JPS63205370A - Coloring material composition containing gypsum and production thereof - Google Patents
Coloring material composition containing gypsum and production thereofInfo
- Publication number
- JPS63205370A JPS63205370A JP26686986A JP26686986A JPS63205370A JP S63205370 A JPS63205370 A JP S63205370A JP 26686986 A JP26686986 A JP 26686986A JP 26686986 A JP26686986 A JP 26686986A JP S63205370 A JPS63205370 A JP S63205370A
- Authority
- JP
- Japan
- Prior art keywords
- pigments
- water
- gypsum
- coloring material
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000004040 coloring Methods 0.000 title claims abstract description 15
- 239000010440 gypsum Substances 0.000 title claims abstract description 15
- 229910052602 gypsum Inorganic materials 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000049 pigment Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000975 dye Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 150000004683 dihydrates Chemical class 0.000 claims abstract description 4
- 239000001023 inorganic pigment Substances 0.000 claims description 8
- 239000012860 organic pigment Substances 0.000 claims description 8
- 239000003125 aqueous solvent Substances 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 2
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000003086 colorant Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 235000004936 Bromus mango Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は均一に分散し鮮明な色調を呈するセッコウを用
いた色材組成物及びその製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a coloring material composition using gypsum that is uniformly dispersed and exhibits a clear color tone, and a method for producing the same.
従来、顔料を化粧料基材に配合する時、あらかしめ顔料
をクルクやマイカ等の体質顔料と混合させたちのを用い
、顔料が均一に分散するよう配慮されている。しかしな
がら、体質顔料と混合することにより、顔料の鮮明さが
落ち、また、時として化粧料基剤への分散が完全でなく
色ブッとして観察されることがある。更には外観色と塗
布色とが異なる等の欠点がある。Conventionally, when blending pigments into cosmetic base materials, care has been taken to ensure that the pigments are evenly dispersed by mixing a toning pigment with an extender pigment such as curcum or mica. However, when mixed with an extender pigment, the sharpness of the pigment decreases, and sometimes the dispersion into the cosmetic base is not complete and the color appears dull. Furthermore, there are drawbacks such as the appearance color and the coating color being different.
本発明者等はこのような従来の顔料と体質顔料の混合分
散方法にかわるものとして鋭意研究をかさねた結果、セ
ッコウを用いることにより先の欠点を解決でき、しかも
顔料のみならず染料や天然色素にも応用出来る方法を見
いだした。As a result of extensive research into an alternative to the conventional method of mixing and dispersing pigments and extender pigments, the present inventors found that by using gypsum, the above drawbacks could be solved. I found a method that can be applied to
(問題点を解決するための手段〕
すなわち本発明は、二水セッコウと、無機顔料、有機顔
料、染料および天然色素の一種または二種以上とからな
る色材組成物である。(Means for Solving the Problems) That is, the present invention is a coloring material composition comprising gypsum dihydrate and one or more types of inorganic pigments, organic pigments, dyes, and natural pigments.
以下本発明の構成について詳述する。The configuration of the present invention will be explained in detail below.
本発明の色材組成物は二水セッコウと、無機顔料、有機
顔料、染料および天然色素の一種または二種以上とから
なる。無機顔料は、酸化チタン、酸化鉄(ヘンガラ)、
黄酸化鉄、黒酸化鉄、カーボンブランク、マンゴハイオ
レソト、コバルトハイオレソト、酸化クロム、水酸化ク
ロム、チタン酸コバルト、群青、紺青等であり、有機顔
料は、赤色202号、赤色204号、赤色226号、黄
色401号、青色404号等であり、染料あるいは天然
色素は人体に対して無害なものであればよく、それらの
一種または二種以上の混合物を使用する。The coloring material composition of the present invention comprises gypsum dihydrate and one or more of inorganic pigments, organic pigments, dyes, and natural pigments. Inorganic pigments include titanium oxide, iron oxide (hengara),
Yellow iron oxide, black iron oxide, carbon blank, mango hiolesotho, cobalt hiolesotho, chromium oxide, chromium hydroxide, cobalt titanate, ultramarine, deep blue, etc., and the organic pigments include Red No. 202, Red No. 204, and Red. No. 226, Yellow No. 401, Blue No. 404, etc. The dye or natural pigment may be one that is harmless to the human body, and one or a mixture of two or more of them may be used.
本発明の色材組成物は、三水セ、コウ25〜99.9重
量%、および無機顔料、有機顔料、染料および天然色素
の一種または二種以上が0.1〜75重量%の組成範囲
よりなるものである。The coloring material composition of the present invention has a composition range of 25 to 99.9% by weight of Sanshuise, Kou, and 0.1 to 75% by weight of one or more of inorganic pigments, organic pigments, dyes, and natural pigments. It is more than that.
本発明の色材組成物の製造法はとくに限定されないが、
1分子当り0〜0.5モルの水を結晶水として持つセノ
コウと、無機顔料、有機顔料、染料および天然色素の一
種または二種以上と、水又は水性溶媒水溶液とを混合し
、固化後粉砕し製造するのが、最も効率的である。Although the method for producing the coloring material composition of the present invention is not particularly limited,
Mix cypress having 0 to 0.5 mol of water per molecule as crystal water, one or more types of inorganic pigments, organic pigments, dyes, and natural pigments, and water or an aqueous solution of an aqueous solvent, solidify and then pulverize. It is most efficient to manufacture
水性溶媒とは、水に相溶し、最後の粉砕工程前、 の
時点で揮散し残存しないものであればよく、ア七トン、
メチルアルコール、エチルアルコール等が使用される。The aqueous solvent may be any solvent as long as it is compatible with water and does not volatilize and remain before the final pulverization step.
Methyl alcohol, ethyl alcohol, etc. are used.
上記製造方法を、より具体的に示す。The above manufacturing method will be explained more specifically.
たとえば、先ず1分子当り0〜0.5モルの水を結晶水
として持つセッコウ25〜99.9部を、 0.1〜7
5部の無機顔料、有機顔料、染料および天然色素の一種
または二種以上とを均一に攪拌混合する。For example, first, 25 to 99.9 parts of gypsum having 0 to 0.5 mol of water per molecule as crystal water, 0.1 to 7
5 parts of one or more of inorganic pigments, organic pigments, dyes, and natural pigments are uniformly stirred and mixed.
これに25〜150部の水又は水性溶媒を添加して攪拌
混合し均一に分散する。これを3〜24時間室時間室温
放置−40〜80風乾燥機によって乾燥する。25 to 150 parts of water or an aqueous solvent is added to this and mixed with stirring to uniformly disperse the mixture. This is left at room temperature for 3 to 24 hours and dried in a -40 to 80 wind dryer.
次いでこれを粉砕して目的とする色材組成物を得ること
が出来る。この場合、粒径は任意にコントロール出来る
が、0.01〜10μが好ましい。Next, this can be pulverized to obtain the desired coloring material composition. In this case, the particle size can be controlled arbitrarily, but is preferably 0.01 to 10μ.
以上のように本発明に従って得られたセソ“コラを用い
た色材組成物は、例えばメーキャンプ化粧料基剤に配合
した時、分散性がよく鮮明な色調を呈し且つ色ブツがな
く、しかも外観色と塗布色とが一致しやすい優れた性質
を持つ。As described above, the colorant composition using seso-kola obtained according to the present invention has good dispersibility, exhibits a clear color tone, has no color spots, and has no uneven color when blended into a make-up cosmetic base, for example. It has an excellent property of making it easy for the external color to match the coating color.
本発明の色材組成物は化粧料、塗料、合成樹脂その他各
種の被着色物の着色剤として有効に使用できるものであ
る。The coloring material composition of the present invention can be effectively used as a coloring agent for cosmetics, paints, synthetic resins, and various other objects to be colored.
更に表面を親油化処理あるいは親7に化処理することに
より、応用範囲が広くなる。親油化処理とは、例えばシ
リコンあるいは親油性界面活性剤により表面処理するこ
とであり、親油化処理とは、例えばポリビニルアルコー
ルのような水溶性樹脂あるいは親油性界面活性剤により
表面処理することである。Furthermore, by subjecting the surface to lipophilic treatment or oleophilic treatment, the range of applications can be widened. Lipophilic treatment refers to surface treatment with, for example, silicone or a lipophilic surfactant, and lipophilic treatment refers to surface treatment with, for example, a water-soluble resin such as polyvinyl alcohol or a lipophilic surfactant. It is.
ここで、本発明によって作られた色材組成物の優れた性
質を試験した結果を述べる。Here, the results of testing the superior properties of the colorant composition made according to the present invention will be described.
色調の鮮明さについて、単純に体質顔料と色材を攪拌混
合粉砕したものと比較した結果を表−1に示す。Table 1 shows the results of a comparison of the clarity of color tone with that obtained by simply stirring and pulverizing extender pigments and coloring materials.
特性値としては表色法の一つであるハンターのI5、a
、b値を用い、次の二つの式から鮮やかさの尺度である
彩度(C)と色の濃さを表す色濃度(ΔEw)で比較し
た。CもΔEWも大きい値の方が色が鮮明であることを
示す。The characteristic values are Hunter's I5, a, which is a color system.
, b value was used, and the following two equations were used to compare saturation (C), which is a measure of vividness, and color density (ΔEw), which is a measure of color density. The larger the value of both C and ΔEW, the clearer the color.
・ 彩度(C) = J’;”−コT
・ 色1度(ΔEw)=
表−1かられかるように、いずれの場合も本発明によっ
て作られた色材組成物の方がCとΔEwが大きい値を示
し色調での優位性は明らかである。- Saturation (C) = J';''-koT - Color degree (ΔEw) = As seen from Table 1, in all cases, the color material composition made according to the present invention is better than C. ΔEw shows a large value, and the superiority in color tone is clear.
(以下余白) 表−1 ※ 粉末同志で攪拌混合粉砕したもの。(Margin below) Table-1 *Those powders are mixed and ground by stirring.
つぎに実施例をあげて、本発明をさらに詳細に説明する
。本発明はこれにより限定されるものではない。Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby.
実施例1
ヘンガラ50部と市販の焼セッコウ50部をヘンシェル
ミキサーにて攪拌混合し、均一に分散する。Example 1 50 parts of hengara and 50 parts of commercially available calcined gypsum were stirred and mixed using a Henschel mixer to uniformly disperse the mixture.
これに水100部を添加し攪拌混合する。その後バット
に取り出し、−夜室温放置後、60’C熱風乾燥で3時
間乾燥し粉砕機にて粉砕する。Add 100 parts of water to this and mix with stirring. Thereafter, it was taken out into a vat, left to stand overnight at room temperature, dried with hot air at 60'C for 3 hours, and pulverized with a pulverizer.
実施例2
ヘンガラ25部、黄酸化鉄25部市販の焼セッコウ50
部をヘンシェルミキサーにて攪拌混合し、均一に分散す
る。これに水125部を添加し攪拌混合する。その後ハ
ントに取り出し、−夜室温放置後、6Q’c熱風乾燥で
3時間乾燥し粉砕機にて粉砕する。Example 2 25 parts of Hengara, 25 parts of yellow iron oxide, 50 parts of commercially available calcined gypsum
Stir and mix the two parts using a Henschel mixer to uniformly disperse the mixture. Add 125 parts of water to this and mix with stirring. Thereafter, the mixture was taken out into a hunter, left at room temperature overnight, dried with 6Q'c hot air for 3 hours, and pulverized with a pulverizer.
実施例3
赤色226号50部と無水セン3950部をヘンシェル
ミキサーにて攪拌混合し、均一に分散する。これに水1
00部とエチルアルコール25部を添加し攪拌混合する
。その後ハツトに取り出し、−夜室温放置後、60°C
熱風乾燥で3時間乾燥し粉砕機にて粉砕する。Example 3 50 parts of Red No. 226 and 3,950 parts of anhydride were stirred and mixed in a Henschel mixer and uniformly dispersed. Add 1 water to this
00 parts and 25 parts of ethyl alcohol were added and mixed with stirring. After that, take it out in a hat and leave it at room temperature overnight, then 60°C.
Dry with hot air for 3 hours and pulverize with a pulverizer.
実施例4
黄色401号25部とナイロンパウダー25部、市販の
焼セッコウ50部をヘンシェルミキサーにて攪拌混合し
、均一に分散する。これに水100部とエチルアルコー
ル25部を添加し攪拌混合する。その後ハントに取り出
し、−夜室温放置後、60℃熱風乾燥で3時間乾燥し粉
砕機にて粉砕する。Example 4 25 parts of Yellow No. 401, 25 parts of nylon powder, and 50 parts of commercially available calcined gypsum were stirred and mixed in a Henschel mixer to uniformly disperse them. 100 parts of water and 25 parts of ethyl alcohol are added to this and mixed with stirring. Thereafter, the mixture was taken out in a hunter, left overnight at room temperature, dried with hot air at 60°C for 3 hours, and pulverized in a pulverizer.
実施例5
青色404号25部、雲母チタン系パール剤25部、市
販の焼セッコウ50部をヘンシェルミキサーにて攪拌混
合し、均一に分散する。これに水100部とエチルアル
コール25部を添加し攪拌混合する。その後バットに取
り出し、−夜室温放置後、60℃熱風乾燥で3時間乾燥
し粉砕機にて粉砕する。Example 5 25 parts of Blue No. 404, 25 parts of mica titanium based pearling agent, and 50 parts of commercially available calcined gypsum were stirred and mixed in a Henschel mixer to uniformly disperse them. 100 parts of water and 25 parts of ethyl alcohol are added to this and mixed with stirring. Thereafter, it was taken out into a vat, left to stand overnight at room temperature, dried with hot air at 60°C for 3 hours, and pulverized using a pulverizer.
比較例1.2
実施例1.2において、市販の焼セノコウをタルクに置
換して同様の製造条件で色材組成物を調製した。Comparative Example 1.2 A coloring material composition was prepared under the same manufacturing conditions as in Example 1.2, except that talc was substituted for commercially available calcined sardine.
実施例1及び2における色材組成物を配合したファンデ
ーションは、比較例1.2における色材組成物を配合し
たファンデーションと比較し、色ブツは認められず、ま
た、外観色と塗布色の差がほとんどない。The foundations blended with the colorant compositions in Examples 1 and 2 were compared with the foundations blended with the colorant compositions in Comparative Example 1.2, and no color spots were observed, and there was no difference between the appearance color and the applied color. There are almost no
比較例3
実施例3において、無水セッコウをマイカに置換して同
様の製造条件で色材組成物を調製した。Comparative Example 3 A coloring material composition was prepared under the same manufacturing conditions as in Example 3 except that anhydrous gypsum was replaced with mica.
実施例3の色材組成物を配合した粉末固型状アイシャド
ーは、比較例3の色材組成物を配合したものより色調が
鮮明であった。The powdered solid eyeshadow blended with the colorant composition of Example 3 had a clearer color tone than the powdered solid eyeshadow blended with the colorant composition of Comparative Example 3.
特許出廓人 株式会社 資生党 手続補正書(自発) 昭和62年10月5日Patent distributor Shiseito Co., Ltd. Procedural amendment (voluntary) October 5, 1986
Claims (2)
び天然色素の一種または二種以上とからなる色材組成物
。(1) A coloring material composition comprising gypsum dihydrate and one or more types of inorganic pigments, organic pigments, dyes, and natural pigments.
つセッコウと、無機顔料、有機顔料、染料および天然色
素の一種または二種以上と、水または水性溶媒水溶液と
を混合し、固化後粉砕することを特徴とする色材組成物
の製造法。(2) Mixing gypsum having 0 to 0.5 mol of water per electron as crystal water, one or more of inorganic pigments, organic pigments, dyes and natural pigments, and water or an aqueous solution of an aqueous solvent, A method for producing a coloring material composition, which comprises pulverizing after solidification.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26686986A JPS63205370A (en) | 1986-11-10 | 1986-11-10 | Coloring material composition containing gypsum and production thereof |
US07/766,892 US5221342A (en) | 1986-11-10 | 1991-09-25 | Coloring composition and production method and use thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26686986A JPS63205370A (en) | 1986-11-10 | 1986-11-10 | Coloring material composition containing gypsum and production thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63205370A true JPS63205370A (en) | 1988-08-24 |
JPH0573145B2 JPH0573145B2 (en) | 1993-10-13 |
Family
ID=17436781
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26686986A Granted JPS63205370A (en) | 1986-11-10 | 1986-11-10 | Coloring material composition containing gypsum and production thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63205370A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015045994A1 (en) * | 2013-09-30 | 2015-04-02 | 吉野石膏株式会社 | Coloring agent composition and method for producing same |
-
1986
- 1986-11-10 JP JP26686986A patent/JPS63205370A/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015045994A1 (en) * | 2013-09-30 | 2015-04-02 | 吉野石膏株式会社 | Coloring agent composition and method for producing same |
JPWO2015045994A1 (en) * | 2013-09-30 | 2017-03-09 | 吉野石膏株式会社 | Colorant composition and method for producing the same |
US9630884B2 (en) | 2013-09-30 | 2017-04-25 | Yoshino Gypsum Co., Ltd. | Coloring agent composition and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
JPH0573145B2 (en) | 1993-10-13 |
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