JPS63135476A - Material for displaying quantity of received light - Google Patents

Material for displaying quantity of received light

Info

Publication number
JPS63135476A
JPS63135476A JP28279086A JP28279086A JPS63135476A JP S63135476 A JPS63135476 A JP S63135476A JP 28279086 A JP28279086 A JP 28279086A JP 28279086 A JP28279086 A JP 28279086A JP S63135476 A JPS63135476 A JP S63135476A
Authority
JP
Japan
Prior art keywords
light
phycoerythrin
received
display material
amount display
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP28279086A
Other languages
Japanese (ja)
Other versions
JPH0662929B2 (en
Inventor
Fukuya Kamoda
鴨田 福也
Isamu Harasawa
原沢 勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NORIN SUISANSYO KAJIYU SHIKENJO
Nippon Carbide Industries Co Inc
Original Assignee
NORIN SUISANSYO KAJIYU SHIKENJO
Nippon Carbide Industries Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NORIN SUISANSYO KAJIYU SHIKENJO, Nippon Carbide Industries Co Inc filed Critical NORIN SUISANSYO KAJIYU SHIKENJO
Priority to JP61282790A priority Critical patent/JPH0662929B2/en
Publication of JPS63135476A publication Critical patent/JPS63135476A/en
Publication of JPH0662929B2 publication Critical patent/JPH0662929B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To obtain a material for displaying the quantity of received light, which is non-toxic acid makes it possible to identify the degree of fading over a period of the initial stage of light reception to the final stage thereof with the naked eye, by causing the subtraction of colors in proportion to the quantity of received light. CONSTITUTION:A material for displaying the quantity of received light causes the subtraction of colors in proportion to the quantity of received light. The material reduces the screening ratio of light having a specified wavelength in proportion to the quantity of received light. Namely, it is a material which allows the transmittance of light having said wavelength to be increased. For example, when the material is phycoerythrin extracted from the cell of algae of Rodophyceae, the screening ratio of light having a wavelength of 550nm, which is received by phycoerythrin, is reduced and deep red is faded from pink to colorless as the quantity of received light by deep red phycoerythrin is increased. Thus, the quantity of received light can be simply measured by the degree of fading with the naked eye. The quantity of light having a wavelength of 280-700nm, pref. 450-600nm can be displayed with good accuracy.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は新規な受光量表示素材に関し、更に詳しくは光
線を受光した光線量に相応して特定の波長の光の遮蔽率
が減少し、換言すれば該波長の透過率が増加する簡便な
高精度の受光量表示素材であり、例えば受光量表示素材
が藻類細胞から抽出した紅色のフィコエリスリンの場合
はフイコエリスリンが受光すると550nmの波長の光
の遮蔽が減少し受光前は紅色のフィコエリスリンが受光
するにしたがい紅色が退色し、退色の表示の場合により
受光けが測定できる簡便な受光量表示素材に関する。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a novel material for displaying the amount of received light, and more specifically, the present invention relates to a novel material for displaying the amount of light received, and more specifically, the shielding rate of light of a specific wavelength decreases in accordance with the amount of light received. In other words, it is a simple and highly accurate light receiving amount display material that increases the transmittance of the wavelength. For example, if the light receiving amount display material is red phycoerythrin extracted from algae cells, when the phycoerythrin receives light, it will transmit light at 550 nm. This invention relates to a simple material for displaying the amount of light received, in which the shielding of light of the same wavelength is reduced, the red color of phycoerythrin fades as the light is received, and the fading of the light can be measured in the case of display of fading.

〔従来の技術〕[Conventional technology]

従来から感光素材として写真等で利用されているハロゲ
ン化銀、複写紙等に使用されているジアゾニウム化合物
等各種存在している。
Conventionally, there have been various types of photosensitive materials, such as silver halide, which has been used in photography, and diazonium compounds, which have been used in copying paper.

しかしこれらの感光素材は受光することにより発色する
化合物であり、初期の受光に対しては鋭敏に感光するが
受光後期のある程度感光が進行してからは肉眼では判断
し難くなり相応した受光量を測定し難い笠の欠点がある
。しかもある種のものは毒性も強く高価である等の欠点
も有している。
However, these photosensitive materials are compounds that develop color when they receive light, and although they are sensitive to the initial light reception, after the light sensitivity has progressed to a certain extent in the later stages of light reception, it becomes difficult to judge with the naked eye, and it is difficult to judge the amount of light received accordingly. There is a drawback of the shade that is difficult to measure. Moreover, some of them also have drawbacks such as being highly toxic and expensive.

(発明の解決しようとする問題点) 本発明の受光ω表示素材は受光することにより減色し、
しかも受光量に相応して退色して最終的には無色透明に
なる受光素材であり、受光初期から後期まで受光mに相
応して遮蔽率が減少し、すなわち発色物質が受光量に相
応し鋭敏に退色するので受光初期から後期まで退色の度
合が肉眼で簡単に識別可能であり、しかも毒性は全くな
く、取り扱いも簡便で安価な受光量表示木材である。
(Problems to be solved by the invention) The light-receiving ω display material of the present invention reduces color by receiving light,
Moreover, it is a light-receiving material that fades in proportion to the amount of light it receives and eventually becomes colorless and transparent, and its shielding rate decreases in proportion to the amount of light it receives from the early stage to the late stage of light reception.In other words, the color-forming material becomes sensitive and becomes colorless in proportion to the amount of light it receives. Since the color fades rapidly, the degree of discoloration can be easily recognized with the naked eye from the early stage to the late stage of light reception.Moreover, it is completely non-toxic, easy to handle, and inexpensive wood for displaying the amount of light received.

かくのごとく本発明の受光M表示素材は前記欠点を改良
した新規な受光量表示素材である。
As described above, the light-receiving M display material of the present invention is a novel light-receiving amount display material that has improved the above-mentioned drawbacks.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は前述の問題点を解決すべくなされたものであり
、光線を受光した光線量に相応して減色することを特徴
とする受光ω表示素材を提供するものである。さらに詳
しくは光線を受光した光線量に相応して特定の波長の光
の遮蔽率が減少し、換言すれば該波長の透過率が増大す
る簡便な受光量表示素材であり、例えば受光量表示素材
が藻類ill胞から抽出した紅色のフィコエリスリンの
場合はフィコエリスリンが受光すると550nmの波長
の光の遮蔽率が減少し、受光前の紅色のフィコエリスリ
ンが受光するにしたがい紅色がピンク、無色と鋭敏に退
色し、退色の表示の度合により肉眼で簡単に受光量が1
lll定できる簡便で、精度の良い受光量表示素材を提
供するものである。
The present invention has been made in order to solve the above-mentioned problems, and provides a light-receiving ω display material which is characterized in that its color decreases in accordance with the amount of light received. More specifically, it is a simple material for displaying the amount of light received, in which the shielding rate of light of a specific wavelength decreases in accordance with the amount of light received, in other words, the transmittance of the wavelength increases. In the case of red phycoerythrin extracted from algae ill vacuoles, when phycoerythrin receives light, the shielding rate of light with a wavelength of 550 nm decreases, and as the red phycoerythrin receives light before receiving light, the red becomes pink. Colorless and rapidly fading, depending on the degree of fading, the amount of light received can easily be reduced to 1 with the naked eye.
The object of the present invention is to provide a simple and highly accurate display material for the amount of received light that can be determined.

本発明において「光線」とは自然光、人工光等であり、
さらにはこれ等光線の混合光であってもよい。人工光と
しては例えば各種蛍光灯、水銀灯、ハロゲンランプ、陽
光ランプ、白熱灯及びアーク灯等から発する光であり、
自然光としては太陽光、太陽光から特定波長を吸収した
光、太陽光の透過を一定化率が遮蔽した光等いずれの光
であってもよい。
In the present invention, "light ray" refers to natural light, artificial light, etc.
Furthermore, it may be a mixed light of these light rays. Examples of artificial light include light emitted from various fluorescent lamps, mercury lamps, halogen lamps, sunlight lamps, incandescent lamps, arc lamps, etc.
The natural light may be any light such as sunlight, light obtained by absorbing a specific wavelength from sunlight, or light whose transmission of sunlight is blocked at a constant rate.

また光線は少なくとも280〜700 ni、好ましく
は450〜600 nm特に好ましくは480〜590
 nmに含まれる波長域の光線の受光量が精度良く表示
もしくは標示される。
The light beam also has a wavelength of at least 280 to 700 ni, preferably 450 to 600 nm, particularly preferably 480 to 590 nm.
The amount of received light in the wavelength range included in nm is displayed or labeled with high accuracy.

また「減色」とは受光量表示素材が自から有する色の特
定波長における光線の遮蔽率の減少であり、色の度合か
らみたら特定色の退色を意味する。
Further, "color reduction" refers to a decrease in the shielding rate of light rays at a specific wavelength of the color that the light reception amount display material has itself, and means fading of a specific color in terms of the degree of color.

また本発明における「受光量表示素材」とは受光量に相
応して減色する素材ならばいずれの素材でもよいが、好
ましくは藻類細胞より抽出した色素、特に好ましくはフ
ィコエリスリン類フィコシアニン、クロ[Iフィル、更
に好ましくはフィコエリスリン類が該素材として適用で
きる。フィコシアニン類には、アロフィコシアニンB1
アロフィコシアニン、C−フィコシアニン、R−フィコ
シアニン及びフイコエリスロシアニン等が含まれ、中で
もC−フィコシアニンが好ましく、フィコエリスリン類
には、C−フィコエリスリン、B−フィコエソスリン及
びR−フィコエリスリン等が含まれ、中でもB−フィコ
エリスリンが好ましい。
In addition, the "received light amount display material" in the present invention may be any material as long as it reduces color in accordance with the amount of received light, but is preferably a pigment extracted from algae cells, particularly preferably a phycoerythrin, phycocyanin, or Ifil, more preferably phycoerythrins, can be used as the material. Phycocyanins include allophycocyanin B1
These include allophycocyanin, C-phycocyanin, R-phycocyanin, phycoerythrocyanin, etc., of which C-phycocyanin is preferred, and phycoerythrins include C-phycoerythrin, B-phycoesothrin, R-phycoerythrin, etc. Among them, B-phycoerythrin is preferred.

本発明において言う「藻類」とは、大部分が水生でその
細胞は、単体、群体または系状体など極めて単純なもの
で、光合成によって生育する植物であって、具体的には
山岸高旺編「植物系統分類の基礎」 (昭和50年5月
15日四 図鑑の北隆館発行)記載の植物であり、さら
に具体的には、地衣類、藍藻植物門、紅藻植物門、黄藻
植物閂、橙藻植物門、褐藻植物門、繰出植物門、緑藻植
物門及び輪藻植物門であり、好ましくは紅藻植物門、藍
藻植物門、緑藻植物門待に好ましくは紅藻植物門である
In the present invention, "algae" refers to plants that are mostly aquatic and whose cells are extremely simple, such as single units, colonies, or systems, and that grow through photosynthesis. These are the plants described in "Basics of Plant Systematic Classification" (published by Hokuryukan in the Illustrated Encyclopedia on May 15, 1975), and more specifically, include lichens, cyanobacteria, red algae, and yellow algae. The phylum Alcophyta, the phylum Oophyceta, the phylum Phaeophycea, the phylum Chlorophyta, the phylum Chlorophyta, and the phylum Ringophyta, preferably the phylum Rhodophyta, the phylum Cyanophyta, the phylum Chlorophyta, and preferably the phylum Rhodophyta. .

特に紅藻植物の細胞から抽出したフィコエリスリン(p
hycoerythrin)の場合、紅色のフィコエリ
スリン水溶液は550nmllに吸収波長を有し、光線
を受光すると550n11の波長の光の遮蔽率が減少し
、受光前の紅色のフィコエリスリンが受光するにしたが
い紅色がピンク、透明無色と退色する。
In particular, phycoerythrin (p
In the case of phycoerythrin), the red phycoerythrin aqueous solution has an absorption wavelength of 550nml, and when it receives light, the shielding rate of light with a wavelength of 550n11 decreases, and as the reddish phycoerythrin receives the light, it becomes reddish. It becomes pink, transparent and colorless and fades.

また藍藻植物から得たフィコシアニン (phycocyanin)はアイ色を呈し、受光する
にしたがい退色する。
Furthermore, phycocyanin obtained from blue-green algae plants exhibits an eye-colored color that fades as it receives light.

また緑藻植物から得たクロロフィルは緑色を呈し受光す
るにしたがい退色する。
In addition, chlorophyll obtained from green algae exhibits a green color, which fades as it receives more light.

本発明の受光(至)表示素材はそのまま使用する以外に
水もしくは溶剤に溶解して、溶液を透明な試験管に入れ
て使用したり、該溶液を紙や布に含浸してリドマス試験
紙のように使用する。また減色した表示より受光量を定
量する方法としては先に受光量と光線の遮蔽率を示す関
係図もしくは標準退色見本を作成しておき測定した表示
と比較して受光量を算出するのが門便で、しかも精度の
よい受光量測定方法となる。
In addition to using the light-receiving display material of the present invention as it is, it can also be used by dissolving it in water or a solvent and putting the solution in a transparent test tube, or by impregnating paper or cloth with the solution and using it as a Lidmus test strip. Use as follows. In addition, the best way to quantify the amount of light received from a color-reduced display is to first create a relationship diagram showing the amount of light received and the light shielding rate or a standard fading sample, and then calculate the amount of light received by comparing it with the measured display. This is a convenient and highly accurate method for measuring the amount of received light.

〔発明の効果〕〔Effect of the invention〕

かくして本発明の受光量表示素材は簡便でしかも精度の
よい受光量の測定が可能になるので、例えば、 1、簡易臼射吊計 2、日焼警報器(適度な日光浴を楽しむため)3、農作
物の日照測定器(J1作物に見合った日照量を与えたり
果実等の収穫の時期を定めるため) 4、ベット類の日光不足警報器 5、光化学反応調節器 等光0測定機の光量センサーとして使用でき、標準色差
計等と組合せて受光量測定器を作るのに利用することが
できる。
In this way, the received light amount display material of the present invention enables simple and accurate measurement of the amount of received light, so for example: 1. A simple mortar hanger 2. A sunburn alarm (for enjoying a moderate amount of sunbathing) 3. Sunshine measurement device for agricultural crops (to provide the amount of sunlight commensurate with J1 crops and to determine the timing of harvesting fruits, etc.) 4. Lack of sunlight alarm for beds 5. As a light amount sensor for light 0 measurement devices such as photochemical reaction regulators. It can be used in combination with a standard color difference meter, etc. to create a received light amount measuring device.

以下実施例及び参考例を挙げて、さらに詳しく説明する
A more detailed explanation will be given below with reference to Examples and Reference Examples.

実施例 紅藻であるポルフィリゾイウムクルエンタム(Porp
hylidiulCrtlentLlm )を表−1に
示す培養液中で、温度28℃に維持しつつ、炭酸ガスを
3%添加した空気を常時バブリング供給し、7日間培養
した。増殖した藻体を遠心分離し、次いで表−2に示し
たリン酸カリウムバッファー溶液に懸濁させ、超音波細
胞破壊機により藻体膜を破壊し、さらに、破壊された藻
体膜を遠心分離した。得られた上澄液に硫酸アンモニア
が25%になる様硫酸アンモニアを添加し、塩析、沈殿
した粗B−フィコエリスリンを遠心分離した。得られた
粗B−フィコエリスリンを表−2に示したリン酸バッフ
ァー溶液に溶解させ粗B−フイコエリスリン0.5%水
溶液を得た。得られた粗B−フィコエリスリン溶液の吸
光特性を第1図に示した。
Example Red alga Porphyrizoium cruentum (Porp
hylidiulCrtlentLlm) was cultured in the culture solution shown in Table 1 for 7 days while maintaining the temperature at 28° C. and constantly bubbling air containing 3% carbon dioxide gas. The grown algae are centrifuged, then suspended in the potassium phosphate buffer solution shown in Table 2, the algae membranes are destroyed using an ultrasonic cell breaker, and the destroyed algae membranes are further centrifuged. did. Ammonia sulfate was added to the obtained supernatant so that the ammonia sulfate content was 25%, salting out, and the precipitated crude B-phycoerythrin was centrifuged. The obtained crude B-phycoerythrin was dissolved in the phosphate buffer solution shown in Table 2 to obtain a 0.5% crude B-phycoerythrin aqueous solution. The absorption characteristics of the obtained crude B-phycoerythrin solution are shown in FIG.

この吸光度特性は文献(chemrstry andB
iochemistry of Plant Pigm
ents、 E、dited byT、H、Goodw
in、 Volun+al  32811〜35 op
 )記載のB−フイコエリスリン溶液の吸光度特性と一
致した。
This absorbance characteristic is described in the literature (chemrstry and B
iochemistry of Plant Pigm
ents,E,dited byT,H,Goodw
in, Volun+al 32811~35 op
The absorbance characteristics were consistent with those of the B-phycoerythrin solution described in ).

表−1 表−2 参考例 △、フィコエリスリン水溶液の調製      4実施
例で得られたB−フィコエリスリン水溶液を純水で希釈
してB−フィコエリスリン5ρgm水溶液を調製した(
以後A液という)。
Table-1 Table-2 Reference Example △, Preparation of phycoerythrin aqueous solution The B-phycoerythrin aqueous solution obtained in Example 4 was diluted with pure water to prepare a B-phycoerythrin 5pgm aqueous solution (
(hereinafter referred to as liquid A).

B、日射闇討としての利用例 A液を第2図に示したガラス製容器に80%充填し、そ
れをff13図に示したリンゴ樹につるし、A液の受光
1と、A液の退色度合を調査した。なお、ガラス製容器
の受光部以外には黒色ビニールテープを巻き、さらに外
側をアルミ箔でカバーし、中の水温が50℃以下となる
様にした。退色度合は、分光々度肝で、550nmll
に於ける光線透過率を測定した。
B. Example of use as a solar radiation filter Fill the glass container shown in Figure 2 with 80% of Liquid A, hang it on the apple tree shown in Figure ff13, and measure the light reception 1 of Liquid A and the degree of discoloration of Liquid A. investigated. In addition, black vinyl tape was wrapped around the glass container other than the light-receiving part, and the outside was covered with aluminum foil so that the water temperature inside was kept at 50° C. or lower. The degree of fading is 550nml by spectrophotometry.
The light transmittance was measured.

その結果を第4図に示した。第4図から、A液の受光量
に相応してB−フィコエリスリン溶液の遮蔽率が減少し
、B−フィコエリスリンの赤色が退色したことが判る。
The results are shown in Figure 4. From FIG. 4, it can be seen that the shielding rate of the B-phycoerythrin solution decreased in proportion to the amount of light received by the A solution, and the red color of B-phycoerythrin faded.

なお第5図より、この退色は、受光によって上昇した温
度によって退色したものでなく、受光量によってのみ、
退色したものであることが判る。
Furthermore, from Fig. 5, this discoloration is not caused by the temperature rising due to the reception of light, but only by the amount of light received.
It appears that the color has faded.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は実施例のB−フイコエリスリン溶液の化膜光度
の波長別特性図であり、第2図はB−フィコエリスリン
溶液を入れた日射量の積咋測定器でありa=15.5c
m  b=3.0cm  C=2.00であり、第3図
は日r!Jffiの積算測定器を樹につるした使用例の
図であり、第4図は550nmにおける光線透過率と受
光77k (Caj! /an2)との関係図であり第
5図は暗黒条件下における550nmの光線透過率と温
度との関係図である。
FIG. 1 is a characteristic diagram of the film luminosity of the B-phycoerythrin solution according to wavelength, and FIG. 2 is a solar radiation measurement device containing the B-phycoerythrin solution, with a=15 .5c
m b = 3.0 cm C = 2.00, and Figure 3 shows day r! This is a diagram of an example of the use of Jffi's integration measuring device hung on a tree. Figure 4 is a diagram of the relationship between light transmittance at 550 nm and received light of 77k (Caj!/an2), and Figure 5 is a diagram of the relationship between the light transmittance at 550 nm and the received light at 77k (Caj!/an2). Figure 5 is the graph at 550 nm under dark conditions. FIG. 2 is a diagram showing the relationship between light transmittance and temperature.

Claims (10)

【特許請求の範囲】[Claims] (1)光線を受光した光線量に相応して減色することを
特徴とする受光量表示素材。
(1) A light-receiving amount display material that is characterized by decreasing color in accordance with the amount of light received.
(2)減色が550nmにおける光線の遮蔽率の減少で
ある、特許請求の範囲第1項記載の受光量表示素材。
(2) The light reception amount display material according to claim 1, wherein the color reduction is a decrease in the shielding rate of light rays at 550 nm.
(3)減色が赤色光の退色である、特許請求の範囲第1
項記載の受光量表示素材。
(3) Claim 1, wherein the color reduction is fading of red light.
Received light amount display material as described in section.
(4)光線が自然光及び/又は人工光である、特許請求
の範囲第1〜3項のいずれか1項に記載の受光量表示素
材。
(4) The light reception amount display material according to any one of claims 1 to 3, wherein the light ray is natural light and/or artificial light.
(5)光線が少なくとも280〜700nmの波長域の
光線である、特許請求の範囲第1〜4項のいずれか1項
に記載の受光量表示素材。
(5) The light reception amount display material according to any one of claims 1 to 4, wherein the light ray is a light ray in a wavelength range of at least 280 to 700 nm.
(6)光線が少なくとも450〜600nmの波長域の
光線である、特許請求の範囲第1〜4項のいずれか1項
に記載の受光量表示素材。
(6) The light reception amount display material according to any one of claims 1 to 4, wherein the light ray is a light ray in a wavelength range of at least 450 to 600 nm.
(7)受光量表示素材が藻類細胞より抽出した色素であ
る、特許請求の範囲第1項記載の受光量表示素材。
(7) The light reception amount display material according to claim 1, wherein the light reception amount display material is a pigment extracted from algae cells.
(8)藻類が紅藻類である、特許請求の範囲第7項記載
の受光量表示素材。
(8) The received light amount display material according to claim 7, wherein the algae is red algae.
(9)受光量表示素材がフイコエリスリン、フイコシア
ニン及びクロロフィル等より選ばれた少なくとも1種で
ある、特許請求の範囲第7項記載の受光量表示素材。
(9) The light reception amount display material according to claim 7, wherein the light reception amount display material is at least one selected from phycoerythrin, phycocyanin, chlorophyll, and the like.
(10)フイコエリスリンがB−フイコエリスリンであ
る、特許請求の範囲第9項記載の受光量表示素材。
(10) The light reception amount display material according to claim 9, wherein the phycoerythrin is B-phycoerythrin.
JP61282790A 1986-11-27 1986-11-27 Received light amount display material Expired - Lifetime JPH0662929B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61282790A JPH0662929B2 (en) 1986-11-27 1986-11-27 Received light amount display material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61282790A JPH0662929B2 (en) 1986-11-27 1986-11-27 Received light amount display material

Publications (2)

Publication Number Publication Date
JPS63135476A true JPS63135476A (en) 1988-06-07
JPH0662929B2 JPH0662929B2 (en) 1994-08-17

Family

ID=17657118

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61282790A Expired - Lifetime JPH0662929B2 (en) 1986-11-27 1986-11-27 Received light amount display material

Country Status (1)

Country Link
JP (1) JPH0662929B2 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55149812A (en) * 1979-05-11 1980-11-21 Nippon Kanko Shikiso Kenkyusho:Kk Illumination intensity indicating material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55149812A (en) * 1979-05-11 1980-11-21 Nippon Kanko Shikiso Kenkyusho:Kk Illumination intensity indicating material

Also Published As

Publication number Publication date
JPH0662929B2 (en) 1994-08-17

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