JPS63161079A - Solid detergent composition - Google Patents
Solid detergent compositionInfo
- Publication number
- JPS63161079A JPS63161079A JP61310387A JP31038786A JPS63161079A JP S63161079 A JPS63161079 A JP S63161079A JP 61310387 A JP61310387 A JP 61310387A JP 31038786 A JP31038786 A JP 31038786A JP S63161079 A JPS63161079 A JP S63161079A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- solid detergent
- present
- solid
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013042 solid detergent Substances 0.000 title claims description 22
- 239000000203 mixture Substances 0.000 title claims description 14
- -1 amino acid salt Chemical class 0.000 claims description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 150000004665 fatty acids Chemical class 0.000 claims description 15
- 230000002378 acidificating effect Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 125000002252 acyl group Chemical group 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000344 soap Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 12
- 238000005187 foaming Methods 0.000 description 11
- 239000007787 solid Substances 0.000 description 9
- 229940024606 amino acid Drugs 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 6
- 239000008233 hard water Substances 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 238000000465 moulding Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 3
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229940073490 sodium glutamate Drugs 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- GMJDFXNXFYRCRD-UHFFFAOYSA-L [Na+].[Na+].CCCCCCCCCCCCOC(=O)CCC([O-])=O.CCCCCCCCCCCCOC(=O)CCC([O-])=O Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CCC([O-])=O.CCCCCCCCCCCCOC(=O)CCC([O-])=O GMJDFXNXFYRCRD-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- TYTGWHZODQKWEF-UHFFFAOYSA-N 1-o-dodecyl 4-o-sulfo butanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCC(=O)OS(O)(=O)=O TYTGWHZODQKWEF-UHFFFAOYSA-N 0.000 description 1
- XLJNWPNOVKHJFK-UHFFFAOYSA-N 2-sulfo-2-tetradecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCC(S(O)(=O)=O)(C(O)=O)CC(O)=O XLJNWPNOVKHJFK-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 241000060350 Citronella moorei Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- SXBBFOVRSQCYFE-SQKCAUCHSA-L disodium;(2s)-2-(tetradecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O SXBBFOVRSQCYFE-SQKCAUCHSA-L 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940071180 lauryl sulfosuccinate Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000932 sedative agent Substances 0.000 description 1
- 230000001624 sedative effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- IEXXLSKKBWIDAC-ZOWNYOTGSA-M sodium;(3s)-3-(dodecanoylamino)-4-hydroxy-4-oxobutanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CC(O)=O IEXXLSKKBWIDAC-ZOWNYOTGSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、固形洗浄剤に関するものであって、更に詳し
くは、皮膚に対する刺激が少なく、溶崩性（溶は崩れ）
、摩擦溶解度、使用投石ケン容器に放置した場合の付着
性（以下、付着性という）等が改良されており、使用感
が良く顔面用、身体用として好適な固形洗浄剤に関する
。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a solid detergent, and more specifically, a solid detergent that is less irritating to the skin and is dissolvable (does not disintegrate when dissolved).
The present invention relates to a solid detergent that has improved frictional solubility, adhesion when left in a stone container (hereinafter referred to as adhesion), etc., and is comfortable to use and suitable for use on the face and body.
（従来の技術）
身体用固形洗浄剤の原料は大半が脂肪酸塩系石ケンで占
められているのが現状である。しかしこの脂肪酸塩系石
ケンには次の様な欠点がある。(Prior Art) Currently, most of the raw materials for solid body cleansers are fatty acid salt soaps. However, this fatty acid salt based soap has the following drawbacks.
（ａ） 硬水中では、水不溶性のスカムが発生すると
共に、起泡力、洗浄力が著しく低下する。(a) In hard water, water-insoluble scum is generated and the foaming power and cleaning power are significantly reduced.
（ｂ）ｐＨが１０〜１１と高く、アルカリに弱い人にと
っては、好ましくない。(b) It has a high pH of 10 to 11, which is not preferable for people who are sensitive to alkalis.
これらのき点を補う石ケンとしては、中性石ケンまたは
弱酸性石ケンがある。Soaps that compensate for these drawbacks include neutral soaps and weakly acidic soaps.
例えば、中性石ケンとして、直鎖アルキルベンゼンスル
ホン酸塩や、ラウリル硫酸塩を基剤とする固形石ケンが
あるが、これらは硬水中でもスカムの発生がなく、起泡
力、洗浄力にすぐれているが、脱脂力が大きく皮膚に対
する刺激が強く、また溶崩性が大きく摩擦溶解度も高い
。For example, as neutral soaps, there are solid soaps based on linear alkylbenzene sulfonates and lauryl sulfates, but these do not form scum even in hard water and have excellent foaming and cleaning power. However, it has a high degreasing power and is highly irritating to the skin, and also has a high dissolution property and high friction solubility.
しかし同じ中性石ケンとして直鎮状アルファオレフィン
スルホン酸塩は、上記の２つと比較し、皮膚に対して刺
激が少ない。又、硬水中でもスカムを発生せず、洗浄力
、起泡力も優れているが、溶崩性が大きく摩擦溶解度が
高いという欠点がある。However, as a neutral soap, straight alpha olefin sulfonate is less irritating to the skin than the above two. In addition, it does not generate scum even in hard water and has excellent detergency and foaming power, but it has the drawback of being highly dissolvable and having high friction solubility.
一万、Ｎ−アシル酸性アミノ酸塩は、上記のものと異な
り、ｐＨは皮膚と同等の弱酸性（５〜７）であるため°
、皮膚に対する刺激が少なく、さらに硬水中での性能も
ほぼ満足のいくものである。Unlike the above, N-acyl acidic amino acid salts have a slightly acidic pH (5 to 7), which is the same as that of the skin.
It is less irritating to the skin, and its performance in hard water is almost satisfactory.
器に放置した際に、石ケン容器に付着してしまうという
問題が残されている。There remains the problem that soap sticks to the soap container when left in the container.
そのためこの種の固形洗浄剤の石ケン容器への°付着性
、溶崩性、摩擦溶解度、使用感等に閃する欠点を、改善
すべく研究が数多く行なわれているが、充分滴定し得る
結果は得られていない。Therefore, many studies have been conducted to improve the shortcomings of this type of solid detergent, such as its adhesion to soap containers, dissolution, friction solubility, and feeling of use. has not been obtained.
（発明が解決しようとする問題点）
そこで、本発明者等は、この欠点を改良せんとして鋭意
研究した結果、Ｎ−長鎖アシル酸性アミノ酸塩に持定量
のアルキルスルホコハク酸塩と高級アルコール、高級脂
肪酸とを配合することによって、Ｎ−長鎖アシル酸性ア
ミノ酸塩の特長を活かしながら、前記欠点を悉く改良し
得ると共に、優れた固形洗浄剤を工業的有利に製造し得
ることを見出し、本発明を完成した。(Problems to be Solved by the Invention) Therefore, as a result of intensive research in an attempt to improve this drawback, the present inventors have found that a certain amount of alkyl sulfosuccinate and a higher alcohol are added to an N-long chain acyl acidic amino acid salt. It has been discovered that by blending N-long chain acyl acidic amino acid salts with fatty acids, all of the above-mentioned drawbacks can be improved while making use of the characteristics of N-long chain acyl acidic amino acid salts, and an excellent solid detergent can be industrially advantageously produced. completed.
本発明の目的は、皮膚に対する刺激が少なく、溶崩性、
摩擦溶解度、使用感、付着性が改良されており、良好な
固形洗浄剤組成物を提供することにある。The purpose of the present invention is to cause less irritation to the skin, to be dissolvable,
The object of the present invention is to provide a solid detergent composition with improved frictional solubility, feeling of use, and adhesion.
（間組点を解決するための手段）
すなわち、本発明は、下記Ａ、Ｂ、Ｃ，Ｄ、Ｅの５成分
を含む固形洗浄剤組成物である。(Means for solving the interpolation point) That is, the present invention is a solid detergent composition containing the following five components A, B, C, D, and E.
（Ａ）Ｎ−長鎖アシル酸性アミノ酸塩： ４０〜７５重
五１（１／ａの）アルキルスルホコハク酸塩：１０〜４
６重妃％（Ｃ）高級アルコール ： ２〜２
０重量％（Ｄ）高級脂肪酸 ＝ ２〜２０
１急％（ト）水 ： １〜１８
重量％本発明でＡ成分として使用するＮ−長鎖アシル酸
性アミノ酸塩は、下記の一般式Ｃ１）、 （２）で表わ
される化合物が好ましく、該組成物中の飢は４０〜７５
重魚％である。(A) N-long chain acyl acidic amino acid salt: 40-75 51 (1/a) alkyl sulfosuccinate: 10-4
6% (C) Higher alcohol: 2-2
0% by weight (D) higher fatty acid = 2-20
1 steep% (g) water: 1-18
Weight% The N-long chain acyl acidic amino acid salt used as component A in the present invention is preferably a compound represented by the following general formula C1) or (2), and the starvation content in the composition is 40 to 75%.
Heavy fish%.
ＣＨ９
Ｒ−Ｎ −ＣＨＣＯＯＭ −（２）
（式中、Ｒは炭素数１２〜１８のアルキル基またはアル
ケニル基で、ＸはＣＨ２ＣＨ２Ｃ００Ｍまたは水素原子
、Ｍは水素原子、アルカリ金属、ＮＨ４又はアルカノー
ルアミンより誘導されるカチオンである。）
Ｂ成分として使用するアルキルスルホコハク酸塩は、下
記の一般式（３）で表わされる化合物が好ましく、その
−他または二種以上が組合せて使用され、該組成物中の
量は１０〜４６重籏％である。CH9 RN -CHCOOM -(2)
(In the formula, R is an alkyl group or alkenyl group having 12 to 18 carbon atoms, X is CH2CH2C00M or a hydrogen atom, and M is a cation derived from a hydrogen atom, an alkali metal, NH4, or an alkanolamine.) As component B The alkyl sulfosuccinate used is preferably a compound represented by the following general formula (3), and others or a combination of two or more are used, and the amount in the composition is 10 to 46% by weight. .
Ｒ−ＣＨ２−０−Ｃ−ＣＨ−Ｃｋｌｚ −ＣＯＯＭｔ
（３）５０３Ｍ２
（上記式中でＲは、炭素数１２〜１４のアルキル基また
はアルケニル基で、Ｍｌ ＋ Ｍ２は、アルカリ金属、
ＮＨ４またはアルカノールアミンから誘導されるカチオ
ンである。）
Ｃ成分として使用する高級アルコールは炭素数が１２〜
２２の飽和脂肪族アルコールが好ましく、その一種また
二種以上組合せて使用され、該組成物中の量は２〜２０
重二％である。２重量％よりも少ないと使用感９石ケン
容器からの剥離性（付着性）９作業性（型離れ）、溶筋
性、摩擦溶解度がわるくなり、２０重量％よりも多くな
ると、使用感、起泡力９作業性（成型性）がわるくなる
ので好ましくない。R-CH2-0-C-CH-Cklz-COOMt
(3) 503M2 (In the above formula, R is an alkyl group or alkenyl group having 12 to 14 carbon atoms, Ml + M2 is an alkali metal,
It is a cation derived from NH4 or an alkanolamine. ) The higher alcohol used as component C has 12 or more carbon atoms.
22 saturated aliphatic alcohols are preferred, and one or more of them are used in combination, and the amount in the composition ranges from 2 to 20
It is 2%. If it is less than 2% by weight, the feeling of use will be poor.9 The peelability (adhesiveness) from the soap container will be poor. Foaming power 9: Unfavorable because workability (moldability) deteriorates.
またＤ成分の高級脂肪酸は、総炭素数が１２〜２２の飽
和脂肪酸が好ましく、その一種または二種以上が組合せ
て使用され、該組成物中の瓜は２〜２０重量％である。Further, the higher fatty acid of component D is preferably a saturated fatty acid having a total carbon number of 12 to 22, and one or more of these are used in combination, and the amount of melon in the composition is 2 to 20% by weight.
２重量％よりも少ないと、使用感９石ケン容器からの剥
離性（付；１性）、゛溶崩性、摩擦溶解度がわるくなり
、２０重１％よりも多くなると、使用感、起泡力９作業
性（成型性。If it is less than 2% by weight, the feeling of use will be poor.The peelability from the soap container (adhesive; 1), disintegration, and friction solubility will be poor; if it is more than 20% by weight, the feeling of use and foaming will be poor. Power 9 Workability (Moldability.
型離れ）がわるくなるので好ましくない。This is not preferable because it will cause a problem with mold release.
本発明の組成物を固形成型するためには、Ｅ成分である
水分を１〜１８重怠％必要とする。水の添加により組成
物は可型化され、ロール混線、プロラダー押出し、型打
成型の操作を容易にする。In order to form the composition of the present invention into a solid form, 1 to 18 weight percent of water, which is component E, is required. The addition of water renders the composition moldable, facilitating operations such as roll crossing, pro-ladder extrusion, and stamping.
水分の配合１は前記のＡ成分、Ｂ成分、更には後で述べ
る任意成分の種類および配合量を変えることが必要であ
るが、配合量が１８％を超えると、組成物は軟らかくな
り、固形物の成型が困難となるので好ましくない。For moisture formulation 1, it is necessary to change the types and amounts of the above-mentioned A component and B component as well as optional components described later, but if the amount exceeds 18%, the composition will become soft and solid. This is not preferable because it makes it difficult to mold the product.
尚、使用目的（必要）に応じて、本発明の固形顔料、染
料＋ ｐＨ調整剤、金属イオン封鎖剤、や皮膚にマイ
ルドな、前記のアルキルスルホコハク酸塩以外のアニオ
ン界面活性剤（炭素数１２〜２８の１ｌｉｉ１鎮状アル
フアオレフインスルホン酸塩。Depending on the purpose of use (required), the solid pigment of the present invention, dye + pH adjuster, metal ion sequestering agent, anionic surfactant (carbon number 12) that is mild to the skin and other than the alkyl sulfosuccinate mentioned above ~28 1lii1 sedative alpha olefin sulfonate.
両性界面活性剤（イミダシリン型、ベタイン型。Ampholytic surfactants (imidacillin type, betaine type.
置換アミノ酸型）、高級脂肪酸アルカノールアミド（高
級脂肪酸モノエタノールアミド、高級脂肪酸ジェタノー
ルアミド等）、その他の油性物質（ラノリン、流動パラ
フィン、固形パラフィン等）等を本発明の前記効果を阻
害しない＄５囲内で、併用配合することができる。Substituted amino acid type), higher fatty acid alkanolamide (higher fatty acid monoethanolamide, higher fatty acid jetanolamide, etc.), other oily substances (lanolin, liquid paraffin, solid paraffin, etc.), etc. that do not inhibit the above-mentioned effects of the present invention $ 5 They can be combined within the range.
本発明の固形洗浄剤の製造方法としては、Ｎ−長鎖アシ
ル酸性アミノ酸塩と、アルキルスルホコハク酸塩と高級
アルコールと高級脂肪酸と、必要に応じて前述の任意成
分とを、水分の共存状態で必要とあらば加温しながら混
合し、乾燥後、ロールおよびプロラダーを用いて、混練
し、押出し、型打ちする機械練り製造方式が一般的であ
るが、枠線り方式によっても製造することができる。The method for producing the solid detergent of the present invention involves mixing an N-long chain acyl acidic amino acid salt, an alkyl sulfosuccinate, a higher alcohol, a higher fatty acid, and optionally the above-mentioned optional components in the coexistence of water. The most common method is to mix with heating if necessary, and after drying, knead, extrude, and mold using rolls and a pro-ladder, but it can also be manufactured by a frame-forming method. can.
（本発明の効果） 本発明の固形洗浄剤は、 （イ）硬水、軟水のいずれにおいても良好な起泡力。(Effects of the present invention) The solid detergent of the present invention is (a) Good foaming power in both hard and soft water.
洗浄力を発揮し、水不溶性のスカムを発生しない０
（ロ） ｐＨが弱酸性〜中性で皮膚に対してマイルドで
あって、皮膚刺激がなく、使用時のぬるつきＱゝ゛低減
し、しかも使用感が良く使用後の皮膚にしっとりとした
感触を与える。Demonstrates cleaning power and does not generate water-insoluble scum (B) pH is weakly acidic to neutral, mild to the skin, does not irritate the skin, reduces slimy Qゝ゛ when used, and It is easy to use and leaves the skin feeling moisturized after use.
？今 従来の合成固形洗浄剤に比べ、溶崩性が小さく、
ＪＪ擦溶解度も低いが、使用に際しては適度に溶ける。? Compared to conventional synthetic solid detergents, it is less soluble and
JJ has a low solubility, but dissolves appropriately when used.
に）使用後、石ケン箱の中や、タイル上等の平滑面の上
に放置しても強く付着することがない。) After use, it will not stick strongly even if left in a soap box or on a smooth surface such as a tile.
（ホ）製造時の作業性（成型性、型崩れ）が良く、製造
が極めて容易である。(e) Workability during manufacturing (moldability, deformation) is good, and manufacturing is extremely easy.
（実施例）
次に実施例と比較例を示して本発明の構成と効実用テス
ト（皮膚への刺激、使用感、石ケン容器からの剥離性）
、の試験方法について説明する。(Example) Next, Examples and Comparative Examples will be shown to show the structure of the present invention and practical tests of effectiveness (skin irritation, feeling of use, removability from soap containers).
We will explain the test method for .
■摩擦溶屏度：
ＪＩＳ−に３３０４−１９５６に準じて行なった０
■溶崩性（Ｘ）
固形洗浄剤を２０℃の水中に２時間つるして浸漬した後
のふやけ部分をスパチュラで削りとり重量変化を％に示
した。■Friction dissolution: 0 according to JIS-3304-1956 ■Dissolution (X) Suspend the solid detergent in water at 20°C for 2 hours, then scrape off the softened part with a spatula and measure the weight. Changes are expressed in %.
■起泡力
ロスマイルス法に準じて行なった。（可動濃度０．２５
％、４０℃）
■実用テスト
女子２０人（パネラ−）が固形洗浄剤を１週間連続使用
した場合の、皮膚への刺激性、使用感（しっとり感、さ
っばり感等）９石ケン容器からの剥離性（石ケン容器へ
の付着性）の良否を判断してアンケートに答え、その評
価を以下のように判定した。■Foaming power It was carried out according to the Ross Miles method. (Movable density 0.25
%, 40℃) ■Practical test 20 women (panelists) used a solid detergent for one week continuously, and the skin irritation and feeling (moist feeling, light feeling, etc.) were evaluated from 9 soap containers. The quality of the removability (adhesiveness to the soap container) was judged and answered in a questionnaire, and the evaluation was determined as follows.
評価基準 評価記号
良いと答えた人が１８Å以上の場合・・・・・・ ◎／
ｌ ／／ が１４〜１７人の場合・・・ Ｏ〃
〃 が８人〜１８人の場合・・・ △〃 〃 が７
Å以下の場合・・・・・・・・・ ×■作巣性：
固形洗浄剤の製造時（成型時）の成型のし易さくパーの
しまり）、石ケン金型の型層れの良否を熟練技術者が判
定した。Evaluation criteria If the number of people who answered that the evaluation symbol is good is 18 Å or more... ◎/
If l // is 14 to 17 people... O〃
If 〃 is 8 to 18 people... △ 〃 is 7
Å or less・・・・・・ × ■Nest-building property: Ease of molding and tightness of par during manufacturing of solid cleaning agent (when molding), quality of mold layering of soap mold was judged by a skilled engineer.
実施例Ｉ
Ｎ−混合脂肪酸アシル−し−グルタミン酸ナトリウム（
Ｎ−ラウロイル−Ｌ−グルタミン酸ナトリウムとＮ−ミ
リストイル−し−グルタミン酸ナトリウムとの等景況合
物）５０重量％、ラウリルコハク酸二ナトリウム２０重
′！に％、セチルアルコール５ＭＭ％、ステアリルアル
コール７重量％、ステアリン酸ｔｏｗｎ％および水８重
量％を小型ロールで充分に混練し、次いで口金を４５℃
に保った小型押出機で棒状に押出して、型打機で成型し
て、本発明の固形洗浄剤を得た。Example I Sodium N-mixed fatty acid acyl-glutamate (
Equivalent compound of sodium N-lauroyl-L-glutamate and sodium N-myristoyl-glutamate) 50% by weight, disodium lauryl succinate 20% by weight! %, cetyl alcohol 5 MM%, stearyl alcohol 7% by weight, stearic acid town% and water 8% by weight were thoroughly kneaded using a small roll, and then the nozzle was heated at 45°C.
The solid detergent of the present invention was obtained by extruding it into a rod shape using a small extruder maintained at a temperature of 100 mL and molding it using a molding machine.
比較例１
次に、比較のために、ラウリルコハク酸二ナトリウムを
使用せずかつＮ−混合脂肪酸アシル−Ｌ−グルタミン酸
ナトリウム７０重危％を使用する他は、実施例１の本発
明と同様に行なって、比較の固形洗浄剤を得た。Comparative Example 1 Next, for comparison, the same procedure as in the present invention of Example 1 was carried out except that disodium lauryl succinate was not used and 70% sodium N-mixed fatty acid acyl-L-glutamate was used. A comparative solid cleaning agent was obtained.
これらの固形洗浄剤について前記の如く試験した結果を
第１表に示した。Table 1 shows the results of testing these solid detergents as described above.
第 １ 表
第１表の結果からも明らかなように、本発明の固形洗浄
剤は、溶崩性、摩擦溶解度１石ケン容器から剥離性、＃
換起泡力、使用感において、比較品よりも優れている。Table 1 As is clear from the results in Table 1, the solid detergent of the present invention has disintegration properties, frictional solubility 1, peelability from soap containers, #
It is superior to comparative products in terms of foaming power and feeling of use.
実施例２〜５および比較例２〜５
後記第２表に示す処方で実施例１と同様に行なって、実
施例２〜５および比較例２〜５の各固形洗浄剤を得た。Examples 2 to 5 and Comparative Examples 2 to 5 Solid cleaning agents of Examples 2 to 5 and Comparative Examples 2 to 5 were obtained in the same manner as in Example 1 using the formulations shown in Table 2 below.
その試験結果を第２表に示した。The test results are shown in Table 2.
第２表より明らかな通り、実施例２〜５に示す本発明の
組成物は、比較例２に示すＮ−混合脂肪酸アシル−し−
グルタミン酸ナトリウムのみを成型したものと比べ溶崩
性、摩擦溶解度、帯書起泡力、使用感１石ケン容器から
の剥離性において大巾に改良されている。As is clear from Table 2, the compositions of the present invention shown in Examples 2 to 5 are the same as those shown in Comparative Example 2.
Compared to a molded product containing only monosodium glutamate, it has greatly improved dissolution properties, frictional solubility, foaming power, ease of use, and removability from soap containers.
またラウリルスルホコハク酸二ナトリウムのみを配合し
た比較例３および高級アルコールのみを配合した比較例
５および高級脂肪酸のみを配合した比較例４では、作業
性、摩該溶解度、使用感。Furthermore, Comparative Example 3 in which only disodium lauryl sulfosuccinate was blended, Comparative Example 5 in which only higher alcohol was blended, and Comparative Example 4 in which only higher fatty acid was blended had poor workability, abrasive solubility, and feeling of use.
が無配合の比較例２よりもやや良くなってはいるが、不
充分であり、本発明のアルキルスルホコハク酸塩および
Ｎ−長鎖アシル酸性アミノ酸塩に高級アルコールと高級
脂肪酸との両者を組合せて併用する場合（本発明）の作
用効果は顕著であることを示している。また比較例６〜
７から、高級アルコールや高級脂肪酸の配合呈が２０ｍ
ｍ％を超えると、作業性、＃＃＃起泡力右よび使用感が
低下することが明白である。Although it is slightly better than Comparative Example 2 without the addition, it is still insufficient. It is shown that the effect when used in combination (the present invention) is remarkable. Also, Comparative Example 6~
From 7, the combination of higher alcohols and higher fatty acids is 20m
It is clear that when the amount exceeds m%, workability, foaming power, and feeling of use deteriorate.
実施例６
Ｎ−混合脂肪酸アシル−し−グルタミン酸ナトリウム４
５重試％、ラウリルスルホコハク酸二カブリセリン１．
０重量％、ラウリン酸ジエタールアミド５ム駕％、酸化
チタン０．１５５重量、香料０．５重量％、エデト酸四
ナトリウム４水塩０．１恵量％、精製水１０．２５重量
％を配合し実施例１と同様に成型して本発明の固形洗浄
剤を得た。Example 6 N-mixed fatty acid acyl-sodium glutamate 4
5% test, dicabrycerin lauryl sulfosuccinate 1.
0% by weight, 5% by weight of diethalamide lauric acid, 0.155% by weight of titanium oxide, 0.5% by weight of fragrance, 0.1% by weight of tetrasodium edetate tetrahydrate, 10.25% by weight of purified water. The solid detergent of the present invention was obtained by blending and molding in the same manner as in Example 1.
実施例７
Ｎ−混合脂肪酸アシル−し−グルタミン酸ナトリウム５
０重量％、ミリスチルスルホコハク酸二量％、ポリエチ
レングリコール６０００（平均分子量６０００）５重量
％、酸化チタン０．１５重量％、香料０．５重量％、エ
デト酸四ナトリウム４水塩０．１ｆｉｆｆｉ％、精製水
６．２５重量％を配合し、実施例１と同様に成型して本
発明の固形洗浄剤を得た。Example 7 N-mixed fatty acid acyl-sodium glutamate 5
0% by weight, myristyl sulfosuccinic acid 2%, polyethylene glycol 6000 (average molecular weight 6000) 5% by weight, titanium oxide 0.15% by weight, fragrance 0.5% by weight, edetate tetrasodium tetrahydrate 0.1fiffi%, 6.25% by weight of purified water was blended and molded in the same manner as in Example 1 to obtain a solid detergent of the present invention.
実施例８
Ｎ−ラウロイル−Ｌ−アスパラギン酸モノナトリウム４
０重三％、Ｎ−ステアロイル−Ｌ−グルタミン酸カリウ
ム１５重量％、ラウリルスルホコハク酸二ナトリウム１
５重量％、ステアリルアルコール１０重量％、ステアリ
ン酸５重短％、ベヘニルアルコール１重２％、ミリスチ
ルアルコール１重量％、セラノール６重鍾％、酸化チタ
ン０．１５重量％、香料０．５型皿％、エデト酸四ナト
リウム４水塩０．１ ｉ量％、精製水６．２５重量％を
配合し、実施例１と同様に成型して、本発明の固形洗浄
剤を得た。Example 8 Monosodium N-lauroyl-L-aspartate 4
3% by weight, potassium N-stearoyl-L-glutamate 15% by weight, disodium lauryl sulfosuccinate 1% by weight
5% by weight, stearyl alcohol 10%, stearic acid 5%, behenyl alcohol 1% 2%, myristyl alcohol 1%, seranol 6%, titanium oxide 0.15%, fragrance 0.5%. , 0.1 i weight % of tetrasodium edetate tetrahydrate, and 6.25 weight % of purified water were blended and molded in the same manner as in Example 1 to obtain a solid detergent of the present invention.
実施例９
Ｎ−混合脂肪酸アシル−し−グルタミン酸ナトリウム４
０重量％、ラウリルスルホコハク酸二ナトリウム２８重
量％、ステアリルアルコール７重景％、ヤシ油アルキル
Ｎ−カルボキシエチルＮ −ヒドロキシエチルイミダツ
リウムベタインナトリウム８重量％、ミリスチン酸１重
急％、ステアリン酸６重量％、ベヘニン酸１重量％、セ
ラノール５重λ％、酸化チタン０，１５重量％、香料０
．５重量％、エデト酸四ナトリウム４水塩０．１重量％
、精製水８．２５重量％を１６合し、実施例１と同様に
成型して、本発明の固形洗浄剤を得た。Example 9 N-mixed fatty acid acyl-sodium glutamate 4
0% by weight, 28% by weight of disodium lauryl sulfosuccinate, 7% by weight of stearyl alcohol, 8% by weight of coconut oil alkyl N-carboxyethyl N-hydroxyethylimidatulium betaine sodium, 1% myristic acid, 6% by weight of stearic acid Weight %, behenic acid 1 weight %, seranol 5 weight %, titanium oxide 0.15 weight %, fragrance 0
．． 5% by weight, edetate tetrasodium tetrahydrate 0.1% by weight
and 8.25% by weight of purified water were combined and molded in the same manner as in Example 1 to obtain a solid detergent of the present invention.
前記の実施例６〜実施例９で得られた、本発明の固形洗
浄剤は、何れも実施例１〜５と同様に皮膚への刺激が少
なく（◎）、溶崩性が５．０〜６．２の範囲内で小さく
、摩擦溶解度は４３〜４８で低く、また硬水中の起泡力
、洗浄力も充分であり、石ケン容器への付着性も改善さ
れている他使用時の感触（特にぬるつき感）が大幅に改
善出来、使用後ゝ−一。The solid detergents of the present invention obtained in Examples 6 to 9 above all had little irritation to the skin (◎) as in Examples 1 to 5, and the dissolution properties were 5.0 to 5.0. It is small within the range of 6.2, its friction solubility is low at 43-48, and it has sufficient foaming and cleaning power in hard water, and has improved adhesion to soap containers. In particular, the slimy feeling (slimy feeling) was significantly improved, and after using it.
Claims (1)
剤組成物。 （Ａ）Ｎ−長鎖アシル酸性アミノ酸塩：４０〜７５重量
％ （Ｂ）アルキルスルホコハク酸塩：１０〜４６重量％ （Ｃ）高級アルコール：２〜２０重量％ （Ｄ）高級脂肪酸：２〜２０重量％ （Ｅ）水：１〜１３重量％(1) A solid detergent composition containing the following five components A, B, C, D, and E. (A) N-long chain acyl acidic amino acid salt: 40-75% by weight (B) Alkyl sulfosuccinate: 10-46% by weight (C) Higher alcohol: 2-20% by weight (D) Higher fatty acid: 2-20% by weight Weight% (E) Water: 1-13% by weight
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61310387A JPS63161079A (en) | 1986-12-25 | 1986-12-25 | Solid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61310387A JPS63161079A (en) | 1986-12-25 | 1986-12-25 | Solid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63161079A true JPS63161079A (en) | 1988-07-04 |
| JPH0543000B2 JPH0543000B2 (en) | 1993-06-30 |
Family
ID=18004644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61310387A Granted JPS63161079A (en) | 1986-12-25 | 1986-12-25 | Solid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63161079A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359099A (en) * | 1989-07-28 | 1991-03-14 | Kawaken Fine Chem Co Ltd | Improved solid detergent |
| JPH0450300A (en) * | 1990-06-15 | 1992-02-19 | Kanebo Ltd | Solid cleaning agent composition |
| JPH1180800A (en) * | 1997-09-01 | 1999-03-26 | Nippon Soda Co Ltd | Slightly water-soluble solid composition and its production |
| WO2003010274A1 (en) * | 2001-07-23 | 2003-02-06 | Unilever Plc | Skin cleansing bar with low mush |
| JP2003183152A (en) * | 2001-12-21 | 2003-07-03 | Kanebo Ltd | Creamy cleansing preparation for skin |
| JP2005325244A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Solid cleanser composition |
| JP2005325243A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Cleanser composition |
-
1986
- 1986-12-25 JP JP61310387A patent/JPS63161079A/en active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359099A (en) * | 1989-07-28 | 1991-03-14 | Kawaken Fine Chem Co Ltd | Improved solid detergent |
| JPH0450300A (en) * | 1990-06-15 | 1992-02-19 | Kanebo Ltd | Solid cleaning agent composition |
| JPH1180800A (en) * | 1997-09-01 | 1999-03-26 | Nippon Soda Co Ltd | Slightly water-soluble solid composition and its production |
| WO2003010274A1 (en) * | 2001-07-23 | 2003-02-06 | Unilever Plc | Skin cleansing bar with low mush |
| JP2003183152A (en) * | 2001-12-21 | 2003-07-03 | Kanebo Ltd | Creamy cleansing preparation for skin |
| JP2005325244A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Solid cleanser composition |
| JP2005325243A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0543000B2 (en) | 1993-06-30 |
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