JPS6318421Y2 - - Google Patents
Info
- Publication number
- JPS6318421Y2 JPS6318421Y2 JP1980178900U JP17890080U JPS6318421Y2 JP S6318421 Y2 JPS6318421 Y2 JP S6318421Y2 JP 1980178900 U JP1980178900 U JP 1980178900U JP 17890080 U JP17890080 U JP 17890080U JP S6318421 Y2 JPS6318421 Y2 JP S6318421Y2
- Authority
- JP
- Japan
- Prior art keywords
- mol
- paper
- eva
- filter element
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 15
- 239000002131 composite material Substances 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 238000007127 saponification reaction Methods 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000000123 paper Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 239000000306 component Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- -1 Polyethylene terephthalate Polymers 0.000 description 2
- 239000008358 core component Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Description
【考案の詳細な説明】
本考案はエチレンー酢酸ビニル共重合体ケン化
物すなわち、エチレンービニルアルコール共重合
体(EVAと略記する)を一成分とする複合繊維
を含む湿式抄紙よりつくられた気体または液体を
過するフイルターエレメントに関するものでと
りわけ耐油性に優れた湿式抄紙からなるフイルタ
ーエレメントに関するものである。[Detailed description of the invention] The present invention is a gas or This invention relates to a filter element that allows liquid to pass through, and particularly to a filter element made of wet paper that has excellent oil resistance.
従来からフイルターエレメント素材としては各
種天然繊維有機化学繊維及び無機繊維からなる編
織物,不織布,紙が広く使用されている。 Conventionally, knitted fabrics, nonwoven fabrics, and paper made of various natural fibers, organic chemical fibers, and inorganic fibers have been widely used as filter element materials.
しかし耐油性の要求される分野ではガラス繊維
が主体として専ぱら使用されている。ガラス繊維
フイルターは価格的に汎用の有機化学繊維を用い
るフイルターに比べると高価であり、さらに、有
機合成繊維とのなじみが悪く両者の混用もなかな
かうまく行くものではない。 However, in fields where oil resistance is required, glass fiber is mainly used. Glass fiber filters are more expensive than filters using general-purpose organic chemical fibers, and are not compatible with organic synthetic fibers, making it difficult to mix them together.
本考案者らはこのような問題に鑑みて種々研究
をした結果、EVAを一成分とする複合繊維を含
む湿式抄紙よりなるフイルターエレメントがその
品質,製造工程共に優れたものであることを見出
した。 The inventors of the present invention conducted various studies in light of these problems and found that a filter element made of wet paper that contains composite fibers containing EVA as one component is superior in both quality and manufacturing process. .
すなわち本考案によるフイルターエレメントは
フイルター効率が高いだけでなくEVAの特性と
しての耐油性が発揮されて耐油性が良好で、各種
油中の異物を過除去することが長期に連続して
行なう事ができる。しかも、一般の不織布製フイ
ルターと異なりケーキ層の剥離性もよく、逆洗再
使用も可能である。これら性能は、繊維繊度,抄
紙条件等の選択範囲によつて任意コントロールで
きる。 In other words, the filter element according to the present invention not only has high filter efficiency, but also exhibits the oil resistance characteristic of EVA, and has good oil resistance, and can continuously remove foreign substances from various oils over a long period of time. can. Furthermore, unlike general non-woven fabric filters, the cake layer has good removability and can be backwashed and reused. These performances can be arbitrarily controlled by selecting ranges such as fiber fineness and paper making conditions.
一方本考案フイルターエレメント用の湿式抄紙
は工程において、吸水状態で湿熱接着し易すく、
また水分蒸発后は粘着トラブルが全くない。又
EVAはバインダー効果をもつているので特に他
のヒートシール性繊維を混抄しなくても又二次的
な接着工程を付与しなくても、通常の抄紙工程中
の乾燥プロセスで繊維相互の熱融着が形成され紙
は極めて強力な紙力を有する。 On the other hand, in the process of wet paper making for filter elements of the present invention, it is easy to bond with wet heat while absorbing water.
Also, there is no problem with adhesion after the water evaporates. or
Since EVA has a binder effect, it is possible to heat-fuse the fibers together during the drying process during the normal papermaking process, without having to mix other heat-sealable fibers or apply a secondary bonding process. A bond is formed and the paper has extremely strong paper strength.
本考案のEVAとは、エチレン含量が30〜70モ
ル%、酢酸ビニル部分のケン化度が98モル%以上
のエチレン・酢酸ビニル共重合体ケン化物であ
る。エチレン含量が30モル%以下では熱分解のた
めEVAを使つた熱溶融複合紡糸が任意の熱可塑
性ポリマーとの組合せで可能とは限らなくなり、
しかも融点が180℃以上で接着処理がしにくくな
る。またエチレン含量が70モル%以上ではEVA
の耐油性が急激に低下してしまうし、抄紙プロセ
スで湿熱接着しにくく、また乾熱接着では粘着し
易く、やはり好ましくない。またケン化度が98モ
ル%以下では、熱溶融複合紡糸する時にもう一方
の複合成分の選択範囲が狭まり、又繊維あるいは
紙の製造プロセスで粘着しやすい。 The EVA of the present invention is a saponified ethylene/vinyl acetate copolymer having an ethylene content of 30 to 70 mol% and a degree of saponification of the vinyl acetate portion of 98 mol% or more. When the ethylene content is below 30 mol%, thermal decomposition makes it impossible to perform hot-melt composite spinning using EVA in combination with any thermoplastic polymer.
Moreover, when the melting point is 180°C or higher, it becomes difficult to perform adhesive processing. Also, if the ethylene content is 70 mol% or more, EVA
The oil resistance of the material decreases rapidly, it is difficult to bond with wet heat during the papermaking process, and it tends to stick when bonded with dry heat, which is also undesirable. If the degree of saponification is less than 98 mol%, the selection range of the other composite component will be narrowed during hot-melt composite spinning, and it will tend to stick during the fiber or paper manufacturing process.
EVAと複合紡糸できる他の熱可塑性ポリマー
としてはポリオレフイン,ポリエステル,ポリア
ミド等の任意の溶融紡糸可能なものが用いられ
る。 Other thermoplastic polymers that can be composite-spun with EVA include polyolefins, polyesters, polyamides, and other materials that can be melt-spun.
湿式抄紙して得る紙の素材としては、本考案の
複合繊維を50重量%以上使用する。他素材として
はパルプ,麻のような天然繊維,ビニロン,エス
テル,レーヨンのような有機化学繊維,あるいは
ガラス繊維のような無機繊維と混抄してもよい。 The composite fiber of the present invention is used in an amount of 50% or more by weight as the paper material obtained by wet papermaking. Other materials may include pulp, natural fibers such as linen, organic chemical fibers such as vinylon, ester, and rayon, or inorganic fibers such as glass fiber.
抄紙及びフイルターエレメントの成形加工は公
知の装置により行なうことが可能である。 Paper making and filter element molding can be carried out using known equipment.
つぎに実施例による本考案を説明する。 Next, the present invention will be explained using examples.
実施例 1
ポリエチレンテレフタレート(PET)を芯成
分とし、エチレン含量45モル%ケン化度99.5%の
EVAを鞘成分とする、芯成分/鞘成分=70/30
(重量比)であるような複合紡糸を行ない、つい
で延伸,切断して繊度1.5dr,繊維長5mmのPET
とEVAからなる複合繊維を得、これをシヨート
カツトして製紙原材を得た。この複合繊維70重量
%及びパルプ30重量%を混合し、0.1%濃度で粘
剤としてPEO(製鉄化学製),分散剤としてゾン
デスKV(松本油脂製)を用いて分散し、通常の
短網抄紙機で混抄、140℃に設定した乾燥機を通
過させて厚さ0.5mmの紙をえた。Example 1 Polyethylene terephthalate (PET) was used as the core component, and the ethylene content was 45 mol% and the degree of saponification was 99.5%.
With EVA as the sheath component, core component/sheath component = 70/30
(weight ratio), then stretched and cut to produce PET with a fineness of 1.5 dr and a fiber length of 5 mm.
A composite fiber consisting of EVA and EVA was obtained, and this was short-cut to obtain papermaking raw material. 70% by weight of this composite fiber and 30% by weight of pulp were mixed and dispersed at a concentration of 0.1% using PEO (manufactured by Steel Chemical Co., Ltd.) as a sticky agent and ZONDES KV (manufactured by Matsumoto Yushi Co., Ltd.) as a dispersant, and then used for ordinary short net paper making. The paper was mixed in a machine and passed through a dryer set at 140°C to obtain paper with a thickness of 0.5 mm.
この紙を枠に両面に張り付け、このフイルター
エレメントを12枚組合せてフイルターを構成し、
このフイルターでA重油中にカーボンブラツクが
混合した液を過した。このとき過面積5300cm2
でカーボンブラツク吸着量が約400gまでの過
圧約0.3Kg/cm2で処理できた。 This paper is pasted on both sides of the frame, and 12 of these filter elements are combined to form a filter.
A mixture of carbon black and heavy oil A was passed through this filter. At this time, the excess area is 5300cm 2
It was possible to process the carbon black at an overpressure of approximately 0.3 kg/cm 2 up to approximately 400 g of carbon black adsorption.
これに対して従来のポリエチテル製不織布のメ
ツシユフイルターでは過圧約3.0Kg/cm2を必要
とし、過面積9000cm2でカーボンブラツク吸着量
が200gであり、前記本考案フイルターの方がは
るかに優れた処理能力と耐油耐久性があつた。 On the other hand, the conventional mesh filter made of non-woven polyethylene fabric requires an overpressure of approximately 3.0 kg/cm 2 and has an overarea of 9000 cm 2 and an adsorption amount of carbon black of 200 g, making the filter of the present invention far superior. Excellent processing ability and oil resistance.
第1図は本考案フイルターエレメントの模式図
を示す。
1……フイルター用湿式抄紙、2……取付け
枠。
FIG. 1 shows a schematic diagram of the filter element of the present invention. 1...Wet paper making for filters, 2...Mounting frame.
Claims (1)
のケン化度が98モル%以上のエチレン・酢酸ビニ
ル共重合体ケン化物と他の熱可塑性ポリマーとか
らなる複合繊維を50重量%以上含む湿式抄紙して
得た紙よりなる耐油性に優れたことを特徴とする
フイルターエレメント。 Wet-processed paper containing 50% by weight or more of composite fibers made of a saponified ethylene/vinyl acetate copolymer with an ethylene content of 30 to 70 mol% and a degree of saponification of the vinyl acetate portion of 98 mol% or more and another thermoplastic polymer. A filter element made of paper obtained by the above-mentioned process, which is characterized by its excellent oil resistance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1980178900U JPS6318421Y2 (en) | 1980-12-11 | 1980-12-11 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1980178900U JPS6318421Y2 (en) | 1980-12-11 | 1980-12-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5799716U JPS5799716U (en) | 1982-06-19 |
JPS6318421Y2 true JPS6318421Y2 (en) | 1988-05-24 |
Family
ID=29974107
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1980178900U Expired JPS6318421Y2 (en) | 1980-12-11 | 1980-12-11 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6318421Y2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016055248A (en) * | 2014-09-09 | 2016-04-21 | 株式会社クラレ | Solid-liquid separation filter material |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2389529C2 (en) * | 2004-11-05 | 2010-05-20 | Дональдсон Компани, Инк. | Filtration material (versions) and method of filtration (versions) |
JP5127533B2 (en) * | 2008-03-28 | 2013-01-23 | 株式会社クラレ | Filter and manufacturing method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS509161A (en) * | 1973-05-28 | 1975-01-30 | ||
JPS5171566A (en) * | 1974-12-19 | 1976-06-21 | Mitsubishi Rayon Co | Eaafuirutaano seizohoho |
JPS5477703A (en) * | 1977-11-29 | 1979-06-21 | Chisso Corp | Wet producing method of nonwoven fabric |
JPS551379A (en) * | 1979-01-10 | 1980-01-08 | Nippon Synthetic Chem Ind Co Ltd:The | Conjugate fiber |
-
1980
- 1980-12-11 JP JP1980178900U patent/JPS6318421Y2/ja not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS509161A (en) * | 1973-05-28 | 1975-01-30 | ||
JPS5171566A (en) * | 1974-12-19 | 1976-06-21 | Mitsubishi Rayon Co | Eaafuirutaano seizohoho |
JPS5477703A (en) * | 1977-11-29 | 1979-06-21 | Chisso Corp | Wet producing method of nonwoven fabric |
JPS551379A (en) * | 1979-01-10 | 1980-01-08 | Nippon Synthetic Chem Ind Co Ltd:The | Conjugate fiber |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016055248A (en) * | 2014-09-09 | 2016-04-21 | 株式会社クラレ | Solid-liquid separation filter material |
Also Published As
Publication number | Publication date |
---|---|
JPS5799716U (en) | 1982-06-19 |
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