JPS63146019A - Color liquid crystal display element - Google Patents

Color liquid crystal display element

Info

Publication number
JPS63146019A
JPS63146019A JP61292432A JP29243286A JPS63146019A JP S63146019 A JPS63146019 A JP S63146019A JP 61292432 A JP61292432 A JP 61292432A JP 29243286 A JP29243286 A JP 29243286A JP S63146019 A JPS63146019 A JP S63146019A
Authority
JP
Japan
Prior art keywords
color
liquid crystal
crystal display
metal
display element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61292432A
Other languages
Japanese (ja)
Inventor
Yuzo Hayashi
祐三 林
Toshio Miura
寿夫 三浦
Shozo Takamura
高村 章三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alps Alpine Co Ltd
Original Assignee
Alps Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alps Electric Co Ltd filed Critical Alps Electric Co Ltd
Priority to JP61292432A priority Critical patent/JPS63146019A/en
Publication of JPS63146019A publication Critical patent/JPS63146019A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133521Interference filters

Landscapes

  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

PURPOSE:To permit display of a sharp color tone by constituting a color filter of an interference filter consisting of multilayered inorg. films. CONSTITUTION:The color filter is constituted of the interference filter consisting of the multi-layered inorg. films. For example, metal oxides such as titanium oxide and silicon oxide, metal fluorides such as cerium fluoride and magnesium fluoride and others such as metal fluorides,metal chlorides and metal nitrides which are stable and can form thin films are selectively usable as the material for the multi-layered inorg. films. More specifically, the interference filter which allows the transmission of light of a specific wavelength region can be formed by selecting the material from the above-mentioned materials and forming the multi-layered films while controlling the film thickness. The sharp color display is thereby permitted.

Description

【発明の詳細な説明】 「産業上の利用分野」 本発明は、例えばTV画像やカラーグラフィック画像を
゛表示するためのカラー液晶表示素子に関し、特に、カ
ラー表示のためのカラーフィルタの改良に関する。
DETAILED DESCRIPTION OF THE INVENTION "Field of Industrial Application" The present invention relates to a color liquid crystal display element for displaying, for example, TV images or color graphic images, and particularly relates to improvements in color filters for color display.

「従来技術J 近年、液晶表示素子は、薄型で低電圧駆動で 、き、消
費電力か小さいという特色をもつことがら、フラットデ
ィスプレイとして急速に市場のニーズが高まってきでい
る。従来は、モノカラーのものが主流であったか、赤、
緑、青(以下、各々R,G、Bと略称する)等のカラー
フィルタを用い、フルカラー表示再縁なカラー液晶表示
素子が商品化されてきている。また、駆動の面からは、
走査線数の多い画像表示が可能などといったことから、
TFTなとのスイッチング素子で液晶を駆動する方式が
併せ用いられようとしでいる。
"Prior Art J" In recent years, liquid crystal display elements have been characterized by being thin, low-voltage drive, and low power consumption, so the market needs for flat displays have been rapidly increasing. red,
Color liquid crystal display elements capable of full-color display have been commercialized using color filters such as green and blue (hereinafter abbreviated as R, G, and B, respectively). Also, from the perspective of driving,
Because it is possible to display images with a large number of scanning lines,
A system in which liquid crystals are driven by switching elements such as TFTs is also being used.

このような従来のカラー液晶表示素子の一例を説明する
と、例えば第4図に示すように、ガラス基板1の上に画
素電極6および配向膜7を順次形成したものと、ガラス
基板2の上にカラーフィルタ3、共通電極4および配向
膜5を順次積層して形成したものとを、各々の電極が内
側になるように対向配ゴし、周縁部をシール材10によ
って貼り合せでセルを構成し、真空封入法等によって液
晶11ヲ前記液晶セル内に充填し、ガラス基板1.2の
外側に偏光板8.9を設置しでいる。カラーフィルタ3
は、舅5図に示すように、R,G、8か各画素電極6に
対応して形成されている。このカラーフィルタ3として
は、例えば、カゼイン系やアクリル系の光感光性樹脂を
ガラス基板2に塗布し、フォトリングラフィ法によりパ
ターン化し、酸′1染料で染着させものや、昇華性染料
をガラス基板2に直接被着ざぜたものや、電着によりガ
ラス基板2に電気化学的に染顔料を析出させたものなど
が採用されている。
To explain one example of such a conventional color liquid crystal display element, for example, as shown in FIG. A color filter 3, a common electrode 4, and an alignment film 5 are sequentially laminated and arranged facing each other so that each electrode is on the inside, and the peripheral edge is bonded with a sealing material 10 to form a cell. A liquid crystal 11 is filled into the liquid crystal cell by a vacuum filling method or the like, and a polarizing plate 8.9 is placed outside the glass substrate 1.2. color filter 3
As shown in FIG. 5, R, G, and 8 are formed corresponding to each pixel electrode 6. The color filter 3 may be made by coating a casein-based or acrylic-based photosensitive resin on the glass substrate 2, patterning it by photophosphorography, and dyeing it with an acid'1 dye, or dyeing it with a sublimation dye. Some examples include those in which the dye is deposited directly on the glass substrate 2, and those in which dyes and pigments are electrochemically deposited on the glass substrate 2 by electrodeposition.

「発明か解決しようとする問題点」 しかしなから、従来のカラー液晶表示素子におけるカラ
ーフィルタは、カラーの着色種として有機系の染料ある
いは顔料を用いており、第6図のR,0,8の波長に対
する透過率を表わした分光特′注に示されるように、R
,G、Bの波長の近くにおける透過率の立ち上かつか暖
やかであり、そのためカラーフィルタの色純度が低く、
鮮明な色調表示を提供することかできないという問題点
かあった。
``Problems to be solved by the invention'' However, the color filters in conventional color liquid crystal display elements use organic dyes or pigments as the coloring species, and R, 0, 8 in FIG. As shown in the spectroscopic special note showing the transmittance for the wavelength of
, G, and B wavelengths, the rise of the transmittance is warm and the color purity of the color filter is low.
There was a problem in that it was not possible to provide clear color tone display.

したかっで、本発明の目的は、カラーフィルタの色純度
を分光学的に理想に近い状態に高めることにより、鮮明
な色調表示を可能としたカラー液晶表示素子を提供する
ことにある。
Therefore, it is an object of the present invention to provide a color liquid crystal display element that can display clear color tones by increasing the color purity of a color filter to a spectroscopically ideal state.

「問題点を解決するための手段」 本発明によるカラー液晶表示素子は、カラーフィルタが
無機系の多層膜からなる干渉フィルターで構成されてい
ることを特徴とする。
"Means for Solving the Problems" The color liquid crystal display element according to the present invention is characterized in that the color filter is composed of an interference filter made of an inorganic multilayer film.

「作用」 このように、無機系の多層膜からなる干渉フィルターを
用いることにより、R,0,8の波長の近くにおける透
過度の立ち上かつか急峻な分光特性を得ることかでき、
R,G、8の選択された波長のみそ透過させることによ
って、鮮明な色調表示を可能とすることができる。
"Operation" In this way, by using an interference filter made of an inorganic multilayer film, it is possible to obtain a spectral characteristic with a steep rise in transmittance near the wavelengths of R, 0, and 8.
By transmitting only selected wavelengths of R, G, and 8, it is possible to display clear color tones.

上記干渉フィルターを構成する無機系多層膜の材料とし
では、例えば、酸化チタン、酸化ケイ素、酸化セリウム
、酸化ジルコニウム、酸化アルミニウム等の金属酸化物
、フッ化セリウム、フッ化マグネシウム、フッ化カルシ
ウム等の金属フッ化物、その他、金属硫化物、金属塩化
物、金属窒化物等であっても安定なもので1膜が形成で
きる材料であれば選択して使用できる。そして、これら
の中から材料を選定し、膜厚をコントロールして多層膜
を形成することにより、特定波長域の光を透過する干渉
フィルターを作成することができる。なお、R,G、B
の多色パターンは、それぞれの透過色を有する干渉フィ
ルターをフォトリングラフィ法などの技術によって順次
パターン形成することによって形成することができる。
Examples of materials for the inorganic multilayer film constituting the interference filter include metal oxides such as titanium oxide, silicon oxide, cerium oxide, zirconium oxide, and aluminum oxide, cerium fluoride, magnesium fluoride, and calcium fluoride. Metal fluorides, metal sulfides, metal chlorides, metal nitrides, etc. can be selected and used as long as they are stable and can form a single film. By selecting materials from these materials and forming a multilayer film by controlling the film thickness, it is possible to create an interference filter that transmits light in a specific wavelength range. In addition, R, G, B
The multicolor pattern can be formed by successively patterning interference filters having respective transmission colors using a technique such as photolithography.

しかしながら、上記のような干渉フィルターを用いた場
合、干渉フィルターの一般的な欠点としで、視角が状く
なる傾向かある。すなわち、視角かすれると、−的とす
る色とはすれた色の光が透過して視認されるからである
。このため、未発明のカラー液晶表示素子は、特に投写
形ディスプレイのライトバルブとして適している。この
ようにライトバルブとしで利用した場合には、視角が固
定されるので、上記のような問題点が生じることはない
からである。ま・た、この場合には、アクティブマトリ
クスタイプに限らす、単純マトリクスタイプのものに適
用しても良好なコントラストが得られるという利点もあ
る。
However, when using an interference filter as described above, a general drawback of interference filters is that the viewing angle tends to be distorted. That is, when the viewing angle is blurred, light of a color other than the target color is transmitted and visually recognized. Therefore, the uninvented color liquid crystal display element is particularly suitable as a light valve for a projection display. This is because when used as a light valve in this way, the viewing angle is fixed, so the above-mentioned problems do not occur. Additionally, in this case, there is an advantage that good contrast can be obtained even when applied not only to active matrix types but also to simple matrix types.

「発明の実施例」 茶1図には、本発明の一寅流側であるカラー液晶表示素
子の断面図が示されでいる。
"Embodiments of the Invention" Fig. 1 shows a cross-sectional view of a color liquid crystal display element, which is one aspect of the present invention.

このカラー液晶表示素子は、笥4図に示した従来例にお
けるカラーフィルタ3の代りに、無機系多層膜からなる
干渉フィルタ12を用いている他は、上記従来例と同様
な構成となっている。干渉フィルタ12は、例えば、酸
化チタン、酸化ケイ素、酸化セリウム、酸化ジルコニウ
ム、酸化アルミニウム等の金属酸化物、フ・ン化セlノ
ウム、フッ化マグネシウム、フッ化カルシウム等の金属
フッ化物、その他、金属硫化物、金属塩化物、金属窒化
物等から選択された材料がらなっ、これらの材料からな
る複数の薄膜を組合せて所定の厚さに積層して形成され
でいる。そして、R,6,8の各波長1浅の光を透過す
るそれぞれのフィルターを、フォトリングラフィ法など
によってパターン化しつつ順次形成することによって構
成されている。
This color liquid crystal display element has the same structure as the conventional example described above, except that an interference filter 12 made of an inorganic multilayer film is used in place of the color filter 3 in the conventional example shown in Figure 4. . The interference filter 12 is made of, for example, metal oxides such as titanium oxide, silicon oxide, cerium oxide, zirconium oxide, and aluminum oxide, metal fluorides such as cerium fluoride, magnesium fluoride, and calcium fluoride, and others. It is made of a material selected from metal sulfides, metal chlorides, metal nitrides, etc., and is formed by combining a plurality of thin films made of these materials and laminating them to a predetermined thickness. It is constructed by sequentially forming filters of R, 6, and 8, each of which transmits light with one wavelength shallower, while patterning them using a photolithography method or the like.

こうして作成した干渉フィルター12のR,G、Bの波
長に対する透通率を表わした分光特性を第2図に示す。
FIG. 2 shows the spectral characteristics representing the transmittance of the interference filter 12 thus prepared for the R, G, and B wavelengths.

このように、R,G、Bの各特定波長領域においで、急
峻に立ち上がったスペクトルか得られる。このため、こ
の液晶表示素子は、各画素電極6を透過してくる光が、
純粋なR,G、8の色をなしてあつ、鮮やかな色調を有
する表示画像を得ることかできる。
In this way, a spectrum that rises sharply can be obtained in each of the specific wavelength regions of R, G, and B. Therefore, in this liquid crystal display element, the light passing through each pixel electrode 6 is
It is possible to obtain a display image that is composed of pure R, G, and 8 colors and has a vivid tone.

菓3図には、上記カラー液晶表示素子を投写形ディスプ
レイのライトバルブとして使用した例が示されでいる。
Figure 3 shows an example in which the color liquid crystal display element described above is used as a light valve of a projection display.

すなわち、図1こ占いて、21は光源、22は集光レン
ズ、23は上記のカラー液晶表示素子、24は拡大レン
ズ、25は半透明スフ1ノーンである。光源21がら発
せられる光は、集光レンズ22で収束され、液晶表示素
子23を通って電圧印加された画素電極6の部分から特
定の色の光となっで透過する。この透過光は、拡大しシ
ズ24(こより拡大されて半透明スクリーン25に写し
出される。このような投写形ディスプレイに適用した場
合には、視角か固定されるため、視角のすれによる干渉
フィルター12の透過色のずれを防止でき、干渉フィル
ター12の欠点も回避できる。
That is, in FIG. 1, 21 is a light source, 22 is a condensing lens, 23 is the above-mentioned color liquid crystal display element, 24 is a magnifying lens, and 25 is a translucent screen. Light emitted from the light source 21 is converged by a condenser lens 22, passes through the liquid crystal display element 23, and passes through the portion of the pixel electrode 6 to which a voltage is applied as light of a specific color. This transmitted light is enlarged and projected onto a semi-transparent screen 25. When applied to such a projection display, the viewing angle is fixed, so the interference filter 12 may be affected by the deviation of the viewing angle. It is possible to prevent shifts in transmitted color and also avoid the drawbacks of the interference filter 12.

なお、上記実施例において、干渉フィルター12は、共
通電極4か形成されたガラス基板2の内面に形成されで
いるか、干渉フィルター12は、画素電極6か形成され
たガラス基板1の内面に形成してもよく、あるいはガラ
ス基板1.2のいずれかの外面に形成してもよい。
In the above embodiments, the interference filter 12 is formed on the inner surface of the glass substrate 2 on which the common electrode 4 is formed, or the interference filter 12 is formed on the inner surface of the glass substrate 1 on which the pixel electrode 6 is formed. Alternatively, it may be formed on any outer surface of the glass substrate 1.2.

「発明の効果」 以上説明したように、本発明によれば、無機系の多層膜
からなる干渉フィルターを用いることにより、R,G、
8の波長の近くにあける透過率の立ち上かつか急峻な分
光特性を得ることかでき、R,G、8の選択された波長
のみを透過させることによって、鮮明な色調表示を可能
とすることかできる。
"Effects of the Invention" As explained above, according to the present invention, by using an interference filter made of an inorganic multilayer film, R, G,
It is possible to obtain a steep spectral characteristic with a rise in transmittance near the wavelength of 8, and to enable clear color tone display by transmitting only selected wavelengths of R, G, and 8. I can do it.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例であるカラー液晶表示素子の
断面図、第2図は上記カラー液晶表示素子に用いた干渉
フィルターの分光特性を示す図表、第3図は上記カラー
液晶表示素子を用いた投写形ディスプレイの一例を示す
概略断面図、第4図は従来のカラー液晶表示素子の一例
を示す断面図、菌5図はカラーフィルターのパターンを
示す平面図、第6図は従来のカラー液晶表示素子にあい
で用いられでいるカラーフィルタの分光特性を示す図表
である。 図中、1.2はガラス基板、4は共通電極、5は配向膜
、6は画素電極、7は配向膜、8.9は偏光板、10は
シール材、11は液晶、12は干渉フィルターである。
Fig. 1 is a cross-sectional view of a color liquid crystal display element which is an embodiment of the present invention, Fig. 2 is a chart showing the spectral characteristics of the interference filter used in the above color liquid crystal display element, and Fig. 3 is a diagram showing the above color liquid crystal display element. 4 is a sectional view showing an example of a conventional color liquid crystal display element, Fig. 5 is a plan view showing a color filter pattern, and Fig. 6 is a schematic sectional view showing an example of a conventional color liquid crystal display element. 1 is a chart showing spectral characteristics of color filters used in color liquid crystal display elements. In the figure, 1.2 is a glass substrate, 4 is a common electrode, 5 is an alignment film, 6 is a pixel electrode, 7 is an alignment film, 8.9 is a polarizing plate, 10 is a sealing material, 11 is a liquid crystal, 12 is an interference filter It is.

Claims (3)

【特許請求の範囲】[Claims] (1)表示パターンに対応した多色のカラーフィルタを
有するカラー液晶表示素子において、前記カラーフィル
タが無機系の多層膜からなる干渉フィルターで構成され
ていることを特徴とするカラー液晶表示素子。
(1) A color liquid crystal display element having a multicolor color filter corresponding to a display pattern, characterized in that the color filter is constituted by an interference filter made of an inorganic multilayer film.
(2)特許請求の範囲第1項において、前記無機系の多
層膜が、金属酸化物、金属フッ化物、金属硫化物、金属
塩化物および金属窒化物から選ばれた材料からなるカラ
ー液晶表示素子。
(2) The color liquid crystal display element according to claim 1, wherein the inorganic multilayer film is made of a material selected from metal oxides, metal fluorides, metal sulfides, metal chlorides, and metal nitrides. .
(3)特許請求の範囲第1項または第2項において、投
写形ディスプレイのライトバルブとして使用されるカラ
ー液晶表示素子。
(3) A color liquid crystal display element according to claim 1 or 2, which is used as a light valve of a projection display.
JP61292432A 1986-12-10 1986-12-10 Color liquid crystal display element Pending JPS63146019A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61292432A JPS63146019A (en) 1986-12-10 1986-12-10 Color liquid crystal display element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61292432A JPS63146019A (en) 1986-12-10 1986-12-10 Color liquid crystal display element

Publications (1)

Publication Number Publication Date
JPS63146019A true JPS63146019A (en) 1988-06-18

Family

ID=17781714

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61292432A Pending JPS63146019A (en) 1986-12-10 1986-12-10 Color liquid crystal display element

Country Status (1)

Country Link
JP (1) JPS63146019A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02149881A (en) * 1988-11-30 1990-06-08 Hosiden Electron Co Ltd Color liquid crystal display device
JPH02269315A (en) * 1988-12-15 1990-11-02 Hughes Aircraft Co Projector using liquid crystal device with reflection type color filter
EP0412921A2 (en) * 1989-08-11 1991-02-13 International Business Machines Corporation Thin film transistor liquid crystal display device with optical interference color filters
EP0478621A1 (en) * 1989-06-17 1992-04-08 GLICK, William F. Color display system using thin film color control
DE4444557B4 (en) * 1993-12-01 2005-03-24 Matsushita Electric Industrial Co., Ltd., Kadoma Display panel, projection display device with such a display panel and viewfinder with such a display panel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02149881A (en) * 1988-11-30 1990-06-08 Hosiden Electron Co Ltd Color liquid crystal display device
JPH02269315A (en) * 1988-12-15 1990-11-02 Hughes Aircraft Co Projector using liquid crystal device with reflection type color filter
EP0478621A1 (en) * 1989-06-17 1992-04-08 GLICK, William F. Color display system using thin film color control
EP0478621A4 (en) * 1989-06-17 1993-02-03 William F. Glick Color display system using thin film color control
EP0412921A2 (en) * 1989-08-11 1991-02-13 International Business Machines Corporation Thin film transistor liquid crystal display device with optical interference color filters
DE4444557B4 (en) * 1993-12-01 2005-03-24 Matsushita Electric Industrial Co., Ltd., Kadoma Display panel, projection display device with such a display panel and viewfinder with such a display panel

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