JPS63248898A - Cleanser composition for white part of tire - Google Patents
Cleanser composition for white part of tireInfo
- Publication number
- JPS63248898A JPS63248898A JP8287987A JP8287987A JPS63248898A JP S63248898 A JPS63248898 A JP S63248898A JP 8287987 A JP8287987 A JP 8287987A JP 8287987 A JP8287987 A JP 8287987A JP S63248898 A JPS63248898 A JP S63248898A
- Authority
- JP
- Japan
- Prior art keywords
- tire
- white part
- yellowing
- composition
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 29
- 238000004140 cleaning Methods 0.000 claims description 10
- 230000003287 optical effect Effects 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 6
- 239000002798 polar solvent Substances 0.000 claims description 6
- 239000012459 cleaning agent Substances 0.000 description 22
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 21
- 238000004383 yellowing Methods 0.000 description 19
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000003599 detergent Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 4
- -1 acetate ester Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- 208000023514 Barrett esophagus Diseases 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- AFYCEAFSNDLKSX-UHFFFAOYSA-N coumarin 460 Chemical compound CC1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 AFYCEAFSNDLKSX-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- OTNIKUTWXUODJZ-UHFFFAOYSA-N 7-(ethylamino)-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(NCC)=CC=C21 OTNIKUTWXUODJZ-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 210000001072 colon Anatomy 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は、タイヤ用の洗浄剤組成物に関するもので、
特に自転車タイヤの白色部分の黄ばみの除去を目的とし
た洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) This invention relates to a cleaning composition for tires.
In particular, the present invention relates to a cleaning composition for removing yellowing from the white parts of bicycle tires.
（従来の技術）
自動車及び自転車のタイヤには軟化剤、劣化防止剤、加
硫促進剤等種々の充填剤が配合されており、これらは時
間の経過と共にタイヤ表面に滲出してタイヤを黄変して
外観を損なうことか屡ある。この黄変はタイヤの白色部
分において特に目立つ。(Prior art) Automobile and bicycle tires are compounded with various fillers such as softeners, anti-deterioration agents, and vulcanization accelerators, which ooze out onto the tire surface over time and cause the tires to yellow. This often results in damage to the appearance. This yellowing is particularly noticeable in the white parts of the tire.
これを除去する方法として、例えばベンゼン、トルエン
等の芳香族系の洗浄剤、クロロセン、パークレン等の塩
素系洗浄剤、界面活性剤を水で溶解させた洗浄剤や、ブ
チルカルピトールとアセトンを主剤とするタイヤ用クリ
ーナー（特公昭５９−２３５９７号公報）及び沸点１６
０℃以上にエーテルアルコール又はその酢酸エステルと
アセトンを主剤とするタイヤ用クリーナー（特公昭５９
−２：１５９８号公報）等が利用されてきた。Methods for removing this include aromatic detergents such as benzene and toluene, chlorine detergents such as chlorocene and perchlorine, detergents in which surfactants are dissolved in water, and detergents containing butyl calpitol and acetone as main agents. Tire cleaner (Japanese Patent Publication No. 59-23597) and boiling point 16
Tire cleaner containing ether alcohol or its acetate ester and acetone as main ingredients at temperatures above 0℃
2:1598) etc. have been used.
（発明が解決しようとする問題点）
これらの洗浄剤は、タイヤの白色部分の表面に滲出した
黄変成分の除去に対しては有効であるか、タイヤの白色
部分の表面に滲出ずに至らず、表面近くにある黄変成分
については除去が不充分であり、したかってこれらの洗
浄剤を使用してもタイヤ白色部分の黄変を完全に除去し
、元の白さに戻すことばてきない。(Problems to be Solved by the Invention) Are these cleaning agents effective in removing yellowing components that have oozed out on the surface of the white part of the tire? First, the removal of yellowing components near the surface is insufficient, so even if these cleaning agents are used, it is impossible to completely remove the yellowing from the white part of the tire and restore it to its original whiteness. .
また、タイヤの白色部分の表面に滲出ずに至らず、表面
近くにある黄変成分を除去するために、上記のような洗
浄剤を多量に使用する場合、例えばベンゼン、トルエン
等の洗浄剤についてはタイヤを膨張させるという難点が
あり、更にクロロセン、パークレン等の塩素系の洗浄剤
についてはタイヤを溶解し、溶解されたタイヤ成分がタ
イヤ白色部に溶剤の蒸発により残留するという難点かあ
る。In addition, when using a large amount of the above-mentioned cleaning agents in order to remove yellowing components that are near the surface of the white part of the tire without oozing out, for example, cleaning agents such as benzene and toluene should be used. has the disadvantage that it inflates the tire, and chlorine-based cleaning agents such as chlorocene and perchlorene also have the disadvantage that they dissolve the tire and the dissolved tire components remain in the white part of the tire due to evaporation of the solvent.
更に、カービトール類、エーテルアルコール又はその酢
酸エステルについては沸点が高く、乾燥か遅いため、一
度取れた汚れが再付着し、かえって外観を損なう結果と
なるなどの難点かある。Furthermore, carbitols, ether alcohols, or their acetate esters have high boiling points and slow drying times, which causes problems such as the fact that dirt that has been removed once is reattached, resulting in a deterioration of the appearance.
そこで、この発明はタイヤに悪影響を与えることなく、
タイヤの白色部分を元の白さに戻すことかてき、しかも
一度取れた汚れが再付着することかないようなタイヤの
白色部分用洗浄剤を開発することを目的とする。Therefore, this invention has no negative effect on tires,
To develop a cleaning agent for the white part of a tire that can return the white part of the tire to its original whiteness and prevent dirt once removed from re-attaching.
（問題点を解決するための手段）
この発明は、上記目的を達成するため、鋭意研究の結果
、油溶性の蛍光増白剤０．０１〜５．０ｗｔ１及び沸点
１５０°（Ｊｔ下（７）極性溶剤９５．０〜９９．９９
ｗｔＬｉ： リ成るタイヤの白色部分用洗浄剤組成物を
提案するものである。(Means for Solving the Problems) In order to achieve the above-mentioned object, the present invention has been developed based on the results of intensive research, using an oil-soluble optical brightener of 0.01 to 5.0wt1 and a boiling point of 150° (Jt below (7)). Polar solvent 95.0-99.99
wtLi: We propose a cleaning agent composition for white parts of tires consisting of:
即ち、この発明において油溶性の蛍光増白剤と極性溶剤
を必須成分としているが、この極性溶剤はタイヤ内部よ
り滲出して白色部の表面にある黄変成分、或いはタイヤ
の白色部分の表面に付着した汚染物質が有効に除去され
る。更に、タイヤの白色部分の表面に滲出ずに至らず、
表面近くにある黄変成分については蛍光増白剤は油溶性
であるために、タイヤ内に浸透する。このため、タイヤ
の白色部の白さか強調され、黄ばみは打ち消される。し
たかって、この発明の洗浄剤を使用する場合にはタイヤ
白色部分の黄ばみかなくなり、元の白さに復元されるの
である。That is, in this invention, an oil-soluble fluorescent whitening agent and a polar solvent are essential components, but this polar solvent exudes from the inside of the tire and causes yellowing components on the surface of the white part, or yellowing components on the surface of the white part of the tire. Adhering contaminants are effectively removed. Furthermore, it does not ooze out onto the surface of the white part of the tire,
Yellowing components near the surface of the tire penetrate into the tire because the optical brightener is oil-soluble. Therefore, the whiteness of the white part of the tire is emphasized, and the yellowing is canceled out. Therefore, when the cleaning agent of the present invention is used, the yellowing of the white part of the tire disappears and the tire is restored to its original whiteness.
また、この発明ではベンゼン、トルエン等の芳香族系の
溶剤、クロロセン、パールレン等の塩素系溶剤を使用し
ないため、タイヤの膨潤、溶解などの悪影響がなく、ま
た使用する極性溶剤は洟点か１５０℃以下の低沸点であ
るため、塗布後速やかに乾燥し、汚れが再付着すること
かない。In addition, this invention does not use aromatic solvents such as benzene and toluene, or chlorinated solvents such as chlorocene and pearlene, so there is no adverse effect such as swelling or dissolution of the tire. Because it has a low boiling point below ℃, it dries quickly after application and prevents stains from re-attaching.
この発明て使用する油溶性の蛍光増白剤としては１例え
ば４−メチル−７−シエチルアミノクマリン（商品名Ｈ
ａｋｋｏｌ Ｐ：昭和化学社製）、商品名Ｈａｋｋｏｌ
Ｓ−１００（住友化学社製）、商品名ＷｈｉｔｅｘＢ
Ｆ（住友化学社製）、商品名Ｗｈｉｔｅｘ ＲＰ （住
友化学社製）、商品名Ｗｈｉｔｅｘ ＷＳ （住友化学
社製）等を挙げることができる。The oil-soluble optical brightener used in this invention includes 1, for example, 4-methyl-7-ethylaminocoumarin (trade name: H
akkol P: manufactured by Showa Kagaku Co., Ltd.), trade name Hakkol
S-100 (manufactured by Sumitomo Chemical Co., Ltd.), trade name WhitexB
F (manufactured by Sumitomo Chemical Co., Ltd.), trade name Whitex RP (manufactured by Sumitomo Chemical Co., Ltd.), and trade name Whitex WS (manufactured by Sumitomo Chemical Co., Ltd.).
その使用濃度は０．０１〜５．Ｏｗｔ！であるが、望ま
しくは０．５〜２．Ｏｗｔ＄の範囲である。０．５ｗｔ
＄以下であるとその増白効果かやや劣り、０．０１ｗｔ
＄以下であると蛍光増白剤による効果があまり期待でき
ない。The concentration used is 0.01-5. Owt! However, preferably 0.5 to 2. It is in the range of Owt$. 0.5wt
If it is less than $, the whitening effect is slightly inferior, 0.01wt
If the amount is less than $, the effect of the optical brightener cannot be expected to be significant.
一方、蛍光増白剤を２．Ｏｗｔ＄以上添加した場合、タ
イヤ白色部に対する増白効果に大きな差は見られないか
、特に５ｗｔ＄以上の濃度になると洗浄剤そのものの粘
度か増加し、液の安定性が悪く蛍光増白剤か析出するこ
ともある。また、経済的にも不利益となる。On the other hand, 2. When Owt$ or more is added, there is no significant difference in the whitening effect on the white part of the tire.In particular, when the concentration exceeds 5wt$, the viscosity of the cleaning agent itself increases, the stability of the liquid is poor, and the optical brightener It may also precipitate. It is also economically disadvantageous.
また、１５０℃以下の低沸点の極性溶剤としてはタイヤ
に対して影響が少ない溶剤から選択され、具体的にはメ
チルセロソルブ、エチルセロソルブ等のセロワルツ類、
メタノール、エタノール、イソプロピルアルコール等の
低級アルコール類、フッ化エチレン等のフロン溶剤等を
挙げることができるが、特にエチルセロソルブが良好で
ある。In addition, the polar solvent with a low boiling point of 150°C or less is selected from solvents that have little effect on tires, and specifically, methyl cellosolve, ethyl cellosolve, etc.
Examples include lower alcohols such as methanol, ethanol, and isopropyl alcohol, and chlorofluorocarbon solvents such as fluorinated ethylene, but ethyl cellosolve is particularly good.
なお、極性溶剤の使用濃度は上記油溶性蛍光増白剤の使
用濃度に対応において９５．０〜９９．９９Ｗｔ＄であ
る。The concentration of the polar solvent used is 95.0 to 99.99 Wt$, corresponding to the concentration of the oil-soluble optical brightener used.
これらの組成物に艶出し剤を加えることによって、タイ
ヤ白色部に艶を出しより白く見せることかできる。また
、艶保持剤を加えることによってタイヤ白色部に生じた
艶を長期間保持することかできる。更に、紫外線吸収剤
などの老化防止剤を加えることによってタイヤ白色部の
亀裂の発生を抑制することがてきると同時に、再度の黄
変化を抑制することができる。By adding a polishing agent to these compositions, the white part of the tire can be glossed to make it look whiter. Furthermore, by adding a gloss retainer, the gloss generated in the white part of the tire can be maintained for a long period of time. Furthermore, by adding an anti-aging agent such as an ultraviolet absorber, it is possible to suppress the occurrence of cracks in the white part of the tire, and at the same time, it is possible to suppress yellowing again.
ここて、使用される艶出し剤としては、流動パラフィン
、ジメチルシリコーンオイル、メチルフェニルシリコー
ンオイル、アルキル変性シリコーンオイル、アミノ変性
シリコーンオイル等が挙げられ、その割合はこの発明の
組成物に対して２〜２０ｗｔＸが適当である。Here, examples of the polishing agent used include liquid paraffin, dimethyl silicone oil, methylphenyl silicone oil, alkyl-modified silicone oil, amino-modified silicone oil, etc., and the ratio thereof is 2% to the composition of the present invention. ~20wtX is appropriate.
また、艶保持剤としては艶出し機能と酸化防止性能をも
合せ持つものから選択され、具体的にはラノリン、黄ペ
ソ、パラフィンワックス、ステアリン酸などのワックス
類を挙げることかできる、その割合はこの発明の組成物
に対して１．０〜５、０ｗｔ％か適切である。In addition, the gloss retaining agent is selected from those that have both a polishing function and an antioxidant property, and specific examples include waxes such as lanolin, yellow peso, paraffin wax, and stearic acid, and their proportions are 1.0 to 5.0 wt% is suitable for the composition of this invention.
更に、老化防止剤として使用される紫外線吸収剤は例え
ば、２，４−ジ−ｔ−ブチルフェニル−３′、５′−シ
ーｔ−ブチル−４′−ハイドロオキシベンゾエート、α
−ナフチルアミン、ｐ−ｔ−ブチルフェニルサリチル酸
エステル、２．４−ジ−ハイドロオキシベンゾフェノン
、２−ハイドロオキシ−４−ｎ−オクトキシベンゾフェ
ノン等を挙げることができる。その割合としてはこの発
明の組成物に対して０．１〜５ ｗｔ＄で適切であり、
これにより大腸光線からタイヤを保護することができる
。Further, UV absorbers used as anti-aging agents include, for example, 2,4-di-t-butylphenyl-3',5'-sheet-t-butyl-4'-hydroxybenzoate, α
-naphthylamine, pt-butylphenyl salicylic acid ester, 2,4-di-hydroxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone and the like. The appropriate proportion is 0.1 to 5 wt$ for the composition of this invention,
This protects the tires from the colon rays.
（発明の効果）
この発明の洗浄剤は、例えばディツシュベーパー、或い
はウェススポンジ等に含浸させ、自転車、自動車タイヤ
の白色部分を洗浄するのであるか、この際上述のように
極性溶剤と油溶性蛍光増白剤の協動作用によりがタイヤ
の白色部の白さが強調され、元の白さに戻るのである。(Effects of the Invention) The cleaning agent of the present invention can be impregnated into dish vapor or a waste sponge to clean the white parts of bicycle and automobile tires. Due to the cooperative action of the optical brightener, the whiteness of the white parts of the tire is emphasized, returning it to its original whiteness.
更に、艶出し剤、艶保持剤、老化防止剤等を加えること
により洗浄されたタイヤ白色部の再度の黄変化か妨害さ
れ、長期間タイヤ白色部の白さを持続されるのである。Furthermore, by adding a polishing agent, a gloss-retaining agent, an anti-aging agent, etc., the yellowing of the washed white part of the tire is prevented, and the whiteness of the white part of the tire is maintained for a long period of time.
（実施例） 以下、この発明の実施例を示す。(Example) Examples of this invention will be shown below.
実施例
洗浄剤組成（１）
Ｈａｋｋｏｌ Ｓ−１００４，０＄
エチルセロソルツ ９６．０％洗浄
剤組成（２）
Ｗｈｉｔｅｘ ＢＦ ２
．０％エチルセロソルブ ５０．０＄
イソプロピルアルコール ４８．０％洗浄
剤組！、（３）
Ｗｈｉｔｅｘ ＲＰ Ｏ，
０２！エチルセロソルブ ６０．０３
イソプロピルアルコール ３９．９８２洗浄
剤組成（４）
１１ａｋｋｏｌ Ｐ ５．
（Ｈエチルセロソルブ ３５．０％イ
ソプロピルアルコール ３０．０％洗浄剤組
成（５）
１（ａｋｋｏｌ Ｐ １．
０！メチルセロソルブ ５０．０％イ
ソプロピルアルコール ４９．０％洗浄剤組
成（６）
Ｈａｋｋｏｌ Ｐ １．０
＄エチルセロソルツ ３０．０％イソ
プロピルアルコール ２０．０％フロン１１
３ ３４．０！ジメチルシリコ
ーンオイル（１０００ｃｓｔ） １５．０％洗節剤組成
（７）
Ｈａｋｋｏｌ Ｐ Ｏ，
Ｉ！エチルセロソルブ ４４．０％フ
ロン１１３５０．Ｈ
ステアリンｍ ｓ、ａ＠洗浄剤
組成（８）
ＷｈｉＬｅｘ ＢＦ ２．
０！メチルセロソルブ ５５．０％フ
ロン１１：ｌ ４０．Ｏ＄パ
ラフィンワックス ３．０％洗浄剤組
成（９）
１１ａｋｋｏｌ Ｐ １．
０＄エチルセロソルツ ５６．０％フ
ロン１１３ ４０．０＄２．４
−シハイドロオキシベンゾフェノン３．０％比較洗浄剤
組成（１）
アルキルベンゼンスルりオン酸ナトリウム５ｚ水
９５％比較洗浄剤
組成（２）
ヤシ油脂肪酸アミド ＩＯ！水
用比較洗浄剤組成（
３）
ＰＯＥ（２５）ノニルフェノールエーテル ５ｚ水
９５２比較洗
浄剤組成（４）
プチルカービトール ８Ｈアセトン
２０２比較洗炸剤組成（５
）
ジエチルゲルコールジエチルエーテル ８ｏｚアセトン
２０駕比較洗浄剤組成
（６）
ベンゼン １０ｏｚ比較洗
浄剤組成（７）
クロロセン １００ｚ比較洗
浄剤組成（８）
１１ａｋｋｏｌ Ｐ ０．Ｏ
０５＄メチルセロソルブ ５ｏｚイ
ソプロピルアルコール ４９．９９５＄［試験
方法］
（１）被洗浄物・・・汚れた（黄変した）自転車タイヤ
の白色部分
（２）洗浄剤 ・・・洗浄剤組成（１）〜（９）及び比
較洗浄剤組成（１）〜（８）
（３）洗浄方法
（ａ）洗浄性試験・・・各洗浄剤をティッシュペーパー
に含浸させ、黄変したタイ
ヤの白色部分を擦り（５回）
目視により判断する。Example cleaning agent composition (1) Hakkol S-1004, 0$ Ethyl Cellosolt 96.0% Cleaning agent composition (2) Whitex BF 2
．． 0% ethyl cellosolve 50.0$
Isopropyl alcohol 48.0% cleaning agent set! , (3) Whitex RP O,
02! Ethyl cellosolve 60.03
Isopropyl alcohol 39.982 Cleaning agent composition (4) 11akkol P 5.
(H Ethyl cellosolve 35.0% Isopropyl alcohol 30.0% Cleaning agent composition (5) 1 (akkol P 1.
0! Methyl cellosolve 50.0% Isopropyl alcohol 49.0% Cleaning agent composition (6) Hakkol P 1.0
$ Ethyl cello salt 30.0% isopropyl alcohol 20.0% Freon 11
3 34.0! Dimethyl silicone oil (1000cst) 15.0% Detergent composition (7) Hakkol P O,
I! Ethyl Cellosolve 44.0% Freon 11350. H Stearin m s, a@Cleaning agent composition (8) WhiLex BF 2.
0! Methyl cellosolve 55.0% Freon 11:l 40. O$ Paraffin wax 3.0% Cleaning agent composition (9) 11akkol P 1.
0$ Ethyl cello salt 56.0% Freon 113 40.0$2.4
-Sihydroxybenzophenone 3.0% Comparative detergent composition (1) Sodium alkylbenzene sulfurionate 5z water
95% comparison detergent composition (2) Coconut oil fatty acid amide IO! water
Comparative detergent composition for
3) POE (25) Nonylphenol ether 5z water
952 comparative detergent composition (4) Butyl carbitol 8H acetone
202 Comparative explosive detergent composition (5
) Diethyl gelcol diethyl ether 8oz Acetone 20oz comparative cleaning composition (6) Benzene 10oz comparative cleaning composition (7) Chlorocene 100z comparative cleaning composition (8) 11akkol P 0. O
05$ Methyl Cellosolve 5oz Isopropyl Alcohol 49.995$ [Test Method] (1) Object to be cleaned: white part of dirty (yellowing) bicycle tire (2) Cleaning agent: Cleaning agent composition (1) ~ (9) and comparative cleaning agent compositions (1) ~ (8) (3) Cleaning method (a) Cleaning performance test...Tissue paper was impregnated with each cleaning agent, and the white part of the yellowed tire was rubbed ( 5 times) Judge by visual inspection.
［判断基準］ ◎・・・黄変がよく取れ、元の白さに戻る。[Evaluation criteria] ◎... Yellowing is removed well and the color returns to its original whiteness.
○・・・黄変が大体取れた。○...The yellowing was mostly removed.
△・・・黄変が少し取れた。△...The yellowing was slightly removed.
Ｘ・・・黄変が殆ど取れなかった。X: Almost no yellowing was removed.
（ｂ）汚れの再汚染性試験
洗浄試験したティッシュペーパーを濡れているうちに、
洗浄したタイヤ白色部に塗り付けて５分後に観察する。(b) Re-staining property test While the tissue paper used in the cleaning test is still wet,
Apply it to the white part of the cleaned tire and observe after 5 minutes.
［判断基準］ ◎・・・再汚染か全くない △・・・再汚染が認められた。[Evaluation criteria] ◎・・・Re-contamination or not at all △... Re-contamination was observed.
×・・・再汚染が激しくゴムが溶解又は膨潤した。×: Severe recontamination caused the rubber to dissolve or swell.
口・・・ティッシュペーパーに汚れが移ていないため、
再汚染しない。Mouth: Since the dirt has not been transferred to the tissue paper,
Do not re-contaminate.
結果を下記表に示す。The results are shown in the table below.
洗浄剤組成 洗浄性 再汚染性 再黄変までの日数（
＊）
（１） ◎ ◎ ５日（２）
◎ ◎ ５ｎ
（３） ○ ◎
５ ツノ（４） ◎ ◎
５ ツノ（５） ◎
◎ ５ ツノ（６）
◎ ０ ８ ツノ（７
） ○ ◎
７ ツノ（８） ◎ ◎ ９ｎ
（９） ○ ◎
９ ツノ比較洗浄剤
組成
（１）ｘ口
（２）Δ口
（３）ｘ口
（４） △ △
（５） △ △
（６） △ Ｘ
（７） △ ×
（８） △ ◎
＊ ウェザメーターにかけて観察した。Cleaning agent composition Cleanability Re-staining ability Days until re-yellowing (
*) (1) ◎ ◎ 5th (2)
◎ ◎ 5n (3) ○ ◎
5 Horn (4) ◎ ◎
5 Horn (5) ◎
◎ 5 Horn (6)
◎ 0 8 Horn (7
) ○ ◎
7 Horn (8) ◎ ◎ 9n (9) ○ ◎
9 Horn comparison cleaning composition (1) x port (2) Δ port (3) x port (4) △ △ (5) △ △ (6) △ Observed.
Claims (1)
℃以下の低沸点極性溶剤９５．０〜９９．９９ｗｔ％よ
り成るタイヤの白色部分用洗浄剤組成物。Oil-soluble optical brightener 0.01-5.0wt% and 150%
A cleaning composition for white parts of tires comprising 95.0 to 99.99 wt% of a low boiling point polar solvent having a temperature of 0.degree. C. or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287987A JPH0776358B2 (en) | 1987-04-06 | 1987-04-06 | Cleaning agent composition for white part of tire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287987A JPH0776358B2 (en) | 1987-04-06 | 1987-04-06 | Cleaning agent composition for white part of tire |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63248898A true JPS63248898A (en) | 1988-10-17 |
| JPH0776358B2 JPH0776358B2 (en) | 1995-08-16 |
Family
ID=13786564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8287987A Expired - Fee Related JPH0776358B2 (en) | 1987-04-06 | 1987-04-06 | Cleaning agent composition for white part of tire |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0776358B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093750A (en) * | 2010-11-26 | 2011-06-15 | 山西青山化工有限公司 | Method for preparing disulfonic acid liquid fluorescent brightening agent with low temperature stability |
| WO2013093896A1 (en) * | 2011-12-23 | 2013-06-27 | Bridgestone Corporation | Coloured tyre portions |
-
1987
- 1987-04-06 JP JP8287987A patent/JPH0776358B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093750A (en) * | 2010-11-26 | 2011-06-15 | 山西青山化工有限公司 | Method for preparing disulfonic acid liquid fluorescent brightening agent with low temperature stability |
| WO2013093896A1 (en) * | 2011-12-23 | 2013-06-27 | Bridgestone Corporation | Coloured tyre portions |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0776358B2 (en) | 1995-08-16 |
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