JPS63158242A - Vibration-damping steel plate having excellent weldability - Google Patents

Vibration-damping steel plate having excellent weldability

Info

Publication number
JPS63158242A
JPS63158242A JP61197038A JP19703886A JPS63158242A JP S63158242 A JPS63158242 A JP S63158242A JP 61197038 A JP61197038 A JP 61197038A JP 19703886 A JP19703886 A JP 19703886A JP S63158242 A JPS63158242 A JP S63158242A
Authority
JP
Japan
Prior art keywords
steel plate
iron
resin
welding
damping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61197038A
Other languages
Japanese (ja)
Inventor
東 光郎
加藤 昭年
榊原 洋史
竹内 玉行
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP61197038A priority Critical patent/JPS63158242A/en
Publication of JPS63158242A publication Critical patent/JPS63158242A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は溶接性にすぐれた制振鋼板に関するものである
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a damping steel plate with excellent weldability.

(従来の技術) 近年、自動車、建材、家電製品等て使用状態に於ける静
粛性の要求か高まってきた。実用条件における振動抑制
の具体的方法としては種々考えられるが、有力な手段と
して振動発生源と振動授受側の間に高抵抗の振動減衰部
を設ける方法かある。このために鋼板間に粘りi性特性
を有する樹脂を挟んだ、いわゆるサンドイッチ型(また
は拘束型)の制振鋼板か、かかる用途に対して一部採用
されている。
(Prior Art) In recent years, there has been an increasing demand for quiet operation of automobiles, building materials, home appliances, etc. Various methods can be considered as specific methods for suppressing vibration under practical conditions, but one effective method is to provide a high-resistance vibration damping section between the vibration source and the vibration transmitting/receiving side. For this reason, so-called sandwich-type (or restraint-type) vibration damping steel plates, in which a resin having a sticky characteristic is sandwiched between steel plates, are partially used for such applications.

振動抑制能に優れた制振性樹脂は適正な粘弾性特性を当
該温度域て有しており、外部から印加された振動を樹脂
構成分子のズリ、その他の変形により熱エネルギー等に
変換、放出し振動を効果的に抑制するものである。しか
しこれらの樹脂は。
The vibration-damping resin, which has excellent vibration-suppressing ability, has appropriate viscoelastic properties in the relevant temperature range, and converts externally applied vibrations into thermal energy, etc. through shearing of resin constituent molecules and other deformation, and releases it. This effectively suppresses vibration. But these resins.

一般の樹脂と全く同様に冷延鋼板、各種めっき鋼板に比
して導電性か低いためにスポット溶接、シーム溶接、プ
ロジェクション溶接等の電気抵抗溶接が困難で、実用化
にあたって最大の問題であった。
Just like general resin, it has lower conductivity than cold-rolled steel sheets and various plated steel sheets, making it difficult to perform electric resistance welding such as spot welding, seam welding, and projection welding, which was the biggest problem in putting it into practical use. .

この問題を解決する方法として、樹脂層中に導電性物質
、例えば鉄粉、ステンレス粉、グラファイト粉等を分散
せしめて溶接時に導電回路を形成せしめる方法(特開昭
57−1488411号、57−183580号)、鋼
板に凹凸をつけて電極チップによる加圧時に表裏鋼板が
容易に接触して導電回路を形成する方法、等が提案され
ている。
A method to solve this problem is to form a conductive circuit during welding by dispersing conductive substances such as iron powder, stainless steel powder, graphite powder, etc. A method has been proposed in which the front and back steel plates easily come into contact with each other when pressure is applied by an electrode tip by forming irregularities on the steel plate to form a conductive circuit.

(発明が解決しようとする問題点) 制振鋼板の溶接性能の付与は基本的には上記手段により
良好な抵抗溶接が可能であるが、溶接安定性について仔
細に調査すると、1枚の制振鋼板の中でも溶接性能が冷
延鋼板並に良好な部分と、溶接時にスパークを特に生じ
易い部分、あるいは電極チップの溶着が生じる部分、甚
だしい場合には通電不能の部分が生じる場合のある事が
確認された。これらの溶接不良部分は被溶接材の極く一
部に生じる現象であるが、一般に広く採用されている自
動連続溶接プロセスにおいては、致命的な問題になる0
本発明はこの局部的溶接欠陥を有利に解決したものであ
る。
(Problems to be Solved by the Invention) Basically, it is possible to impart good welding performance to vibration-damping steel plates by using the above-mentioned means, but a detailed investigation of welding stability reveals that a single vibration-damping steel plate It has been confirmed that there are parts of the steel plate whose welding performance is as good as that of cold-rolled steel sheets, and parts where sparks are particularly likely to occur during welding, parts where the electrode tip welds, and in extreme cases, parts where it is impossible to conduct electricity. It was done. These welding defects are a phenomenon that occurs in only a small part of the material to be welded, but they can become a fatal problem in the automatic continuous welding process that is generally widely adopted.
The present invention advantageously solves this localized welding defect.

(問題点を解決するための発明の概要)溶接安定性を確
保する上での第一の要件は樹脂の厚み、導電物質のサイ
ズ、形状、添加比率或いは鋼板表面形状の均一安定性に
あるが、これは従来技術の範囲で対応出来る。しかしこ
れのみでは不十分な場合があり、本発明はかかる点にお
いて本発明者等の研究の中から完成したもので新規且つ
有益な技術を提示するものである。すなわち。
(Summary of the invention to solve the problem) The first requirement for ensuring welding stability is the thickness of the resin, the size, shape, and addition ratio of the conductive material, and the uniformity and stability of the surface shape of the steel plate. , this can be handled within the scope of conventional technology. However, this alone may not be sufficient, and the present invention has been completed through research by the present inventors in this respect, and presents a new and useful technique. Namely.

本発明者等は、溶接不良部を仔細に調査しその原因を調
査した結果、従来技術ベースの諸特性は異常なくても、
溶接不良が発生する場合が意外に多い事を確認した。そ
してこの原因は導電性物質を含む樹脂層と鋼板表面との
間のミクロ的空隙によるものであり、比較的高粘度の樹
脂を適用した場合、又は導電性物質のサイズが樹脂膜厚
の0.9倍以下の場合に生じ易い事、更に表皮に冷延鋼
板を用いた場合は、かかるミクロ的空隙を相対的に生じ
易い事を見出し、かつ、このミクロ的空隙は制振鋼板を
例えば180℃X2G分加熱する等、熱負荷をかけた後
冷却する際に生じる場合のある事も確認した。
The inventors of the present invention have carefully investigated defective welding areas and investigated the causes thereof.
It was confirmed that welding defects occur in a surprising number of cases. This is caused by microscopic voids between the resin layer containing the conductive substance and the surface of the steel plate, and when a relatively high viscosity resin is used, or the size of the conductive substance is 0.05% of the resin film thickness. We found that such micro-voids are relatively likely to occur when the damping steel plate is heated to 180°C or less when the damping steel plate is heated to 180°C or less. It has also been confirmed that this may occur when cooling after applying a heat load such as heating for X2G.

この解決方法として、樹脂と鋼板表面との親和性を高く
する事が有効で、具体的にはこの間の樹脂のヌレ性を良
くする事が極めて重要である事が判明した0図面には不
飽和ポリエステル樹脂を用いた場合の樹脂〜各種鋼板間
のヌレ性を調べた結果を示す0図より鉄−亜鉛合金めっ
き鋼板(図の掲示試料は鉄濃度12Xの鉄−溶融亜鉛合
金めっき鋼板の場合)のヌレ性が良い事がわかる。この
理由は鉄−亜鉛合金めっき鋼板の表面が冷延鋼板、亜鉛
めっき鋼板等に比して相対的に多孔質であり、したがっ
て見掛けの表面積に対する真の表面積が大きいため、樹
脂の表面拡がり性が良くなったものと思われる。実施例
として後に示す溶接安定性試験結果においても、鉄−亜
鉛合金めっき鋼板の有利性は明白である。
As a solution to this problem, it is effective to increase the affinity between the resin and the steel sheet surface. Specifically, it has been found that it is extremely important to improve the wetting properties of the resin during this time. Figure 0 shows the results of investigating the wettability between resin and various steel plates when polyester resin is used. Iron-zinc alloy plated steel plate (The sample shown in the figure is an iron-zinc alloy plated steel plate with an iron concentration of 12X) It can be seen that the wettability is good. The reason for this is that the surface of iron-zinc alloy plated steel sheets is relatively porous compared to cold-rolled steel sheets, galvanized steel sheets, etc., and the true surface area is larger than the apparent surface area. It seems to have gotten better. The advantages of iron-zinc alloy plated steel sheets are also evident in the welding stability test results shown later as examples.

本発明は、かかる見地から少なくとも制振性樹脂と接触
する2枚の鋼板面の片側に鉄−亜鉛合金めっき層を配置
することを基本にするものである。制振性樹脂と接する
2枚の鋼板表面が共に鉄−亜鉛合金めっきである事が最
も望ましいが。
From this point of view, the present invention is based on disposing an iron-zinc alloy plating layer on at least one side of the surfaces of the two steel plates that come into contact with the damping resin. It is most desirable that the surfaces of the two steel plates in contact with the damping resin are both plated with iron-zinc alloy.

例えば片側にのみ鉄−亜鉛合金めっきを配し、他面に冷
延鋼板を配しても、両面共冷延鋼板のみから成り立つ構
成に比して、大幅に溶接安定性が向上する。制振性樹脂
に接触する面と反対面の表面性状については本発明で特
に規定するものでないが、鉄−亜鉛合金めっき鋼板の製
造の容易さから表裏同種のめっきを行うか、或いは樹脂
と接する面にのみ鉄−亜鉛合金めっきを配し、他面は冷
延鋼板の表面を得る片面めっき方式の鋼板が有利に適用
出来る。
For example, even if iron-zinc alloy plating is applied only to one side and cold-rolled steel plate is applied to the other side, welding stability is significantly improved compared to a configuration in which both sides are made of only cold-rolled steel plates. The surface properties of the surface opposite to the surface in contact with the damping resin are not particularly specified in the present invention, but from the viewpoint of ease of manufacturing the iron-zinc alloy plated steel sheet, the same type of plating is applied to the front and back surfaces, or the surface that is in contact with the resin is plated with the same type. A single-sided plated steel plate in which iron-zinc alloy plating is applied only to one side and the other side has the surface of a cold-rolled steel plate can be advantageously applied.

本発明で適用する鉄−亜鉛合金めっき鋼板のめっき層組
成について、鉄濃度は4〜17%が9ましい、鉄濃度4
$以下では制振樹脂とのヌレ性が冷延鋼板とほぼ等しく
なり、樹脂と鋼板表面の接触状態がミクロ的に不完全な
部分が生じ、本発明の目的を満足しない事が判り好まし
くない、鉄濃度18%〜30%の領域では樹脂〜鋼板間
の接触は良好であるが、鉄濃度をこの範囲にまで高める
事につき格別のメリットがなく、むしろ加工成形にとも
なうめっき皮膜の部分的剥離現象が生じ易くなる等の不
具合を生じるので好ましくない。
Regarding the plating layer composition of the iron-zinc alloy plated steel sheet applied in the present invention, the iron concentration is preferably 4 to 17%, and the iron concentration is 4%.
If the temperature is less than $1, the wettability with the damping resin will be almost the same as that of the cold rolled steel sheet, and the contact state between the resin and the steel sheet surface will be microscopically incomplete, which is undesirable because it will not satisfy the purpose of the present invention. In the iron concentration range of 18% to 30%, the contact between the resin and the steel plate is good, but there is no particular advantage to increasing the iron concentration to this range, and rather the phenomenon of partial peeling of the plating film that occurs during processing and forming. This is not preferable because it causes problems such as an increased likelihood of .

なお本発明にかかる鉄−亜鉛合金めっき鋼板は溶融亜鉛
を加熱処理して得る方法、或いは鉄−亜鉛合金を電気め
っきで得る方法のいずれをも採用してもほぼ等しい良好
な結果が得られる。なお本発明の基本は鉄−亜鉛合金層
に立脚したものであるが、この皮膜の構成成分は鉄−亜
鉛を基本としつつも従来技術で意図的、或いは製造過程
で不可避的に混入する成分、例えばアルミニウム、マグ
ネシウム、鉛、錫、銅等が微量、乃至極く少量含有して
いても、当然の事ながら本発明の効果をいささかも損な
うものでない。
It should be noted that the iron-zinc alloy plated steel sheet according to the present invention can be obtained by either a method of heat-treating molten zinc or a method of obtaining an iron-zinc alloy by electroplating, and almost the same good results can be obtained. The basics of the present invention are based on an iron-zinc alloy layer, but although the constituent components of this film are iron-zinc, they do not contain components intentionally or unavoidably mixed in with the prior art during the manufacturing process. For example, even if trace amounts or very small amounts of aluminum, magnesium, lead, tin, copper, etc. are contained, the effects of the present invention will not be impaired in the slightest.

制振樹脂層の厚みについて、本発明は樹脂と鋼板の接触
界面に関するものであるので、樹脂の厚みに直接的な関
係はないが、樹脂層の厚みが0.02mm以下では溶接
性能は良好になる方向にあるが制振性能が急激に低下す
る不具合をきたす、又、樹脂層の厚みが上限0.12m
■を越えると、本発明の構成においても、溶接時におけ
る樹脂の熱分解に伴う溶接部近傍の鋼板のフクレ等を生
じ易くなり、かつ溶接時の通電回路の確保が不安定にな
る傾向にあり、好ましくない。
Regarding the thickness of the damping resin layer, since the present invention relates to the contact interface between the resin and the steel plate, there is no direct relationship to the thickness of the resin, but welding performance is good when the thickness of the resin layer is 0.02 mm or less. However, the damping performance will suddenly decrease, and the thickness of the resin layer will be at the upper limit of 0.12 m.
If (2) is exceeded, even in the configuration of the present invention, blistering of the steel plate near the welded area due to thermal decomposition of the resin during welding tends to occur, and securing of the current-carrying circuit during welding tends to become unstable. , undesirable.

本発明にかかる製品の利用用途から、制振鋼板の表皮材
として使用する鋼板の厚みは0.2mm以上にする0片
側の表皮厚が0.21腸以下では溶接自体は安定したも
のを得るが、溶接部の鋼板のフクレが大きくなり、溶接
部外観、或いは溶接部の疲労強度が低下するので好まし
くない0表皮厚が1.5厘■以上では溶接性能に格別の
不利益が生じるものではないが、これ以上の厚みは実用
上無意味であり、経済上好ましくない。
Considering the application of the product according to the present invention, the thickness of the steel plate used as the skin material of the damping steel plate should be 0.2 mm or more. If the skin thickness on one side is 0.21 mm or less, the welding itself will be stable. If the skin thickness is 1.5 mm or more, there will be no particular disadvantage in welding performance. However, a thickness greater than this is practically meaningless and economically undesirable.

本発明に適用する鉄−亜鉛合金めっき鋼板表面はクロメ
ート処理が接着強度を長期にわたり維持する為には好ま
しいが、クロメート処理を行なわなくても、本発明の目
的は十分達成する事が可能である。
Although chromate treatment is preferable for the surface of the iron-zinc alloy plated steel sheet applied to the present invention in order to maintain adhesive strength over a long period of time, it is possible to sufficiently achieve the purpose of the present invention without chromate treatment. .

(実施例) 次に本発明の実施例を比較例とともに第1表に挙げる。(Example) Next, Examples of the present invention are listed in Table 1 along with comparative examples.

1)使用鋼板 ■冷延鋼板(連鋳アルミギルド鋼板、板厚0.5鵬■) ■鉄−亜鉛合金めっき鋼板(鉄濃度8.51及び12%
 、鍍金皮膜量40g/w″、板厚0.5mm 、 り
e+メート処理済、Cr付着量35〜48 mg/11
′)■亜鉛めっき鋼板(亜鉛付着量40g/7 、板厚
0.5mm 、 クロメート付着量28〜35 mg/
i )2)使用樹脂 不飽和ポリエステル樹脂、シクロヘキサノン溶媒中に乾
燥用ψとして35wt$溶解 樹脂厚(30用、50終、105μ) 3)導電性付与剤 ■鉄粉(粒径32〜53uL) ■ステンレス粉(SO3410、粒径32〜53ル)■
グラファイト末(粒径2〜5川) 4)サンドイッチラミネート条件 1枚の鋼板片面に導電性付与剤を添加した樹脂(溶剤で
希釈)を塗布し、150℃で2分間乾燥後、他面(樹脂
を塗布していない)の鋼板と貼り合わせる。ついで熱板
を用いこのサンドイッチ状の鋼板を加圧力、10Kg/
cw′で20θ℃×3分間加熱圧着して、所定の供試材
を得る。
1) Steel plate used ■ Cold-rolled steel plate (continuously cast aluminum guild steel plate, plate thickness 0.5 mm) ■ Iron-zinc alloy plated steel plate (iron concentration 8.51 and 12%)
, plating film amount 40g/w'', board thickness 0.5mm, Ri-e+mate treated, Cr adhesion amount 35-48 mg/11
')■ Galvanized steel sheet (zinc coating amount 40g/7, plate thickness 0.5mm, chromate coating amount 28~35mg/
i) 2) Resin used Unsaturated polyester resin, cyclohexanone solvent as ψ for drying 35 wt $ Dissolved resin thickness (30, 50 final, 105μ) 3) Conductivity imparting agent ■ Iron powder (particle size 32-53 uL) ■ Stainless steel powder (SO3410, particle size 32-53L) ■
Graphite powder (particle size 2 to 5) 4) Sandwich lamination conditions A resin containing a conductivity imparting agent (diluted with a solvent) is applied to one side of a steel plate, and after drying at 150°C for 2 minutes, the other side (resin bonded to a steel plate (not coated). Then, using a hot plate, this sandwich-shaped steel plate was pressed with a pressure of 10 kg/
A predetermined test material is obtained by heat-pressing at 20θ°C for 3 minutes at cw'.

5)溶接条件:ドーム型Cu−Cr電極を使用、加圧力
200 Kg、電IIi、a KA、時間14サイクル
テ上記ラミネート鋼板と板厚1.0腸膳の冷延鋼板、重
ね合せてスポット溶接。
5) Welding conditions: using a dome-shaped Cu-Cr electrode, pressing force 200 Kg, electric IIi, a KA, time 14 cycles. The above laminated steel plate and a cold rolled steel plate with a plate thickness of 1.0 mm were overlapped and spot welded.

[評価方法] 溶接安定性:同一条件で各200枚の試験片を作成し、
各々スポット溶接をおこない、スパーク、電極溶着、未
通電等を溶接不良と見做し。
[Evaluation method] Welding stability: 200 test pieces were created under the same conditions,
Perform spot welding for each, and consider sparks, electrode welding, non-energization, etc. as welding defects.

200点の溶接により生じた溶接不良の個数を表示した
The number of welding defects caused by welding 200 points is displayed.

(発明の効果) 本発明によれば、従来の制振鋼板において見られた局部
的溶接欠陥を解消することが出来、工業的に大きな効果
を得ることが可能となった。
(Effects of the Invention) According to the present invention, it is possible to eliminate localized welding defects observed in conventional damping steel plates, and it has become possible to obtain great industrial effects.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は各表皮材と樹脂とのヌレ性の関係を示す説明図で
ある。
The drawings are explanatory diagrams showing the relationship of wettability between each skin material and resin.

Claims (3)

【特許請求の範囲】[Claims] (1)樹脂層を芯にしたサンドイッチ型制振鋼板に於い
て、樹脂層に導電性付与物質として金属粒子または炭素
系粉末またはこれらの混合物質を分散し、樹脂層を挟む
2枚の鋼板として鉄−亜鉛合金めっき鋼板、または鉄−
亜鉛合金めっき鋼板と冷延鋼板からなる事を特徴とする
溶接性能に優れた制振鋼板。
(1) In a sandwich-type vibration damping steel plate with a resin layer as the core, metal particles, carbon-based powder, or a mixture thereof as a conductive substance is dispersed in the resin layer, and the resin layer is sandwiched between two steel plates. Iron-zinc alloy plated steel sheet, or iron-
A vibration-damping steel plate with excellent welding performance that is made of a zinc alloy-plated steel plate and a cold-rolled steel plate.
(2)導電性を付与された樹脂層の厚みが0.02mm
〜0.12mmである特許請求の範囲第1項記載の制振
鋼板。
(2) The thickness of the conductive resin layer is 0.02 mm
The damping steel plate according to claim 1, which has a thickness of 0.12 mm.
(3)表皮材に使用する鋼板の厚みが0.2〜1.5m
mであり、且つ鉄−亜鉛合金めっき層中の鉄濃度が4〜
17%である特許請求の範囲第1項又は第2項記載の制
振鋼板。
(3) The thickness of the steel plate used for the skin material is 0.2 to 1.5 m.
m, and the iron concentration in the iron-zinc alloy plating layer is 4 to
17% of the damping steel plate according to claim 1 or 2.
JP61197038A 1986-08-25 1986-08-25 Vibration-damping steel plate having excellent weldability Pending JPS63158242A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61197038A JPS63158242A (en) 1986-08-25 1986-08-25 Vibration-damping steel plate having excellent weldability

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Application Number Priority Date Filing Date Title
JP61197038A JPS63158242A (en) 1986-08-25 1986-08-25 Vibration-damping steel plate having excellent weldability

Publications (1)

Publication Number Publication Date
JPS63158242A true JPS63158242A (en) 1988-07-01

Family

ID=16367692

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Link
JP (1) JPS63158242A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0274331A (en) * 1988-09-10 1990-03-14 Nkk Corp Resin laminate steel plate
JPH0564860A (en) * 1991-09-06 1993-03-19 Kobe Steel Ltd Resin composite type steel plate
JPH0664087A (en) * 1992-08-18 1994-03-08 Nippon Steel Corp Composite steel plate having synthetic resin intermediate layer
US7510621B2 (en) 2004-09-22 2009-03-31 General Motors Corporation Conductive adhesive bonding
US7833630B2 (en) 2004-12-20 2010-11-16 Gm Global Technology Operations, Inc. Weldable metal composites and methods
US9005768B2 (en) 2011-02-21 2015-04-14 Productive Research Composite materials including regions differing in properties and methods
US9115264B2 (en) 2010-02-15 2015-08-25 Productive Research Llc Delamination resistant, weldable and formable light weight composites
US9233526B2 (en) 2012-08-03 2016-01-12 Productive Research Llc Composites having improved interlayer adhesion and methods thereof
US9239068B2 (en) 2009-12-28 2016-01-19 Productive Research Llc Processes for welding composite materials and articles therefrom
US9434134B2 (en) 2008-08-18 2016-09-06 Productive Research Llc Formable light weight composites
US11338552B2 (en) 2019-02-15 2022-05-24 Productive Research Llc Composite materials, vehicle applications and methods thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53128687A (en) * 1977-04-14 1978-11-09 Kobe Steel Ltd Vibration-damping and sound insulating board having excellent spot welding property
JPS57163560A (en) * 1981-03-31 1982-10-07 Sumitomo Metal Ind Laminated metallic plate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53128687A (en) * 1977-04-14 1978-11-09 Kobe Steel Ltd Vibration-damping and sound insulating board having excellent spot welding property
JPS57163560A (en) * 1981-03-31 1982-10-07 Sumitomo Metal Ind Laminated metallic plate

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0274331A (en) * 1988-09-10 1990-03-14 Nkk Corp Resin laminate steel plate
JPH0564860A (en) * 1991-09-06 1993-03-19 Kobe Steel Ltd Resin composite type steel plate
JPH0664087A (en) * 1992-08-18 1994-03-08 Nippon Steel Corp Composite steel plate having synthetic resin intermediate layer
US7510621B2 (en) 2004-09-22 2009-03-31 General Motors Corporation Conductive adhesive bonding
US7833630B2 (en) 2004-12-20 2010-11-16 Gm Global Technology Operations, Inc. Weldable metal composites and methods
US9889634B2 (en) 2008-08-18 2018-02-13 Productive Research Llc Formable light weight composites
US9434134B2 (en) 2008-08-18 2016-09-06 Productive Research Llc Formable light weight composites
US9239068B2 (en) 2009-12-28 2016-01-19 Productive Research Llc Processes for welding composite materials and articles therefrom
US10457019B2 (en) 2010-02-15 2019-10-29 Productive Research Llc Light weight composite material systems, polymeric materials, and methods
US9415568B2 (en) 2010-02-15 2016-08-16 Productive Research Llc Formable light weight composite material systems and methods
US9849651B2 (en) 2010-02-15 2017-12-26 Productive Research Llc Formable light weight composite material systems and methods
US9115264B2 (en) 2010-02-15 2015-08-25 Productive Research Llc Delamination resistant, weldable and formable light weight composites
US9981451B2 (en) 2010-02-15 2018-05-29 Productive Research Llc Delamination resistant, weldable and formable light weight composites
US10710338B2 (en) 2010-02-15 2020-07-14 Productive Research Llc Delamination resistant, weldable and formable light weight composites
US11084253B2 (en) 2010-02-15 2021-08-10 Productive Research Llc Light weight composite material systems, polymeric materials, and methods
US11331880B2 (en) 2010-02-15 2022-05-17 Productive Research Llc Delamination resistant, weldable and formable light weight composites
US9962909B2 (en) 2011-02-21 2018-05-08 Productive Research Llc Composite materials including regions differing properties, and methods
US9005768B2 (en) 2011-02-21 2015-04-14 Productive Research Composite materials including regions differing in properties and methods
US9233526B2 (en) 2012-08-03 2016-01-12 Productive Research Llc Composites having improved interlayer adhesion and methods thereof
US11338552B2 (en) 2019-02-15 2022-05-24 Productive Research Llc Composite materials, vehicle applications and methods thereof

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