JPS63129975A - Food preservative - Google Patents
Food preservativeInfo
- Publication number
- JPS63129975A JPS63129975A JP61278332A JP27833286A JPS63129975A JP S63129975 A JPS63129975 A JP S63129975A JP 61278332 A JP61278332 A JP 61278332A JP 27833286 A JP27833286 A JP 27833286A JP S63129975 A JPS63129975 A JP S63129975A
- Authority
- JP
- Japan
- Prior art keywords
- preservative
- food
- foods
- mixture
- glycine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005452 food preservative Substances 0.000 title claims abstract description 17
- 235000019249 food preservative Nutrition 0.000 title claims abstract description 17
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 19
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000013922 glutamic acid Nutrition 0.000 claims abstract description 12
- 239000004220 glutamic acid Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004471 Glycine Substances 0.000 claims abstract description 10
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims abstract description 8
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims abstract description 7
- 235000003704 aspartic acid Nutrition 0.000 claims abstract description 7
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 235000013305 food Nutrition 0.000 abstract description 10
- 235000013372 meat Nutrition 0.000 abstract description 8
- 239000003755 preservative agent Substances 0.000 abstract description 7
- 230000002335 preservative effect Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 2
- 235000021067 refined food Nutrition 0.000 abstract 2
- 244000005700 microbiome Species 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 10
- 235000001014 amino acid Nutrition 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000008101 lactose Substances 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 241001660259 Cereus <cactus> Species 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 230000001028 anti-proliverative effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- MPOKJOWFCMDRKP-UHFFFAOYSA-N gold;hydrate Chemical compound O.[Au] MPOKJOWFCMDRKP-UHFFFAOYSA-N 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 235000021056 liquid food Nutrition 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 235000019449 other food additives Nutrition 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 235000020991 processed meat Nutrition 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000012137 tryptone Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は特定の天然アミノ酸を混合した新しい食品保存
剤に関するもので、食品一般に広く適用できるが、特に
水産物練製品や畜肉加工品の保存に好適である。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a new food preservative containing a specific natural amino acid, which can be widely applied to foods in general, but is particularly applicable to the preservation of seafood paste products and processed meat products. suitable.
従来、食品加工とくに水産物や畜肉の加工業界において
は、有害汚染細菌類の増殖抑制に対して、通常は圧倒的
にソルビン酸を使用することが多く、ときには重合リン
酸の塩が酢酸ナトリウム或いはグリシンとの併用で使用
されていた。しかしながら、このような従来法は、菌の
増殖を抑制する力においてはそれなりの効果を有してい
たが、その使用に際しては使用制限等好筐しくない点が
あつ友。Traditionally, in food processing, especially in the marine products and meat processing industries, sorbic acid has been overwhelmingly used to suppress the growth of harmful contaminating bacteria, and sometimes polymerized phosphoric acid salts have been used in combination with sodium acetate or glycine. It was used in conjunction with. However, although such conventional methods have some effectiveness in suppressing the growth of bacteria, they have disadvantages such as restrictions on their use.
そこで近時、釉々の食品保存剤についての検討がなされ
、アミノ酸を添加した保存方法としても、食品材料にク
エン酸とグルタミン酸とを添加する方法(特開昭57−
43669号、同57−132868号ン、グルタミン
酸とグルタミン酸ナトリウムとき添加する方法(%開昭
59−66861号)および食品をグルタミン酸水溶液
に浸漬する方法(特開昭58−179470号)などが
研究されていた。Therefore, recently, studies have been conducted on food preservatives for glazes, and a method of adding citric acid and glutamic acid to food materials (Japanese Unexamined Patent Publication No. 1986-1999) has been proposed as a preservation method with the addition of amino acids.
No. 43669, No. 57-132868, a method of adding glutamic acid and sodium glutamate (% 1986-66861), and a method of immersing food in an aqueous glutamic acid solution (Japanese Patent Laid-Open No. 179470/1987), etc. Ta.
上記のような研究がなされているにも拘らず、実際の有
害汚染菌に対して有効な食品保存剤についての実用化に
はいまひとつの感があり、その開発がまたれてい九。Despite the above-mentioned research, there is still a long way to go in terms of practical application of food preservatives that are actually effective against harmful contaminating bacteria, and the development of food preservatives has been slow.
本発明者等は、天然素材のみで有効な食品保存剤全開発
すべく鋭意研究音電ねていたところ、特定の天然型アミ
ノ酸の混合物が実際の有讐汚tarium等の増殖抑制
に著効を有すること’kflって本発明を完成した。The present inventors were conducting intensive research to develop an effective food preservative made only from natural materials, and discovered that a mixture of specific natural amino acids was actually effective in inhibiting the growth of tharium, etc. Having completed the present invention.
即ち、本発明に係る食品保存剤は、グリシン、グルタミ
ン酸お工びアスノ母うイン酸の混合物全有効成分とした
こと全特徴とするものでろゐ。That is, the food preservative according to the present invention is characterized in that its active ingredients are a mixture of glycine, glutamic acid, and asno-porous acid.
本発明に係る食品保存剤は、上記3種のアミノ酸の混合
物上有効成分とするものであるが、更に稀釈剤或いは賦
形剤として他の食品岳加物例えば食塩、乳糖、他のアミ
ノ酸類などkll&加してもよい。The food preservative according to the present invention has a mixture of the above three amino acids as an active ingredient, but may also contain other food additives such as salt, lactose, other amino acids, etc. as a diluent or excipient. You may also add kll&.
本発明に係る食品保存剤上実際に使用するに当っては、
粉末状の保存剤を食品材料に鑑別混合し、必要にLじて
成型・加工するとか、粉末状の保存剤?食品表面に散布
するとか、或いは保存剤金水などの溶媒に溶解lたは分
散させてその液上食品表面に這布ま九は噴霧しtす、食
品を液に浸漬させるなど種々の方法で使用することがで
きる。In actual use of the food preservative according to the present invention,
Powdered preservatives are mixed with food ingredients, molded and processed as needed, or powdered preservatives? It can be used in various ways, such as by spraying it on the food surface, or by dissolving or dispersing it in a solvent such as preservative gold water, and then spraying it on the surface of the liquid food, or by immersing the food in the liquid. can do.
本発明に係る食品保存剤に有効成分として含まれる3種
のアミノ酸の混合比は、好ましくはグリシン全10とし
次ときに、重量比でグルタミン酸約1〜5、アスパラギ
ン酸約2〜10であり、効果と経済性との両面上考慮し
たとき特に好ましくは、グリシン10に対し′てグルタ
ミン酸1〜2、アスパラギン酸2〜4程度でるる。The mixing ratio of the three types of amino acids contained as active ingredients in the food preservative according to the present invention is preferably a total of glycine of 10, and then a weight ratio of about 1 to 5 for glutamic acid and about 2 to 10 for aspartic acid, In view of both effectiveness and economy, it is particularly preferable that the ratio of glutamic acid to 10 glycine is about 1 to 2 and about 2 to 4 aspartic acid.
次に実施例をあけて本発明全史に具体的に説明するが、
本発明はこれによって限定されるものではない。Next, the entire history of the present invention will be explained in detail with reference to Examples.
The present invention is not limited thereby.
実施例1
後記組成の食品鑑別剤の10%水浴液を第1表に記載の
珈々の添加量(培地に対する浴衣の重fil)で通常の
ブイヨン培地に添加し、培地全加熱滅菌しt後これに有
害汚染菌を接種し、30℃で72時間培養し、歯の増殖
状況勿培地の濁り具合で肉眼判定し第1表に示す結果を
得次。(−1は菌の増殖による濁りがみられないもの、
(+)は濁りの生じ友ものでその数が多いもの程濁りが
ひどいことを示す。Example 1 A 10% water bath solution of a food identification agent having the composition described below was added to a normal bouillon medium in the amounts listed in Table 1 (the weight of Yukata relative to the medium), and the medium was completely sterilized by heating. This was inoculated with harmful contaminating bacteria and cultured at 30°C for 72 hours. The growth of the teeth and the turbidity of the medium were visually determined to obtain the results shown in Table 1. (-1 means no turbidity due to bacterial growth,
(+) means that turbidity occurs, and the greater the number, the more severe the turbidity.
食品添加剤組成(100F)
アスノリギン酸 20?、
グルタミン酸 10F
グリシン 50F
食 塩 1f
乳糖 19?
試験に供し次有害汚染菌
B、Cereus (以下B、C+と略)、B、 L
icheniformis (以下B、L、と略)、
B、Megaterium (以下B、M、と略)。Food additive composition (100F) Asnorigic acid 20? , Glutamic acid 10F Glycine 50F Salt 1F Lactose 19? The following harmful contaminating bacteria B, Cereus (hereinafter abbreviated as B, C+), B, L were subjected to the test.
ichiniformis (hereinafter abbreviated as B, L),
B, Megaterium (hereinafter abbreviated as B, M).
第1表
上記の結果から明らかなように、本発明に係る食品保存
剤は、実際に遭遇する複数の有害汚染菌に対してバラン
スのよい増殖抑制力?有する。As is clear from the above results in Table 1, does the food preservative of the present invention have a well-balanced growth inhibiting ability against multiple harmful contaminating bacteria that are actually encountered? have
実施例2
椎々の魚肉または畜肉を細片化し、重量で4倍量の熱水
(85℃以上)で15分間抽出し、冷却後濾過して抽出
液とし友、これを用いて食品保存剤の増殖抑制効果上み
几。Example 2 Seedling fish or livestock meat is cut into small pieces, extracted with 4 times the weight of hot water (85°C or higher) for 15 minutes, cooled and filtered to obtain an extract liquid, which is used to make a food preservative. The anti-proliferative effect of .
試料液のvI4i:上記抽出液に実施例1で使用したの
と同じ食品龜加剤水溶液全第2表に記載の種々の添加量
(重tチ)で添加したものを試料とし次。Sample liquid vI4i: The same aqueous food flavoring agent solution used in Example 1 was added to the above extract at various amounts (by weight) listed in Table 2.
試料培地の*a:通常のトリプトンソイ寒天培地の表面
に試料g、t−平均して塗布し、試料培地とし友。*a of sample medium: Samples g and t are averaged and applied on the surface of a normal tryptone soy agar medium and used as a sample medium.
菌の接a[:102オーダー/11Lt濃度の細菌全試
料培地に接種した。Bacterial inoculation A [:102 order/11 Lt concentration] was inoculated into the bacterial whole sample medium.
効果判定:菌を接し几培地を30℃で保存し、5日目(
畜肉では2日目と5日目)の菌の増殖状況を肉眼判定し
比、←)は増殖していない。Effect evaluation: In contact with bacteria, store the medium at 30°C, and on the 5th day (
In the case of meat, the growth status of bacteria on the 2nd and 5th day (2nd and 5th day) was determined with the naked eye.
(+)は増殖したものを示し、(+)の数の多い方が増
殖が盛んであること金示す。(+) indicates that the cells have proliferated, and a larger number of (+) indicates more active proliferation.
第 2 表
上記の表から明らかなように、本発明の食品ム加物は低
濃度で光分魚畜肉における有害細菌の増殖を抑制した。Table 2 As is clear from the above table, the food additives of the present invention inhibited the growth of harmful bacteria in fish and meat at low concentrations.
実施例3
魚肉tたは畜肉をミンチで磨砕し、これ全加熱滅菌後実
施例1で使用したのと同じ本発明の食品保存剤の水溶液
金第3表に記載の極々の添加量(夏jt%)で加えて充
分混合した。混合物全再度加熱滅菌し九後滅菌し几10
0Mのビーカーに入れ、30℃の恒温槽に保存する(大
気と流通)。峠時的に劣化を観察した。劣化は腐敗臭と
液化とにより判定し、(−1は無変化であり、(+)は
腐敗臭および/ま友は液化の生起したことを示しその数
の多いもの程劣化がすすんでいることを示す。Example 3 Fish meat or livestock meat was ground with mince, and after complete heat sterilization, an aqueous solution of the food preservative of the present invention, which was the same as that used in Example 1, was prepared in the extremely additive amount listed in Table 3. jt%) and thoroughly mixed. The whole mixture was heat sterilized again and then sterilized for 10 minutes.
Place in a 0M beaker and store in a constant temperature bath at 30°C (circulation with air). Deterioration was observed over time. Deterioration is determined based on putrid odor and liquefaction (-1 means no change, (+) means putrid odor and/or liquefaction has occurred, and the higher the number, the more advanced the deterioration is. shows.
第 3 表
上記の表から明らかなように、本発明の食品拾加剰は魚
畜肉における有害細菌増殖全顕著に抑制し友。Table 3 As is clear from the above table, the food supplement of the present invention significantly inhibits the growth of harmful bacteria in fish and meat.
〔発明の効果」
アスパラギン酸、グルタミン酸およびグリシンの混合物
は、食品一般特に魚肉、畜肉を原料とする加工食品の保
存に際して問題とされている有害汚染la菌類に対して
、顕著な増殖抑制効果を有し、安全な食品保存剤として
極めて有効であつfc。[Effects of the Invention] A mixture of aspartic acid, glutamic acid, and glycine has a remarkable growth-inhibiting effect on harmful contaminating la. It is extremely effective as a safe food preservative and fc.
Claims (1)
合物を有効成分とする食品保存剤。 2、グリシン、グルタミン酸およびアスパラギン酸の混
合比が10:1〜5:2〜10である特許請求の範囲第
1項記載の食品保存剤。[Claims] 1. A food preservative containing a mixture of glycine, glutamic acid and aspartic acid as an active ingredient. 2. The food preservative according to claim 1, wherein the mixing ratio of glycine, glutamic acid and aspartic acid is 10:1 to 5:2 to 10.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61278332A JPS63129975A (en) | 1986-11-21 | 1986-11-21 | Food preservative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61278332A JPS63129975A (en) | 1986-11-21 | 1986-11-21 | Food preservative |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63129975A true JPS63129975A (en) | 1988-06-02 |
Family
ID=17595852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61278332A Pending JPS63129975A (en) | 1986-11-21 | 1986-11-21 | Food preservative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63129975A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH022328A (en) * | 1988-06-09 | 1990-01-08 | Ueno Seiyaku Oyo Kenkyusho:Kk | Preservation of food |
-
1986
- 1986-11-21 JP JP61278332A patent/JPS63129975A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH022328A (en) * | 1988-06-09 | 1990-01-08 | Ueno Seiyaku Oyo Kenkyusho:Kk | Preservation of food |
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