JPS6319343B2 - - Google Patents
Info
- Publication number
- JPS6319343B2 JPS6319343B2 JP54129089A JP12908979A JPS6319343B2 JP S6319343 B2 JPS6319343 B2 JP S6319343B2 JP 54129089 A JP54129089 A JP 54129089A JP 12908979 A JP12908979 A JP 12908979A JP S6319343 B2 JPS6319343 B2 JP S6319343B2
- Authority
- JP
- Japan
- Prior art keywords
- phenoxy resin
- film
- cloth
- fabrics
- release paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 239000013034 phenoxy resin Substances 0.000 claims description 15
- 229920006287 phenoxy resin Polymers 0.000 claims description 15
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 8
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
本発明は布類の接着及び表面加工方法に関する
ものである。更に詳しくは、ビスフエノールＡと
エピクロルヒドリンより重合されたフエノキシ樹
脂のフイルムを布類に加熱圧着することを特徴と
する布類の接着及び表面加工方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for bonding and surface finishing fabrics. More specifically, the present invention relates to a fabric adhesion and surface treatment method characterized by heat-pressing a film of phenoxy resin polymerized from bisphenol A and epichlorohydrin to fabric.
一般に衣料、バツグ等に使用される布類は縫製
により縫い合わされて接合されているが、非常に
多くの労力を要し、また糸の切断による分離が簡
単に起こり、製造面、品質面共に問題が多かつ
た。また、この方法を改良する方法として、ナイ
ロン12共重合物のフイルムを布類の間に挿入して
加熱圧着する方法が行われているが、価格が非常
に高く、また融点が高いために接着に長い時間を
要し、工業的に見て問題が多かつた。 Cloths used for clothing, bags, etc. are generally sewn together by sewing, but this requires a great deal of labor and can easily separate due to thread cutting, causing problems in terms of both manufacturing and quality. There were many. In addition, as an improvement to this method, a nylon 12 copolymer film is inserted between cloths and bonded under heat, but this method is very expensive and has a high melting point, so It took a long time and caused many problems from an industrial perspective.
また、布類の防水加工等の表面加工においても
従来、樹脂加工や前記ナイロン12共重合物フイル
ムの加熱圧着などの方法が採られているが、同様
に価格や生産性の点から不満足な点が多かつた。 In addition, methods such as resin processing and heat-pressing of the nylon-12 copolymer film have been conventionally used for surface treatments such as waterproofing of fabrics, but these methods also have unsatisfactory points in terms of cost and productivity. There were many.
本発明者等はかかる問題につき検討を重ねた結
果、次のような方法を発明するに至つた。すなわ
ち、ビスフエノールＡとエピクロルヒドリンより
重合された構造式
で表わされるフエノキシ樹脂のフイルムを布類に
加熱圧着する方法である。 As a result of repeated studies on this problem, the present inventors came up with the following method. That is, the structural formula polymerized from bisphenol A and epichlorohydrin This is a method in which a phenoxy resin film represented by the formula is heat-pressed onto cloth.
本発明に使用されるフエノキシ樹脂は軟化点が
約100℃と非常に低く、低温短時間で加熱融着を
行うことができ、また価格も安価であるので、非
常に経済的である。本発明のフエノキシ樹脂は前
記のようにビスフエノールＡとエピクロルヒドリ
ンより重合されるが、重合度は成形性、熱変形性
等から100位が適当である。また、フエノキシ樹
脂のフイルム化は通常の押出機で加熱融解後、Ｔ
ダイ法あるいはチユーブラー法により成膜する方
法、あるいは溶剤に溶解した後流延乾燥する方法
等が適用できるが、特にこれらに限定されるもの
ではない。 The phenoxy resin used in the present invention has a very low softening point of about 100° C., can be heat-fused at low temperatures in a short time, and is inexpensive, making it very economical. The phenoxy resin of the present invention is polymerized from bisphenol A and epichlorohydrin as described above, and the degree of polymerization is preferably about 100 from the viewpoint of moldability, heat deformability, etc. In addition, phenoxy resin is made into a film by heating and melting it in an ordinary extruder, then using T
A method of forming a film by a die method or a tubular method, a method of dissolving in a solvent and then casting and drying, etc. can be applied, but the method is not particularly limited to these.
本発明法における布類とは、衣料、コンテナバ
ツグ、補強材等に使用される天然繊維あるいは合
成繊維の織物、不織布等を意味する。 The term "fabrics" as used in the method of the present invention means woven or nonwoven fabrics made of natural fibers or synthetic fibers used for clothing, container bags, reinforcing materials, and the like.
また、本発明法における接着方法は、布類同志
の接着の場合はフエノキシ樹脂フイルムあるいは
それをマイクロスリツトしたテープを２枚の布類
の間に挿入し、片側あるいは両側の布類の外側か
ら加熱した金属板等で圧着すれば良い。布類が極
度に厚く熱伝導性が悪い時は予め布類を加熱して
おくと良い結果が得られる。また、布類の表面加
工の場合は布類にフエノキシ樹脂フイルムを重ね
更にその上に離型紙を乗せ、離型紙の外側から加
熱した金属板等で圧着すれば良い。圧着時の加熱
温度はいずれの場合もフエノキシ樹脂の軟化温度
より少し高い温度、すなわち110〜150℃が好まし
い。 In addition, in the case of bonding fabrics together, the bonding method according to the present invention involves inserting a phenoxy resin film or a tape made by micro-slitting it between two fabrics, and starting from the outside of the fabric on one or both sides. It may be crimped with a heated metal plate or the like. If the cloth is extremely thick and has poor thermal conductivity, good results can be obtained by heating the cloth in advance. In addition, in the case of surface treatment of cloth, a phenoxy resin film may be layered on the cloth, and a release paper may be placed on top of the phenoxy resin film, and the film may be pressed from the outside of the release paper with a heated metal plate or the like. The heating temperature during compression bonding is preferably a temperature slightly higher than the softening temperature of the phenoxy resin, that is, 110 to 150°C.
以下、実施例により更に詳しく説明する。 A more detailed explanation will be given below with reference to Examples.
実施例 １
フエノキシ樹脂チツプを40mm押出機で220℃に
溶融し、Ｔダイより40℃の冷却ロール上に押出し
て厚さ70μのフイルムを成膜した。Example 1 Phenoxy resin chips were melted at 220° C. using a 40 mm extruder and extruded from a T-die onto a cooling roll at 40° C. to form a film with a thickness of 70 μm.
このフエノキシ樹脂フイルムを幅10mmにマイク
ロスリツトした後、２枚のポリエステル製布地の
間に挿入し、120℃で４秒間アイロンで圧着した。
圧着された布地をフエノキシ樹脂フズイルムの長
さ方向と直角に15mmの幅で切り出し、Ｔ型剥離強
度を測定したところ、約４Kgであり、良好な値で
あつた。 This phenoxy resin film was microslit to a width of 10 mm, inserted between two polyester fabrics, and pressed together with an iron at 120° C. for 4 seconds.
The crimped fabric was cut out to a width of 15 mm perpendicular to the length direction of the phenoxy resin film, and the T-peel strength was measured, which was approximately 4 kg, which was a good value.
実施例 ２
実施例１と同じフエノキシ樹脂フイルムをポリ
エステル製不織布の上に重ね、更に離型紙を乗せ
て離型紙の上から熱ローラーにより130℃で１秒
間圧着した。圧着後離型紙をはずし、15mm幅で切
り出して、フエノキシ樹脂フイルムとポリエステ
ル製不織布とのＴ型剥離強度を測定したところ、
約3.5Kgであり、良好な接着性を示していた。Example 2 The same phenoxy resin film as in Example 1 was placed on a polyester nonwoven fabric, and a release paper was further placed on top of the release paper, and the film was pressed onto the release paper at 130° C. for 1 second using a hot roller. After crimping, the release paper was removed and a 15 mm wide piece was cut out to measure the T-peel strength between the phenoxy resin film and the polyester nonwoven fabric.
The weight was approximately 3.5 kg, indicating good adhesion.
Claims (1)
重合された下記の構造式をもつフエノキシ樹脂の
フイルムを２枚の布類の間に挿入または布類の表
面に重ね合わせた後、加熱圧着することを特徴と
する布類の接着及び表面加工法。 [Claims] 1. A film of phenoxy resin polymerized from bisphenol A and epichlorohydrin and having the following structural formula is inserted between two pieces of cloth or superimposed on the surface of the cloth, and then bonded under heat and pressure. A fabric adhesion and surface treatment method characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12908979A JPS5653072A (en) | 1979-10-05 | 1979-10-05 | Adhesion and surface working method for cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12908979A JPS5653072A (en) | 1979-10-05 | 1979-10-05 | Adhesion and surface working method for cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5653072A JPS5653072A (en) | 1981-05-12 |
| JPS6319343B2 true JPS6319343B2 (en) | 1988-04-22 |
Family
ID=15000798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12908979A Granted JPS5653072A (en) | 1979-10-05 | 1979-10-05 | Adhesion and surface working method for cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5653072A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0513246Y2 (en) * | 1987-10-09 | 1993-04-07 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0761702B2 (en) * | 1986-09-17 | 1995-07-05 | アキレス株式会社 | Solvent resistant rubberized cloth for clothing |
-
1979
- 1979-10-05 JP JP12908979A patent/JPS5653072A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0513246Y2 (en) * | 1987-10-09 | 1993-04-07 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5653072A (en) | 1981-05-12 |
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