JPS63196697A - Liquid cleanser composition - Google Patents
Liquid cleanser compositionInfo
- Publication number
- JPS63196697A JPS63196697A JP2775087A JP2775087A JPS63196697A JP S63196697 A JPS63196697 A JP S63196697A JP 2775087 A JP2775087 A JP 2775087A JP 2775087 A JP2775087 A JP 2775087A JP S63196697 A JPS63196697 A JP S63196697A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- liquid cleanser
- cleanser composition
- present
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 14
- 239000007788 liquid Substances 0.000 title claims description 8
- -1 alkali metal salt Chemical class 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000004115 Sodium Silicate Substances 0.000 description 6
- 229910052911 sodium silicate Inorganic materials 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- CKLJMWTZIZZHCS-UHFFFAOYSA-N D-OH-Asp Natural products OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CKLJMWTZIZZHCS-UWTATZPHSA-N L-Aspartic acid Natural products OC(=O)[C@H](N)CC(O)=O CKLJMWTZIZZHCS-UWTATZPHSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229960005261 aspartic acid Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical group OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、硬表面を磨く際に、摩擦抵抗が小さく軽い力
で洗浄できる液体クレンザ−組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a liquid cleanser composition that has low frictional resistance and can be cleaned with light force when polishing hard surfaces.
従来多くの液体クレンザ−組成物が提案されている０例
えば、保存安定性に関しては特開昭５７−１６０９８号
公報、特開昭５７−１００１９８号公報、特開昭５５−
５９４７号公報、洗浄力に関しては特開昭５１−５０９
０９号公報、研摩表面の傷つけ性と研磨剤の粒径に関し
ては特開昭５２−１３３３０６号公報、特開昭５９−８
４９９９号公報などの多くの技術が知られている。しか
しながら、洗浄面にかかる力と組成との関係についての
研究はなされていない。Many liquid cleanser compositions have been proposed in the past.
No. 5947, and regarding cleaning power, see Japanese Patent Application Laid-Open No. 51-509.
No. 09, and JP-A-52-133306 and JP-A-59-8 regarding the damage resistance of the abrasive surface and the particle size of the abrasive.
Many techniques are known, such as Japanese Patent No. 4999. However, no study has been conducted on the relationship between the force applied to the cleaning surface and the composition.
クレンザ−でステンレスなどの金属面を洗浄する場合、
より軽い力で簡単に汚れが落とせることが望ましいが、
従来のクレンザ−では、かなり力を加えないと充分な洗
浄力は期待できない。When cleaning metal surfaces such as stainless steel with a cleanser,
It is desirable to be able to easily remove dirt with a lighter force, but
With conventional cleansers, sufficient cleaning power cannot be expected unless considerable force is applied.
又、力を加えすぎると金属面に傷をっけ易くなる。Also, if too much force is applied, the metal surface will be easily scratched.
洗浄作業中には、汚れのついていない部分にも摩擦抵抗
が働き、無駄な力が費やされており、傷っけの原因とな
っている。そこで、汚れのついていない部分における摩
擦抵抗を低くし、汚れの付着している部分により効率的
に力が伝わるようにすればより軽い力で効率的に汚れを
落とすことができる。During cleaning, frictional resistance acts even on areas that are not contaminated, wasting force and causing damage. Therefore, by lowering the frictional resistance in areas that are not contaminated so that force is transmitted more efficiently to areas that have dirt, dirt can be removed more efficiently with a lighter force.
本発明者らは鋭意研究の結果、特定の配合系において、
本発明の目的を達成し得ることを見い出し本発明を完成
した。As a result of intensive research, the present inventors found that in a specific formulation system,
The inventors discovered that the object of the present invention can be achieved and completed the present invention.
即ち、本発明は、
＋８） 高級脂肪酸アルカノールアミド又はそのアル
キレンオキサイド付加物
（ｂｌ アルキルベンゼンスルホン酸アルカリ金属塩
を２．０≧（ａ） ／ （ｂ＞≧１．２の割合で、（ａ
ｌ ＋ （ｂｌ −４〜８重量％含有し、更に
（ｃ） 水不溶性研磨剤 １０〜７０重量％（ｄ）
高級脂肪酸又はそのアルカリ金属塩０．０３〜１重量
％
ｆｅ） ２価以上のアルコール ０．２〜０．５重量
％（ｆ） アルカノールアミン ０．０１〜０．３重
量％を含有することを特徴とする液体クレンザ−組成物
を提供する。That is, the present invention provides the following methods:
l + (bl - Contains 4 to 8% by weight, and further (c) water-insoluble abrasive 10 to 70% by weight (d)
Characteristically, it contains higher fatty acids or their alkali metal salts 0.03 to 1% by weight fe) dihydric or higher alcohols 0.2 to 0.5% by weight (f) alkanolamines 0.01 to 0.3% by weight A liquid cleanser composition is provided.
本発明において用いられる高級脂肪酸アルカン−ルアミ
ド又はそのアルキレンオキサイド付加物＋８）としては
、例えば式（１）で示される高級脂肪酸（ｃ，〜Ｃ！。Examples of higher fatty acid alkanylamides or alkylene oxide adducts thereof used in the present invention include higher fatty acids (c, ~C!) represented by formula (1).
）エタノールアミド又はそのエチレンオキサイド付加物
が挙げられる。) Ethanolamide or its ethylene oxide adduct.
（Ｒは炭素数８〜２０の脂肪酸の残基、ｍ＋ｎ＝１〜１
０）
本発明において用いられるアルキルベンゼンスルホン酸
塩（ｂ）は、アルキル鎖が直鎖又は分枝鎖で、アルキル
鎖の末端又は中間にベンゼンスルホン酸基がついており
、対イオンは、ナトリウム、カリウムなどのアルカリ金
属塩である。(R is a residue of a fatty acid having 8 to 20 carbon atoms, m+n=1 to 1
0) The alkylbenzenesulfonic acid salt (b) used in the present invention has a linear or branched alkyl chain, a benzenesulfonic acid group is attached at the end or middle of the alkyl chain, and the counter ion is sodium, potassium, etc. It is an alkali metal salt of
アルキルとしてはＣ３〜ＣｔＳのものが好ましい。As the alkyl, those of C3 to CtS are preferable.
（ａ）成分、（ｂ）成分の合計配合量は４〜８重量％で
あり、且つｔａｌ成分と（ｂ）成分の配合比率は２．０
≧（ａｌ ／ （ｂ）≧１．２の範囲になければ、摩擦
抵抗の小さい組成物は得られない。The total amount of components (a) and (b) is 4 to 8% by weight, and the ratio of tal component to component (b) is 2.0%.
Unless the range is ≧(al/(b)≧1.2), a composition with low frictional resistance cannot be obtained.
本発明において用いられる水不溶性研磨剤（ｃ）として
は、二酸化ケイ素、酸化アルミニウム、水酸化アルミニ
ウム、酸化マグネシウム、酸化チタン、炭化ケイ素、炭
酸カルシウム、リン酸カルシウム、酸化クロム、合成ゼ
オライト、天然ゼオライト、あるいはコランダム、エメ
リー、けい石、石英砂、カルサイト、ドロマイト、塩化
ビニル、ポリスチレン、ポリエチレン、ＡＢＳなどのポ
リマービーズなどが挙げられる。The water-insoluble abrasive (c) used in the present invention includes silicon dioxide, aluminum oxide, aluminum hydroxide, magnesium oxide, titanium oxide, silicon carbide, calcium carbonate, calcium phosphate, chromium oxide, synthetic zeolite, natural zeolite, or corundum. , emery, silica, quartz sand, calcite, dolomite, vinyl chloride, polystyrene, polyethylene, ABS, and other polymer beads.
このうち、平均粒径１〜４０μの二酸化ケイ素、炭酸カ
ルシウム、合成ゼオライトが最も普通に用いられる。（
ｃ）成分は１０〜７０重量％、好ましくは２０〜６０重
量％配合される。Among these, silicon dioxide, calcium carbonate, and synthetic zeolites with an average particle size of 1 to 40 microns are most commonly used. (
Component c) is blended in an amount of 10 to 70% by weight, preferably 20 to 60% by weight.
本発明において用いられる高級脂肪酸又はその塩（ｄ）
としては、炭素数８〜２２の脂肪族カルボン酸又はその
塩が好ましく、対イオンは（ｂ）アルキルベンゼンスル
ホン酸塩の対イオンと同じものが挙げられる。（ｄ）成
分は０．０３〜１重量％、好ましくは０．０３〜０．５
重量％配合される。Higher fatty acid or salt thereof used in the present invention (d)
Preferably, the aliphatic carboxylic acid having 8 to 22 carbon atoms or a salt thereof is used, and the counter ion is the same as the counter ion of the alkylbenzenesulfonate (b). Component (d) is 0.03 to 1% by weight, preferably 0.03 to 0.5%
% by weight is added.
本発明に用いられる２価以上のアルコール（ｅ）として
はエチレングリコール、ジエチレングリコール１、グリ
セリン、ジグリセリン、ソルビトールなどが挙げられる
。中でもグリセリンが特に望ましい。（ｅ）成分は組成
物中に０．２〜０．５重量％配合される。Examples of the dihydric or higher alcohol (e) used in the present invention include ethylene glycol, diethylene glycol 1, glycerin, diglycerin, and sorbitol. Among them, glycerin is particularly desirable. Component (e) is blended in the composition in an amount of 0.2 to 0.5% by weight.
本発明において用いられるアルカノールアミン（ｆ）と
しては、モノエタノールアミン、ジェタノールアミン、
トリエタノールアミンが好ましく、組成物中に０．０１
〜０．３重量％配合される。The alkanolamine (f) used in the present invention includes monoethanolamine, jetanolamine,
Triethanolamine is preferred, with 0.01
~0.3% by weight is blended.
本発明の目的は、前述したように特定の界面活性剤を特
定の比率で用い、特定の成分を少量配合することにより
達成される。The object of the present invention is achieved by using specific surfactants in specific ratios and blending specific components in small amounts, as described above.
本発明の実施にあたって、本発明の効果を損なわない範
囲でポリオキシエチレンアルキルエーテル、ポリオキシ
エチレンアルキルフェニルエーテル、ポリオキシエチレ
ンポリオキシプロピレンブロックコポリマーなどの非イ
オン界面活性剤を加えてもよいし、更に必要に応じて、
分散安定剤、溶剤、ハイドロトロープ剤、殺菌剤、香料
、顔料、染料等を任意に添加することが出来る。In carrying out the present invention, nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, etc. may be added to the extent that the effects of the present invention are not impaired. Furthermore, if necessary,
Dispersion stabilizers, solvents, hydrotropes, bactericides, fragrances, pigments, dyes, etc. can be optionally added.
分散安定剤としては、マロン酸、リンゴ酸、酒石酸、ク
エン酸、Ｌ−アスパラギン酸又はその塩などの炭素数３
〜８のジ又はトリカルボン酸又はそれらの塩、珪酸ソー
ダ、例えば珪酸ソーダ１号、珪酸ソーダ２号、珪酸ソー
ダ３号、珪酸ソーダ４号、オルソ珪酸ソーダ、セスキ珪
酸ソーダ、メタ珪酸ソーダや硫酸マグネシウム、塩化カ
ルシウムなどのアルカリ土類金属塩、溶剤としては、エ
チルアルコール、ブチルアルコール等の脂肪族−価アル
コール、エチレングリコール、プロピレングリコール、
ポリエチレングリコール、ポリプロピレングリコール、
或いはそれらの脂肪族低級アルコール（メチル、エチル
、プロピル、ブチル等の）・エーテル等が挙げられる。As a dispersion stabilizer, a carbon number 3 such as malonic acid, malic acid, tartaric acid, citric acid, L-aspartic acid or its salt is used.
~8 di- or tricarboxylic acids or salts thereof, sodium silicate, such as sodium silicate No. 1, sodium silicate No. 2, sodium silicate No. 3, sodium silicate No. 4, sodium orthosilicate, sodium sesquisilicate, sodium metasilicate, and magnesium sulfate. , alkaline earth metal salts such as calcium chloride, solvents such as aliphatic alcohols such as ethyl alcohol and butyl alcohol, ethylene glycol, propylene glycol,
polyethylene glycol, polypropylene glycol,
Alternatively, aliphatic lower alcohols (such as methyl, ethyl, propyl, butyl) and ethers thereof may be mentioned.
ハイドロトロープ剤としては、パラトルエンスルホン酸
塩、キシレンスルホン酸塩、クメンスルホン酸塩、尿素
等が使用出来る。As the hydrotrope, paratoluene sulfonate, xylene sulfonate, cumene sulfonate, urea, etc. can be used.
液のｐＨは、優れた洗浄力を発揮するように、中性から
アルカリ性に調整されるものである。The pH of the liquid is adjusted from neutral to alkaline so as to exhibit excellent cleaning power.
本発明の液体クレンザ−組成物は、金属表面を磨くに際
し、摩擦抵抗が小さく、軽い力で洗浄でき、傷つけにく
く、且つ洗浄力に優れている。The liquid cleanser composition of the present invention has low frictional resistance when polishing metal surfaces, can be cleaned with light force, is hard to damage, and has excellent cleaning power.
以下、実施例により説明するが、本発明は、この実施例
に限定されるものではない。Examples will be described below, but the present invention is not limited to these examples.
表１に示す組成物を調製し、各組成物の摩擦抵抗、洗浄
力、傷付は性について以下の様に評価した。The compositions shown in Table 1 were prepared, and the frictional resistance, cleaning power, and scratch resistance of each composition were evaluated as follows.
く摩擦抵抗〉
水を含ませ軽く絞ったスポンジ（３Ｘ７ｃｍ）に試料１
ｇを均一に塗布した。ステンレス板上で荷重１ｋｇで、
上記のスポンジを運かすに必要な横方向の引張り力（ｇ
）を測定した。配合■を１とした時の引張り力を摩擦抵
抗とした。Frictional resistance〉 Place sample 1 on a damp sponge (3 x 7 cm) that has been wrung out slightly.
g was applied uniformly. With a load of 1 kg on a stainless steel plate,
The lateral tensile force (g) required to move the above sponge
) was measured. The tensile force when the formulation (■) was set to 1 was defined as the frictional resistance.
〈洗浄力〉
ナタネ油／カーボンブラック＝９／１を鉄板上に薄く塗
り、１８０℃×４０分処理した。<Cleaning power> A thin layer of rapeseed oil/carbon black = 9/1 was applied onto an iron plate and treated at 180°C for 40 minutes.
水を含ませ軽く絞ったスポンジ（３Ｘ７ｃｍ）に試料を
１ｇ塗付し、荷重１ｋｇで、この鉄板を５０回洗浄した
。1 g of the sample was applied to a sponge (3 x 7 cm) moistened with water and lightly squeezed, and the iron plate was washed 50 times with a load of 1 kg.
洗浄率（％）
９１〜１００・・・・・・５
６６〜９０・・・・・・４
３６〜６５・・・・・・３
１１〜３５・・・・・・２
０〜１０・・・・・・１
く傷付性〉
試料１ｇを採取し、ウレタンスポンジにて浴槽や流し台
の材質であるステンレス表面を５ｏ回洗浄後、傷の有無
を肉眼観察し、評価を行った。Cleaning rate (%) 91-100...5 66-90...4 36-65...3 11-35...2 0-10... ...1. Scratch Resistance> 1 g of the sample was taken, and after cleaning the stainless steel surface, which is the material of the bathtub and sink, 5 times with a urethane sponge, the presence or absence of scratches was visually observed and evaluated.
○・・・傷付けない ◎・・・通常は問題ないが強くこするとやや傷付ける △・・・やや傷付ける ×・・・傷付ける○・・・Do not hurt ◎・・・Normally there is no problem, but if you rub it too hard, it will cause some damage. △・・・Slightly hurts ×・・・hurt
Claims (1)
レンオキサイド付加物 （ｂ）アルキルベンゼンスルホン酸アルカリ金属塩 を２．０≧（ａ）／（ｂ）≧１．２の割合で、（ａ）＋
（ｂ）＝４〜８重量％含有し、更に （ｃ）水不溶性研磨剤１０〜７０重量％ （ｄ）高級脂肪酸又はそのアルカリ金属塩０．０３〜１
重量％ （ｅ）２価以上のアルコール０．２〜０．５重量％ （ｆ）アルカノールアミン０．０１〜０．３重量％を含
有することを特徴とする液体クレンザー組成物。 ２（ｅ）成分がグリセリンである特許請求の範囲第１項
記載の液体クレンザー組成物。[Scope of Claims] 1(a) higher fatty acid alkanolamide or its alkylene oxide adduct (b) alkali metal salt of alkylbenzenesulfonic acid in a ratio of 2.0≧(a)/(b)≧1.2, ( a)+
(b) = 4 to 8% by weight, further (c) water-insoluble abrasive 10 to 70% by weight (d) higher fatty acid or its alkali metal salt 0.03 to 1
A liquid cleanser composition characterized in that it contains (e) 0.2 to 0.5 weight % of a dihydric or higher alcohol; and (f) 0.01 to 0.3 weight % of an alkanolamine. 2. The liquid cleanser composition according to claim 1, wherein component 2(e) is glycerin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2775087A JPS63196697A (en) | 1987-02-09 | 1987-02-09 | Liquid cleanser composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2775087A JPS63196697A (en) | 1987-02-09 | 1987-02-09 | Liquid cleanser composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63196697A true JPS63196697A (en) | 1988-08-15 |
| JPH0380840B2 JPH0380840B2 (en) | 1991-12-26 |
Family
ID=12229702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2775087A Granted JPS63196697A (en) | 1987-02-09 | 1987-02-09 | Liquid cleanser composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63196697A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998055573A1 (en) * | 1997-06-04 | 1998-12-10 | Toto Ltd. | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
| WO1998058045A1 (en) * | 1997-06-17 | 1998-12-23 | Unilever Plc | Abrasive cleaning composition |
| JP2017155198A (en) * | 2016-03-04 | 2017-09-07 | Ａｔシリカ株式会社 | Polishing composition |
-
1987
- 1987-02-09 JP JP2775087A patent/JPS63196697A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998055573A1 (en) * | 1997-06-04 | 1998-12-10 | Toto Ltd. | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
| WO1998058045A1 (en) * | 1997-06-17 | 1998-12-23 | Unilever Plc | Abrasive cleaning composition |
| JP2017155198A (en) * | 2016-03-04 | 2017-09-07 | Ａｔシリカ株式会社 | Polishing composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0380840B2 (en) | 1991-12-26 |
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