JPS63242587A - Decoloring pen for no-carbon paper - Google Patents

Decoloring pen for no-carbon paper

Info

Publication number
JPS63242587A
JPS63242587A JP62078739A JP7873987A JPS63242587A JP S63242587 A JPS63242587 A JP S63242587A JP 62078739 A JP62078739 A JP 62078739A JP 7873987 A JP7873987 A JP 7873987A JP S63242587 A JPS63242587 A JP S63242587A
Authority
JP
Japan
Prior art keywords
desensitizer
pen
paper
felt
tip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62078739A
Other languages
Japanese (ja)
Inventor
Toshio Miike
三池 富志雄
Makoto Negishi
誠 根岸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Paper Mills Ltd
Original Assignee
Mitsubishi Paper Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Paper Mills Ltd filed Critical Mitsubishi Paper Mills Ltd
Priority to JP62078739A priority Critical patent/JPS63242587A/en
Publication of JPS63242587A publication Critical patent/JPS63242587A/en
Pending legal-status Critical Current

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  • Color Printing (AREA)

Abstract

PURPOSE:To enable handy application of the title pen at the time of use of a no-carbon paper by a terminal user and make it possible to decolor a developed color part or to prevent color development at a part at which color development is unrequired, by filling a felt-tip pen type container with a composition in which the weight ratio of a desensitizer solution to a volatile solvent is set in a specified range. CONSTITUTION:A desensitizer dispersed in a volatile solvent is contained in an ink-containing space part 1 in a writing barrel part 3. When this pen is used, the desensitizer permeates into a felt-made writing tip 2 supported by a holder 4 and a tip support part 5, and the desensitizer is moved from the space part 1 to the front end part of the writing tip 2 making contact with a paper. A composition comprising the desensitizer solution and the volatile solvent in a weight ratio of 95:5-20:80 is contained in the apace part 1 of a felt-tip pen type container. This felt-tip pen is useful in decoloring a developed color part or preventing color development at a part at which color development is unrequired, without leaving any apparently conspicuous marks, in use of a no-carbon paper.

Description

【発明の詳細な説明】 (A)  座業上の利用分野 本発明は、メーカーホン感圧初写紙における既発色部の
消色るるいは発色不安mF9rの未然発色防止全目的と
するフェルトペンに関するものである。
DETAILED DESCRIPTION OF THE INVENTION (A) Field of use for sedentary work The present invention is a felt-tip pen for the general purpose of preventing discoloration of already colored areas on pressure-sensitive first copy paper or preventing color development of mF9r, which is unstable in color development. It is related to.

メーカーホン感圧?lIh紙は、カーホンレスペーパー
とも称されて耽に実用となって久しい。
Manufacturer phone pressure sensitive? IIh paper, also called carphoneless paper, has been in practical use for a long time.

こnは通常電子供与性無色染料の浴数を内凧するマイク
ロカンセルを産膜した下用紙と電子受答性−色相(I−
産膜した下用紙とから基本的に成り、圧力により上用紙
のマイクロカフセル中の無色染料か放出され、下J41
紙上の顕色剤と遭遇して発色し可視複五伽が得られる。
This is usually done by using a base paper coated with microcancelles containing an electron-donating colorless dye and an electron-accepting color (I-).
The colorless dye in the microcave cells of the upper paper is released by pressure, and the lower J41
When it encounters the color developer on the paper, it develops a color and a visible double color is obtained.

更に、上用紙と下用紙の役割りヲ兼ねた杉の中用紙(紙
の如き支持体の一方の面に無色染料解触内職マイクロカ
ンセルを他方の面へ顕色剤を塗設したもの)全両者の1
…へ挿入すれば、史に多数枚の初耳が得られる。また支
持体の一方の面へ無色染料浴液内蔵マイクロカプセルの
層と顕色剤から成るノーを槓)#I堕収、めるいは混然
一体単一層菫収することにより一枚の紙でも感圧発色泳
が得られ、セルフコンテインド紙として使われている。
In addition, cedar medium paper (a paper-like support with colorless dye-dissolved microcancelles coated on one side and a color developer coated on the other side), which also served as the top paper and bottom paper, was used. 1 of both
If you insert it into ..., you can get many first impressions of history. In addition, by layering a layer of microcapsules containing a colorless dye bath solution and a color developer on one side of the support, a layer of colorless dye bath liquid and a color developer can be layered onto one side of the support. It produces pressure-sensitive color dyes and is used as self-containing paper.

(H)  従来の技術 ノーカーボン感圧複写紙の既発色Sを拍色する目的とし
ては、床端ユーザーにおいては遥箒の紙の場合と同様に
、既発色層tかきl’slJる方法による砂7角しゴム
、既発色部を被蝋してし1ワ不透明白色修正准、未然発
色防止を目的としては、印桐桑省においてu t4j 
Abejインキ用として減感インキか1史用されている
(H) Conventional technology For the purpose of adding color to the already-developed color S of carbonless pressure-sensitive copying paper, the user uses a method of scratching the already-developed color layer, as in the case of Harukahoki paper. Rubber with 7 corners of sand is used to wax the already colored parts to correct the opaque white color and to prevent color development in advance.
Desensitized ink has been used for some time for Abej ink.

(Q 兄四が解決しようとする間組点 しかし、砂Y日しゴム、不透明白色1−正准では過用部
分の紙の面質が変化したり、未発色部と消色部とに色の
差が出て、外観上目出ってしまう、特に、不透明白色修
正液は適用部分が白色不透明であるため、曲以外の着色
された紙に適用する場合、特に目出つという欠点を有す
る。また、減感インキは印刷業者のみ使用され、ノーカ
ーボン感圧複写紙の末端ユーザーが容易に入手できるも
のではなく、しかも液状であるので手軽に使用できない
欠点があった。
(Q. Brother 4 tried to solve the problem of setting points. However, with sand Y date rubber, opaque white 1-Semi-standard, the surface quality of the paper in overused areas changes, and the color changes between uncolored areas and erased areas. In particular, the opaque white correction fluid has a disadvantage in that it is noticeable when applied to colored paper other than music because the applied area is white and opaque. Further, desensitizing ink is used only by printing companies and is not easily available to end users of carbonless pressure-sensitive copying paper, and furthermore, it is in a liquid state, so it has the disadvantage that it cannot be used easily.

本発明は、末端ユーザーがノーカーボン感圧複写紙の使
用時に手軽に外観上目立さすに、しかも着色された紙に
も適用できる、既発色部の消色あるいは発色不要箇所の
未然発色防止を目的とする消色ペンを提供するものであ
る。
The present invention allows end users to easily make the appearance more noticeable when using carbonless pressure-sensitive copying paper, and can also be applied to colored paper by decoloring already colored areas or preventing coloring from areas where coloring is not required. The purpose of this invention is to provide a decolorizing pen.

(D)問題点を解決するための手段と作用本発明は減感
剤溶液と揮発性溶剤との重量割合が95:5から20:
 soの組成物をフェルトペン型容器に充填したノーカ
ーボン感圧複写紙用消色ペンである。
(D) Means and Effects for Solving the Problems The present invention provides that the weight ratio of the desensitizer solution and the volatile solvent is from 95:5 to 20:
This is a decolorizing pen for carbonless pressure-sensitive copying paper in which a felt-tip pen type container is filled with the composition of SO.

本発明の消色ペンについて図面に基づいて説明すると、
第1図において、揮発性溶剤にて分散された減感剤が筆
記用柄部(3)内部のインキ収納空間部(1)に容填さ
れている。ペン使用時は、ホルダー(4)及び芯体保持
部(5)によって保(以下余白) 持されたフェルト製の亀記用芯体(2)に減感剤が浸透
し、インキ収納空間部(1)から筆記用芯体(2)の紙
に接触する先端部まで減感剤が移動する。なお、芯体保
持部(5)と筆記用柄部(3)は、密閉用カラー(6)
により結合されている。
The decolorizing pen of the present invention will be explained based on the drawings.
In FIG. 1, a desensitizer dispersed in a volatile solvent is contained in an ink storage space (1) inside a writing handle (3). When using the pen, the desensitizer penetrates into the felt core (2) held by the holder (4) and core holder (5) (hereinafter referred to as the margin), and the ink storage space ( The desensitizer moves from 1) to the tip of the writing core (2) that contacts the paper. In addition, the core holding part (5) and writing handle part (3) are sealed with a sealing collar (6).
are connected by.

ペン不便用時は、ふfc(7)で芯体保持部(5)を積
うことにより、揮発性溶剤の揮発を防止する白減感々1
」浴准甲の減感剤VC関しては従来多数の提案が児らn
たが、水牛の使用実績からセレクトさ才したものとして
、脂肋旅モノアミン、ジアミン、トリアミン等へのアル
キレンオキサイド(物1えは、エチレンオキサイド、フ
ロピレンオキサイド、フチレンえキサイド等付加化付物
がよく知られている(特公昭46−29546号、特公
昭46−23850号、特公昭50−14571号、特
公昭49−19647号、特公昭49−23008号、
特公昭50−29365号、特公昭51−39571号
、’4mLlflbti−67291号郷)。
When the pen is inconvenient, the white desensitizer 1 prevents volatile solvents from volatilizing by stacking the core holder (5) with the fc (7).
Many proposals have been made regarding the desensitizing agent VC for bathing.
However, from the experience of using buffalo, alkylene oxides (additional additives such as ethylene oxide, propylene oxide, ethylene oxide, etc.) to fatty monoamines, diamines, triamines, etc. Well known (Special Publication No. 46-29546, Special Publication No. 46-23850, Special Publication No. 14571-1971, Special Publication No. 19647-1972, Special Publication No. 49-23008,
Special Publication No. 50-29365, Special Publication No. 51-39571, '4mLlflbti-67291).

凪にこの他に、カナオン型界III r6性削と称すべ
き第四叔アンモニウム極型のものや、ノニオン型界面活
性剤と称すべき、各種のポリアルキレンオキサイド、も
しくは高級アルキル基置換フェノールのポリアルキレン
オキサイド付加化合物等が実用レベルのものとして著名
である。
In addition to Nagi, we also use the 4th grade ammonium polar type, which should be called Kanaon-type Kai III r6-type surfactants, various polyalkylene oxides, which should be called nonionic surfactants, or polyalkylenes of higher alkyl group-substituted phenols. Oxide addition compounds and the like are well known as being of practical level.

さらに、筆記用減感インキとして、筆記あるいは紙の適
#3部分の固気の変化において最適な敵性にするため、
アルコール等の揮発性浴剤により5〜80%、好lしく
は10〜50%に希釈して使用するのがよい。
In addition, as a desensitizing ink for writing, in order to have optimal resistance to changes in solidity of the appropriate part of writing or paper,
It is preferable to use it by diluting it with a volatile bath agent such as alcohol to 5 to 80%, preferably 10 to 50%.

(匂実施例 三菱製紙株発光、束年インキ製造株製造の[三菱フレキ
ン減感インキM−2」と三菱製紙株発光、東洋インキ製
造eIJ製造の揮発性溶剤lN0−702Jk50:5
0の比率で混合し、図−1の如き外径20鵬、長さ90
ムのカラス製の筆記用柄部tもつ、インキ木収稍のフェ
ルトペンへ谷tA した。
(Odor Example: [Mitsubishi Flexin Desensitizing Ink M-2] manufactured by Mitsubishi Paper Mills Co., Ltd., Bunnen Ink Manufacturing Co., Ltd. and Volatile Solvent lN0-702Jk50:5 manufactured by Mitsubishi Paper Mills Co., Ltd. Luminescence, Toyo Ink Manufacturing Co., Ltd. eIJ
Mix at a ratio of
I decided on a felt-tip pen with a writing handle made of dark crow and an ink storage area.

なお、lN0−702Jはメタノール、エタノール、酢
酸エチルの50:40:10の混合物でりる0 このフェルトペン2mいて、インキをノーカーボン感圧
複写紙の発色部へ塗布したところ、紙の面質を変化させ
ることなく、外観上目立せずに完全に消色することがで
きた。
In addition, lN0-702J is a mixture of methanol, ethanol, and ethyl acetate in the ratio of 50:40:10.When ink was applied to the colored area of carbonless pressure-sensitive copying paper using a 2 m felt-tip pen, the surface quality of the paper was It was possible to completely erase the color without changing the color or making it noticeable in appearance.

また、このフェルトペンを用いて、インキをノーカーボ
ン感圧抜与紙の未発色部へ塗布し、上用蛾と下用紙′?
f:京ね上用紙上から加圧筆記したところ全く発色せず
未然に発色を防1FすることができたO (旬 発明の効果 実施例1から明らかなように、本発明のフェルトペンは
、メーカーホン感圧類′4紙の使用時に外観上目立さ丁
に既発色部の71色めるいは発色部の不要箇所の未然発
色防Ll:を手軽に行な2う上で有用なものである。
Also, using this felt-tip pen, apply ink to the uncolored areas of the carbonless pressure-sensitive paper, and then apply the ink to the upper and lower paper.
f: When pressure was applied to write on top of paper, no color developed, and color development could be prevented by 1F. When using pressure-sensitive paper from the manufacturer, it is useful for easily marking 71 colors in the already colored areas or preventing color development in areas where the colored areas are not needed. It is.

【図面の簡単な説明】[Brief explanation of drawings]

1、インキ収梢窒間部 2、車hピ用芯体 3、筆記#4悄部 4ホルダ、− 5、芯体保持部 6、密閉用カラー 7、ふた ふr; 葎1己片tS体 ネルグー 窓閉用カラー 箪言己閂、H4甲 イシへ1(1勺空間郁 1. Ink storage area 2. Core body for car hpi 3. Writing #4 Yube 4 holder, - 5. Core holding part 6. Sealing collar 7. Lid Fr; 葎 1self piece tS body Nergoo window closing collar Qinggon Koun, H4 Ko Ishie 1 (1 Kukan Kukan)

Claims (1)

【特許請求の範囲】[Claims] 減感剤溶液と揮発性溶剤との重量割合が95:5から2
0:80の組成物をフェルトペン型容器に充填したメー
カーホン感圧複写紙用消色ペン
The weight ratio of desensitizer solution and volatile solvent is 95:5 to 2.
Manufacturer Hong's decolorizing pen for pressure-sensitive copying paper filled with a 0:80 composition in a felt pen type container.
JP62078739A 1987-03-30 1987-03-30 Decoloring pen for no-carbon paper Pending JPS63242587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62078739A JPS63242587A (en) 1987-03-30 1987-03-30 Decoloring pen for no-carbon paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62078739A JPS63242587A (en) 1987-03-30 1987-03-30 Decoloring pen for no-carbon paper

Publications (1)

Publication Number Publication Date
JPS63242587A true JPS63242587A (en) 1988-10-07

Family

ID=13670255

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62078739A Pending JPS63242587A (en) 1987-03-30 1987-03-30 Decoloring pen for no-carbon paper

Country Status (1)

Country Link
JP (1) JPS63242587A (en)

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