JPS6317799B2 - - Google Patents
Info
- Publication number
- JPS6317799B2 JPS6317799B2 JP4612180A JP4612180A JPS6317799B2 JP S6317799 B2 JPS6317799 B2 JP S6317799B2 JP 4612180 A JP4612180 A JP 4612180A JP 4612180 A JP4612180 A JP 4612180A JP S6317799 B2 JPS6317799 B2 JP S6317799B2
- Authority
- JP
- Japan
- Prior art keywords
- potassium
- gunpowder
- whistle
- phthalate
- fireworks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003721 gunpowder Substances 0.000 claims description 12
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 6
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 claims description 6
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- GOMCKELMLXHYHH-UHFFFAOYSA-L dipotassium;phthalate Chemical compound [K+].[K+].[O-]C(=O)C1=CC=CC=C1C([O-])=O GOMCKELMLXHYHH-UHFFFAOYSA-L 0.000 claims description 5
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 3
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 3
- FRMWBRPWYBNAFB-UHFFFAOYSA-M potassium salicylate Chemical compound [K+].OC1=CC=CC=C1C([O-])=O FRMWBRPWYBNAFB-UHFFFAOYSA-M 0.000 description 3
- 229960003629 potassium salicylate Drugs 0.000 description 3
- 229960004025 sodium salicylate Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 235000010235 potassium benzoate Nutrition 0.000 description 2
- 229940103091 potassium benzoate Drugs 0.000 description 2
- 239000004300 potassium benzoate Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 229960003885 sodium benzoate Drugs 0.000 description 2
- 239000013078 crystal Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Landscapes
- Toys (AREA)
Description
【発明の詳細な説明】
本発明は、玩具用打揚げ花火の笛音火薬に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a whistle gunpowder for toy fireworks.
近年この種の打揚げ花火に花火飛走中笛音を生
ぜしめる笛音火薬を使用したものが市販されてい
る。この笛音火薬は、一般に過塩素酸カリウム、
硝石の如き酸化剤と還元剤としてのサリチル酸ナ
トリウム、サリチル酸カリウム、安息香酸ナトリ
ウム、安息香酸カリウム等のうちの１種または数
種を例えば７：３の配合割合で配合してなるもの
であつた（特公昭51−5042号参照）。しかし、サ
ルチル酸ナトリウム、安息香酸ナトリウム、安息
香酸カリウムは吸湿性があつて、湿度の高い地域
では吸湿して点火し難く、実用的でない。又、サ
ルチル酸カリウムは医薬品に使用されていて高価
ゆえ、低廉な花火となし得ない欠点があつた。 In recent years, fireworks of this kind that use whistle-sounding gunpowder, which produces a whistling sound while the fireworks are flying, have become commercially available. This whistling gunpowder is generally made of potassium perchlorate,
It was made by blending an oxidizing agent such as saltpeter with one or more of sodium salicylate, potassium salicylate, sodium benzoate, potassium benzoate, etc. as a reducing agent in a mixing ratio of, for example, 7:3 ( (See Special Publication No. 51-5042). However, sodium salicylate, sodium benzoate, and potassium benzoate are hygroscopic and difficult to ignite in areas with high humidity, making them impractical. In addition, potassium salicylate is used in medicine and is expensive, so it has the disadvantage that it cannot be used as an inexpensive firework.
本発明は前記の欠点を解消した笛音火薬の提供
を目的としている。 The object of the present invention is to provide a whistle gunpowder that eliminates the above-mentioned drawbacks.
本発明に係る笛音火薬は、過塩素酸カリウム、
硝石の如き酸化剤とフタル酸カリウム、フタル酸
水素カリウムのいずれか一方または双方の還元剤
を配合してなるものである。かかる笛音火薬にお
いては湿気に強く、特にフタル酸水素カリウムは
無水結晶であるから、水分が吸収され難い。従つ
て、かかる配合とした笛音火薬を用いた打揚げ花
火は多湿状態の下においても容易に点火できて笛
音を伴う打揚げ花火を観賞することができる。ま
た、フタル酸水素カリウム、フタル酸カリウムは
工業用原料であるから、同じ還元剤として使用さ
れている従来のサルチル酸ナトリウム、サルチル
酸カリウムのような医薬品となるものに比べて著
しく低廉であり、製品価格を大幅に低減すること
ができる。 The whistle gunpowder according to the present invention includes potassium perchlorate,
It is a mixture of an oxidizing agent such as saltpeter and a reducing agent of either potassium phthalate or potassium hydrogen phthalate, or both. Such whistling gunpowder is resistant to moisture, and in particular potassium hydrogen phthalate is anhydrous crystal, so it is difficult to absorb moisture. Therefore, fireworks using such a combination of whistle-sounding gunpowder can be easily ignited even in humid conditions, and the fireworks can be enjoyed with the whistle-sounding sound. In addition, since potassium hydrogen phthalate and potassium phthalate are industrial raw materials, they are significantly cheaper than conventional pharmaceutical products such as sodium salicylate and potassium salicylate, which are also used as reducing agents. Product prices can be significantly reduced.
以上説明した如く本発明に係る笛音火薬は、湿
気に強いので、これを用いた打揚げ花火は雨天等
湿気の多い時でも実施することができ、しかも安
価に提供できるという優れた効果を奏する。 As explained above, the whistle-sounding gunpowder according to the present invention is resistant to moisture, so it can be used to set off fireworks even in humid weather such as rainy days, and it has the excellent effect of being able to be provided at a low cost. .
次に、本発明の実施例を示すが、これらは本発
明を例示するためのものであつて、本発明に対し
なんらかの制限をするためのものではない。 Next, examples of the present invention will be shown, but these are for illustrating the present invention and are not intended to limit the present invention in any way.
実施例 １
下記の配合割合の笛音火薬を調整し、紙製パイ
プに詰めて打揚げ花火製品に仕上げたところ、多
湿状態の下で容易に点火でき、効果的な笛音を伴
う製品が得られた。Example 1 When a whistle-sounding gunpowder was prepared in the following proportion and packed into a paper pipe to create a fireworks product, a product that could be easily ignited under humid conditions and produced an effective whistle sound was obtained. It was done.
過塩素酸カリウム 65重量％
フタル酸カリウムとフタル酸水素カリウム
35重量％
実施例 ２
実施例１のものと略同様の製品が得られた。Potassium perchlorate 65% by weight Potassium phthalate and potassium hydrogen phthalate
35% by weight Example 2 A product substantially similar to that of Example 1 was obtained.
過塩素酸カリウム 65重量％ フタル酸カリウム 35重量％ 実施例 ３ 実施例１のものと略同様の製品が得られた。Potassium perchlorate 65% by weight Potassium phthalate 35% by weight Example 3 A product substantially similar to that of Example 1 was obtained.
過塩素酸カリウム 65重量％ フタル酸水素カリウム 35重量％Potassium perchlorate 65% by weight Potassium hydrogen phthalate 35% by weight
Claims (1)
化剤と還元剤よりなる笛音火薬において、還元剤
にフタル酸カリウム、フタル酸水素カリウムのい
ずれか一方または双方を用いたことを特徴とする
玩具用打揚げ花火の笛音火薬。1. A whistling gunpowder comprising an oxidizing agent for whistling gunpowder such as potassium perchlorate and saltpeter and a reducing agent, characterized by using either or both of potassium phthalate and potassium hydrogen phthalate as the reducing agent. Whistling gunpowder for toy fireworks.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4612180A JPS56145193A (en) | 1980-04-07 | 1980-04-07 | Whistling gunpowder for toy rocket firework |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4612180A JPS56145193A (en) | 1980-04-07 | 1980-04-07 | Whistling gunpowder for toy rocket firework |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56145193A JPS56145193A (en) | 1981-11-11 |
| JPS6317799B2 true JPS6317799B2 (en) | 1988-04-15 |
Family
ID=12738153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4612180A Granted JPS56145193A (en) | 1980-04-07 | 1980-04-07 | Whistling gunpowder for toy rocket firework |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56145193A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0256595U (en) * | 1988-10-13 | 1990-04-24 | ||
| CN104557352A (en) * | 2015-01-05 | 2015-04-29 | 浏阳市诚发科技有限公司 | Sulfur-free environment-friendly gun propellant |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57149892A (en) * | 1981-03-11 | 1982-09-16 | Mantsuna Shiyouten Kk | Whistling agent |
| CN109704894A (en) * | 2017-10-26 | 2019-05-03 | 湖南省醴陵市创客中小企业服务中心有限公司 | A kind of firework coating medicine |
-
1980
- 1980-04-07 JP JP4612180A patent/JPS56145193A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0256595U (en) * | 1988-10-13 | 1990-04-24 | ||
| CN104557352A (en) * | 2015-01-05 | 2015-04-29 | 浏阳市诚发科技有限公司 | Sulfur-free environment-friendly gun propellant |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56145193A (en) | 1981-11-11 |
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