JPS63199775A - Water-soluble solid drawing utensil - Google Patents
Water-soluble solid drawing utensilInfo
- Publication number
- JPS63199775A JPS63199775A JP3246587A JP3246587A JPS63199775A JP S63199775 A JPS63199775 A JP S63199775A JP 3246587 A JP3246587 A JP 3246587A JP 3246587 A JP3246587 A JP 3246587A JP S63199775 A JPS63199775 A JP S63199775A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- water
- fatty acid
- soluble solid
- solid drawing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007787 solid Substances 0.000 title claims abstract description 37
- 239000001993 wax Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 29
- -1 polyoxyethylene Polymers 0.000 claims abstract description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- 239000004359 castor oil Substances 0.000 claims abstract description 6
- 235000019438 castor oil Nutrition 0.000 claims abstract description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 6
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 4
- 240000007594 Oryza sativa Species 0.000 claims abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 3
- 235000013871 bee wax Nutrition 0.000 claims abstract description 3
- 239000012166 beeswax Substances 0.000 claims abstract description 3
- 239000004204 candelilla wax Substances 0.000 claims abstract description 3
- 235000013868 candelilla wax Nutrition 0.000 claims abstract description 3
- 229940073532 candelilla wax Drugs 0.000 claims abstract description 3
- 239000004203 carnauba wax Substances 0.000 claims abstract description 3
- 235000013869 carnauba wax Nutrition 0.000 claims abstract description 3
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012170 montan wax Substances 0.000 claims abstract description 3
- 239000012188 paraffin wax Substances 0.000 claims abstract description 3
- 235000009566 rice Nutrition 0.000 claims abstract description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract 2
- 239000000600 sorbitol Substances 0.000 claims abstract 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- 239000003086 colorant Substances 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 229920001214 Polysorbate 60 Polymers 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 239000000049 pigment Substances 0.000 abstract description 17
- 239000004606 Fillers/Extenders Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 150000004665 fatty acids Chemical class 0.000 abstract description 5
- 239000004094 surface-active agent Substances 0.000 abstract description 5
- 238000004040 coloring Methods 0.000 abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005456 glyceride group Chemical group 0.000 abstract 1
- 239000012182 japan wax Substances 0.000 abstract 1
- 229920000136 polysorbate Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000035900 sweating Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- LVOJOIBIVGEQBP-UHFFFAOYSA-N 4-[[2-chloro-4-[3-chloro-4-[(5-hydroxy-3-methyl-1-phenylpyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-methyl-2-phenylpyrazol-3-ol Chemical compound CC1=NN(C(O)=C1N=NC1=CC=C(C=C1Cl)C1=CC(Cl)=C(C=C1)N=NC1=C(O)N(N=C1C)C1=CC=CC=C1)C1=CC=CC=C1 LVOJOIBIVGEQBP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- HBHZKFOUIUMKHV-UHFFFAOYSA-N chembl1982121 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HBHZKFOUIUMKHV-UHFFFAOYSA-N 0.000 description 1
- GTRGJJDVSJFNTE-UHFFFAOYSA-N chembl2009633 Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=CC2=C1N=NC1=CC=CC=C1 GTRGJJDVSJFNTE-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 description 1
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、水溶性固形描画材に関するものであり、より
詳細には水に溶けやすいにもかかわらず、ベトつきのな
い、書き味の優れた水溶性固形描画材に関する。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to a water-soluble solid drawing material, and more specifically, it relates to a water-soluble solid drawing material, and more specifically, it is non-sticky and has an excellent writing taste despite being easily soluble in water. Regarding water-soluble solid drawing materials.
（従来の技術）
従来水溶性固形描画材は、着色顔料や体質顔料などの顔
料類と高級脂肪酸のグリセリンエステルや高級−価アル
コールと高級脂肪酸とのエステルであるロウも含む一般
のワックス類と界面活性剤を混合した後、所望の形に成
形する方法で製造されていた。(Prior art) Conventional water-soluble solid drawing materials have an interface between pigments such as coloring pigments and extender pigments, and general waxes including glycerin esters of higher fatty acids and waxes that are esters of higher-hydric alcohols and higher fatty acids. It was manufactured by mixing an active agent and then molding it into the desired shape.
（発明が解決しようとする問題点） しかしこの様な水溶性固形描画材においては。(Problem that the invention attempts to solve) However, in such water-soluble solid drawing materials.
使用する界面活性剤のＨＬＢ価が１０以下の場合、親木
性が低下して水に溶けにくくなり、また１０以上の場合
はワックスとの相溶性が低下する為、成形後長期間放置
した場合など界面活性剤の発汗現象によりベタついたり
、ガラス、プラスチック、金属、陶器などの非吸収面に
描画後、水分を含んだ布などで消去しても色残りが生じ
るなどの欠点がある。If the HLB value of the surfactant used is less than 10, the wood affinity will decrease and it will become difficult to dissolve in water, and if it is more than 10, the compatibility with wax will decrease, so if it is left for a long time after molding. There are drawbacks such as stickiness due to the perspiration phenomenon of surfactants, and residual color that remains even after drawing on non-absorbing surfaces such as glass, plastic, metal, and ceramics and erasing with a damp cloth.
その他、この種の固形描画材としては、ポリエチレング
リコールと非イオン系界面活性剤を使用したもの（特開
昭５９−１７８３６９号公報）。In addition, this type of solid drawing material uses polyethylene glycol and a nonionic surfactant (Japanese Patent Laid-Open No. 178369/1983).
石ケンを着色したもの（特開昭５９−９６１７９号公報
）、常温固形のワックスを乳化したもの（特開昭５７−
９２０６９号公報）等が知られているが、いずれも筆記
強度、書き味の点で満足のいくものではなかった。Colored soap (Japanese Unexamined Patent Publication No. 59-96179), emulsified wax that is solid at room temperature (Japanese Unexamined Patent Publication No. 57-1988)
92069), but none of them were satisfactory in terms of writing strength and writing feel.
（問題点を解決するための手段）
本発明によれば、常温で固形のワックス類、ＨＬＢ価１
０以上の非イオン系界面活性剤及びヒドロキシル価８０
以上のワックス類から成る基剤に着色料を配合して成る
ことを特徴とする水溶性固形描画材が提供される。(Means for Solving the Problems) According to the present invention, waxes that are solid at room temperature, HLB value 1
Nonionic surfactant with 0 or more and hydroxyl number 80
A water-soluble solid drawing material is provided, which is characterized in that it is made by blending a coloring agent into a base made of the above-mentioned waxes.
（作用）
本発明で使用するヒドロキシル価８０以上のワックス類
は、極性物質と無極性物質との混和を助ける結合剤とな
るため、ＨＬＢ価ｌＯ以上の非イオン系界面活性剤と常
温固形のワックス類の混合物にヒドロキシル価８０以上
のワックス類を添加することにより、相溶性が向上し、
長期間の放置による界面活性剤の発汗現象であるベタつ
きが防止されるのである。(Function) The waxes with a hydroxyl value of 80 or more used in the present invention act as a binder that helps mix polar substances and non-polar substances, so they are combined with a nonionic surfactant with an HLB value of 1O or more and a wax that is solid at room temperature. By adding a wax with a hydroxyl value of 80 or more to a mixture of the above, the compatibility is improved,
This prevents stickiness, which is a phenomenon caused by the sweating of surfactants when left for a long period of time.
また、ヒドロキシル価８０以上のワックス類を使用する
ことにより、ＨＬＢ価が１０以上という親水性の高い非
イオン系界面活性剤が有効に使用でき、これにより固形
描画材に水溶性を安定に且つ持続して賦与することがで
きる。In addition, by using waxes with a hydroxyl value of 80 or more, highly hydrophilic nonionic surfactants with an HLB value of 10 or more can be effectively used, thereby stably and sustaining water solubility in solid drawing materials. It can be given as a gift.
（発明の好適実施態様）
本発明において使用する、常温固形のワックス類は、パ
ラフィンワックス、マイクロワックス、ケトンワックス
、木ろう、みつろう、ライスワックス、カルナバワック
ス、キャンデリラワックス、モンタンワックスが挙げら
れ、単独または混合物として用いることも可能である。(Preferred embodiment of the invention) The waxes that are solid at room temperature used in the present invention include paraffin wax, micro wax, ketone wax, Japanese wax, beeswax, rice wax, carnauba wax, candelilla wax, and montan wax. It is also possible to use them alone or as a mixture.
本発明においては、常温固形のワックス類を１０乃至６
０重量％、特に２０乃至４０重量％の量で用いることも
重量であり、この量が上記範囲よりも少ないと水溶性描
画材に必要な固着力やソフトな書き味が失われることに
なり、一方上記範囲よりも多いと水溶性が低下してしま
う。In the present invention, waxes that are solid at room temperature are used in a range of 10 to 6
It is also important to use it in an amount of 0% by weight, especially 20 to 40% by weight, and if this amount is less than the above range, the adhesion force and soft writing feel necessary for water-soluble drawing materials will be lost. On the other hand, if the amount exceeds the above range, water solubility will decrease.
また本発明に用いるＨＬＢ価ｌＯ以上の非イオン系界面
活性剤としては、ポリエチレングリコールモノステアレ
ート（花王■製、商品名エマノーン３１９９．ＨＬＢ価
１９．１）、ポリオキシエチレンノニルフェニルエーテ
ル（花王■製、商品名エマルゲン９３０、ＨＬＢ価１５
．１）、ポリオキシエチレンソルビタントリステアレー
ト（花王■製、商品名レオドールＴＷ−３３２０、ＨＬ
Ｂ価１０．５）、ポリエチレングリコールステアリルエ
ーテル（花王■製、商品名レベノールＦＷ、ＨＬＢ価１
＆２）等が挙げられ、これらは単独又は混合物として用
いることができる。Examples of nonionic surfactants with an HLB value of 10 or higher used in the present invention include polyethylene glycol monostearate (manufactured by Kao ■, trade name Emanone 3199, HLB value 19.1), polyoxyethylene nonylphenyl ether (Kao ■) Manufactured by Emulgen 930, HLB value 15
．． 1) Polyoxyethylene sorbitan tristearate (manufactured by Kao ■, trade name Rheodol TW-3320, HL
B value 10.5), polyethylene glycol stearyl ether (manufactured by Kao ■, trade name Levenol FW, HLB value 1)
&2), and these can be used alone or as a mixture.
本発明においては、ＨＬＢ価ｌＯ以上の非イオン系界面
活性剤を５乃至５０重量％、特に好ましくは１０乃至２
５重量％の量で用いることも重要であり、この量が上記
範囲よりも少ないと水溶性に劣るようになり、一方上記
範囲よりも多いとベトつきの原因となる。In the present invention, 5 to 50% by weight of a nonionic surfactant having an HLB value of 1O or more, particularly preferably 10 to 2% by weight, is used.
It is also important to use an amount of 5% by weight; if this amount is less than the above range, the water solubility will be poor, while if it is more than the above range, it will cause stickiness.
更にまた１本発明で用いるヒドロキシル価８０以上のワ
ックス類としては、硬化ひまし油、酸化マイクロクリス
タリンワックス、部分水添ひまし油等が挙げられ、これ
らは単独又は混合物として用いることができる。Furthermore, waxes having a hydroxyl value of 80 or more used in the present invention include hydrogenated castor oil, oxidized microcrystalline wax, partially hydrogenated castor oil, and the like, and these can be used alone or as a mixture.
本発明においては、ヒドロキシル価８０以上のワックス
類を５乃至６０重量％、特に好ましくはｌＯ乃至４０重
量％の量で用いることも重量であり、この量が上記範囲
より少ないと、十分な相溶性が期待できず、ベトつきの
原因となり、一方上記範囲よりも多いと、製品が脆くな
りすぎて折損しやすくなってしまう。In the present invention, waxes having a hydroxyl value of 80 or more are used in an amount of 5 to 60% by weight, particularly preferably 10 to 40% by weight, and if this amount is less than the above range, sufficient compatibility is achieved. If the amount exceeds the above range, the product becomes too brittle and easily breaks.
本発明において、顔料及び体質顔料としては、従来固形
描画材に使用されているものが全て制限なしに使用する
ことができる。顔料及び体質顔料の適当な例は、これに
限定されないが、次の通りである。In the present invention, all pigments and extender pigments conventionally used in solid drawing materials can be used without limitation. Suitable examples of pigments and extender pigments include, but are not limited to, the following:
黒色顔料
カーボンブラック、ランプブラック、ポーンブラック、
鉄黒。Black pigment carbon black, lamp black, pawn black,
Iron black.
黄色顔料
黄色酸化鉄、ハンザイエロー、ナフトールイエロー、チ
タンイエロー、ベンジジンイエロー、パーマネントイエ
ロー。Yellow pigment yellow iron oxide, Hansa yellow, naphthol yellow, titanium yellow, benzidine yellow, permanent yellow.
橙色顔料
パーマネントオレンジ、パルカンオレンジ、ベンジジン
オレンジ、インダスレンブリリアントオレンジ。Orange pigments permanent orange, palkan orange, benzidine orange, industhrene brilliant orange.
赤色顔料
ベンガラ、リソールレッド、ブリリアントカーミノ２パ
ーマネントレツド。Red pigment Red Garla, Resole Red, Brilliant Carmino 2 Permanent Red.
紫色顔料
マンガン紫、ファーストバイオレット、メチルバイオレ
ットレーキ、キナクリドンバイオレット。Violet pigments manganese violet, first violet, methyl violet lake, quinacridone violet.
青色顔料
紺青、フタロシアンブルー、群青、ファーストスカイブ
ルー。Blue pigments navy blue, phthalocyan blue, ultramarine blue, first sky blue.
緑色顔料
マラカイトグリーンレーキ、フタロシアニングリーン、
ナフトールグリーン。Green pigment malachite green lake, phthalocyanine green,
naphthol green.
白色顔料 チタン白、亜鉛華。white pigment Titanium white, zinc white.
蛍光顔料
体質顔料
炭酸カルシウム、硫酸バリウム、硫酸カルシウム、炭酸
マグネシウム、クレー、シリカ、タルク、アルミナホワ
イト。Fluorescent pigment extender pigments calcium carbonate, barium sulfate, calcium sulfate, magnesium carbonate, clay, silica, talc, alumina white.
中でもタルクが従来のクレヨンに最も近い書き味を与え
る。Among them, talc provides a writing taste that is closest to that of conventional crayons.
顔料の全体当り含有量はｌ乃至３０重量％、特に２乃至
２０重量％が好ましく１体質顔料の全体当りの含有量は
１乃至２５重量％、特に２乃至１５重量％の量で存在さ
せることが望ましい。The total content of pigments is preferably 1 to 30% by weight, particularly 2 to 20% by weight, and the total content of extender pigments is preferably 1 to 25% by weight, particularly 2 to 15% by weight. desirable.
本発明による水溶性固形描画材には、上述した必須成分
に加えて、任意の助剤を配合できる０例えば、香料等を
微量配合することもできる。In addition to the above-mentioned essential components, the water-soluble solid drawing material according to the present invention may contain any auxiliary agent, such as a small amount of perfume.
本発明の水溶性固形描画材は、常温固形のワックス類、
ＨＬＢ価が１０以上の非イオン系界面活性剤、ヒドロキ
シル価８０以上のワックス類及び顔料を混練し、この混
線組成物を加熱溶融して注型成形するか、或いは押出成
形に付し、冷却、固化することにより製造される。混練
操作は組成物の粘稠度に応じて、ヘンシェルミキサー、
バンバ１１ ３ Ｊ、 ４４− Ｍ ＋Ｌ ａ
ｂ ｂｂ ｆ’Ｒ÷スートｖ←Ｌ１倫易に行われる。The water-soluble solid drawing material of the present invention includes waxes that are solid at room temperature,
A nonionic surfactant with an HLB value of 10 or more, a wax with a hydroxyl value of 80 or more, and a pigment are kneaded, and this mixed wire composition is heated and melted and cast or extruded, cooled, Manufactured by solidification. Depending on the consistency of the composition, the kneading operation can be carried out using a Henschel mixer,
Bamba 11 3 J, 44-M +La
b bb f'R ÷ suit v ← L1 is executed.
（発明の効果）
本発明によれば、描画性に優れ、且つ長期間の保存によ
るベタつきのない、また、ガラス、プラスチック、金属
、陶磁器などの非吸収面に描画後水分を含んだ布で消去
しても、色残りなど生じることなく簡単に拭き取り可能
な水溶性固形描画材を得ることができる。(Effects of the Invention) According to the present invention, it has excellent drawing properties, does not become sticky due to long-term storage, and can be erased with a damp cloth after drawing on non-absorbing surfaces such as glass, plastic, metal, and ceramics. It is possible to obtain a water-soluble solid drawing material that can be easily wiped off without leaving any color residue.
（実施例）
本発明を以下の実施例で詳細に説明する。尚、以下の実
施例は一例であり、本発明がこれに限定されるものでは
ない。(Example) The present invention will be explained in detail in the following example. Note that the following examples are merely examples, and the present invention is not limited thereto.
表１に示す組成（実施例１〜３、比較例）をそれぞれミ
キシングロールにより混練し、加熱溶融した後注型成形
により４種の水溶性固形描画材を作製した。The compositions shown in Table 1 (Examples 1 to 3, Comparative Examples) were kneaded using a mixing roll, heated and melted, and then cast to produce four types of water-soluble solid drawing materials.
それぞれ比較検討を行ったところ、実施例１〜３の水溶
性固形描画材は、画用紙に描画後、水分を含んだ筆で溶
かしたところ、顔料分散性に優れ、水彩画的な絵を作成
することができたが、辻較例の水溶性固形描画材は顔料
の分散性が悪く、むらが生じてしまった。A comparative study was conducted on each, and it was found that the water-soluble solid drawing materials of Examples 1 to 3 had excellent pigment dispersibility and were able to create watercolor-like pictures when drawn on drawing paper and then dissolved with a moistened brush. However, the water-soluble solid drawing material of Tsuji Comparative Example had poor pigment dispersibility, resulting in unevenness.
更に、実施例１〜３、比較例の４種の水溶性固形描画材
を３７℃の恒温槽に内に放置したところ、１時間後に比
較例の水溶性固形描画材には発汗現象によるベタつきが
見られたが、実施例１〜３の水溶性固形描画材は２４時
間たっても発汗現象によるベタつきは見られなかった。Furthermore, when the four types of water-soluble solid drawing materials of Examples 1 to 3 and Comparative Example were left in a constant temperature bath at 37°C, the water-soluble solid drawing materials of Comparative Example became sticky due to sweating phenomenon after 1 hour. However, in the water-soluble solid drawing materials of Examples 1 to 3, no stickiness due to sweating was observed even after 24 hours.
また、ガラスにそれぞれ描画した後、水分を含んだ布で
拭いたところ、実施例１〜３の水溶性固形描画材で描い
たガラス面は、簡単且つ完全に拭き取ることができたが
、比較例の水溶性固形描画材で描いたガラス面は、なか
なか拭き取ることができず色残りが生じてしまった。In addition, after each drawing on the glass, when wiped with a damp cloth, the glass surface drawn with the water-soluble solid drawing materials of Examples 1 to 3 could be easily and completely wiped off, but the comparative example The glass surface painted with the water-soluble solid drawing material was difficult to wipe off, resulting in color residue.
Claims (5)
イオン系界面活性剤及びヒドロキシル価８０以上のワッ
クス類から成る基剤に着色料を配合して成ることを特徴
とする水溶性固形描画材。(1) A water-soluble solid drawing characterized by blending a coloring agent into a base consisting of a wax that is solid at room temperature, a nonionic surfactant with an HLB value of 10 or more, and a wax with a hydroxyl value of 80 or more. Material.
量％、非イオン系界面活性剤が５乃至５０重量％及びヒ
ドロキシル価８０以上のワックス類が５乃至６０重量％
の量で存在する特許請求の範囲第１項の水溶性固形描画
材。(2) 5 to 60% by weight of waxes that are solid at room temperature, 5 to 50% by weight of nonionic surfactants, and 5 to 60% by weight of waxes with a hydroxyl value of 80 or more
The water-soluble solid drawing material of claim 1 present in an amount of .
、マイクロワックス、ケトンワックス、木ろう、みつろ
う、ライスワックス、カルナバワックス、キャンデリラ
ワックス、モンタンワックスの内少なくとも一つである
特許請求の範囲第１項記載の水溶性固形描画材。(3) Claim 1, wherein the wax that is solid at room temperature is at least one of paraffin wax, micro wax, ketone wax, Japanese wax, beeswax, rice wax, carnauba wax, candelilla wax, and montan wax. Water-soluble solid drawing material as described.
ン脂肪酸エステル、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンアルキルアリルエーテル、ポリ
オキシエチレンソルビタン脂肪酸エステル、ポリオキシ
エチレンソルビトール脂肪酸エステル、グリセリン脂肪
酸エステルの内少なくとも一つである特許請求の範囲第
１項記載の水溶性固形描画材。(4) The nonionic surfactant is one of polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl allyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, and glycerin fatty acid ester. At least one water-soluble solid drawing material according to claim 1.
ひまし油、酸化マイクロクリスタリンワックス、部分水
添ひまし油の内少なくとも一つである特許請求の範囲第
１項記載の水溶性固形描画材。(5) The water-soluble solid drawing material according to claim 1, wherein the wax having a hydroxyl value of 80 or more is at least one of hydrogenated castor oil, oxidized microcrystalline wax, and partially hydrogenated castor oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3246587A JPH0832846B2 (en) | 1987-02-17 | 1987-02-17 | Water-soluble solid drawing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3246587A JPH0832846B2 (en) | 1987-02-17 | 1987-02-17 | Water-soluble solid drawing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63199775A true JPS63199775A (en) | 1988-08-18 |
| JPH0832846B2 JPH0832846B2 (en) | 1996-03-29 |
Family
ID=12359717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3246587A Expired - Lifetime JPH0832846B2 (en) | 1987-02-17 | 1987-02-17 | Water-soluble solid drawing material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0832846B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06100801A (en) * | 1992-09-17 | 1994-04-12 | Nippon Kiyouzai Seisakusho:Kk | Water color |
| EP0742273A2 (en) * | 1995-05-09 | 1996-11-13 | Buncho Corporation | Solid painting material |
| JP2002332445A (en) * | 2000-06-23 | 2002-11-22 | Sakura Color Prod Corp | Unburned core of colored pencil |
| JP2003105247A (en) * | 2001-09-28 | 2003-04-09 | Pentel Corp | Metal powder-containing water-soluble solid drawing material |
| CN102816476A (en) * | 2012-09-18 | 2012-12-12 | 上海绿菱特种蜡制品厂 | Preparation method of special color painting wax |
| EP4101648A4 (en) * | 2020-02-05 | 2024-02-28 | Nippon Kayaku Kk | Ink, inkjet printing method, and printing medium |
-
1987
- 1987-02-17 JP JP3246587A patent/JPH0832846B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06100801A (en) * | 1992-09-17 | 1994-04-12 | Nippon Kiyouzai Seisakusho:Kk | Water color |
| EP0742273A2 (en) * | 1995-05-09 | 1996-11-13 | Buncho Corporation | Solid painting material |
| EP0742273A3 (en) * | 1995-05-09 | 1998-07-15 | Buncho Corporation | Solid painting material |
| JP2002332445A (en) * | 2000-06-23 | 2002-11-22 | Sakura Color Prod Corp | Unburned core of colored pencil |
| JP2003105247A (en) * | 2001-09-28 | 2003-04-09 | Pentel Corp | Metal powder-containing water-soluble solid drawing material |
| CN102816476A (en) * | 2012-09-18 | 2012-12-12 | 上海绿菱特种蜡制品厂 | Preparation method of special color painting wax |
| EP4101648A4 (en) * | 2020-02-05 | 2024-02-28 | Nippon Kayaku Kk | Ink, inkjet printing method, and printing medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0832846B2 (en) | 1996-03-29 |
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