JPS6321268A - Surface coated board-form rock - Google Patents
Surface coated board-form rockInfo
- Publication number
- JPS6321268A JPS6321268A JP16318786A JP16318786A JPS6321268A JP S6321268 A JPS6321268 A JP S6321268A JP 16318786 A JP16318786 A JP 16318786A JP 16318786 A JP16318786 A JP 16318786A JP S6321268 A JPS6321268 A JP S6321268A
- Authority
- JP
- Japan
- Prior art keywords
- stone
- oya stone
- oya
- plate
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011435 rock Substances 0.000 title description 3
- 239000004575 stone Substances 0.000 claims description 53
- 229920003002 synthetic resin Polymers 0.000 claims description 15
- 239000000057 synthetic resin Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 description 11
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 9
- 239000004566 building material Substances 0.000 description 6
- 238000010276 construction Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241000356114 Trachytes Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910000498 pewter Inorganic materials 0.000 description 1
- 239000010957 pewter Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002345 surface coating layer Substances 0.000 description 1
Landscapes
- Paper (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、建材並びに装飾材として用いられる板状大谷
石の本来の美感を維持しながら増強度並びにそりを防止
するために透明な合成樹脂で表面被覆を施した板状大谷
石に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention is directed to the use of transparent synthetic resin to improve the strength and prevent warping while maintaining the original beauty of plate-shaped Oya stone used as building materials and decorative materials. This paper relates to plate-shaped Oya stone whose surface has been coated with.
大谷石は栃木県大谷地方の地下層より切り出し産出され
る有名な石材であるが、その成因は日本列島の大半が海
中にあり、一部が海面上に突出していた時代に岩盤の長
い裂は目から噴出しておびただしい流紋岩質角礫（石英
粗面岩）の火山灰、砂礫が海水中に沈澱し、凝固したも
のが大谷石であるといわれている。その石質は耐火、耐
震力が強く、乾湿性に富み、軽重（比重１．９９）で加
工しやすく、土木建築用石材としてその用途はすこぶる
広汎であり、我国における需要は年々高まっている。特
に、地下層より産出された直後の青味を帯びた班模様は
、優美で建築材及び装飾材として大いに好まれ、土木建
築用、スポーツ施設用あるいは石垣、門柱、玄関、池等
、多方面に使用されている。Oya stone is a famous stone that is cut and produced from underground layers in the Oya region of Tochigi Prefecture, and its origins date back to a time when most of the Japanese archipelago was underwater, with some parts protruding above the sea surface, and long cracks in the bedrock formed. Oya stone is said to be formed by the volcanic ash and gravel of numerous rhyolitic breccias (quartz trachytes) ejected from the eye, which precipitated in seawater and solidified. The stone has strong fire and earthquake resistance, excellent dryness and moisture resistance, is light in weight (specific gravity 1.99), and is easy to process.It has a wide range of uses as a stone for civil engineering and construction, and its demand in Japan is increasing year by year. In particular, the bluish pattern immediately after it is produced from the underground layer is elegant and highly preferred as a building material and decorative material, and can be used for many purposes such as civil engineering construction, sports facilities, stone walls, gateposts, entrances, ponds, etc. used in
この様に装飾性に冨んだ大谷石の班模様は、白色凝灰岩
に青味を帯びた第二鉄（Ｆｅ −５Ｏｎ・ｎＨ２Ｏ）
が混在しているために生じるものであるが、地下層より
採掘され空気中に触れた時から経時的にその色調が変化
し、更に風化する過程を経るために、建材・装飾材とし
て耐久性及びその美感が要求されていた。The highly decorative pattern of Oya stone is made of white tuff with a bluish tinge of ferric iron (Fe-5On・nH2O).
The color tone changes over time from the time it is mined from the underground layer and comes into contact with the air, and it also undergoes a process of weathering, making it durable as a building material and decorative material. and its beauty was in demand.
更に、需要が増大した大谷石の資源量は限りがあり、年
々不足の危機を来たす現状では、地下層より採掘したブ
ロック状の大谷石材を積層せずに板状に裁断した大谷石
を建築−母材表面に張り付ける等手段が考え出されてい
る。Furthermore, as the demand for Oya stone has increased, the resources of Oya stone are limited, and there is a risk of shortage year after year. Some methods have been devised, such as attaching it to the surface of the base material.
しかし、板状大谷石を装飾材として使用する事は、凝灰
岩の石質から起因するもろさによって、作業中に破断し
たり、あるいは長時間経過後に微妙なそりを生じ、更に
は前記した様に大谷石特有の斑模様が板状に伴う表面積
の増大によって酸化が進行し、変色及び風化を促進する
。However, when using Oya stone as a decorative material, due to the brittle nature of the tuff, it may break during work or cause slight warping after a long period of time. Oxidation progresses due to the increased surface area associated with the plate-like mottled pattern unique to stones, which promotes discoloration and weathering.
〔問題点を解決するための手段および作用〕本発明は上
記に鑑みてなされたものであり、既に建造されたあるい
は切り出した大谷石表面の色調を使用者の好みの色調あ
るいは任意の個所の色調を維持し、風化をを停止し、更
に板状大谷石の破壊強度を高め、そりを防止するため、
大谷石表面の色調変化過程に任意の個所の表面に透明な
合成樹脂を塗膜した板状大谷石を提供するものである。[Means and effects for solving the problem] The present invention has been made in view of the above, and it is possible to change the color tone of the surface of Oya stone that has already been constructed or cut out to the user's favorite color or the color tone of any part. In order to maintain this, stop weathering, further increase the breaking strength of the plate-shaped Oya stone, and prevent warping.
To provide a plate-shaped Oya stone whose surface is coated with a transparent synthetic resin at any location during the color tone change process of the Oya stone surface.
以下本発明による表面被覆を施した板状大谷石を説明す
る。The plate-shaped Oya stone with the surface coating according to the present invention will be explained below.
地下層に埋積された白目あるいは前回の積層岩から露天
掘、抗内堀で採掘されたブロック状の大谷石は水分を多
量に含有し、前記した白色凝灰岩に青味を帯びた第二鉄
（Ｆｅ”・Ｓｏ、・ｎＨ２Ｏ）が散在している。この斑
模様は、空気中に触れると水分が乾燥し経時的に茶褐色
の第二鉄（Ｆｅ （ＯＨ）・５０４）に変化し、大谷石
の斑模様は茶味を帯び、全体として色性せた色調になる
。更に酸化が進行すると、第二鉄がＦｅ （ＯＢ） ３
あるいはＰｅ２（Ｓｏｔ） ３に腐食され、脱落し、周
辺の凝灰岩が風化するに到ってブロック材の原形状が維
持できなくなる。Block-shaped Oya stone, which is excavated from pewter or previously laminated rock buried in the underground layer, by open pit or inland trenches, contains a large amount of water, and contains the aforementioned white tuff with bluish ferric iron ( This mottled pattern is caused by the moisture drying up when exposed to the air and changing to brownish ferric iron (Fe (OH) 504) over time. The mottled pattern has a brownish tinge, and the overall color tone becomes darker.As oxidation progresses further, ferric iron changes to Fe (OB) 3
Alternatively, it is corroded by Pe2(Sot)3 and falls off, and the surrounding tuff weathers, making it impossible to maintain the original shape of the block material.
そこで本発明によると、第１図は本発明の一実施例を示
すものであり、地下数十メートルに達する原石採石場に
おいて、採掘平面を縦横に所定間隙をもって掘下げてな
る基準面上のブロック群を、基準面より所要な寸法の石
材を切削し、大谷石のもつ優美さを維持出来るブロック
自動切削装置等によって前記石材装飾材として建材の用
途に合わせて所定の板状に裁断された板状石材１と、板
状石材１の全面＋ａ）あるいは片面（ｂｌに例えばキシ
レン及びサク酸エチールを１：１に配合した二液性の溶
剤型ウレタン−アクリル系樹脂（あるいは分散型水系ウ
レタン樹脂ディスパージョンでもよい）を刷毛あるいは
当該溶剤に浸漬する事によって、大谷石石材表面に均一
に塗布した合成樹脂２とから成る。Therefore, according to the present invention, FIG. 1 shows an embodiment of the present invention, in which a group of blocks on a reference plane are formed by digging down the quarry plane vertically and horizontally with predetermined gaps in a raw stone quarry that reaches several tens of meters underground. The stone is cut into the required dimensions from the standard surface, and cut into a predetermined plate shape according to the use of the stone decorative material as a building material using an automatic block cutting device or the like that can maintain the elegance of Oya stone. The stone 1 and the entire surface +a) or one side of the stone 1 (bl is a two-component solvent-type urethane-acrylic resin (or dispersion-type water-based urethane resin dispersion) in which xylene and ethyl succinate are mixed in a 1:1 ratio. The synthetic resin 2 is uniformly applied to the surface of Oya stone by using a brush or dipping it in the solvent.
合成樹脂２は塗装作業性の観点から前記キシレン及びサ
ク酸エチールを混合してから、表面に一様に塗布するま
での可使時間は８Ｈ程度であって、その後指触乾燥性は
３０分程度であった。From the viewpoint of painting workability, synthetic resin 2 has a pot life of about 8 hours after mixing the xylene and ethyl succinate until it is uniformly applied to the surface, and is dry to the touch after that for about 30 minutes. Met.
一方浸漬した場合には、石材の浸漬時間及び引き上げ速
さによって、塗布量が決まり、樹脂塗布量／石材重量が
１．３〜１．７％程度の塗布量で室温に２４Ｈ放置する
と透明な均一な被覆が施された。On the other hand, in the case of immersion, the coating amount is determined by the immersion time of the stone and the lifting speed.If the resin coating amount/stone weight is about 1.3 to 1.7% and left at room temperature for 24 hours, it will become transparent and uniform. A special coating was applied.
この様な被覆が施されると、前記した第二鉄が第二鉄に
変化する色調変化の段階と、第二鉄から風化に到る段階
が完全に阻止され、採石当初の青味を帯びた色調を維持
しながら、風化を防止出来る。When such a coating is applied, the above-mentioned stage of color change in which ferric iron changes to ferric iron and the stage of weathering from ferric iron are completely inhibited, and the stone retains its original bluish tinge. It can prevent weathering while maintaining the original color tone.
第２図は本発明の他の実施例を示すものであり、第１図
同様大釜石の石材１と、白色の凝灰岩３と、青味を帯び
た鉄分の斑模様４と、この青味を帯びた斑模様が茶褐色
に色調変化した第二鉄５と、石材１表面の任意個所に塗
布された前記合成樹脂２から成る。合成樹脂２は石材１
の表面に塗布したい形状に貫通したマスクをあてがい、
刷毛等で所定量を塗布する。FIG. 2 shows another embodiment of the present invention, and similarly to FIG. It consists of ferric iron 5 with a mottled pattern that has changed in color to brownish-brown, and the synthetic resin 2 coated on arbitrary parts of the surface of the stone 1. Synthetic resin 2 is stone 1
Apply a penetrating mask to the shape you want to coat on the surface of the
Apply the specified amount with a brush, etc.
この様な被覆が施されると、合成樹脂２で被覆されない
石材表面は、経時的に変化し、被覆された青味の斑模様
と独特の色調合を楽しむことが出来る。When such a coating is applied, the surface of the stone that is not coated with the synthetic resin 2 changes over time, allowing the user to enjoy the coated bluish mottled pattern and unique color combination.
第３図は前記第１図、第２図の表面被覆を施した板状大
谷石の建築材あるいは装飾材としての利用例であり、（
ａ）は前記第１図の全面に合成樹脂の表面被覆を施した
板状大谷石裏面に接着剤６を塗布し、建築母材７に張り
付けたものであり、Ｔｂｌは片面に合成樹脂の表面被覆
を施した板状大谷石の反対面に接着材６を塗布して建築
母材７に張り付けたものである。Figure 3 shows an example of the use of plate-shaped Oya stone with the surface coating shown in Figures 1 and 2 as a building material or decorative material.
In a), adhesive 6 is applied to the back side of the plate-shaped Oya stone whose entire surface is coated with synthetic resin as shown in FIG. An adhesive 6 is applied to the opposite side of the coated plate-shaped Oya stone and it is attached to a construction base material 7.
前記合成樹脂の表面被覆を施した板状大谷石及び被覆を
施さない板状大谷石の強度を比較するために、同寸法の
板状大谷石の四角に支点を置き、中心部に負荷を与えた
ところ、溶剤型ウレタン・アクリン系樹脂を被覆した大
谷石の支持荷重が大きく、明らかに破壊強度の高い板状
大谷石を得ることが出来た。In order to compare the strength of the plate-shaped Oya stone with the synthetic resin surface coating and the plate-shaped Oya stone without the coating, a fulcrum was placed at the square of the plate-shaped Oya stone of the same size, and a load was applied to the center. As a result, Oya stone coated with solvent-based urethane/acrylic resin had a large supporting load, and it was possible to obtain plate-shaped Oya stone with clearly high breaking strength.
以上説明した通り、本発明の合成樹脂の表面被覆を施し
た板状大谷石によれば、大谷石表面の色調変化過程に任
意の個所の表面に透明な合成樹脂を塗膜したため、
既に建造されたあるいは切り出した大谷石表面の色調を
使用者の好みの色調あるいは任意の個所の破壊強度を高
めそれを防止することが出来る。As explained above, according to the plate-shaped Oya stone whose surface is coated with the synthetic resin of the present invention, since the transparent synthetic resin is coated on the surface of arbitrary parts during the color tone change process of the Oya stone surface, the surface of the Oya stone has already been constructed. Alternatively, the color tone of the surface of the cut Oya stone can be set to the user's preference, or the fracture strength at any location can be increased to prevent this.
第１図ｆａ） （ｂ）は板状大谷石に表面被覆を施した
断面図、第２図は板状大谷石に任意の形状に表面被覆を
施した平面図及び断面図、第３図（ａ） （ｂｌは、板
状大谷石を建築母材に張り付けた断面図。
符号の説明
１・・・板状大谷石 ２・・・表面被覆層（合成樹脂
）３・・・凝灰岩 ４・・・斑模様５・・・第二
鉄 ６・・・接着剤７・・・建築母材
特 許 出 願人 有限会社屏風岩石材部同
三井東圧化学株式会社
代理人 弁理士 松 原 伸 ２同 同
村 木 清 用量 同
上 島 淳 −第１図
第２図Fig. 1 fa) (b) is a cross-sectional view of a plate-shaped Oya stone with a surface coating applied, Fig. 2 is a plan view and a cross-sectional view of a plate-shaped Oya stone with a surface coating applied to an arbitrary shape, and Fig. 3 ( a) (BL is a cross-sectional view of plate-shaped Oya stone attached to the building material. Explanation of symbols 1...Plate-shaped Oya stone 2...Surface coating layer (synthetic resin) 3...Tuff 4...・Mottled pattern 5... Ferric iron 6... Adhesive 7... Construction base material patent Applicant: Byobu Rock Materials Department Co., Ltd.
Mitsui Toatsu Chemical Co., Ltd. Agent Patent Attorney Shin Matsubara 2 Same Kiyoshi Muraki Dosage Same
Atsushi Ueshima - Figure 1 Figure 2
Claims (3)
記薄板表面の全面あるいは一部分で阻止する透明な合成
樹脂の被覆層を有することを特徴とする表面被覆を施し
た板状大谷石。(1) A surface coating characterized by having a thin plate-like Oya stone and a transparent synthetic resin coating layer that prevents the oxidation process of iron contained in the thin plate-like Oya stone on the entire surface or a part of the thin plate surface. A plate-shaped Oya stone with
樹脂である特許請求の範囲第１項記載の表面被覆を施し
た板状大谷石。(2) The surface-coated Oya stone plate according to claim 1, wherein the synthetic resin coating layer is a solvent-based urethane-acrylic resin.
スパージョンである特許請求の範囲第１項記載の表面被
覆を施した板状大谷石。(3) The surface-coated Oya stone plate according to claim 1, wherein the synthetic resin coating layer is a dispersed water-based urethane resin dispersion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16318786A JPS6321268A (en) | 1986-07-11 | 1986-07-11 | Surface coated board-form rock |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16318786A JPS6321268A (en) | 1986-07-11 | 1986-07-11 | Surface coated board-form rock |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6321268A true JPS6321268A (en) | 1988-01-28 |
Family
ID=15768914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16318786A Pending JPS6321268A (en) | 1986-07-11 | 1986-07-11 | Surface coated board-form rock |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6321268A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0671624A (en) * | 1992-07-30 | 1994-03-15 | Mitsubishi Materials Corp | Concrete product with artificial stone and its production |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50105551A (en) * | 1973-12-15 | 1975-08-20 | ||
| JPS5213519A (en) * | 1975-07-24 | 1977-02-01 | Brother Ind Ltd | Building materials consisting of natural stones |
| JPS543830A (en) * | 1977-06-13 | 1979-01-12 | Shintarou Nitsuta | Method of preventing wethering oyaishii bonded stones by coating with synthetic resin |
-
1986
- 1986-07-11 JP JP16318786A patent/JPS6321268A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50105551A (en) * | 1973-12-15 | 1975-08-20 | ||
| JPS5213519A (en) * | 1975-07-24 | 1977-02-01 | Brother Ind Ltd | Building materials consisting of natural stones |
| JPS543830A (en) * | 1977-06-13 | 1979-01-12 | Shintarou Nitsuta | Method of preventing wethering oyaishii bonded stones by coating with synthetic resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0671624A (en) * | 1992-07-30 | 1994-03-15 | Mitsubishi Materials Corp | Concrete product with artificial stone and its production |
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| Saikia et al. | Elements of civil engineering | |
| Blair | The building materials of Otago and south New Zealand generally | |
| Yapp | Official catalogue of the Great Exhibition of the Works of Industry of All Nations, 1851 | |
| Ries | Building stones and clay-products: a handbook for architects | |
| Schütznerová-Havelková | The thousand year old building stone of romanesque prague. | |
| Heaton | The preservation of stone | |
| Wood Conroy | Roman wall paintings in the Pafos theatre | |
| Ratcliff | A rock in a hard place: European use of dolerite in Tasmania | |
| Loughlin | Indiana Oolitic Limestone: Relation of its natural features to its commercial grading | |
| Hunt et al. | A Descriptive Guide to the Museum of Practical Geology: With Notices of the Geological Survey of the United Kingdom, the Royal School of Mines, and the Mining Record Office | |
| Mac Culloch | I. Sketch of the Mineralogy of Sky. | |
| Egleston | The cause and prevention of the decay of building stone | |
| Brink | Rock art conservation research at Writing-on-stone Provincial Park, Alberta | |
| Lorenc et al. | Selected, new proposals of geotouristic attractions from Lower Silesia | |
| England | Practical Building Conservation: Stone | |
| Fidler | Notes on building construction | |
| Wiggers | Chicago in Stone and Clay: A Guide to the Windy City's Architectural Geology |