 to 8% can be obtained.
本発明においては、前記の如き混合水溶液以外に各イオ
ンを単独で含有する水溶液を用い、各水溶液とゼオライ
トとを逐次接触させることによって、イオン交換するこ
ともできる。各水溶液中の各イオンの濃度は、前記混合
水溶液中の各イオン濃度に準じて定めることができる。In the present invention, in addition to the mixed aqueous solution as described above, ion exchange can also be performed by using an aqueous solution containing each ion individually and bringing each aqueous solution into contact with the zeolite sequentially. The concentration of each ion in each aqueous solution can be determined according to the concentration of each ion in the mixed aqueous solution.
イオン交換が終了したゼオライトは、充分に水洗した後
、乾燥する。乾燥は、常圧で105℃〜115℃、又は
減圧(1〜3Qtorr)下70℃〜90℃で行うこと
が好ましい。After ion exchange, the zeolite is thoroughly washed with water and then dried. Drying is preferably carried out at 105° C. to 115° C. under normal pressure or at 70° C. to 90° C. under reduced pressure (1 to 3 Qtorr).
本発明の組成物は、抗菌性ゼオライトに加えて、アルコ
ール及び噴射剤を含有する。In addition to the antimicrobial zeolite, the composition of the invention contains alcohol and a propellant.
アルコールとしては、例えばエタノール、等を挙げるこ
とができ、特に安全性の点からエタノールであることが
好ましい。Examples of the alcohol include ethanol, and ethanol is particularly preferred from the viewpoint of safety.
又、噴射剤としてはフロンガス〔例えばトリクロロフル
オロメタン、ジクロロフルオロメタン又はそれらの混合
物、又はジクロロテトラフルオロエタン等〕又は液化石
油ガス〔例えばプロパン、ブタン等〕等を挙げることが
できる。特にブタンであることが好ましい。Examples of the propellant include chlorofluorocarbon gas (for example, trichlorofluoromethane, dichlorofluoromethane, or a mixture thereof, or dichlorotetrafluoroethane) or liquefied petroleum gas (for example, propane, butane, etc.). Particularly preferred is butane.
本発明の組成物は、抗菌性ゼオライト1〜10%、好ま
しくは2〜6%、アルコール29〜49%、好ましくは
35〜40%及び噴射剤50〜70%、好ましくは55
〜65%を含有するものであることが適当である。The composition of the invention comprises 1-10% antibacterial zeolite, preferably 2-6%, alcohol 29-49%, preferably 35-40% and propellant 50-70%, preferably 55%.
It is suitable that the content is 65%.
本発明の抗菌性スプレー用組成物は、常法により、噴霧
器付の缶に密封することによって抗菌性スプレーを得る
ことができる。該スプレーは、クツの消臭用、スポーツ
後の体臭消臭用、デオドラント用、生ゴミ消臭用、防黴
用スプレーとして用いることができる。又、各種樹脂、
紙、木材、セメント、有機壁材、無機壁材、金属等の表
面に抗菌性等を付与する目的で使用することもできる。An antibacterial spray can be obtained from the antibacterial spray composition of the present invention by sealing it in a can with an atomizer according to a conventional method. The spray can be used for deodorizing shoes, body odor after sports, deodorant, garbage deodorizing, and anti-mold spray. Also, various resins,
It can also be used to impart antibacterial properties to the surfaces of paper, wood, cement, organic wall materials, inorganic wall materials, metals, etc.
即ち、例えばポリエチレン、ポリプロピレン、塩化ヒニ
ル、ABSI脂、ナイロン、ポリエステル、ポリ塩化ビ
ニリデン、ポリアミド、ポリスチレン、ポリアセタール
、ポリビニールアルコール、ポリカーボネイト、アクリ
ル樹脂、ふっ素樹脂、ポリウレタンエラストマー、ポリ
エステルエラストマー、フェノール樹脂、ユリア樹脂、
メラミン樹脂、不飽和ポリエステル樹脂、エポキシ樹脂
、ウレタン樹脂、レーヨン、キニプラ、アセテート、ト
リアセテート、ビニリデン、天然及び合成ゴムなどの熱
可塑性又は熱硬化性樹脂にスプレーすることによってコ
ーティングして、これら樹脂に抗菌・防黴・防藻機能を
付加する事が可能である。That is, for example, polyethylene, polypropylene, vinyl chloride, ABSI resin, nylon, polyester, polyvinylidene chloride, polyamide, polystyrene, polyacetal, polyvinyl alcohol, polycarbonate, acrylic resin, fluororesin, polyurethane elastomer, polyester elastomer, phenol resin, urea resin. ,
Antibacterial properties can be applied to thermoplastic or thermosetting resins such as melamine resins, unsaturated polyester resins, epoxy resins, urethane resins, rayon, Kinipla, acetate, triacetate, vinylidene, natural and synthetic rubbers by spraying the coating on them.・It is possible to add anti-mold and anti-algae functions.
塗料分野では油性塗料、ラッカー、フェス、アルキル樹
脂系、アミノアルキド樹脂系、ビニール樹脂系、アクリ
ル樹脂系、エポキシ樹脂系、ウレタン樹脂系、水系、粉
体系、塩化ゴム系、フェノール系、などの各種塗料の塗
膜表面にスプレーすることによりコーティングして、塗
膜に防菌・防黴・防藻機能を付加する事が可能である。In the paint field, there are a variety of oil-based paints, lacquers, paints, alkyl resins, amino alkyd resins, vinyl resins, acrylic resins, epoxy resins, urethane resins, water-based, powder-based, chlorinated rubber-based, phenol-based, etc. It is possible to add antibacterial, anti-mold, and anti-algae functions to the paint film by spraying it on the surface of the paint film.
建築分野では目地材、壁材、タイル、コンクリートなど
の表面にスプレーすることによりコーティングして、抗
菌・防黴・防藻機能を付加する事が可能である。In the construction field, it can be sprayed to coat the surfaces of joints, wall materials, tiles, concrete, etc. to add antibacterial, anti-mold, and anti-algae properties.
製紙分野ではぬれティッシュ、紙包材、セロファン紙、
ダンボール、敷紙、鮮度保持紙にスプレーすることによ
りコーティングしてこれらの紙に抗菌・防黴機能を付加
する事が可能である。In the paper manufacturing field, wet tissues, paper packaging materials, cellophane paper,
It is possible to add antibacterial and anti-mildew properties to cardboard, paperboards, and freshness-preserving papers by spraying them to coat them.
本発明の抗菌性スプレー組成物は、上記の諸分野に限ら
ず、一般細菌・真菌、藻、など微生物の発生、増殖の防
止を必要とするあらゆる分野で利用可能である。The antibacterial spray composition of the present invention can be used not only in the above-mentioned fields but also in any field that requires prevention of the generation and proliferation of microorganisms such as general bacteria, fungi, and algae.
以下本発明を実施例によりさらに詳細に説明する。The present invention will be explained in more detail below with reference to Examples.
参考例(抗菌性ゼオライトの調製法)
ゼオライトハ、A型セ、t 5 イ) (Na20−A
120.:1、9SiO,”XH2O(X = 3〜
5 ) :平均粒径1.5 μra)を使用し た。Reference example (preparation method of antibacterial zeolite)
120. :1,9SiO,"XH2O (X = 3~
5): Average particle size 1.5 μra) was used.
イオン交換の為の各イオンを提供するための塩としテN
H4N 03、A g N Os及びCLI (NO
3) zを使用した。Salt to provide each ion for ion exchange
H4N 03, A g N Os and CLI (NO
3) z was used.
110℃で加熱乾燥したA型ゼオライト粉末1kgに水
を加えて、1.31のスラリーとし、その後撹拌して脱
気し、さらに適量の0.5N硝酸溶液と水とを加えてp
Hを5〜7に調整し、全容を1.81のスラリーとした
。次にイオン交換の為、Nl(、NO。Add water to 1 kg of type A zeolite powder heated and dried at 110°C to make a slurry of 1.31, then stir and degas, and then add an appropriate amount of 0.5N nitric acid solution and water to make a slurry of 1.31.
H was adjusted to 5 to 7, and the entire slurry was made into a 1.81 slurry. Next, for ion exchange, Nl (, NO.
1.5−E−ル/β、AgN0. Q、 l Q モ
ル/ 1 、CLI(NO3)20.35モル/1の混
合水溶液31を加えて全容を4.81とし、このスラリ
ー液を40〜60℃に保持し10〜24時間撹拌しつつ
平衡状態に到達させた状態に保持した。イオン交換終了
後ゼオライト相を口過し室温の水又は温水でゼオライト
相中の過剰の銀イオン及び銅イオンがなくなる迄水洗し
た。次に得られたゼオライトを110℃で加熱乾燥し、
抗菌性ゼオライトを得た。1.5-E-ru/β, AgN0. A mixed aqueous solution 31 of Q, l Q mol/1 and CLI (NO3) 20.35 mol/1 was added to make the total volume 4.81, and this slurry liquid was maintained at 40 to 60°C and stirred for 10 to 24 hours. An equilibrium state was reached and maintained. After the ion exchange was completed, the zeolite phase was passed through the mouth and washed with room temperature water or warm water until excess silver ions and copper ions in the zeolite phase were removed. Next, the obtained zeolite was heated and dried at 110°C,
Antibacterial zeolite was obtained.
実施例(抗菌性試験)
参考例で調製した抗菌性ゼオライ)2g、フロンガス(
フロン12)40g及びエチルアルコール60gからな
るスプレー用組成物を常法によりスプレー缶(120m
!、容)に詰めた。Example (antibacterial test) 2 g of antibacterial zeolite prepared in the reference example, fluorocarbon gas (
A spray composition consisting of 40 g of Freon 12) and 60 g of ethyl alcohol was poured into a spray can (120 m
! , packed).
直径3 cmの乾熱滅菌したろ紙片に上記スプレー用組
成物を一様に2秒間および4秒間噴霧して試験片とした
。なお、該組成物の噴霧量は、風乾後にろ紙片1枚当り
約5mg(2秒間噴霧)および10mg(4秒間噴?!
>となるようにした。The above spray composition was uniformly sprayed on a dry heat sterilized filter paper piece having a diameter of 3 cm for 2 seconds and 4 seconds to prepare a test piece. The spray amount of the composition is approximately 5 mg (sprayed for 2 seconds) and 10 mg (sprayed for 4 seconds?!) per filter paper piece after air drying.
>.
次いで試験片1枚当りの菌数が104〜S個となるよう
に菌液を接種し、細菌は37℃、真菌は30℃で保存し
た。保存開始0 (接種直後)、24および48時間後
に細菌は5CDLP液体培地、真菌はGPLP液体培地
(共に大五栄養化学)で試験片中の菌を洗い出し、洗液
を試験液とした。Next, a bacterial solution was inoculated so that the number of bacteria per test piece was 104 to S, and the bacteria were stored at 37°C and the fungi at 30°C. At 0 (immediately after inoculation), 24 and 48 hours after the start of storage, the bacteria in the test pieces were washed out using 5CDLP liquid medium for bacteria and GPLP liquid medium for fungi (both manufactured by Daigo Nutritional Chemical Co., Ltd.), and the washing liquid was used as the test liquid.
この試験液について菌数測定用培地による混釈平板培養
法(細菌;37℃2日間、真菌;25℃7日間〉により
生残菌数を測定して、試験片1枚当りの生菌数に換算し
た。なお、試験片に接種したのと同量の菌液を直径3
cmの乾熱滅菌したろ紙片に接種し、同様に保存、生菌
数の測定を行い対照とした。結果を表1に示す。For this test solution, the number of viable bacteria was measured by the pour plate culture method (bacteria: 2 days at 37°C, fungi: 7 days at 25°C) using a culture medium for bacterial count measurement, and the number of viable bacteria per test piece was determined. The same amount of bacterial solution as that inoculated on the test piece was
A control paper was inoculated onto a piece of dry heat sterilized filter paper, stored in the same manner, and the number of viable bacteria was measured. The results are shown in Table 1.
(1)試験菌株
巳5cherichia coli IFO3301(
大腸菌)Ataphylococcus aureus
ATCC6538P(黄色ブドウ球菌)
Pseudomonas aeruginosa II
D P−1(緑膿菌)Bacillus cereus
IFO13494(セレウス菌)Aspergill
us niger rFo 4407 (黒麺カビ)C
andida albicans IFO1594(カ
ンデイダ〉(2)m数測定用培地
細菌用 5CDLP寒天培地(大工栄養化学)真菌用
GPLP 寒天培地(大工栄養化学)(3)菌液の調
製
細 菌;普通ブイヨン培地で37℃−夜培養した後、
培養をそのまま滅
菌リン酸緩衝生理食塩水0で希
釈し、調製した。(1) Test strain cherichia coli IFO3301 (
Escherichia coli) Ataphylococcus aureus
ATCC6538P (Staphylococcus aureus) Pseudomonas aeruginosa II
D P-1 (Pseudomonas aeruginosa) Bacillus cereus
IFO13494 (Bacillus cereus) Aspergill
us niger rFo 4407 (black noodle mold) C
andida albicans IFO1594 (Candida> (2) m number measurement medium for bacteria 5CDLP agar medium (Carpenter Nutritional Chemistry) for fungi
GPLP agar medium (Daiko Nutrient Chemistry) (3) Preparation of bacterial solution Bacteria: After culturing in ordinary bouillon medium at 37°C overnight,
The culture was prepared directly by diluting it with 0 sterile phosphate buffered saline.
蒸麺カビ;ポテトデキストロース寒天斜面培地で25℃
7日間培養した後、
滅菌0.(10)5%ジオクチル
スルホコハク酸ナトリウムに分生子
を浮遊させ、調製した。Steamed noodle mold; potato dextrose agar slant medium at 25℃
After culturing for 7 days, sterilize 0. (10) Prepared by suspending conidia in 5% sodium dioctyl sulfosuccinate.
カンディダ、YM寒天斜面培地で25℃2日間培養した
後、滅菌生理食
塩水に菌体を浮遊させ、調製
した。After culturing the cells on a YM agar slant medium at 25° C. for 2 days, the cells were suspended in sterile physiological saline and prepared.
*リン酸−カリウム34gを5(10)dの精製水に溶
解して、IN−水酸化ナトリウム175m1を加えpH
7,2に調製した後、さらに精製水を加え全量を1.(
10)0m1!とする。*Dissolve 34 g of potassium phosphate in 5 (10) d of purified water, add 175 ml of IN-sodium hydroxide, and adjust the pH.
After preparing 7.2, purified water was further added to bring the total amount to 1. (
10) 0m1! shall be.
この溶液1.25rnI!に生理食塩水を加え1.(1
0)0m1!とじたもの。This solution 1.25rnI! Add physiological saline to 1. (1
0)0m1! Something that is bound.
表 1 試験片に接種した試験菌の経時的変化* 供試
品未噴霧のろ紙片
;ト本 表中rlo以下」表示は菌数測定用培地を使
用した時の測定限界Iこよるもので、菌が検出されなか
ったことを意味する。Table 1 Changes over time in test bacteria inoculated onto test pieces* Test sample: unsprayed filter paper; This means that no bacteria were detected.
本発明の組成物を用いれば、簡単かつ確実に物の表面に
抗菌性を付与することができる。By using the composition of the present invention, antibacterial properties can be easily and reliably imparted to the surface of objects.
Claims (12)
抗菌性スプレー用組成物。(1) An antibacterial spray composition containing an antibacterial zeolite, alcohol, and a propellant.
49%及び噴射剤50〜70%を含有する特許請求の範
囲第(1)項記載の組成物。(2) Antibacterial zeolite 1-10%, alcohol 29-29%
49% and 50-70% propellant.
可能なイオンの一部又は全部を抗菌性金属イオンでイオ
ン交換したものである特許請求の範囲第(1)項記載の
組成物。(3) The composition according to claim (1), wherein the antibacterial zeolite is obtained by ion-exchanging some or all of the ion-exchangeable ions in the zeolite with antibacterial metal ions.
から選ばれる少なくとも一種の金属のイオンである特許
請求の範囲第(3)項記載の組成物。(4) The composition according to claim (3), wherein the antibacterial metal ion is an ion of at least one metal selected from the group consisting of silver, copper, and zinc.
さらにアンモニウムイオンでイオン交換されている特許
請求の範囲第(3)項記載の組成物。(5) The composition according to claim (3), wherein a part of the ion-exchangeable ions in the zeolite are further ion-exchanged with ammonium ions.
である特許請求の範囲第(3)項記載の組成物。(6) The composition according to claim (3), wherein the zeolite is a natural zeolite or a synthetic zeolite.
Y型ゼオライト、モルデナイト、クリノプチロライト、
チャバサイト又はエリオナイトである特許請求の範囲第
(3)項記載の組成物。(7) Zeolite is A-type zeolite, X-type zeolite,
Y-type zeolite, mordenite, clinoptilolite,
The composition according to claim (3), which is chabasite or erionite.
mである特許請求の範囲第(1)項記載の組成物。(8) The average particle size of antibacterial zeolite is 0.2 to 10μ
The composition according to claim (1), which is m.
(1)項記載の組成物。(9) The composition according to claim (1), wherein the alcohol is ethanol.
許請求の範囲第(1)項記載の組成物。(10) The composition according to claim (1), wherein the propellant is fluorocarbon gas or liquefied petroleum gas.
ロロフルオロメタン又はそれらの混合物、又はジクロロ
テトラフルオロエタンである特許請求の範囲第(10)
項記載の組成物。(11) Claim No. 10, wherein the fluorocarbon gas is trichlorofluoromethane, dichlorofluoromethane, or a mixture thereof, or dichlorotetrafluoroethane.
Compositions as described in Section.
請求の範囲第(10)項記載の組成物。(12) The composition according to claim (10), wherein the liquefied petroleum gas is propane or butane.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62085355A JPH0742207B2 (en) | 1987-04-07 | 1987-04-07 | Antibacterial spray composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62085355A JPH0742207B2 (en) | 1987-04-07 | 1987-04-07 | Antibacterial spray composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63250325A true JPS63250325A (en) | 1988-10-18 |
JPH0742207B2 JPH0742207B2 (en) | 1995-05-10 |
Family
ID=13856386
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62085355A Expired - Lifetime JPH0742207B2 (en) | 1987-04-07 | 1987-04-07 | Antibacterial spray composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0742207B2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02125717A (en) * | 1988-11-04 | 1990-05-14 | Toppan Printing Co Ltd | Antifungal plastic container, its manufacturing device and manufacture |
EP0697212A2 (en) | 1994-07-19 | 1996-02-21 | Shinagawa Fuel Co., Ltd. | Deodorant cosmetic composition superior in resistance to discoloration and dispersion |
JP2008505123A (en) * | 2004-07-02 | 2008-02-21 | ナノスケール マテリアルズ アイエヌシー. | Organic biocidal decontamination composition |
WO2009025071A1 (en) | 2007-08-20 | 2009-02-26 | Shiseido Company, Ltd. | Preparation for external application to skin |
EP2324887A1 (en) | 2002-10-25 | 2011-05-25 | Shiseido Company, Limited | Deodorizing skin treatment composition |
ITMO20110192A1 (en) * | 2011-07-29 | 2013-01-30 | Signorini S A S Di Signorini Angel O Antonio E Ca | DEVICE FOR THE SPRAY DISTRIBUTION OF A MEDICAL PRODUCT FOR DISINFECTION AND CYCLING OF CUTE LESA |
JP2021187819A (en) * | 2020-06-04 | 2021-12-13 | 石原ケミカル株式会社 | Antimicrobial composition and aerosol composition for antibacterial treatment therewith |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58103301A (en) * | 1981-12-14 | 1983-06-20 | Toyo Aerosol Kogyo Kk | Powdery aerosol suspension liquid |
JPS59186908A (en) * | 1983-04-08 | 1984-10-23 | Nippon Chem Ind Co Ltd:The | Agricultural and horticultural fungicide |
-
1987
- 1987-04-07 JP JP62085355A patent/JPH0742207B2/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58103301A (en) * | 1981-12-14 | 1983-06-20 | Toyo Aerosol Kogyo Kk | Powdery aerosol suspension liquid |
JPS59186908A (en) * | 1983-04-08 | 1984-10-23 | Nippon Chem Ind Co Ltd:The | Agricultural and horticultural fungicide |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02125717A (en) * | 1988-11-04 | 1990-05-14 | Toppan Printing Co Ltd | Antifungal plastic container, its manufacturing device and manufacture |
EP0697212A2 (en) | 1994-07-19 | 1996-02-21 | Shinagawa Fuel Co., Ltd. | Deodorant cosmetic composition superior in resistance to discoloration and dispersion |
US5723110A (en) * | 1994-07-19 | 1998-03-03 | Shinagawa Fuel Co., Ltd. | Deodorant cosmetic composition superior in resistance to discoloration and dispersion |
EP0697212B1 (en) * | 1994-07-19 | 2002-01-30 | Shinanen Co., Ltd. | Deodorant cosmetic composition superior in resistance to discoloration and dispersion |
EP2324887A1 (en) | 2002-10-25 | 2011-05-25 | Shiseido Company, Limited | Deodorizing skin treatment composition |
JP2008505123A (en) * | 2004-07-02 | 2008-02-21 | ナノスケール マテリアルズ アイエヌシー. | Organic biocidal decontamination composition |
WO2009025071A1 (en) | 2007-08-20 | 2009-02-26 | Shiseido Company, Ltd. | Preparation for external application to skin |
ITMO20110192A1 (en) * | 2011-07-29 | 2013-01-30 | Signorini S A S Di Signorini Angel O Antonio E Ca | DEVICE FOR THE SPRAY DISTRIBUTION OF A MEDICAL PRODUCT FOR DISINFECTION AND CYCLING OF CUTE LESA |
JP2021187819A (en) * | 2020-06-04 | 2021-12-13 | 石原ケミカル株式会社 | Antimicrobial composition and aerosol composition for antibacterial treatment therewith |
Also Published As
Publication number | Publication date |
---|---|
JPH0742207B2 (en) | 1995-05-10 |
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