JPS63241055A - Chlorinated polymer composition - Google Patents
Chlorinated polymer compositionInfo
- Publication number
- JPS63241055A JPS63241055A JP7521287A JP7521287A JPS63241055A JP S63241055 A JPS63241055 A JP S63241055A JP 7521287 A JP7521287 A JP 7521287A JP 7521287 A JP7521287 A JP 7521287A JP S63241055 A JPS63241055 A JP S63241055A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- vinyl chloride
- polymer
- stabilizer
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- 239000000203 mixture Substances 0.000 title description 3
- RUDUCNPHDIMQCY-UHFFFAOYSA-N [3-(2-sulfanylacetyl)oxy-2,2-bis[(2-sulfanylacetyl)oxymethyl]propyl] 2-sulfanylacetate Chemical compound SCC(=O)OCC(COC(=O)CS)(COC(=O)CS)COC(=O)CS RUDUCNPHDIMQCY-UHFFFAOYSA-N 0.000 claims abstract description 3
- JOBBTVPTPXRUBP-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS JOBBTVPTPXRUBP-UHFFFAOYSA-N 0.000 claims abstract description 3
- YAAUVJUJVBJRSQ-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2-[[3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propoxy]methyl]-2-(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS YAAUVJUJVBJRSQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003381 stabilizer Substances 0.000 abstract description 6
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 8
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 2
- 239000012776 electronic material Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- ZSAZGCBSZUURAX-UHFFFAOYSA-N 1-chloro-4-(diethoxyphosphorylsulfanylmethylsulfanyl)benzene Chemical compound CCOP(=O)(OCC)SCSC1=CC=C(Cl)C=C1 ZSAZGCBSZUURAX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101000574396 Homo sapiens Protein phosphatase 1K, mitochondrial Proteins 0.000 description 1
- 102100025799 Protein phosphatase 1K, mitochondrial Human genes 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 （１）産業上の利用分野 本発明は塩素含有樹脂組成物に関する。[Detailed description of the invention] (1) Industrial application fields The present invention relates to chlorine-containing resin compositions.
さらに詳しくは金属を含有せずに優れた熱安定性、透明
性を発揮し、好ましくは電子材料間係に用途を有する塩
素含有樹脂組成物に関する。More specifically, the present invention relates to a chlorine-containing resin composition that does not contain metal, exhibits excellent thermal stability and transparency, and is preferably used in electronic materials.
（２）従来技術
塩素含有樹脂は、加熱成型加工を行なう際に、主として
脱塩化水素に起因する熱分解を起しやすく、このために
加工製品の機械的性質の劣化、色調の悪化を生じ、著し
い不利益をまねく、かかる不利益をさけるために、一種
または数種の熱安定剤を該樹脂に添加し、加工工程にお
ける劣化を抑制する必要がある。(2) Prior art Chlorine-containing resins tend to undergo thermal decomposition mainly due to dehydrochlorination when subjected to heat molding, which causes deterioration of mechanical properties and color tone of processed products. In order to avoid such disadvantages, it is necessary to add one or more heat stabilizers to the resin to suppress deterioration during processing.
従来かかる目的で各種の化合物が使用されてきた。Various compounds have been used for this purpose in the past.
しかし、通常は金属を含有する化合物が存在しないと充
分な効果が得られなかったので、ある種の用途（例えば
電子材料部品の梱包容器、ケース、設備等）に使用する
場合、゛使用前に水洗、酸洗を行なう場合があり、かか
る場合に金属化合物を含んだ樹脂の場合、金属が溶出す
ることがあり、不適であった。However, normally, sufficient effects could not be obtained without the presence of metal-containing compounds, so when used for certain purposes (e.g. packaging containers, cases, equipment, etc. for electronic material parts), Washing with water or pickling may be carried out, and in such cases, if the resin contains a metal compound, the metal may be eluted, which is not suitable.
従って、金属を含有しない安定剤として、アルキルフェ
ノール化合物、有機リン化合物、エポキシ化合物、等が
使用されていたが、安定効果（主として熱安定効果）は
不充分であフた。Therefore, alkylphenol compounds, organic phosphorus compounds, epoxy compounds, and the like have been used as metal-free stabilizers, but their stabilizing effects (mainly thermal stabilizing effects) are insufficient.
（３）発明の目的
本発明者等は、かかる現状に鑑み種々検討を瓜ね、金属
を含まない化合物で優れた安定効果（主として熱安定効
果）、透明性を発揮する塩素含有樹脂組成物を見いだす
ことを目的とした。(3) Purpose of the Invention In view of the current situation, the present inventors conducted various studies and developed a chlorine-containing resin composition that is a metal-free compound that exhibits excellent stabilizing effects (mainly thermal stabilizing effects) and transparency. The purpose was to find out.
（４）発明の構成
本発明は下記式（１）〜（３）の化合物の１種あるいは
、２種以上を含有する塩素含有樹脂組成物である。(4) Structure of the Invention The present invention is a chlorine-containing resin composition containing one or more of the compounds represented by the following formulas (1) to (3).
（ＩＩＳ−Ｃ１１２−Ｃ−０−ＣＩＩ＊ ）ａ−Ｃ（
１）ペンタエリスリトールテトラ（チオグリコレート）
以下ｒ’ＴＴＧと略す。(IIS-C112-C-0-CII*)a-C(
1) Pentaerythritol tetra (thioglycolate)
Hereinafter abbreviated as r'TTG.
（ＪＩＳ Ｃｌｌ２−ＣｌＩ２−Ｃ−ＯＣｌＩ２ ）
ａ Ｃ（２）ペンタエリスリトールテトラ（３−メル
カプトプロピオネート）以下ｒ’ ＴＭＰと略す。(JIS Cll2-ClI2-C-OClI2)
a C(2) Pentaerythritol tetra(3-mercaptopropionate) Hereinafter abbreviated as r' TMP.
（ＩＩＳ ＣｌＩ２ ＣｌＩ２ ＣＯＣｌＩ２
）ｓ−Ｃ−ジペンタエリスリトールヘキサ（３−メルカ
プトプロピオネート）以下ＤＩＩＭＰと略す。(IIS ClI2 ClI2 COClI2
) s-C-dipentaerythritol hexa(3-mercaptopropionate) Hereinafter abbreviated as DIIMP.
上記化合物の添加量は塩素含有樹脂１００重量部に対し
て０．０１〜ｌＯ重量部、好ましくは０．１〜５重量部
である。必要に応じて従来から使用されている金属を含
まない安定剤、酸化防止剤、紫外線吸収剤等を適宜含有
させることは差し支えない、塩素含有樹脂としては塩化
ビニル樹脂、塩素化塩化ビニル樹脂、エチレン化塩化ビ
ニル樹脂、それらと他の樹脂との共重合体等が挙げられ
る。The amount of the above compound added is 0.01 to 10 parts by weight, preferably 0.1 to 5 parts by weight, per 100 parts by weight of the chlorine-containing resin. If necessary, conventionally used metal-free stabilizers, antioxidants, ultraviolet absorbers, etc. may be added as appropriate. Examples of chlorine-containing resins include vinyl chloride resin, chlorinated vinyl chloride resin, and ethylene. Examples include vinyl chloride resins and copolymers of these and other resins.
以下に実施例により具体的に説明する。This will be specifically explained below using examples.
実施例１〜８
表−１の配合を、１７０℃の８インチロールで５分間混
練し厚さ０．３ｍｍのシート作成し、このシートを供試
料とし１８０℃のギアーオーブンで赤褐色に変色する時
間を測定し、熱安定性を評価した。また、１７０℃のプ
レス機で５０ｋｇ／ｃｍ２加圧下５分間プレスを行い、
厚さ２ｍｍのシートを作成し初期着色と透明性を評価し
た。Examples 1 to 8 The formulation in Table 1 was kneaded for 5 minutes with an 8-inch roll at 170°C to create a sheet with a thickness of 0.3 mm, and this sheet was used as a sample and the time it took for the sheet to turn reddish brown in a gear oven at 180°C. was measured to evaluate thermal stability. In addition, press was performed for 5 minutes under a pressure of 50 kg/cm2 with a press machine at 170°C.
A sheet with a thickness of 2 mm was prepared and its initial coloring and transparency were evaluated.
比較例１〜５
実施例と同様に表−１の配合で本発明に使用するＰＴＴ
Ｇ、 ＰＴＭＰ、ＤＩＩＭＰ以外の有機化合物、金属を
含む化合物を使用し、実施例と比較した。Comparative Examples 1 to 5 PTT used in the present invention with the formulation shown in Table 1 in the same manner as in Examples
Compounds containing organic compounds and metals other than G, PTMP, and DIIMP were used and compared with Examples.
Claims (1)
ンタエリスリトールテトラ（３−メルカプトプロピオネ
ート）、ジペンタエリスリトールヘキサ（３−メルカプ
トプロピオネート）から選ばれる１種または２種以上を
含有する塩素含有樹脂編成物。Chlorine-containing resin knitted material containing one or more selected from pentaerythritol tetra (thioglycolate), pentaerythritol tetra (3-mercaptopropionate), and dipentaerythritol hexa (3-mercaptopropionate) .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7521287A JPS63241055A (en) | 1987-03-28 | 1987-03-28 | Chlorinated polymer composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7521287A JPS63241055A (en) | 1987-03-28 | 1987-03-28 | Chlorinated polymer composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63241055A true JPS63241055A (en) | 1988-10-06 |
Family
ID=13569670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7521287A Pending JPS63241055A (en) | 1987-03-28 | 1987-03-28 | Chlorinated polymer composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63241055A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0354245A (en) * | 1989-07-21 | 1991-03-08 | Nitto Kasei Co Ltd | Stabilized chlorinated vinyl chloride resin composition |
| US6667357B2 (en) | 2000-12-15 | 2003-12-23 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US6747081B2 (en) | 2000-12-15 | 2004-06-08 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US6927247B2 (en) | 2000-12-15 | 2005-08-09 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US7312266B2 (en) | 2000-12-15 | 2007-12-25 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS554334A (en) * | 1978-06-24 | 1980-01-12 | Yoshitomi Pharmaceut Ind Ltd | Pyranopyrazole derivative |
| JPS5661449A (en) * | 1979-10-13 | 1981-05-26 | Neynaber Chemie Gmbh | Method and composition for stabilizing forming polyvinyl chloride material |
| JPS60115651A (en) * | 1983-08-02 | 1985-06-22 | ソシエテ・ナシヨナ−ル・エルフ・アキテ−ヌ | Thermal stabilization for halogenovinyl resin |
-
1987
- 1987-03-28 JP JP7521287A patent/JPS63241055A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS554334A (en) * | 1978-06-24 | 1980-01-12 | Yoshitomi Pharmaceut Ind Ltd | Pyranopyrazole derivative |
| JPS5661449A (en) * | 1979-10-13 | 1981-05-26 | Neynaber Chemie Gmbh | Method and composition for stabilizing forming polyvinyl chloride material |
| JPS60115651A (en) * | 1983-08-02 | 1985-06-22 | ソシエテ・ナシヨナ−ル・エルフ・アキテ−ヌ | Thermal stabilization for halogenovinyl resin |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0354245A (en) * | 1989-07-21 | 1991-03-08 | Nitto Kasei Co Ltd | Stabilized chlorinated vinyl chloride resin composition |
| US6667357B2 (en) | 2000-12-15 | 2003-12-23 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US6747081B2 (en) | 2000-12-15 | 2004-06-08 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US6762231B2 (en) | 2000-12-15 | 2004-07-13 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US6927247B2 (en) | 2000-12-15 | 2005-08-09 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US7250457B2 (en) | 2000-12-15 | 2007-07-31 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
| US7312266B2 (en) | 2000-12-15 | 2007-12-25 | The College Of William And Mary | Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers |
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