JPS63230762A - Polyester resin composition - Google Patents
Polyester resin compositionInfo
- Publication number
- JPS63230762A JPS63230762A JP6756687A JP6756687A JPS63230762A JP S63230762 A JPS63230762 A JP S63230762A JP 6756687 A JP6756687 A JP 6756687A JP 6756687 A JP6756687 A JP 6756687A JP S63230762 A JPS63230762 A JP S63230762A
- Authority
- JP
- Japan
- Prior art keywords
- polyester resin
- weight
- parts
- resistance
- ultra
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001225 polyester resin Polymers 0.000 title claims abstract description 22
- 239000004645 polyester resin Substances 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title claims description 10
- 239000003365 glass fiber Substances 0.000 claims abstract description 10
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims abstract description 8
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- -1 polybutylene terephthalate Polymers 0.000 abstract description 7
- 229920001707 polybutylene terephthalate Polymers 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 4
- 239000006087 Silane Coupling Agent Substances 0.000 abstract description 2
- 238000000149 argon plasma sintering Methods 0.000 abstract description 2
- 238000004898 kneading Methods 0.000 abstract 1
- 238000000196 viscometry Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 13
- 230000000704 physical effect Effects 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000008188 pellet Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はポリエステル樹脂組成物に関するものであり、
更に詳しくはポリエステル樹脂が本来有する優れた性質
に加えて摩擦・摩耗特性、耐衝撃性、耐熱性および耐吸
水性に優れたポリエステル樹脂組成物に関するものであ
る。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a polyester resin composition,
More specifically, the present invention relates to a polyester resin composition that has excellent friction and abrasion properties, impact resistance, heat resistance, and water absorption resistance in addition to the excellent properties that polyester resin inherently has.
（従来波８）
ポリブチレンテレフタレート、ポリエチレンチルフタレ
ートに代表される熱可塑性ポリエステル樹脂は、耐薬品
性、耐熱性、機械的特性、電気的特性、寸法安定性、耐
燃性、自己潤滑性に優れているためギア、カム、軸受、
電動工具部品、コネクター、プラグ、ヒユーズケース等
広汎な用途に用いられている。(Conventional Wave 8) Thermoplastic polyester resins represented by polybutylene terephthalate and polyethylene tylphthalate have excellent chemical resistance, heat resistance, mechanical properties, electrical properties, dimensional stability, flame resistance, and self-lubricating properties. Gears, cams, bearings,
It is used in a wide range of applications such as power tool parts, connectors, plugs, and fuse cases.
しかしながら、一般にポリエステル樹脂は単独では熱変
形温度が機械的強さ、耐衝撃が充分ではない為、これら
を一層改善するために通常ガラス繊維をポリエステル樹
脂に配合することが行なわれている。However, polyester resins generally do not have sufficient thermal deformation temperature, mechanical strength, or impact resistance when used alone, so glass fibers are usually blended into polyester resins in order to further improve these properties.
また、結晶性樹脂特有の自己潤滑性に優れているとは言
え、摺動部品としてみた場合、限界Ｐｖ値が比較的小さ
い梅、低負荷の用途に限定されている。Furthermore, although it has excellent self-lubricating properties unique to crystalline resins, when viewed as a sliding component, it has a relatively small limit Pv value and is limited to low-load applications.
尚、ここでいう限界ＰＶ値とは、一般に軸受材料が、あ
る一定面圧Ｐ （ｋ８／ｃｍ” ）と周速Ｖ（ｍ／ｍ１
ｎ）以上になると材料が融けたり、焼は付いたりする負
荷の限界値を示す。従って限界Ｐｖ値が大きい程、耐摩
擦・摩耗性は良好であり、高負荷に耐えることを意味す
る。Note that the limit PV value here means that the bearing material generally has a certain surface pressure P (k8/cm") and peripheral speed V (m/m1
n) indicates the limit value of the load at which the material will melt or seize. Therefore, the larger the limit Pv value is, the better the friction and wear resistance is, meaning that it can withstand high loads.
このため、従来からポリエステル樹脂の摩擦・摩耗特性
を改善するためにポリ四フッ化エチレン微粉末（以下Ｐ
ＴＦＥと略す）、二硫化モリブデン、グラファイト、炭
素繊維等の固体潤滑剤を添加することが行なわれている
。For this reason, polytetrafluoroethylene fine powder (hereinafter referred to as P
Solid lubricants such as TFE (abbreviated as TFE), molybdenum disulfide, graphite, and carbon fiber have been added.
（発明が解決しようとする問題点）
しかし、これらの固体潤滑剤はいずれも高価であり、多
量に配合すると価格面からの制約のみならず、炭素繊維
を除く他の固体潤滑では、耐衝撃強度を著しく損なうた
め実用上問題であった。(Problem to be solved by the invention) However, all of these solid lubricants are expensive, and if they are blended in large quantities, they are not only limited in terms of price, but also have low impact resistance and strength with other solid lubricants other than carbon fiber. This was a practical problem because it significantly impaired the
本発明は、上記従来技術の問題点を解決し安価で耐摩擦
・摩耗特性、耐衝撃性、耐熱性が優れかつ吸水率の低い
ポリエステル樹脂組成物を提供する事を目的とする。The object of the present invention is to solve the problems of the prior art described above and to provide a polyester resin composition that is inexpensive, has excellent friction/wear resistance, impact resistance, and heat resistance, and has low water absorption.
（問題点を解決するための手段）
即ち、本発明の特徴とするところはポリエステル樹脂１
００重量部に対してガラス繊維１０〜１００重量部、超
高分子量ポリエチレン１〜５０重量部を均一に溶融混練
したポリエステル樹脂組成物であり、得られた樹脂組成
物は摩擦・摩耗特性、耐衝撃性、耐熱性、耐吸水性にお
いて優れている。(Means for solving the problems) That is, the characteristics of the present invention are that polyester resin 1
This is a polyester resin composition in which 10 to 100 parts by weight of glass fiber and 1 to 50 parts by weight of ultra-high molecular weight polyethylene are uniformly melted and kneaded to 00 parts by weight, and the resulting resin composition has excellent friction/wear properties and impact resistance. Excellent in properties, heat resistance, and water absorption resistance.
本発明において使用するポリエステル樹脂は、ポリブチ
レンテリフタレート、ポリエチレンテレフタレート等に
代表される。The polyester resin used in the present invention is typified by polybutylene terephthalate, polyethylene terephthalate, and the like.
また、本発明において用いられるガラス繊維は繊維径φ
３〜２０μｍ好ましくは６〜１３μｍ、繊維長７０〜６
０００μｍ好ましくは１００〜３０００μｍでポリエス
テル樹脂との接着を向上させるためにガラス繊維をシラ
ン系カップリング剤で処理したものを使用することが好
ましい。Furthermore, the glass fiber used in the present invention has a fiber diameter φ
3-20 μm, preferably 6-13 μm, fiber length 70-6
000 μm, preferably 100 to 3000 μm, and it is preferable to use glass fibers treated with a silane coupling agent in order to improve adhesion to the polyester resin.
例えばＮＥＣチョツプドストランドＥＣ３−０３Ｔ−１
９１（日本電気硝子■製）、ＮＥＣチョツプドストラン
ドＥＣ５−０３Ｔ−１８７（日本電気硝子■製）、ＮＥ
ＣガラスパウダーＥＰＧ−７０Ｍ−７０８（日本電気硝
子■製）等がある。For example, NEC chopped strand EC3-03T-1
91 (manufactured by Nippon Electric Glass), NEC chopped strand EC5-03T-187 (manufactured by Nippon Electric Glass), NE
Examples include C glass powder EPG-70M-708 (manufactured by Nippon Electric Glass Co., Ltd.).
また、本発明において使用する超高分子量ポリエチレン
は粘度法による平均分子量が１００万以上、光散乱法で
３００万以上の分子量を有し、例えば三井石油化学工業
■のハイゼツクスミリオンやミベロン、ヘキスト社のホ
スタレンＧＵＲ等が挙げられる。In addition, the ultra-high molecular weight polyethylene used in the present invention has an average molecular weight of 1 million or more by a viscosity method and a molecular weight of 3 million or more by a light scattering method, such as Mitsui Petrochemical Corporation's HiZex Million, Mibellon, Hoechst Co., Ltd. Examples include hostalene GUR.
上記超高分子量ポリエチレンの粉末の粒子径は約２００
μｍ以下で好ましくは５０μｍ以下である。これらのト
ライブレンド物を直接シングルスクリユーにより射出成
形品、押出成形品を得ようとしてもポリエステル樹脂と
超高分子量ポリエチレンとの分散が悪く、均一な成形品
を得ることが困難である。そのため、例えば、２軸押出
機、１軸押出機等により予め均一に混練し、溶融固化し
た樹脂ベレットを得る事が望ましい。The particle size of the ultra-high molecular weight polyethylene powder is approximately 200.
The thickness is not more than μm, preferably not more than 50 μm. Even if attempts are made to obtain injection molded or extrusion molded products from these triblends by direct single screwing, it is difficult to obtain uniform molded products due to poor dispersion of the polyester resin and ultra-high molecular weight polyethylene. Therefore, it is desirable to obtain resin pellets that are uniformly kneaded in advance using a twin-screw extruder, single-screw extruder, etc., and then melted and solidified.
尚、本発明ではポリエステル樹脂１００重量部に対して
ガラス繊維を１０〜１００重量部添加するが、１０重量
部未満では熱変形温度の向上はわずかであり、１００重
量部を越えると樹脂ベレットの製造が困難となる。In the present invention, 10 to 100 parts by weight of glass fiber is added to 100 parts by weight of the polyester resin, but if it is less than 10 parts by weight, the heat distortion temperature will only improve slightly, and if it exceeds 100 parts by weight, the production of resin pellets will be difficult. becomes difficult.
更に、本発明では超高分子量ポリエチレンの添加量はポ
リエステル樹脂１００重量部に対して１〜５０重量部で
あり、好ましくは３〜３０重量部である。１重量部未満
では摩擦・摩耗特性の効果はわずかであり、５０重量部
を越えると機械的強度の低下が大きくなる。Further, in the present invention, the amount of ultra-high molecular weight polyethylene added is 1 to 50 parts by weight, preferably 3 to 30 parts by weight, based on 100 parts by weight of the polyester resin. If it is less than 1 part by weight, the effect on friction and wear properties is slight, and if it exceeds 50 parts by weight, the mechanical strength will be significantly reduced.
本発明の組成物から得られる成形品は融点が１３６℃と
いう低融点の超高分子量ボリチレンを用いているにもか
かわらず、意外な事に熱変形温度が向上し、加えて摩擦
・摩耗特性、耐衝撃性、耐吸水性が向上する。Although the molded article obtained from the composition of the present invention uses ultra-high molecular weight polytylene with a low melting point of 136°C, the heat distortion temperature is surprisingly improved, and in addition, the friction and wear properties are improved. Improves impact resistance and water absorption resistance.
尚、本発明において必要に応じてその他の強化剤、固体
潤滑剤、例えば２硫化モリブデン、グラファイト、４フ
ツ化エチレン、ステアリン酸およびその金属塩、ワック
ス、オイル、充填剤、例えば炭酸カルシウム、クレー、
シリカ、着色剤等を配合しても良い。こうして得らたポ
リエステル樹脂組成物とテストピース用金型を用いて射
出成形を行ない、得られたテストピースを用いて物性を
測定した。以下本発明を実施例を用いてさらに詳述する
が、熱論この範囲に限定するものではない。In addition, in the present invention, other reinforcing agents, solid lubricants such as molybdenum disulfide, graphite, ethylene tetrafluoride, stearic acid and its metal salts, waxes, oils, fillers such as calcium carbonate, clay,
Silica, coloring agents, etc. may be added. Injection molding was performed using the thus obtained polyester resin composition and a test piece mold, and the physical properties were measured using the obtained test piece. The present invention will be explained in more detail below using Examples, but the present invention is not limited to this range of thermal theory.
尚、各種の物性の測定は以下の方法によった。Incidentally, various physical properties were measured by the following methods.
（１）摩擦・摩耗特性 松原式スラスト（限界ｐ
ｖ値） 試験機
Ｖ ＝ １５ｍ／ｍ１ｎ
（２）アイゾツト衝撃強度 ＡＳＴＭ−Ｄ２５６（ノ
ツチ付）
（３）熱変形温度 ＡＳＴＭ−Ｄ６４８（１
８’、 ５ｋｇ／ｃｍ２）
（４）吸水率 ＡＳＴＭ−０５７０（２
３℃Ｘ２４ＨＲＳ）
実施例１
ポリブチレンテレフタレート（ＰＩ３Ｔ ） （ｔｙｐ
ｅ４ ヘキスト社製）１００重量部、ガラス繊維（ＥＣ
５−０３Ｔ−１９１φ１３μｍＸ３ｍｍ１日本電気硝子
■製）４０重量部、超高分子量ポリエチレン（以下ｔＪ
ＨＭＷ−ＰＦ、と略す）（ミベロンＸＭ２２０平均粒子
径３０μｍ）５重量部をポリエチレン製袋内で予め混合
して、２軸押出機（ＰＣＭ−４５池貝鉄工■製）により
２４０℃で溶融混練しペレタイザーでベレット状にし、
このベレット樹脂をテストピース用金型と射出成形機（
アンケルベルブ Ｖ１５−７５ 日本製鋼所■製）を
用いてシリンダ一温度２４０℃で射出成形してテストピ
ースを作成した。このテストピースを用いて各種物性を
測定した値を表１に示す。(1) Friction/wear characteristics Matsubara thrust (limit p
v value) Testing machine V = 15m/m1n (2) Izod impact strength ASTM-D256 (with notch) (3) Heat distortion temperature ASTM-D648 (1
8', 5kg/cm2) (4) Water absorption ASTM-0570 (2
Example 1 Polybutylene terephthalate (PI3T) (typ.
e4 Hoechst) 100 parts by weight, glass fiber (EC
5-03T-191 φ 13 μm
5 parts by weight of HMW-PF) (Mibellon Make it into a pellet shape with
This pellet resin is used in a test piece mold and an injection molding machine (
A test piece was prepared by injection molding using Ankelbelv V15-75 (manufactured by Japan Steel Works, Ltd.) at a cylinder temperature of 240°C. Table 1 shows the values measured for various physical properties using this test piece.
実施例２
実施例１においてＵＨＭＷ−ＰＥ １０重量部を用い
た以外は実施例１と全く同一の操作を行ないテストピー
スを得た。各種物性を表１に示す。Example 2 A test piece was obtained by carrying out exactly the same operation as in Example 1 except that 10 parts by weight of UHMW-PE was used. Various physical properties are shown in Table 1.
実施例３
実施例１においてＵＨＭＷ−ＰＥ ２０重量部を用い
た以外は実施例１と全く同一の操作を行ないテストピー
スを得た。各種物性を表１に示す。Example 3 A test piece was obtained by carrying out exactly the same operation as in Example 1 except that 20 parts by weight of UHMW-PE was used in Example 1. Various physical properties are shown in Table 1.
実施例４
実施例１においてＵＨＭＷ−ＰＥ ３０重量部を用い
た以外は実施例１と全く同一の操作を行ないテストピー
スを得た。各種物性を表１に示す。Example 4 A test piece was obtained by carrying out exactly the same operation as in Example 1 except that 30 parts by weight of UHMW-PE was used. Various physical properties are shown in Table 1.
実施例５
実施例１においてＵＨＭＷ−ＰＥ １０重量部、グラ
ファイト（ＡＴＮｆ１３０ 粒子径０．５〜７μｍ
オリエンタル産業■製）１０重量部を用いた以外は実施
例１と全く同一の操作を行ないテストピースを得た。各
種物性を表１に示す。Example 5 In Example 1, 10 parts by weight of UHMW-PE, graphite (ATNf130, particle size 0.5 to 7 μm)
A test piece was obtained in exactly the same manner as in Example 1, except that 10 parts by weight (manufactured by Oriental Sangyo ■) was used. Various physical properties are shown in Table 1.
比較例Ｉ
ＰＢＴ（ｔｙｐｅ４ ヘキスト社製）、ｔ−単独で２
４０℃で２軸押出機（ＰＣＭ−４５池貝鉄工■製）によ
り溶融混練しペレタイザーでベレット状にし、このベレ
ットをテストピース用金型と射出成形機（アンケルベル
ブ Ｖ１５−７５ 日本製鋼所■製）ｔ′用いてシリ
ンダ一温度２４０℃で射出成形してテストピースを作製
した。このテストピースを用いて各種物性を測定した値
を表１に示す。Comparative Example I PBT (type 4 manufactured by Hoechst), t- alone 2
The mixture was melted and kneaded at 40°C using a twin-screw extruder (PCM-45 manufactured by Ikegai Iron Works) and made into a pellet using a pelletizer. ' A test piece was prepared by injection molding at a cylinder temperature of 240°C. Table 1 shows the values measured for various physical properties using this test piece.
比較例２
実施例１においてＬＩＨＭＷ−ＰＥｔｌ’全く使用しな
かった以外は、実施例１と全く同一の操作を行ないテス
トピースを得た。各種物性を表１に示す。Comparative Example 2 A test piece was obtained by carrying out exactly the same operation as in Example 1, except that LIHMW-PEtl' was not used at all. Various physical properties are shown in Table 1.
以下余白
（効果）
表１から明らかなように本発明のポリエステル樹脂組成
物は、ポリエステル樹脂にガラス繊維と特定の粒子径を
もつＵＨＭＷ−ＰＥを含有している為、摩擦・摩耗特性
、アイゾツト衝撃値、熱変形温度および耐吸水性等の物
性が向上している。The following margins (effects) As is clear from Table 1, the polyester resin composition of the present invention contains glass fiber and UHMW-PE with a specific particle size in the polyester resin. Physical properties such as value, heat distortion temperature, and water absorption resistance are improved.
Claims (1)
１０〜１００重量部、超高分子量ポリエチレン１〜５０
重量部を均一に混練溶融したことを特徴とするポリエス
テル樹脂組成物。1. 10-100 parts by weight of glass fiber per 100 parts by weight of polyester resin, 1-50 parts by weight of ultra-high molecular weight polyethylene
A polyester resin composition characterized in that parts by weight are uniformly kneaded and melted.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62067566A JP2509090B2 (en) | 1987-03-19 | 1987-03-19 | Polyester resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62067566A JP2509090B2 (en) | 1987-03-19 | 1987-03-19 | Polyester resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63230762A true JPS63230762A (en) | 1988-09-27 |
| JP2509090B2 JP2509090B2 (en) | 1996-06-19 |
Family
ID=13348635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62067566A Expired - Lifetime JP2509090B2 (en) | 1987-03-19 | 1987-03-19 | Polyester resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2509090B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0791632A3 (en) * | 1996-02-23 | 1999-09-08 | Ticona GmbH | Resinous moulding matter having reduced wear |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5066548A (en) * | 1973-10-15 | 1975-06-04 | ||
| JPS601254A (en) * | 1983-06-17 | 1985-01-07 | Toray Ind Inc | Polybutylene terephthalate resin composition |
| JPS60144351A (en) * | 1984-01-06 | 1985-07-30 | Mitsui Petrochem Ind Ltd | Thermoplastic resin composition |
| JPS621736A (en) * | 1985-06-27 | 1987-01-07 | Mitsui Petrochem Ind Ltd | Polyolefin powder composition |
-
1987
- 1987-03-19 JP JP62067566A patent/JP2509090B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5066548A (en) * | 1973-10-15 | 1975-06-04 | ||
| JPS601254A (en) * | 1983-06-17 | 1985-01-07 | Toray Ind Inc | Polybutylene terephthalate resin composition |
| JPS60144351A (en) * | 1984-01-06 | 1985-07-30 | Mitsui Petrochem Ind Ltd | Thermoplastic resin composition |
| JPS621736A (en) * | 1985-06-27 | 1987-01-07 | Mitsui Petrochem Ind Ltd | Polyolefin powder composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0791632A3 (en) * | 1996-02-23 | 1999-09-08 | Ticona GmbH | Resinous moulding matter having reduced wear |
| EP1180537A3 (en) * | 1996-02-23 | 2002-03-27 | Ticona GmbH | Polyamide resinous moulding matter having reduced wear |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2509090B2 (en) | 1996-06-19 |
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