JPS6320191A - Surface roughening method for cold rolling roll - Google Patents
Surface roughening method for cold rolling rollInfo
- Publication number
- JPS6320191A JPS6320191A JP61165146A JP16514686A JPS6320191A JP S6320191 A JPS6320191 A JP S6320191A JP 61165146 A JP61165146 A JP 61165146A JP 16514686 A JP16514686 A JP 16514686A JP S6320191 A JPS6320191 A JP S6320191A
- Authority
- JP
- Japan
- Prior art keywords
- roll
- laser
- point
- roughness
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007788 roughening Methods 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims description 14
- 238000005097 cold rolling Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims abstract description 9
- 238000002844 melting Methods 0.000 claims abstract description 7
- 230000008018 melting Effects 0.000 claims abstract description 7
- 238000007711 solidification Methods 0.000 claims description 6
- 230000008023 solidification Effects 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 3
- 230000003746 surface roughness Effects 0.000 abstract description 7
- 230000001360 synchronised effect Effects 0.000 abstract description 2
- 238000005096 rolling process Methods 0.000 description 8
- 229910000734 martensite Inorganic materials 0.000 description 7
- 239000002344 surface layer Substances 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910001566 austenite Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009760 electrical discharge machining Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005422 blasting Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000655 Killed steel Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Heat Treatment Of Articles (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Laser Beam Processing (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は冷間圧延用ロールの粗面化方法に関し、さらに
詳しくは金属材料の冷間圧延または調質圧延用ロールを
所望のパターンと凹凸深さに粗面化し、維持する方法に
関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for roughening a roll for cold rolling, and more specifically, a method for roughening a roll for cold rolling or temper rolling of metal materials into a desired pattern and roughness. Concerning how to roughen and maintain depth.
金属材料の圧延鋼板の重要な品質として表面品質がある
。表面品質には、美麗さ、塗装やほうろうの密着性、プ
レス加工性、耐食性、光沢などがあるが、それらの特性
に板の幾何学的形状すなわち表面粗さが重要な影響をお
よぼす。Surface quality is an important quality of rolled steel sheets, which are metal materials. Surface quality includes beauty, adhesion of paint and enamel, press workability, corrosion resistance, gloss, etc., and the geometric shape of the board, that is, surface roughness, has an important influence on these properties.
それぞれの用途に応じた望ましい表面粗さを持つ金属表
面を得る最も普通の方法は、冷間圧延用ロールまたは/
および調質圧延用ロール表面を所定の粗さに加工してお
き、このロールで鋼板を所定の圧力でI′E延し、板表
面にロール表面の粗さ壷転写せしめる方法である。The most common method of obtaining a metal surface with the desired surface roughness for each application is by cold rolling or/and
In this method, the surface of a temper rolling roll is processed to a predetermined roughness, and a steel plate is I'E-rolled using this roll at a predetermined pressure, thereby transferring the roughness of the roll surface onto the plate surface.
ロール表面を粗面化する方法として従来広く行われてい
る方法には、
(1)ショツトブラスト
(2)放電加工法
がある。Conventionally widely used methods for roughening the roll surface include (1) shot blasting and (2) electrical discharge machining.
ショツトブラストは非常に簡便であり、またこの加工に
よりロール表面が加工硬化してロールの耐摩耗性を向上
させるなどの利点を持っているが、粗さが不均則である
こと、深い粗さがつけにくいことなどの欠点がある。Shot blasting is very simple and has the advantage of work-hardening the roll surface and improving the wear resistance of the roll, but it has the advantage of uneven roughness and deep roughness. It has drawbacks such as being difficult to attach.
放電加工法では、粗さの制御は回転するロールと軸方向
に移動する電極との間の印加電圧と周波数を変えること
により行うが、クレータの大きさを決定する火花の及ぶ
範囲は電極の形状寸法によって決まるので、ある限界を
超えて微細な、ピッチの小さな粗さを得ることは難しい
。また放電加工によって生じた凸部は、機械的に弱く、
圧延中のロールの初期摩耗が激しく、転写された板表面
粗度の変化が激しい。In electrical discharge machining, roughness is controlled by changing the applied voltage and frequency between a rotating roll and an axially moving electrode, but the range of sparks that determines the size of the crater depends on the shape of the electrode. Since it is determined by the dimensions, it is difficult to obtain fine, small-pitch roughness beyond a certain limit. In addition, the convex parts created by electrical discharge machining are mechanically weak.
The initial wear of the rolls during rolling is severe, and the roughness of the transferred plate surface changes drastically.
上記の2つの方法に対し最近レーザビームを用いる加工
方法(以下レーザダル加工と記す)が提案されている。In contrast to the above two methods, a processing method using a laser beam (hereinafter referred to as laser dull processing) has recently been proposed.
例えば特開昭56−160892、特公昭58−255
57、特開昭54−61043、特開昭55−9479
0などである。For example, JP 56-160892, JP 58-255
57, JP-A-54-61043, JP-A-55-9479
0, etc.
・ いずれにもレーザパルスをいかに照射するかについ
て詳細に述べられているが照射されたロールの特性につ
いては言及されていない。- All of them describe in detail how to irradiate laser pulses, but do not mention the characteristics of the irradiated roll.
発明者らはレーザダル加工に基づくロール表面粗面化技
術をT東北すべく研究に着手した。レーザダル加工によ
り粗面化したロールを用い調質圧延したところ、ロール
の初期の摩耗がかなり大きく、本方法の効果が十分発揮
できないことが判明した。The inventors began research to develop roll surface roughening technology based on laser dulling. When temper rolling was carried out using a roll whose surface had been roughened by laser dulling, it was found that the initial wear of the roll was quite large and the effect of this method could not be fully demonstrated.
その原因を追求するためにロールを輪切りにして、表面
近傍の断面組織および硬度分布を調べた結果、凸部のご
とく表面近くに母材よりも軟い残留オーステナイト相が
存在することが分った。In order to investigate the cause, we cut the roll into rings and investigated the cross-sectional structure and hardness distribution near the surface. As a result, we found that there was a retained austenite phase that was softer than the base metal near the surface, like the convex parts. .
本発明はかかる点に着目し、圧延しても摩耗が少なく、
従って粗度低下の少ないパルスレーザによる圧延ロール
の表面粗面化方法を提供するものである。The present invention focuses on this point, and has little wear even when rolled.
Therefore, it is an object of the present invention to provide a method for roughening the surface of a mill roll using a pulsed laser, which causes less reduction in roughness.
すなわち本発明は、冷間圧延用ロールにレーザダル加工
によって粗面化加工を施すに際し、(IIL) 溶融
・凝固時のMs点(マルテンサイト変態の開始温度)が
200℃以上となる成分のロールを用いること。That is, in the present invention, when roughening a cold rolling roll by laser dulling, (IIL) the roll has a component whose Ms point (starting temperature of martensitic transformation) at the time of melting and solidification is 200°C or higher. to use
(b) ロール表面に5X104〜9X10eW /
c m’のエネルギー密度のレーザビームを照射して
粗面化すること。(b) 5X104~9X10eW/on the roll surface
The surface is roughened by irradiation with a laser beam having an energy density of cm'.
を特徴とする冷間圧延用ロールの粗面化方法である。A method for roughening the surface of a cold rolling roll, characterized by:
レーザダル加工後のロール表面層の軟い部分はレーザ照
射により一旦溶融した金属が急冷され、マルテンサイト
に十分変態できずにオーステナイト相が残留したもので
ある。The soft portion of the roll surface layer after laser dulling is caused by the metal being quenched once melted by laser irradiation, and the austenite phase remains without sufficient transformation into martensite.
急冷後十分にマルテンサイト化するかどうかは成分によ
り左右されるMs点によって決定される。Ms点は次式
によって表わされる。(次式は0Fで表わされているの
で℃に換算する)Ms、(’ F)=930−5400
−60Mn−40Cr−3ONi
−20Si−20M。Whether martensite is sufficiently formed after quenching is determined by the Ms point, which depends on the components. The Ms point is expressed by the following equation. (The following formula is expressed in 0F, so convert it to °C) Ms, ('F) = 930-5400
-60Mn-40Cr-3ONi -20Si-20M.
ここで、C,Mn、Cr、Ni 、Si 、Moは各成
分の重量%である。Here, C, Mn, Cr, Ni, Si, and Mo are weight percent of each component.
Ms点は特にCの影響が強く、その他Mn。The Ms point is particularly influenced by C, and the others are Mn.
Crの影響も大きい。The influence of Cr is also large.
C、M n 、 Crの成分が多いとMs点が下がりそ
の結果Mf点も下がる。通常冷間圧延に用いられそいる
ロールの成分ではMs点は100〜150℃である。When the C, Mn, and Cr components are large, the Ms point decreases, and as a result, the Mf point also decreases. The Ms point of roll components commonly used for cold rolling is 100 to 150°C.
詳細な実験によりMs点が200℃以上であればMf点
(マルテンサイト変態の終了温度)は室温以上となリレ
ーザ照射により表面が溶融・凝固後室温まで冷却時点で
十分なマルテンサイト変態が得られることが分った。し
たがって溶融・凝固時のMs点が200℃以上となる成
分系のロールにレーザ照射することでロールの表面層は
残留オーステナイトが極めて少ない状態を達成すること
ができ、レーザ照射後、特別な硬化処理の必要はない。Detailed experiments have shown that if the Ms point is 200°C or higher, the Mf point (the temperature at which martensitic transformation ends) is higher than room temperature. Sufficient martensitic transformation can be obtained when the surface is melted and solidified by laser irradiation and cooled to room temperature. I found out. Therefore, by laser irradiating a roll whose composition has a Ms point of 200°C or higher during melting and solidification, it is possible to achieve a state in which the surface layer of the roll has extremely little residual austenite.After laser irradiation, a special hardening treatment is applied. There is no need for
本発明方法は上記技術手段により従来法に比し格段に優
れた耐摩耗性を付与し、板面粗度変化を小さく抑えるこ
とができる。The method of the present invention uses the above-mentioned technical means to provide much superior wear resistance compared to conventional methods, and can suppress changes in plate surface roughness to a small level.
以下、実施例に基づき、詳細に説明する。 Hereinafter, a detailed explanation will be given based on examples.
第1図に、本発明の実施に好適に用いることのできる粗
面化装置の全体図を示す。FIG. 1 shows an overall view of a surface roughening apparatus that can be suitably used in carrying out the present invention.
旋盤あるいは研削盤などの工作機械と類似の構成からな
るロールの回転支持装M2にロール1を装着し、所定の
速度で回転させる。The roll 1 is attached to a roll rotation support device M2 having a configuration similar to that of a machine tool such as a lathe or a grinder, and is rotated at a predetermined speed.
一方レーザ発振器3から出力されたレーザビームは複数
のミラーを介して、ロール表面に大略垂直に照射される
。レーザビームは、光学装置により所定のビームに調整
され、更にロール表面に焦点を合わせて絞られる。レー
ザ照射ヘッド部4はロール回転之同期した駆動ネジ5の
回転によりロール軸方向にこれと平行して移動すること
ができる。レーザビームはQスイッチにより所定の周波
数にパルス化するか、あるいはメカニカルチョッパによ
りパルス化することができる。このパルスの周波数と出
力およびロール回転数とレーザ照射ヘッドの移動速度の
設定によって表面粗さのパターン、深さを制御すること
ができる。On the other hand, the laser beam output from the laser oscillator 3 is irradiated approximately perpendicularly onto the roll surface via a plurality of mirrors. The laser beam is adjusted to a predetermined beam by an optical device, and further focused and narrowed onto the roll surface. The laser irradiation head section 4 can be moved parallel to the roll axis direction by rotation of the drive screw 5 which is synchronized with the roll rotation. The laser beam can be pulsed to a predetermined frequency by a Q-switch or by a mechanical chopper. The pattern and depth of the surface roughness can be controlled by setting the frequency and output of this pulse, the number of rotations of the roll, and the moving speed of the laser irradiation head.
本発明方法ではこの操作の前に用いるロール成分に関し
溶融・凝固時のMs点が200℃以上となる成分のロー
ルを用いる。その結果ロールは表面まで母材と同等以上
の硬度を有し、優れた耐摩耗性を示す。In the method of the present invention, a roll having a Ms point of 200° C. or higher during melting and solidification is used as the roll component used before this operation. As a result, the roll has a hardness equal to or higher than that of the base material up to the surface, and exhibits excellent wear resistance.
次に具体的な実施例に基づき具体的な処理条件を示す。Next, specific processing conditions will be shown based on specific examples.
実験に用いた圧延機は実験室的な小型圧延機であり、そ
のロールの直径は70 m mである。本ロールを用い
てフープ状材料を連続圧延してロールの摩耗、材料面の
粗度変化を調べた。The rolling mill used in the experiment was a small laboratory rolling mill, and the diameter of its rolls was 70 mm. A hoop-shaped material was continuously rolled using this roll, and roll wear and changes in the roughness of the material surface were investigated.
実験に供したロールの化学成分は、 C:0.85重量% Si:0.8 重量% Mn:0.4 重量% Ni:0.15重量% Cr:2.9 重量% Mo:0.29重量% V:0.01重量% であり、通常広く用いられている成分系である。The chemical composition of the rolls used in the experiment was C: 0.85% by weight Si: 0.8 weight% Mn: 0.4 weight% Ni: 0.15% by weight Cr: 2.9 weight% Mo: 0.29% by weight V: 0.01% by weight This is a commonly used component system.
溶融・凝固時のMs点は152℃である。The Ms point during melting and solidification is 152°C.
比較材としてのロールの化学成分は
C:0.5 重量%
Si:0.8 重量%
Mn:0.8 重量%
Ni:0.2 重量%
Cr:1.0 重量%
Mo:5.O重量%
V:0.01重量%
であり、溶融・凝固時のMs点が200℃以上を狙った
ものでMs点は232℃である。The chemical composition of the roll as a comparative material is C: 0.5% by weight, Si: 0.8% by weight, Mn: 0.8% by weight, Ni: 0.2% by weight, Cr: 1.0% by weight, Mo: 5. O weight % V: 0.01 weight %, and the Ms point during melting and solidification is aimed at 200°C or higher, and the Ms point is 232°C.
ロールの製造プロセスは次のようである。The manufacturing process of the roll is as follows.
すなわち、上記成分の溶鋼を鋳造した後、温度1100
℃で鍛造比3.5まで鍛造した。その後950℃に加熱
空冷するいわゆるノルマ処理を施した。これを800℃
×lθ時間および700℃×10時間のカーバイド球状
化処理をした後、所定の寸法に機械加工した0機械加工
後900℃加熱後油中に焼入れを施した後、650℃の
焼戻しをし、再び機械加工を施し最終寸法にまで仕上げ
た。更に表面層を誘導加熱により900℃に加熱後水中
に焼入れをし、150℃の低温焼戻しを行い、しかる後
最後の表面研磨をした。That is, after casting molten steel with the above components, the temperature is 1100.
It was forged at ℃ to a forging ratio of 3.5. Thereafter, a so-called norm treatment of heating to 950° C. and cooling with air was performed. This is heated to 800℃
After carbide spheroidization treatment for ×lθ hours and 700°C × 10 hours, machined to the specified dimensions.After machining, heated to 900°C, quenched in oil, tempered at 650°C, and then Machined to final dimensions. Furthermore, the surface layer was heated to 900° C. by induction heating, quenched in water, tempered at a low temperature of 150° C., and then the final surface was polished.
このような処理を施したロールは、マルテンサイト素地
中に球状炭化物が一様に分布している健全な組′織を示
す。Rolls subjected to such treatment exhibit a healthy structure in which spherical carbides are uniformly distributed in the martensitic matrix.
このロール表面に本装置を用いて、メカニカルチョッパ
を用いてパルス化したC02ガスレーザビームを照射し
所定の粗さに粗面化加工を施した。Using this apparatus, the surface of this roll was roughened to a predetermined roughness by irradiating a pulsed C02 gas laser beam using a mechanical chopper.
レーザ照射条件として、
レーザ出カニ2kW
パルス周波数=56kHz
エネルギー密度: 6.4X 10BW/ cm” 1
パルス当りの照射時間: 13ILsec照射されてロ
ール表面にできたクレータのピッチ:ロール円周方向、
軸方向とも
170#Lm
である、得られたロール粗度はRmaxが約15ILm
である。Laser irradiation conditions are: Laser power: 2kW, Pulse frequency: 56kHz, Energy density: 6.4X 10BW/cm” 1
Irradiation time per pulse: 13ILsec Pitch of craters formed on the roll surface after irradiation: Roll circumferential direction,
The resulting roll roughness is 170#Lm in both axial directions, and Rmax is approximately 15ILm.
It is.
このように粗面化した従来成分のロール表面近傍の硬度
分布を測定した結果を第2図に示す。FIG. 2 shows the results of measuring the hardness distribution near the roll surface of the conventional component which has been roughened in this way.
′MS点が200℃以上となる成分のロール表面近傍の
硬度分布を測定した結果を第3図に示した。レーザ照射
時の溶融部はその後の冷却で十分にマルテンサイト変態
し表面層は高い硬度を示している。Figure 3 shows the results of measuring the hardness distribution near the roll surface of the components whose MS point is 200°C or higher. The melted part during laser irradiation is sufficiently transformed into martensitic material by subsequent cooling, and the surface layer exhibits high hardness.
この2セツトのロールを用い、板厚0.8 m mの低
炭素Anキルド鋼の冷延後焼鈍した板を圧下率0.8%
で調質圧延をし、板面粗度変化を調べ比較した結果を第
4図に示す。Using these two sets of rolls, a cold-rolled and annealed plate of low carbon An-killed steel with a plate thickness of 0.8 mm was rolled at a reduction rate of 0.8%.
Figure 4 shows the results of temper rolling and comparison of changes in plate surface roughness.
第4図で明らかなようにMs点が232℃のロールにレ
ーザ加工したロールで圧延した場合、従来よりも被圧延
材の粗度低下を著しく軽減することができる。As is clear from FIG. 4, when rolling is performed using a laser-processed roll having an Ms point of 232° C., the decrease in roughness of the rolled material can be significantly reduced compared to the conventional method.
Ms点が200℃以上となる成分のロールにレーザ粗面
化加工を行うことによりレーザダル加工ロールの摩耗、
被圧延材板面の粗度変化が著しく改善される。By performing laser surface roughening on a roll whose Ms point is 200°C or higher, the wear of the laser dulled roll can be reduced.
Roughness changes on the surface of the rolled material are significantly improved.
第1図は本発明方法を好適に実施することのできるロー
ル粗面化加工装置の斜視図、第2図、第3図はロールの
表面からの深さと硬度との関係を示すグラフ、第4図は
実機換算圧延長さと平均表面粗′さとの関係を示すグラ
フである。
l・・・ロール 2・・・ロール回転支持装置
3・・・レーザ発振器 4・・・レーザ照射ヘッド5
・・・レーザ駆動ネジFIG. 1 is a perspective view of a roll surface roughening processing device that can suitably carry out the method of the present invention, FIGS. 2 and 3 are graphs showing the relationship between the depth from the surface of the roll and hardness, and FIG. The figure is a graph showing the relationship between actual machine equivalent pressure extension and average surface roughness. l... Roll 2... Roll rotation support device 3... Laser oscillator 4... Laser irradiation head 5
...Laser drive screw
Claims (1)
溶融・凝固時のMs点が200℃以上となるロール素材
を用い、該ロール表面にレーザビームを照射して粗面化
することを特徴とする冷間圧延用ロールの粗面化方法。1 When roughening the surface of a cold rolling roll,
A method for roughening the surface of a cold rolling roll, comprising using a roll material having an Ms point of 200° C. or higher during melting and solidification, and roughening the surface of the roll by irradiating the surface with a laser beam.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61165146A JPS6320191A (en) | 1986-07-14 | 1986-07-14 | Surface roughening method for cold rolling roll |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61165146A JPS6320191A (en) | 1986-07-14 | 1986-07-14 | Surface roughening method for cold rolling roll |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6320191A true JPS6320191A (en) | 1988-01-27 |
Family
ID=15806760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61165146A Pending JPS6320191A (en) | 1986-07-14 | 1986-07-14 | Surface roughening method for cold rolling roll |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6320191A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0421740A (en) * | 1990-05-14 | 1992-01-24 | Mitsubishi Steel Mfg Co Ltd | Surface roughened roll for cold rolling |
JPH0570883A (en) * | 1991-09-12 | 1993-03-23 | Mitsubishi Steel Mfg Co Ltd | Roughened roll for cold rolling |
-
1986
- 1986-07-14 JP JP61165146A patent/JPS6320191A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0421740A (en) * | 1990-05-14 | 1992-01-24 | Mitsubishi Steel Mfg Co Ltd | Surface roughened roll for cold rolling |
JPH0570883A (en) * | 1991-09-12 | 1993-03-23 | Mitsubishi Steel Mfg Co Ltd | Roughened roll for cold rolling |
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