JPS63189479A - Metallic coating material composition for electrostatic coating - Google Patents
Metallic coating material composition for electrostatic coatingInfo
- Publication number
- JPS63189479A JPS63189479A JP2124387A JP2124387A JPS63189479A JP S63189479 A JPS63189479 A JP S63189479A JP 2124387 A JP2124387 A JP 2124387A JP 2124387 A JP2124387 A JP 2124387A JP S63189479 A JPS63189479 A JP S63189479A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum powder
- metallic
- electrostatic
- coating
- granular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009503 electrostatic coating Methods 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 title abstract description 11
- 238000000576 coating method Methods 0.000 title abstract description 10
- 239000011248 coating agent Substances 0.000 title abstract description 9
- 239000000463 material Substances 0.000 title abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000008199 coating composition Substances 0.000 claims description 17
- 239000003973 paint Substances 0.000 description 22
- 238000010422 painting Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000001154 acute effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は自動車、家′ｉｆｉ製品などに塗装されるメタ
リック塗料組成物に関し、詳しくは静１！塗装に好適な
メタリック塗料組成物に閏する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a metallic paint composition for coating automobiles, household products, etc. A metallic paint composition suitable for painting is used.
［従来の技術］
自動車、家電製品などの表面の塗装には、従来メタリッ
ク塗装が多く用いられている。このメタリック塗装は、
まずアルミニウム粉末を含むメタリック塗料を塗布し、
その表面にさらにクリア塗料を塗布する２コート塗装に
より行なわれている。[Prior Art] Metallic coatings have traditionally been widely used for coating the surfaces of automobiles, home appliances, and the like. This metallic paint
First, apply a metallic paint containing aluminum powder,
This is done using a two-coat method in which clear paint is further applied to the surface.
そしてこれらの塗料を塗装する方法としては静電塗装が
多く利用されている。この静？！ｆ塗装は、吐出された
塗料粒子に電荷を帯電させ、アース電位にある被塗物に
吸引させて付着させることにより塗装する方法であり、
エアスプレー塗装に比べて塗料ロスの低減、塗装品質の
安定化を図ることができる。Electrostatic coating is often used as a method for applying these paints. This quietness? ! f-painting is a method of painting by charging the discharged paint particles with an electric charge and attracting and adhering them to the object to be painted, which is at ground potential.
Compared to air spray painting, paint loss can be reduced and painting quality can be stabilized.
ところでアルミニウム粉末は導電性物質であり、メタリ
ック塗料を静電塗装する場合には静電塗装機先端部に印
加される高電圧がアルミニウム粉末を介して塗料流路な
どを通じて逃げ（以下静電リークという）、静電効果が
充分に得られないという不具合がある。このような不具
合を改良するために、特開昭５６−１００８６５号公報
にはアルミニウム粉末をアミノシラン処理したものが開
示されている。また特開昭６０〜１２１２０１＠公報に
はアルミニウム粉末を樹脂で被覆したものが開示されて
いる。これらはアルミニウム粉末自体を処理して導電性
を低減したものであるが、他に添加剤の添加により塗料
自体の導電性を低減したものも知られている。By the way, aluminum powder is a conductive substance, and when applying electrostatic coating with metallic paint, the high voltage applied to the tip of the electrostatic coating machine escapes through the aluminum powder through the paint flow path (hereinafter referred to as electrostatic leakage). ), there is a problem that sufficient electrostatic effect cannot be obtained. In order to improve such problems, JP-A-56-100865 discloses aluminum powder treated with aminosilane. Furthermore, JP-A-60-121201@ discloses aluminum powder coated with a resin. These paints are made by treating the aluminum powder itself to reduce its conductivity, but there are also known paints in which the conductivity of the paint itself is reduced by adding additives.
［発明が解決しようとする問題点］
アルミニウム粉末を７ミノシランで処理するには、処理
に手間がかかり工数面で不具合がある。[Problems to be Solved by the Invention] Treating aluminum powder with 7-minosilane is time-consuming and disadvantageous in terms of man-hours.
また樹脂で被覆したアルミニウム粉末は金属光沢が低減
するため、メタリック感が劣るという不具合がある。さ
らに添加剤については少量の添加量で静電リークを完全
に解決したものはまだ知られておらず、添加量を多くす
ると塗膜物性、塗装作業性などが低下する場合が多い。Furthermore, aluminum powder coated with a resin has a problem in that the metallic luster is reduced, resulting in a poor metallic feel. Furthermore, as for additives, there is still no known additive that completely solves electrostatic leakage with a small amount of addition, and when the amount of addition is increased, the physical properties of the coating film, painting workability, etc. often deteriorate.
本発明は静電リークを防止し、かつ上記した問題点を克
服するメタリック塗料組成物を提供するものである。The present invention provides a metallic coating composition that prevents electrostatic leakage and overcomes the above-mentioned problems.
［問題点を解決するための手段］
本発明の静電塗装用メタリック塗料組成物は、アルミニ
ウム粉末を含有するメタリック塗料組成物であって、ア
ルミニウム粉末は、長径ａ１短径すおよび厚さＣにおい
て、ａが１００μｍ以下ａ＞ｂ＞ｃかつ１≦ａ／ｃ≦５
の関係にある粒状アルミニウム粉末と、ａ＞ｂ＞ｃかつ
ａ ／ ｃ ＞ ５の関係にある鱗片状アルミニウム粉
末と、からなることを特徴とする。[Means for Solving the Problems] The metallic coating composition for electrostatic coating of the present invention is a metallic coating composition containing aluminum powder, wherein the aluminum powder has a major axis a1 a minor axis and a thickness C. , a is 100 μm or less a>b>c and 1≦a/c≦5
It is characterized by consisting of granular aluminum powder having the relationship of: a>b>c and scaly aluminum powder having the relationship of a/c>5.
メタリック塗料用アルミニウム粉末は、一般に径が数μ
ｍ〜数拾μｍ１厚さが１μｍ以下の鱗片形状をなしてい
る。本発明者はこのようなアルミニウム粉末を含有する
メタリック塗料に静電リークを生じさせ、その部分を観
察した。静電リークの発生部分では、第３図に示すよう
にアルミニウム粉末どうしが繋がって電荷の逃げ道を形
成している。そしてさらに細かく観察したところ、アル
ミニウム粉末の鋭角部分が繋がっていることを見出した
。すなわち電気の特性からアルミニウム粉末の鋭角部分
に電荷が集中し、その部分が他のアルミニウム粉末と繋
がり、このようにしてその繋がりが成長することにより
静電リークが生じることが明らかとなった。本発明はこ
の知見に塁づき鋭意研究の結果なされたものである。Aluminum powder for metallic paints generally has a diameter of several μm.
It has a scale shape of 1 μm or less and a thickness of 1 μm or less. The present inventor caused electrostatic leakage in a metallic paint containing such aluminum powder and observed the leaked area. In the area where electrostatic leakage occurs, as shown in FIG. 3, aluminum powders are connected to each other to form an escape route for charges. Upon closer observation, it was discovered that the acute angles of the aluminum powder were connected. In other words, it has been revealed that due to the electrical characteristics, electric charge is concentrated at the acute angle portion of the aluminum powder, and that portion is connected to other aluminum powder, and as these connections grow, electrostatic leakage occurs. The present invention is based on this knowledge and is the result of intensive research.
本発明のメタリック塗料組成物には、鱗片状アルミニウ
ム粉末と粒状アルミニウム粉末の２種類のアルミニウム
粉末が含有されている。鱗片状アルミニウム粉末は従来
用いられているものと同様のものが用いられ、その形状
は長径ａと厚ざＣとがａ／ｃ＞５の関係にある。一般に
は径が数μｍ゛〜数拾μｍ、厚さが１μｍ以下の形状を
なす。The metallic coating composition of the present invention contains two types of aluminum powder: scaly aluminum powder and granular aluminum powder. The flaky aluminum powder used is the same as that conventionally used, and its shape has a relationship between the major axis a and the thickness C such that a/c>5. Generally, it has a shape with a diameter of several μm to several tens of μm and a thickness of 1 μm or less.
本発明の最大の特徴は、粒状アルミニウム粉末を含有す
るところにある。この粒状アルミニウム粉末は第１図お
よび第２図に示すように、長径ａ１短径すおよび厚さＣ
が、ａが１００μｍ以下ａ〉以下ｃかつ１≦ａ／ｃ≦５
の関係にあるものが用いられる。長径ａが１１００ａを
超えると塗面の平滑性が損われるようになる。通常は１
〜１００μｍの粒度分布のものが用いられる。またａ／
ｃ〉５では静電リーク防止効果がほとんど見られない。The greatest feature of the present invention is that it contains granular aluminum powder. As shown in FIGS. 1 and 2, this granular aluminum powder has a major axis a1 a minor axis and a thickness C.
However, a is 100 μm or less a> or less c and 1≦a/c≦5
Those in the relationship are used. If the major axis a exceeds 1100a, the smoothness of the coated surface will be impaired. Usually 1
A particle size distribution of ~100 μm is used. Also a/
c>5 shows almost no electrostatic leakage prevention effect.
粒状アルミニウム粉末は塗料組成物中に含有されるアル
ミニウム粉末全体１００重ａ％中に３重量％以上含有さ
れることが望ましい。この吊が３重司％より少ないと静
電リーク防止効果が小さくなる。なお、この量の上限は
目的とするメタリック感などに応じて種々選択すること
ができる。It is desirable that the granular aluminum powder is contained in an amount of 3% by weight or more in 100% by weight of the total aluminum powder contained in the coating composition. If this ratio is less than 3%, the electrostatic leakage prevention effect will be reduced. Note that the upper limit of this amount can be variously selected depending on the desired metallic feel and the like.
本発明のメタリック塗料組成物を構成する他の要素とし
ては、樹脂、顔料、染料、溶剤、添加剤などがある。こ
のうちメタリック塗料組成物の大部分を占める樹脂とし
ては、アクリル樹脂、アルキド樹脂、メラミン樹脂、エ
ポキシ樹脂、イソシアネート樹脂など、目的に応じて従
来用いられている樹脂を用いることができる。また顔料
、溶剤、添加剤などの通常の塗料配合材料も、従来と同
様に、目的に応じて種々選択して用いることができる。Other elements constituting the metallic coating composition of the present invention include resins, pigments, dyes, solvents, and additives. As the resin that makes up the majority of the metallic coating composition, conventionally used resins can be used depending on the purpose, such as acrylic resin, alkyd resin, melamine resin, epoxy resin, and isocyanate resin. Also, conventional paint compounding materials such as pigments, solvents, and additives can be selected and used depending on the purpose.
［作用］
本発明の静電塗装用メタリック塗料組成物では、アルミ
ニウム粉末中に粒状アルミニウム粉末を有する。そして
静電塗装時に高電圧が印加されると、第４図に示すよう
に鱗片状アルミニウム粉末１はその鋭角部分に電荷が集
中して繋がって成長を始める。しかし鱗片状アルミニウ
ム粉末１が、含有される粒状アルミニウム粉末２と繋が
ると、粒状アルミニウム粉末２は鱗片状アルミニウム粉
末１に比べて鋭角部分が少なく、かつ丸みをおびている
ために電荷が集中せず分散する。これにより他のアルミ
ニウム粉末と繋がるのが防止され、成長がそこで停市す
ることにより静電リークが防止される。[Function] The metallic coating composition for electrostatic coating of the present invention has granular aluminum powder in the aluminum powder. When a high voltage is applied during electrostatic coating, as shown in FIG. 4, the scale-like aluminum powder 1 begins to grow as charges are concentrated at its acute angles and connected. However, when the scaly aluminum powder 1 connects with the granular aluminum powder 2 contained therein, the granular aluminum powder 2 has fewer acute angles and is rounded compared to the scaly aluminum powder 1, so the charge is not concentrated but dispersed. do. This prevents the aluminum powder from connecting with other aluminum powders and stops the growth there, thereby preventing electrostatic leakage.
［発明の効果］
寸なわら本発明のメタリック塗料組成物によれば、粒状
アルミニウム粉末ににり静電リークが防止されるので静
電塗装性に極めて（７）れでいる。またアルミニウム粉
末の形状を改良したものであるので、メタリック感、塗
装作業性などを損うことがない。さらにアルミニウム粉
末の処理などの工数も不要であるのでコスト面における
不具合も回避される。[Effects of the Invention] According to the metallic coating composition of the present invention, since electrostatic leakage is prevented by the granular aluminum powder, electrostatic coating properties are extremely improved (7). In addition, since the shape of the aluminum powder has been improved, it does not impair the metallic feel or painting workability. Furthermore, since there is no need for man-hours such as processing of aluminum powder, problems in terms of cost can also be avoided.
［実施例］
以下実施例により具体的に説明する。なお、以下にいう
部は全て重量品を意味する。[Example] The following is a concrete explanation using Examples. Note that all parts mentioned below refer to heavy items.
（実施例１）
アクリル樹脂固形分（「アクリディック４７−７１２Ｊ
大日本インキ化学工ｇ（株）製）２５゜２部、メラミン
樹脂固形分（［スーパーベッカミンＧ−８２１−６０Ｊ
大日本インキ化学工業（株）製）９部、鱗片状アルミニ
ウム粉末固形分（長径ａ ５〜５０ Ｉｌｍ Ｎ短径ｂ
１〜５０μｍ、厚さｃＱ。(Example 1) Acrylic resin solid content (“Acridic 47-712J
Dainippon Ink Chemical Co., Ltd.) 25° 2 parts, melamine resin solid content ([Super Beckamine G-821-60J
Dainippon Ink & Chemicals Co., Ltd.) 9 parts, scaly aluminum powder solid content (major axis a 5-50 Ilm N minor axis b
1 to 50 μm, thickness cQ.
１〜１μｍ１ ［アルペースト７１３ＯＮＪ束）羊アル
ミニウム（株）製）３．８部、粒状アルミニウム粉末固
形分（長径８５〜５０μｍ１短径ｂ１〜５０μｍ、厚さ
Ｃ１〜１０μｍ、０．２部、沈降防止剤（「ディスハロ
ン６９００−２０ＸＪ楠本化成（株）製）２部、酢酸エ
チル３８部、ｉ〜ルエン１７，８部、キシレン４部をデ
ィスパーにてよく攪はんして実施例１のメタリック塗料
組成物を調製した。1 to 1 μm1 [Alpaste 713ONJ bundle] manufactured by Hitsuji Aluminum Co., Ltd.) 3.8 parts, solid content of granular aluminum powder (major axis 85 to 50 μm, short axis b1 to 50 μm, thickness C1 to 10 μm, 0.2 parts, sedimentation prevention 2 parts of Dishalon 6900-20XJ manufactured by Kusumoto Kasei Co., Ltd., 38 parts of ethyl acetate, 17.8 parts of i~luene, and 4 parts of xylene were thoroughly stirred with a disper to prepare the metallic paint of Example 1. A composition was prepared.
静電塗￥ｉ殿としてＲＥＡオート静電塗装ガン（日本ラ
ンズバーグ（株）製）を用い、上記メタリック塗料組成
物を用いて５００ｍｍＸ５００ｍｍの中塗、水研を施し
たテストパネルに３０ｃｍの距ｌ！ｌｌｂ日ろ静Ｔｉ塗
装を施した。なお塗装条件は、印加電圧を−４０に、−
５０ＫＶおよび−６０にの３水準とし、塗装空気圧４ｋ
Ｏ／ｃｒｌ、吐出ｆｆ１３００ｍρ／分で行なった。そ
してテストパネルへの塗料の付善状態を目視で判定し、
さらに塗装膜厚を測定し静電塗装性の良否を表に示す。As electrostatic coating, use a REA auto electrostatic coating gun (manufactured by Nippon Landsburg Co., Ltd.) to apply the above metallic paint composition to a 500mm x 500mm intermediate coated and water-polished test panel at a distance of 30cm! llb Hirosei Ti coating was applied. The coating conditions were: the applied voltage was -40, -
Three levels: 50KV and -60, painting air pressure 4K
The discharge was performed at a discharge rate of 1300 mρ/min. Then, visually judge the adhesion of the paint to the test panel,
Furthermore, the coating film thickness was measured and the quality of electrostatic coating properties is shown in the table.
なお、表において、テストパネル表面が完全に塗装され
かつ所定の膜厚が１ｑられているものをＯ１塗装不良の
ものを×とした。In the table, test panels whose surfaces were completely coated and had a predetermined film thickness of 1q were marked as O1, and those with poor coating were marked as x.
（実施例２）
鱗片状アルミニウム粉末の配合量を３．９２部、粒状ア
ルミニウム粉末の配合量を０．０８部とすること以外は
実施例１と同様に塗料組成物を調製し、同様に静電塗装
して結果を表に示す。(Example 2) A coating composition was prepared in the same manner as in Example 1, except that the amount of scaly aluminum powder was 3.92 parts and the amount of granular aluminum powder was 0.08 parts. The results are shown in the table after electrocoating.
（従来例）
鱗片状アルミニウム粉末の配合量を４．００部とし粒状
アルミニウム粉末を用いないこと以外は実施例１と同様
に塗料組成物を調製し、同様に静電塗装して結果を表に
示す。(Conventional Example) A coating composition was prepared in the same manner as in Example 1 except that the amount of flaky aluminum powder was 4.00 parts and granular aluminum powder was not used, and electrostatic coating was performed in the same manner and the results are shown in the table. show.
（評価）
表より明らかに、全アルミニウム粉末中に粒状アルミニ
ウム粉末が５重品％含有された実施例１のメタリック塗
料組成物は、３水準の印加電圧とも静７１塗装性に優れ
ている。これは静電リークが発生しなかったことによる
ものである。また全アルミニウム粉末中に粒状アルミニ
ウム粉末が２干ｍ％含有された実施例２のメタリック塗
料組成物では、通常用いられる一６０ＫＶの印加電圧で
は静電リークが生じて静電塗装性に劣っているが、従来
例のメタリック塗料組成物に比べると一５０ＫＶの印加
電圧において静電塗装性に優れている。(Evaluation) It is clear from the table that the metallic coating composition of Example 1, in which 5 weight percent of granular aluminum powder was contained in the total aluminum powder, was excellent in static 71 paintability at all three levels of applied voltage. This is because no electrostatic leakage occurred. In addition, in the metallic paint composition of Example 2 in which 2 m% of granular aluminum powder was contained in the total aluminum powder, electrostatic leakage occurred at the commonly used applied voltage of -60 KV, resulting in poor electrostatic coating properties. However, compared to conventional metallic coating compositions, it has excellent electrostatic coating properties at an applied voltage of 150 KV.
すなわちこの結果は、実施例の塗料組成物に粒状アルミ
ニウム粉末を配合した効果によるものであることが明ら
かである。That is, it is clear that this result is due to the effect of blending the granular aluminum powder into the coating composition of the example.
第１図および第２図は粒状アルミニウム粉末を示し、第
１図はその平面図、第２図はその正面図である。第３図
は従来のメタリック塗料組成物の静電リーク現象を説明
する説明図、第４図は本発明のメタリック塗料組成物の
静電リーク現象を説明する説明図である。
１・・・鱗片状アルミニウム粉末
２・・・粒状アルミニウム粉末
特許出願人 アイシン化工株式会社
代理人 弁理士 大川 意
向 弁理士 丸山明夫
第３図
第４図1 and 2 show granular aluminum powder, FIG. 1 being a plan view thereof, and FIG. 2 being a front view thereof. FIG. 3 is an explanatory diagram for explaining the electrostatic leak phenomenon of a conventional metallic paint composition, and FIG. 4 is an explanatory diagram for explaining the electrostatic leak phenomenon of the metallic paint composition of the present invention. 1... Scaly aluminum powder 2... Granular aluminum powder Patent applicant Aisin Kako Co., Ltd. Agent Patent attorney Ichi Okawa Patent attorney Akio Maruyama Figure 3 Figure 4
Claims (2)
物であって、 該アルミニウム粉末は、長径ａ、短径ｂおよび厚さｃに
おいて、ａが１００μｍ以下ａ＞ｂ＞ｃかつ１≦ａ／ｃ
≦５の関係にある粒状アルミニウム粉末と、ａ＞ｂ＞ｃ
かつａ／ｃ＞５の関係にある鱗片状アルミニウム粉末と
、からなることを特徴とする静電塗装用メタリック塗料
組成物。(1) A metallic coating composition containing aluminum powder, wherein the aluminum powder has a major axis a, a minor axis b, and a thickness c, in which a is 100 μm or less a>b>c and 1≦a/c
Granular aluminum powder with a relationship of ≦5 and a>b>c
A metallic coating composition for electrostatic coating, characterized in that it is comprised of a scaly aluminum powder having a relationship of a/c>5.
００重量％中に３重量％以上含有されている特許請求の
範囲第１項記載の静電塗装用メタリック塗料組成物。(2) Granular aluminum powder is the whole aluminum powder 1
The metallic coating composition for electrostatic coating according to claim 1, which contains 3% by weight or more in 00% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2124387A JPS63189479A (en) | 1987-01-31 | 1987-01-31 | Metallic coating material composition for electrostatic coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2124387A JPS63189479A (en) | 1987-01-31 | 1987-01-31 | Metallic coating material composition for electrostatic coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63189479A true JPS63189479A (en) | 1988-08-05 |
Family
ID=12049612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2124387A Pending JPS63189479A (en) | 1987-01-31 | 1987-01-31 | Metallic coating material composition for electrostatic coating |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63189479A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008290055A (en) * | 2007-05-28 | 2008-12-04 | Nissan Motor Co Ltd | Repairing method of coating film and repaired coating film |
| CN107573783A (en) * | 2017-10-30 | 2018-01-12 | 惠州市华昱美实业有限公司 | A kind of metallic paint and its preparation technology |
-
1987
- 1987-01-31 JP JP2124387A patent/JPS63189479A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008290055A (en) * | 2007-05-28 | 2008-12-04 | Nissan Motor Co Ltd | Repairing method of coating film and repaired coating film |
| CN107573783A (en) * | 2017-10-30 | 2018-01-12 | 惠州市华昱美实业有限公司 | A kind of metallic paint and its preparation technology |
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