JPS63195200A - Antimicrobial whisker - Google Patents
Antimicrobial whiskerInfo
- Publication number
- JPS63195200A JPS63195200A JP62027625A JP2762587A JPS63195200A JP S63195200 A JPS63195200 A JP S63195200A JP 62027625 A JP62027625 A JP 62027625A JP 2762587 A JP2762587 A JP 2762587A JP S63195200 A JPS63195200 A JP S63195200A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- whiskers
- whisker
- antimicrobial
- substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000845 anti-microbial effect Effects 0.000 title abstract 7
- 239000000126 substance Substances 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 239000010703 silicon Substances 0.000 claims abstract description 8
- -1 silicon quaternary ammonium salt Chemical class 0.000 claims abstract description 6
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 33
- 230000003014 reinforcing effect Effects 0.000 abstract description 3
- 239000004599 antimicrobial Substances 0.000 abstract 2
- 230000003100 immobilizing effect Effects 0.000 abstract 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 14
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 235000019270 ammonium chloride Nutrition 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N Amide-Hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical class [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- QLNOVKKVHFRGMA-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical group [CH2]CC[Si](OC)(OC)OC QLNOVKKVHFRGMA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は抗菌性ウィスカーに関し、例えばフィルター、
床材、壁材、天井材など建材一般、消防服、クーリング
タワーの冷却水、切削油、スフイムコントロール剤およ
び医療用機材の包装紙など衣食住の全般にわたって利用
することができる。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to antibacterial whiskers, such as filters,
It can be used for general building materials such as flooring, wall, and ceiling materials, firefighting uniforms, cooling water for cooling towers, cutting oil, Sufim control agent, and wrapping paper for medical equipment.
（従来の技術）
従来、抗菌性を付与した紙、半透膜、ａ維および布など
が公知であるが、いずれも抗菌剤の保護基材が耐熱性、
補強性あるいは耐摩耗性などの点において問題がある。(Prior art) Paper, semipermeable membranes, α-fibers, cloth, etc. that have antibacterial properties have been known, but in all of them, the protective base material for the antibacterial agent is heat resistant,
There are problems in terms of reinforcing properties and abrasion resistance.
例えば、抗菌性紙としては紙のバイングー中に抗菌剤を
添加し、その抗菌剤を紙のｉ継に移行させる方法（Ｕ
Ｓ Ｐ ４，５３３，４３５）などが知られている。For example, for antibacterial paper, there is a method (U
S P 4,533,435) and the like are known.
また不溶性の板状保護基体、例えばビニロン不織布など
にＡｇ塩を付着させてなる水処理用滅菌剤（特開昭５Ｏ
−１２２２８）なども公知である。In addition, a sterilizer for water treatment is prepared by adhering Ag salt to an insoluble plate-shaped protective substrate, such as vinylon nonwoven fabric (Japanese Patent Laid-Open No.
-12228) and the like are also known.
更に抗菌性半透膜としてはシリコン第４９アンモニウム
塩をセルロース半透膜に付着させる方法（特開昭６Ｏ−
１７２３１０）などがあるが、これらは基材の耐熱性、
抗菌剤の基材からの溶出、基材の強度的な問題および水
系、非水系の両方での使用不可などの点で用途が限定さ
れ、抗菌性物質の幅広い適用が困難である。Furthermore, as an antibacterial semipermeable membrane, a method of attaching a silicon 49th ammonium salt to a cellulose semipermeable membrane (Japanese Unexamined Patent Application Publication No. 1986-60-
172310), but these are based on the heat resistance of the base material,
Applications are limited due to problems such as elution of antibacterial agents from the base material, strength of the base material, and inability to use in both aqueous and non-aqueous systems, making it difficult to widely apply antibacterial substances.
（発明が解決しようとする問題点）
本発明の目的はその基材が耐熱性、耐摩耗性に優れ、高
い強度を有する抗菌性ウィスカーを提供することにある
。(Problems to be Solved by the Invention) An object of the present invention is to provide an antibacterial whisker whose base material has excellent heat resistance, abrasion resistance, and high strength.
また本発明の目的は水系及び非水系の両方で使用可能で
、且つ抗菌剤の溶出の全くない抗菌性ウィスカーを提供
することにある。Another object of the present invention is to provide an antibacterial whisker that can be used in both aqueous and non-aqueous systems and does not elute antibacterial agents at all.
（問題点を解決するための手段）
本発明は抗菌性物質をウィスカーに固定させてなる抗菌
性ウィスカーに係る。(Means for Solving the Problems) The present invention relates to an antibacterial whisker in which an antibacterial substance is fixed to the whisker.
本発明で使用される抗菌性物質としては広く各種の抗菌
性を有する天然物質、合成物質を挙げることができる。The antibacterial substances used in the present invention include a wide variety of natural and synthetic substances having antibacterial properties.
好適な具体例としてはジメチル（オクタデシル）（３−
（）リメトキシシリル）プロピル〕アンモニウムクロラ
イド、ジメチル（ヘキサデシル）（３−（）リメトキシ
シリル）プロピル〕アンモニウムクロライド、ツメチル
（テトラデシル）（３−（）リメトキシシリル）プロピ
ル〕アンモニウムクロライド、ジメチル（ドデシル）（
３−（トリメトキシシリル）プロピル〕アンモニウムク
ロライド、ジメチル（デシル）（３−（）ツメ）キシン
リル）プロピル〕アンモニツムクロライド、ジメチル（
オクチル）（３−（）リメトキシシリル）プロピル〕ア
ンモニウムクロライド等のシリコンｆｊＳＡ級アンモニ
ウム塩、Ｎ−（３−（）リメトキシシリル）プロピル〕
オクチル酸アミド、Ｎ−（３−（）リメトキシシリル）
プロピル〕デシル酸アミド、Ｎ−（３−（）リメトキシ
シリル）プロピル〕ドデシル酸アミド、Ｎ−（３−（）
リメトキシシリル）プロピルコテトラデシル酸アミド、
Ｎ−（３−（）リメトキシシリル）プロピル〕ヘキサデ
シル酸アミド等の長鎖シリコン酸アミドなどを挙げるこ
とができる。これら抗菌性物質は単独又は２種以上を組
合せて使用することができる。A preferred specific example is dimethyl (octadecyl) (3-
()rimethoxysilyl)propyl] ammonium chloride, dimethyl (hexadecyl) (3-()rimethoxysilyl)propyl] ammonium chloride, trimethyl (tetradecyl) (3-()rimethoxysilyl)propyl] ammonium chloride, dimethyl (dodecyl) )(
3-(trimethoxysilyl)propyl]ammonium chloride, dimethyl(decyl)(3-()thume)xinlyl)propyl]ammonium chloride, dimethyl(
octyl)(3-()rimethoxysilyl)propyl] Silicon fj SA class ammonium salts such as ammonium chloride, N-(3-()rimethoxysilyl)propyl]
Octylic acid amide, N-(3-()rimethoxysilyl)
propyl]decylic acid amide, N-(3-()rimethoxysilyl)propyl]dodecylic acid amide, N-(3-()
rimethoxysilyl)propylcotetradecylic acid amide,
Long-chain siliconic acid amides such as N-(3-()rimethoxysilyl)propyl]hexadecylamide and the like can be mentioned. These antibacterial substances can be used alone or in combination of two or more.
本発明に用いるウィズカーとしては前述の抗菌性物質を
固定化でさるものであればよく、例えば、マグネシウム
パイロボレートウィスカー、窒化ケイ素ウィスカー、炭
化ケイ素ウィスカー、チタン酸カリウムウィスカーなど
を例示することができる。ウィスカーの好適な平均粒径
は約０．０１〜２μ転平均繊Ｊｌｌ！には約０．５〜５
，０００μ−が好ましく、虫たアスペクト比は約５０〜
２，５００の範囲が好適である。The whisker used in the present invention may be any whisker that can immobilize the above-mentioned antibacterial substance, and examples thereof include magnesium pyroborate whiskers, silicon nitride whiskers, silicon carbide whiskers, potassium titanate whiskers, and the like. The preferred average particle size of the whiskers is about 0.01 to 2μ average fibers! Approximately 0.5 to 5
,000μ- is preferable, and the aspect ratio is about 50~
A range of 2,500 is preferred.
以上述べたように抗菌性物質とウィスカーとの組合せは
特に限定されるものではないが、好ましくはシリコン第
４級アンモニウム塩とチタン酸カリウムウィスカーの組
合せがよい。As described above, the combination of the antibacterial substance and the whisker is not particularly limited, but a combination of a silicon quaternary ammonium salt and a potassium titanate whisker is preferred.
本発明において抗菌性物質をウィスカーに固定させるに
は、例えば抗菌性物質をメタノール、エタノール、プロ
パ／−ル、ベンゼン等の溶媒に溶解し、これにウィスカ
ーを加えて良く撹拌した後、濃縮、乾燥することにより
行うことができる。尚、その後に遊離の抗菌性物質を洗
浄除去し、再び乾燥することも好ましい。In the present invention, in order to fix the antibacterial substance to the whiskers, for example, the antibacterial substance is dissolved in a solvent such as methanol, ethanol, propyl alcohol, benzene, etc., the whiskers are added thereto, the mixture is thoroughly stirred, and then the substance is concentrated and dried. This can be done by In addition, it is also preferable to wash away the free antibacterial substance after that and dry it again.
（発明の効果）
本発明の抗菌性ウィスカーを用いることによって、抗菌
性物質本来の抗菌力を幅広（利用でさると同時にウィス
カーのもつ特性、例えば耐熱性、・断熱性、補強性およ
び耐摩耗性なども生かすことができ、従来の問題点を解
決することができる。(Effects of the invention) By using the antibacterial whiskers of the present invention, the antibacterial properties inherent to antibacterial substances can be extended to a wide range of uses (in addition to the characteristics of the whiskers, such as heat resistance, heat insulation, reinforcing properties, and abrasion resistance). etc. can be utilized to solve conventional problems.
従って本発明の抗菌性ウィスカーを用いることによって
ウィスカーの特長を生かして抗菌性物質の用途拡大を図
ることができる。Therefore, by using the antibacterial whiskers of the present invention, the features of the whiskers can be utilized to expand the uses of antibacterial substances.
（実 施 例） 以下に実施例及び試験例を挙げて詳しく説明する。(Example) A detailed explanation will be given below with reference to Examples and Test Examples.
実施例１
抗菌性のあるシリコン第４級アンモニウム塩、ジメチル
（オクタデシル）（３−（）リメトキシシリル）プロピ
ル〕アンモニウムクロライド（以下ＯＣＢと略す＞ ７
５ｍｇ（１５０μｍｏｌ）を１０１００Ｏのメタノール
に溶解し、これにチタン酸カリウムウィスカー（人尿化
学製、Ｔ Ｉ ５Ｍ０）を１０．加え、濃縮後、乾燥し
、ＯＣＲをＴ Ｉ ＳＭＯ上に固定化させた。Example 1 Antibacterial silicon quaternary ammonium salt, dimethyl(octadecyl)(3-()rimethoxysilyl)propyl]ammonium chloride (hereinafter abbreviated as OCB)> 7
5 mg (150 μmol) was dissolved in 10100O methanol, and potassium titanate whiskers (manufactured by Jinu Kagaku Co., Ltd., T I 5M0) were added to the solution for 10 minutes. The mixture was added, concentrated, dried, and OCR was immobilized on TISMO.
その後、メタノールで遊離のＯＣＢを洗浄、除去し再び
乾燥した。Thereafter, free OCB was washed and removed with methanol and dried again.
得られた抗菌性ウィスカー（以下ＡＷＢと略す）はＯＣ
ＲがＴｌ５Ｍ０上に固定化しでいることをブロムフェノ
ールブルー（ＢＰＢ）のクロロホルム液で確認後、螢光
Ｘｍでシリコンを定量することによって付着量を求めた
。ＡＷＢ中のＯＣＢ含量は１５μｍｏｆ／ｇ Ｔ Ｉ
ＳＭＯであつた。The obtained antibacterial whiskers (hereinafter abbreviated as AWB) are OC
After confirming that R was immobilized on Tl5M0 using a chloroform solution of bromophenol blue (BPB), the amount of silicon adhered was determined by quantifying silicon using fluorescent Xm. OCB content in AWB is 15 μmof/g T I
It was SMO.
試験例１
実施例１で得られた抗菌性ウィスカーＡＷＢ（１００ｍ
ｇ）を用いてパッチ法により、抗菌スペクトルを測定し
た。測定条件は薗懸濁ｆｉｌｏｏｍｌ（菌数６ ＸＩＯ
” ｃｅｌｌｓ）、温度３０℃である。結果を第１表に
示す。Test Example 1 Antibacterial whisker AWB obtained in Example 1 (100 m
g) was used to measure the antibacterial spectrum by the patch method. The measurement conditions were Sono suspension firoom (bacterial count 6
” cells) at a temperature of 30° C. The results are shown in Table 1.
第１表
試験例２
実施例１で得られた抗菌性ウィスカーＡＷＢを用いて、
下記第２表に示す配合で
（ａ） ミキシングロール； Ｄ ＝ １０ｉｎ、
１６ｒｐｍ（ｂ）ロール温度ｘ時間；１４０〜１４
５℃×５分（ｅ）シート厚み； ０，５＋＊ｍ
の条件で混練してシートを作成し、このシートを用いて
Ｊ Ｉ Ｓ Ｚ２９１１に従って、かびの抗菌性試験
を行った。結果を第３表に示す。Table 1 Test Example 2 Using the antibacterial whiskers AWB obtained in Example 1,
With the formulation shown in Table 2 below, (a) Mixing roll; D = 10 inch;
16 rpm (b) Roll temperature x time; 140-14
5℃ x 5 minutes (e) Sheet thickness: 0.5+*m
A sheet was prepared by kneading under the following conditions, and the antibacterial property test against mold was conducted using this sheet in accordance with JIS Z2911. The results are shown in Table 3.
第 ２ 表
第３表
第３表においでＮｏ、１〜５はそれぞれＰｖＣに対して
ＡＷＢの含量が０ 、０，０６７、０，１００゜０．１
３３及び０．２００ ｗｔ％の場合に相当する。Table 2 Table 3 In Table 3, Nos. 1 to 5 indicate that the AWB content relative to PvC is 0, 0,067, and 0,100°0.1, respectively.
33 and 0.200 wt%.
また＋は菌子着生、 Ｓは胞子付着生、 −は変化なし な示す。Also, + means mycelium epiphyte, S is spore-adhering; - indicates no change.
（以 上）(that's all)
Claims (3)
ウィスカー。(1) Antibacterial whiskers made by fixing antibacterial substances to the whiskers.
特許請求の範囲第１項記載の抗菌性ウィスカー。(2) The antibacterial whisker according to claim 1, wherein the whisker is a potassium titanate whisker.
る特許請求の範囲第１項記載の抗菌性ウィスカー。(3) The antibacterial whisker according to claim 1, wherein the antibacterial substance is a silicon quaternary ammonium salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62027625A JPH0788280B2 (en) | 1987-02-09 | 1987-02-09 | Antibacterial whisker |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62027625A JPH0788280B2 (en) | 1987-02-09 | 1987-02-09 | Antibacterial whisker |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63195200A true JPS63195200A (en) | 1988-08-12 |
| JPH0788280B2 JPH0788280B2 (en) | 1995-09-27 |
Family
ID=12226134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62027625A Expired - Fee Related JPH0788280B2 (en) | 1987-02-09 | 1987-02-09 | Antibacterial whisker |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0788280B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63222100A (en) * | 1987-03-10 | 1988-09-14 | Otsuka Chem Co Ltd | Antimicrobial metal-containing whisker and production thereof |
| JP2004511421A (en) * | 2000-10-17 | 2004-04-15 | ジェイムズ ハーディー リサーチ ピーティーワイ．リミテッド | Fiber cement composite using durable cellulose fibers treated with biocide |
| WO2009013991A1 (en) * | 2007-07-25 | 2009-01-29 | Hiroshima University | Solidified detergent composition and method for producing the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63105173A (en) * | 1986-10-21 | 1988-05-10 | 日機装株式会社 | Surface modifiation of whisker |
-
1987
- 1987-02-09 JP JP62027625A patent/JPH0788280B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63105173A (en) * | 1986-10-21 | 1988-05-10 | 日機装株式会社 | Surface modifiation of whisker |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63222100A (en) * | 1987-03-10 | 1988-09-14 | Otsuka Chem Co Ltd | Antimicrobial metal-containing whisker and production thereof |
| JP2004511421A (en) * | 2000-10-17 | 2004-04-15 | ジェイムズ ハーディー リサーチ ピーティーワイ．リミテッド | Fiber cement composite using durable cellulose fibers treated with biocide |
| WO2009013991A1 (en) * | 2007-07-25 | 2009-01-29 | Hiroshima University | Solidified detergent composition and method for producing the same |
| US8304379B2 (en) | 2007-07-25 | 2012-11-06 | Hiroshima University | Silicon compound-containing solidified detergent composition and method for producing the same |
| JP5424482B2 (en) * | 2007-07-25 | 2014-02-26 | 国立大学法人広島大学 | Solidified cleaning composition and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0788280B2 (en) | 1995-09-27 |
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|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |