JPS63224734A - Paper having adsorbing and deodorizing characteristic - Google Patents
Paper having adsorbing and deodorizing characteristicInfo
- Publication number
- JPS63224734A JPS63224734A JP62058738A JP5873887A JPS63224734A JP S63224734 A JPS63224734 A JP S63224734A JP 62058738 A JP62058738 A JP 62058738A JP 5873887 A JP5873887 A JP 5873887A JP S63224734 A JPS63224734 A JP S63224734A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- sepiolite
- deodorizing
- fibrous
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 46
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 28
- 239000004113 Sepiolite Substances 0.000 claims abstract description 27
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 238000001179 sorption measurement Methods 0.000 claims description 28
- 239000002657 fibrous material Substances 0.000 claims description 7
- 239000002781 deodorant agent Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000012254 powdered material Substances 0.000 claims description 3
- 208000005156 Dehydration Diseases 0.000 claims 1
- 230000018044 dehydration Effects 0.000 claims 1
- 238000006297 dehydration reaction Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 20
- 229910021529 ammonia Inorganic materials 0.000 abstract description 10
- 229920002678 cellulose Polymers 0.000 abstract description 10
- 239000001913 cellulose Substances 0.000 abstract description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000835 fiber Substances 0.000 description 8
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 239000003463 adsorbent Substances 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- -1 5i02 is 52 to 5 5% Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000007966 viscous suspension Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
ａ、産業上の利用分野
本発明は、吸着及び脱臭特性を有する紙に関し、特に、
セピオライトの繊維状物又は粉末状物を用いて吸着及び
脱臭特性を有する紙に関するものである。DETAILED DESCRIPTION OF THE INVENTION a. Industrial Application Field The present invention relates to paper with adsorption and deodorizing properties, in particular:
The present invention relates to paper having adsorption and deodorizing properties using fibrous or powdered sepiolite.
ｂ、従来の技術
従来、用いられていたこの種の吸着及び脱臭特性を有す
る紙としては、種々の構成が提案されているが、これら
の提案を大まかに分けると、活性炭を含む紙及び不織布
状の紙、未処理の普通の紙に化学消臭剤を含浸させるこ
とにより、脱臭特性を持たせたもの等がある。b. Conventional technology Various configurations have been proposed for papers with this kind of adsorption and deodorizing properties that have been used in the past, but these proposals can be roughly divided into paper containing activated carbon and non-woven paper. paper, and paper that has deodorizing properties by impregnating untreated ordinary paper with a chemical deodorizing agent.
これらの従来例として、その代表的な構成について述べ
ると、パルプスラリーに微細粒結晶性オルソリン酸アン
モニウムを混合し、この混合スラリーを抄紙したアンモ
ニアを吸着するシート状物質（特開昭５９−９５９３１
号公報に開示）、パルプに吸着媒体として微粉活性炭を
混入した吸着物質含有紙、海泡石を微細に分割した吸着
媒粉末を含有した吸着物質含有紙（特開昭５３−６６１
１号公報に開示）などが提案されている。To describe a typical configuration of these conventional examples, a sheet-like material that adsorbs ammonia (Japanese Patent Application Laid-open No. 59-95931
(disclosed in Japanese Patent Publication No. 53-661), adsorbent-containing paper in which finely powdered activated carbon is mixed into pulp as an adsorption medium, adsorbent-containing paper containing adsorbent powder made by finely dividing sepiolite (Japanese Patent Laid-Open No. 53-661)
(Disclosed in Publication No. 1) have been proposed.
さらに、セルローズ繊維と、このセルローズ繊維１００
重量部に対して５０ないし３０００重量部の非晶質部を
有する珪酸マグネシウム質粘土鉱物とを主成分としてな
る吸着材料（特開昭６１−１３６４３８号）が提案され
ている。Furthermore, cellulose fiber and this cellulose fiber 100
An adsorption material (Japanese Patent Application Laid-open No. 136438/1983) has been proposed which contains as a main component a magnesium silicate clay mineral having an amorphous part of 50 to 3000 parts by weight.
Ｃ１発明が解決しようとする問題点
従来の吸着及び脱臭特性を有する紙は、以上のように構
成されていたため、次のような種々の問題点を有してい
た。C1 Problems to be Solved by the Invention Conventional paper having adsorption and deodorizing properties was constructed as described above, and therefore had various problems as described below.
（１）、まず、活性炭を含む紙は色が黒色となり、吸着
性も硫黄系化合物の吸着性に優れているが、アンモニア
系の吸着性は小さく、従って脱臭特性は有するが、消臭
性は有していない。(1) First, paper containing activated carbon is black in color and has excellent adsorption properties for sulfur-based compounds, but has low adsorption properties for ammonia-based compounds.Therefore, although it has deodorizing properties, it has no deodorizing properties. I don't have it.
（２）、又、有機繊維からなる不織布の場合、吸水膨潤
剤を含んでいるため、吸水性に優れた特性は有するが、
脱臭性はなく、一般に化学消臭剤等との複合化を必要と
している。(2) Also, in the case of non-woven fabrics made of organic fibers, they contain water-absorbing swelling agents, so they have excellent water-absorbing properties;
It does not have deodorizing properties and generally requires combination with chemical deodorizing agents.
（３）、又、普通の紙に後加工で脱臭性の機能を付加し
たものは、表面が比較的平滑であり、悪臭ガス等を捉え
る働きをする孔の存在が極めて少ないため、吸着特性は
小さく、化学消臭剤の担体としての機能が小であること
が現実の状態である。(3) Also, ordinary paper with deodorizing functions added in post-processing has a relatively smooth surface and has extremely few pores that trap foul-smelling gases, so its adsorption properties are poor. The reality is that it is small and its function as a carrier for chemical deodorants is small.
（４）、又、セピオライトを含む紙は存在するが、
。(4)Although there are papers containing sepiolite,
.
これは、セピオライトが繊維状であること、並びに、耐
熱性を有するが故に、機械的強度及び耐熱性が要求され
るガスケット材料へ主として利用されており、セピオラ
イトの多孔質性に基づく吸着特性を有効に利用した吸着
及び脱臭性を持たせた紙は、未だ存在していない。Because sepiolite is fibrous and has heat resistance, it is mainly used for gasket materials that require mechanical strength and heat resistance. Paper with adsorption and deodorizing properties that can be used for this purpose does not yet exist.
本発明は、以上のような問題点を解決するためになされ
たちのて、特に、セビオライトの繊維状物又は粉末状物
を用いて吸着及び脱臭特性を有する紙を提供することを
目的とする。The present invention was made in order to solve the above-mentioned problems, and in particular, it is an object of the present invention to provide paper having adsorption and deodorizing properties using fibrous or powdered Seviolite.
ｄ３問題点を解決するための手段
本発明による吸着及び脱臭特性を有する紙は、セビオラ
イト繊維状物を粉砕したものからなる繊維状物又は粉末
状物を有し、紙状に形成された構成である。d3 Means for Solving Problems The paper having adsorption and deodorizing properties according to the present invention has a fibrous or powdered material made of crushed Seviolite fibrous material, and is formed into a paper-like structure. be.
６９作 用
本発明による吸着及び脱臭特性を有する紙においては、
セピオライトの結晶構造が断面でみると無数の細多孔質
であるため、吸着及び脱臭効果に優れている。69 Effects In the paper with adsorption and deodorizing properties according to the present invention,
The crystal structure of sepiolite has numerous fine pores when viewed in cross section, so it has excellent adsorption and deodorizing effects.
又、用途に応じて形状の変更や他の材料と組み合わせ、
複合効果を持たせることにより、湿気の吸着剤、アンモ
ニアや硫化水素等の悪臭の脱臭及び消臭材料として広く
利用することができる。Also, depending on the application, the shape can be changed or combined with other materials,
By having multiple effects, it can be widely used as a moisture adsorbent and as a deodorizing and deodorizing material for bad odors such as ammonia and hydrogen sulfide.
ｆ、実施例
以下、図面と共に本発明による吸着及び脱臭特性を有す
る紙の好適な実施例について詳細に説明する。f. Examples Hereinafter, preferred examples of the paper having adsorption and deodorizing properties according to the present invention will be described in detail with reference to the drawings.
本発明において用いられたセビオライトは、大まかには
二種類の産状に分けられる。Seviolite used in the present invention can be roughly divided into two types of occurrence.
その一つは、エバポライト型の鉱床として産出し、他は
二次鉱床として産するものである。One of them is produced as an evaporite type deposit, and the others are produced as secondary deposits.
この二次鉱床として産出するセビオライトは、ドロマイ
ト鉱床中のクラックや断層中へ水に溶解した珪酸分が移
動して二次的に結晶化した鉱床であり、いわゆる、Ｍｏ
ｕｎｔａｉｎ Ｌｅａｔｈｅｒ、Ｍｏｕｎｔａｉｎｃｏ
ｒｋ及びＭｏｕｎｔａｉｎ ｕ＋ｏｏｄ等と呼ばれてい
るものである。Seviolite, which is produced as a secondary deposit, is a deposit in which silicic acid dissolved in water migrates into cracks and faults in dolomite deposits and is secondary crystallized.
untain Leather, Mountainco
These are called rk and Mountain u+ood.
これらの産地としては、スペイン、トルク、アメリカの
ネバダ州、中国の湖南省などが産地として知られている
。Known production areas include Spain, Turkey, Nevada in the United States, and Hunan Province in China.
これらの天然のセピオライトの組成は、産地により異な
るが、例えば、スペイン産の場合、５ｉ０２が５２〜５
５％、ＭｇＯが１５〜２５％、結晶水が１０〜１２％で
ある。The composition of these natural sepiolites varies depending on the region of production, but for example, in the case of Spanish sepiolite, 5i02 is 52 to 5
5%, MgO 15-25%, and water of crystallization 10-12%.
又、中国産の場合、５ｉ０２が３７〜４３％、ＣａＯが
１２〜１６％、ＭｇＯが１７〜２０％、結晶水が１５〜
２０％となっている。In addition, in the case of Chinese products, 5i02 is 37-43%, CaO is 12-16%, MgO is 17-20%, and crystal water is 15-43%.
It is 20%.
このセピオライトは、Ｍｏｕｎｔａｉｎ Ｌｅａｔｌ＋
ｅｒと呼称されるように、非常に柔軟性に富んだ鉱物で
あり、この性質はその結晶構造にトンネルを有している
こと、繊維間や繊維内のトンネルに水分子を結晶水とし
て有していること、並びに、ＳｉＯ，ｓ四面体の反転が
あることが相乗して現われているものと考えられる。This sepiolite is Mountain Leatl+
ER is a very flexible mineral, and its properties include tunnels in its crystal structure, and water molecules as crystal water in the tunnels between and within the fibers. It is thought that this is caused by the synergistic effect of this and the inversion of the SiO,s tetrahedron.
その吸着性能については、前述のトンネル構造によるも
のであり、ゼオライト様の結晶水を有しているからであ
る。Its adsorption performance is due to the above-mentioned tunnel structure and because it has zeolite-like water of crystallization.
結晶内のトンネルに基づく細孔容積は、せいぜいＯ，１
ｍｌ／ｇ程度で、約２５０肩２／ｇ程度である。The pore volume based on tunnels in the crystal is at most O,1
It is about 250 shoulder 2/g in about ml/g.
特に、２００人付近の細孔に特徴があり、その細孔容積
は０．８ｘｌ／ｇと大変大きい容量を示している。この
領域の細孔は、いわゆるｔｒａｓｉｔｉｏｎａｌｐｏｒ
ｅ（）ラジショナル ポアー）と云われるもので、ガス
状分子を吸着するミクロボアーとは異なり、液状のもの
を最小径の毛細管現象で吸い上げるような性質を持って
いる。In particular, the pores around 200 pores are characterized by a very large pore volume of 0.8xl/g. The pores in this region are so-called trasional porosity.
They are called radial pores (radial pores), and unlike micro pores, which adsorb gaseous molecules, they have the property of sucking up liquid substances through capillary action with the smallest diameter.
このトラジショナル ボアーの部分は、約７００℃程度
に加熱したものでも大きく変化することはないので、こ
れは各繊維間に出来る空隙による細孔と考えられる。Since this traditional bore portion does not change significantly even when heated to about 700° C., it is thought that this is a pore formed by voids formed between each fiber.
尚、このセピオライトの産出形態としては、繊維状や粉
末が集合した泥板状となっているので、採鉱後、粉砕及
び解砕等の処理が必要である。Note that this sepiolite is produced in the form of fibers or mud plates made up of powder, so it requires treatment such as crushing and crushing after mining.
次に、加工後のセピオライトと天然のゼオライトの特性
表は次の通りである。Next, the characteristic table of processed sepiolite and natural zeolite is as follows.
＝７一
本発明による紙の主成分であるセピオライトは、繊維状
、粉末状のいずれでも用いることが出来、繊維状物の場
合は、ターボミル、ハンマーミル等中で出来るだけ繊維
を傷めない様に粉砕し、繊維を解離状態にし、柔軟性を
有する繊維とする。=71 Sepiolite, which is the main component of the paper according to the present invention, can be used in either fibrous or powdered form. In the case of fibrous material, it is processed in a turbo mill, hammer mill, etc. in a manner that does not damage the fibers as much as possible. It is crushed to dissociate the fibers and make them flexible.
又、粉末状物の場合も、ターボミル、ハンマーミル等を
用いて１００〜３００メツシユの粉状に粉砕する。この
粉末状物はこのままの状態で使用することができるが、
その吸着特性を向上させるために、５００〜６００℃の
雰囲気中で２０〜３０分間焼成し、付着水を完全に除去
し、活性化させたものを用いるとより効果的である。Also, in the case of a powdered material, it is ground into a powder of 100 to 300 meshes using a turbo mill, a hammer mill, or the like. This powder can be used as is, but
In order to improve its adsorption properties, it is more effective to use one that has been activated by firing in an atmosphere at 500 to 600° C. for 20 to 30 minutes to completely remove attached water.
従って、実際には、前述のセピオライトの粉末状物又は
繊維状物にセルローズパルプを混合し、この混合は表紙
用ビータ−、パルパー等を用いて湿式で行い、シート成
型には一般の抄紙機を用いている。Therefore, in reality, cellulose pulp is mixed with the aforementioned sepiolite powder or fiber, and this mixing is done wet using a cover beater, pulper, etc., and a general paper machine is used to form the sheet. I am using it.
この場合、セピオライトとセルローズの混合化率は、セ
ピオライト１００重量部に対してセルローズパルプ４０
〜４００重量部であることが好ましく、これはセルロー
ズが４０重量部以下であると、セピオライトが水中で分
散し、高粘度の懸濁液（サスペンション）となることに
より、抄紙工程において、セルローズ繊維に対し、目づ
めの作用を有することになって沢水性が阻害されて、抄
紙速度が極度に低下するか又は不可能となる。In this case, the mixing ratio of sepiolite and cellulose is 40 parts by weight of cellulose pulp per 100 parts by weight of sepiolite.
It is preferable that the amount is 400 parts by weight or less, because if the cellulose content is 40 parts by weight or less, sepiolite will be dispersed in water and form a highly viscous suspension (suspension). On the other hand, it has a clogging effect, impeding water flow and making papermaking speed extremely low or impossible.
又、前述と逆に、セルローズの比率が４００部以上に高
くなると、紙の中に占めるセピオライトの含有量が少な
くなり、吸着性が極めて小さくなる。Moreover, contrary to the above, when the ratio of cellulose increases to 400 parts or more, the content of sepiolite in the paper decreases, and the adsorptivity becomes extremely low.
又、本発明による紙の脱臭特性を複合強化するために、
紙の内部に化学消臭剤（例えば、大日精化製の有機酸を
ベースとした複合物）の溶液を表面に吹付け、又は、含
浸によって紙に含ませることができる。Moreover, in order to compound the deodorizing properties of the paper according to the present invention,
A solution of a chemical deodorizer (for example, an organic acid-based compound manufactured by Dainichiseika) can be incorporated into the paper by spraying onto the surface or by impregnation.
さらに、本発明による紙は、消臭剤及び芳香物質の担持
材料として優れた性質を有しているので、芳香剤を表面
に後加工することにより長期間の有効性を保持すること
が出来る。Furthermore, the paper according to the invention has excellent properties as a carrier material for deodorants and fragrances, so that it can maintain long-term effectiveness by post-processing fragrances onto the surface.
次に本発明による吸着及び脱臭特性を有する紙を製造す
るための具体的な実施例について説明する。Next, specific examples for producing paper having adsorption and deodorizing properties according to the present invention will be described.
実施例１
セピオライトの繊維状物を粉砕して解繊したもので、ロ
ータツブ分級篩分は試験の結果、下表のデータが得られ
た。Example 1 Sepiolite fibrous material was pulverized and defibrated, and the rotary tube classification sieve fraction was tested and the data shown in the table below was obtained.
ロータツブ篩分は試験
前述のセピオライト繊維１００部に対し、セルローズパ
ルプ１５０部、有機系バインダー２．５部を４０００部
の水と混合し、実験用ビータを用いて均一なスラリーを
調整した。For the Rotatub sieve, 100 parts of the sepiolite fibers described above, 150 parts of cellulose pulp, and 2.5 parts of an organic binder were mixed with 4000 parts of water, and a uniform slurry was prepared using an experimental beater.
これを手すきの抄紙機を用いて抄造し、脱水乾燥し、厚
さ０．８部肩、密度０．４２９／Ｃ肩３の紙が得られた
。This was made into paper using a hand-made paper machine and dehydrated and dried to obtain paper with a thickness of 0.8 part shoulder and a density of 0.429/C shoulder 3.
実施例２
セピオライトの粉末状物を５００〜６００℃の雰囲気中
で２０分間焼成したものを、粉砕して１００〜３００メ
ツシユの微粉とし、このセピオライト１００部に対し、
セルローズパルプ２３０部、有機系バインダー２．５
部を４０００部の水と混合し、実施例１と同様の操作に
より厚さ０．８ｙｘ、密度０．４５ｇ７ｃｍ３の紙が得
られた。Example 2 Powdered sepiolite was fired in an atmosphere of 500 to 600°C for 20 minutes and then ground to a fine powder of 100 to 300 meshes. For 100 parts of sepiolite,
230 parts of cellulose pulp, 2.5 parts of organic binder
1 part was mixed with 4000 parts of water and the same procedure as in Example 1 was carried out to obtain paper having a thickness of 0.8yx and a density of 0.45g7cm3.
実施例３
実施例２によって得られた組成に対して、化学消臭剤（
大日精化ダイムシュー、有機酸の複合タイプ、粉末状）
５部をビータ−で混合し、実施例１と同様の操作によっ
て厚さ０．８ｙｘ、密度０．４５ｙ／ｃ肩３の紙が得ら
れた。Example 3 A chemical deodorant (
Dainichiseika Dime Shoe, organic acid complex type, powder form)
5 parts were mixed with a beater and the same operation as in Example 1 was performed to obtain paper with a thickness of 0.8 yx and a density of 0.45 y/c shoulder 3.
実施例４
実施例２で得られた紙を、化学消臭剤（大日精化ダイム
シュー、有機酸の複合タイプ、液状）の１％液に含浸し
、乾燥させて、この化学消臭剤を含有した紙が得られた
。Example 4 The paper obtained in Example 2 was impregnated with a 1% solution of a chemical deodorant (Dainichiseika Dime Shoe, organic acid composite type, liquid) and dried to obtain a sample containing this chemical deodorant. paper was obtained.
前記紙の脱臭特性を把握するために、アンモニア、トリ
メチルアミン及び硫化水素に対する特性試験を下記の方
法で行い、顕著な脱臭効果を確認した。In order to understand the deodorizing properties of the paper, characteristic tests against ammonia, trimethylamine, and hydrogen sulfide were conducted in the following manner, and a remarkable deodorizing effect was confirmed.
特性試験Ａ （アンモニアの脱臭）
１ｌ−
３００ｉｊ！容量の三角フラスコに、２８％アンモニア
水１０μβを採取して完全にガス化させた後、サンプル
５０Ｘ１００肩Ｉ１１枚を投入し、２５℃に保存し、所
定の時間経過後、乳用式ガス検知管を用いて、フラスコ
内のアンモニア残存濃度を測定した。Characteristic test A (ammonia deodorization) 1l- 300ij! After collecting 10 μβ of 28% ammonia water into a large Erlenmeyer flask and completely gasifying it, put 11 samples of 50×100 shoulder I and store it at 25°C. The residual concentration of ammonia in the flask was measured using
特性試験Ｂ （）リメチルアミンの脱臭）３００＊１
容景の三角フラスコに０，６％ トリメチルアミン水溶
液１０μｐを採取して、完全にガス化させた後、サンプ
ル５０Ｘ１００１Ｊ１１枚を投入し、２５℃に保存し、
所定の時間経過後、乳用式ガス検知器を用いて、フラス
コ内のトリメチルアミン残存濃度を測定した。Characteristic test B () Deodorization of remethylamine) 300*1
Collect 10 μp of 0.6% trimethylamine aqueous solution into a conical flask, and after completely gasifying it, put 11 samples of 50 x 1001 J and store it at 25 ° C.
After a predetermined period of time had elapsed, the residual concentration of trimethylamine in the flask was measured using a dairy gas detector.
前述の各薬品（アンモニア、トリメチルアミン及び硫化
水素）に対する消臭結果は次の通りである。The deodorizing results for each of the aforementioned chemicals (ammonia, trimethylamine, and hydrogen sulfide) are as follows.
Ｔｒａｃｅは痕跡 （ｐｐＩｌ）ＮＤ は
検出されず
Ｔｒａｃｅは痕跡 （ｐｐｍ）ＮＤ は検
出されず
さらに、アンモニア及び硫化水素に対して、前記グイム
シュー５００２ＦＺのケント紙（１）塗工品を用いた場
合の消臭結果は、第１図及び第２図に示す通りである。Trace is a trace (ppIl) ND is not detected.Trace is a trace (ppm) ND is not detected.Furthermore, the deodorization of ammonia and hydrogen sulfide when using the Kent paper (1) coated product of Guimshu 5002FZ The results are shown in FIGS. 1 and 2.
ｇ、発明の効果
本発明による吸着及び消臭特性を有する紙は、以上のよ
うに構成されているため、次のような効果を得ることが
できる。g. Effects of the Invention Since the paper having adsorption and deodorizing properties according to the present invention is constructed as described above, the following effects can be obtained.
（１）、セピオライトの繊維状物を粉砕して解繊したも
のを用いているため、無数の細孔を有しており、十分な
吸着及び脱臭性を有すると共に、消臭性及び芳香性をも
たせるための化学消臭剤や芳香物質を担持することがで
き、吸着及び脱臭の他に、消臭及び芳香作用を十分に得
ることができる。(1) Because it uses crushed and defibrated sepiolite fibrous material, it has countless pores and has sufficient adsorption and deodorizing properties, as well as deodorizing and aromatic properties. It can support chemical deodorizing agents and aromatic substances, and in addition to adsorption and deodorization, it can also have sufficient deodorizing and aromatic effects.
（２）、従って、本発明による紙は、その吸着及び脱臭
性等を利用することにより、くつ中敷、消臭・吸湿マッ
ト、脱臭用壁掛、脱臭マット、脱臭・芳香紙及びオイル
脱臭装置等への応用が可能となる。(2) Therefore, by utilizing its adsorption and deodorizing properties, the paper according to the present invention can be used in shoe insoles, deodorizing/moisture-absorbing mats, deodorizing wall hangings, deodorizing mats, deodorizing/fragrant papers, oil deodorizing devices, etc. It becomes possible to apply it to
第１図及び第２図は、本発明による紙のアンモニア及び
硫化水素に対する消臭結果を示すための特性図である。FIGS. 1 and 2 are characteristic diagrams showing the deodorizing results of paper according to the present invention against ammonia and hydrogen sulfide.
Claims (6)
繊維状物又は粉末状物を有し、紙状に形成されたことを
特徴とする吸着及び脱臭特性を有する紙(1) A paper having adsorption and deodorizing properties characterized by being formed into a paper-like shape and containing a fibrous or powdered material made of crushed sepiolite fibrous material.
％の範囲で含むことを特徴とする特許請求の範囲第１項
記載の吸着及び脱臭特性を有する紙。(2) 25 to 65% of the fibrous or powdery material
% of paper having adsorption and deodorizing properties as claimed in claim 1.
ていることを特徴とする特許請求の範囲第１項又は第２
項記載の吸着及び脱臭特性を有する紙。(3) The sepiolite is subjected to heating and dehydration treatment, as claimed in claim 1 or 2.
Paper having adsorption and deodorizing properties as described in Section 1.
とする特許請求の範囲第１項乃至第３項の何れかに記載
の吸着及び脱臭特性を有する紙。(4) A paper having adsorption and deodorizing properties according to any one of claims 1 to 3, characterized in that it contains a chemical deodorizing agent therein.
でいることを特徴とする特許請求の範囲第１項乃至第３
項の何れかに記載の吸着及び脱臭特性を有する紙。(5) Claims 1 to 3 contain a liquid chemical deodorant on its surface and inside.
Paper having adsorption and deodorizing properties as described in any of the above.
求の範囲第１項乃至第５項の何れかに記載の吸着及び脱
臭特性を有する紙。(6) A paper having adsorption and deodorizing properties according to any one of claims 1 to 5, characterized in that it contains an aromatic substance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62058738A JPS63224734A (en) | 1987-03-16 | 1987-03-16 | Paper having adsorbing and deodorizing characteristic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62058738A JPS63224734A (en) | 1987-03-16 | 1987-03-16 | Paper having adsorbing and deodorizing characteristic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63224734A true JPS63224734A (en) | 1988-09-19 |
Family
ID=13092857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62058738A Pending JPS63224734A (en) | 1987-03-16 | 1987-03-16 | Paper having adsorbing and deodorizing characteristic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63224734A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5306487A (en) * | 1990-02-12 | 1994-04-26 | Nancy Karapasha | High capacity odor controlling compositions |
| US5407442A (en) * | 1990-02-12 | 1995-04-18 | Karapasha; Nancy | Carbon-containing odor controlling compositions |
| USH1579H (en) * | 1990-02-12 | 1996-08-06 | Furio; Diane L. | Odor-controlling compositions and articles |
| US5679433A (en) * | 1991-10-31 | 1997-10-21 | Kabushiki Kaish Tokiwa Denki | Noncombustible sheet, noncombustible laminated sheet, noncombustible honey comb structural material, noncombustible board, noncombustible molded product, and manufacturing method thereof |
| JP2000189793A (en) * | 1998-12-28 | 2000-07-11 | Nippon Sekisoo Kogyo Kk | Porous mineral-containing formed body and its production |
| US6814759B2 (en) | 2002-08-06 | 2004-11-09 | Board Of Regents Of The University Of Nebraska | Stable zeolite/cellulose composite materials and method of preparation |
| US7122122B2 (en) | 2003-07-22 | 2006-10-17 | Kraft Foods Holdings, Inc. | Molecular imprinting of solute on cellulose/silica composite, and products and uses thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61136436A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136438A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136437A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136439A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
-
1987
- 1987-03-16 JP JP62058738A patent/JPS63224734A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61136436A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136438A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136437A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
| JPS61136439A (en) * | 1984-12-07 | 1986-06-24 | Toyota Central Res & Dev Lab Inc | Malodor absorbing material and its preparation |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5306487A (en) * | 1990-02-12 | 1994-04-26 | Nancy Karapasha | High capacity odor controlling compositions |
| US5407442A (en) * | 1990-02-12 | 1995-04-18 | Karapasha; Nancy | Carbon-containing odor controlling compositions |
| USH1579H (en) * | 1990-02-12 | 1996-08-06 | Furio; Diane L. | Odor-controlling compositions and articles |
| US5679433A (en) * | 1991-10-31 | 1997-10-21 | Kabushiki Kaish Tokiwa Denki | Noncombustible sheet, noncombustible laminated sheet, noncombustible honey comb structural material, noncombustible board, noncombustible molded product, and manufacturing method thereof |
| JP2000189793A (en) * | 1998-12-28 | 2000-07-11 | Nippon Sekisoo Kogyo Kk | Porous mineral-containing formed body and its production |
| US6814759B2 (en) | 2002-08-06 | 2004-11-09 | Board Of Regents Of The University Of Nebraska | Stable zeolite/cellulose composite materials and method of preparation |
| US7122122B2 (en) | 2003-07-22 | 2006-10-17 | Kraft Foods Holdings, Inc. | Molecular imprinting of solute on cellulose/silica composite, and products and uses thereof |
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