JPS6285254A - Photomask - Google Patents

Photomask

Info

Publication number
JPS6285254A
JPS6285254A JP60225748A JP22574885A JPS6285254A JP S6285254 A JPS6285254 A JP S6285254A JP 60225748 A JP60225748 A JP 60225748A JP 22574885 A JP22574885 A JP 22574885A JP S6285254 A JPS6285254 A JP S6285254A
Authority
JP
Japan
Prior art keywords
film
photomask
silver salt
chloride emulsion
salt emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60225748A
Other languages
Japanese (ja)
Inventor
Fumihiro Usui
臼井 文寛
Kotaro Ueno
耕太郎 上野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP60225748A priority Critical patent/JPS6285254A/en
Publication of JPS6285254A publication Critical patent/JPS6285254A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/38Masks having auxiliary features, e.g. special coatings or marks for alignment or testing; Preparation thereof
    • G03F1/48Protective coatings

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)

Abstract

PURPOSE:To omit a thin-film working process and to simplify photomask manufacture by coating the surface of a transparent substrate which has a chloride emulsion film with a transparent film which is harder than the chloride emulsion film. CONSTITUTION:When development is carried out after exposure by a photoplotter, chloride emulsion 1 on the glass substrate 2 is patterned, and silicon oxide forming a protection film 3 is sputtered to 2000Angstrom thickness. Then, the protection film 3 is not dissolved at all even by being swept with acetone which is used for cleaning the ultraviolet-ray cut-off film surface of a photomask, thereby maintaining sufficient durability.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、紫外線遮断を目的とするフォトマスクの紫
外線遮断膜の、ill遺に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an ultraviolet blocking film for a photomask for the purpose of blocking ultraviolet rays.

〔従来の技術〕[Conventional technology]

従来、フォトレジストを加工する為に用いるフォトマス
クの紫外線遮断膜にはクロム、ニッケル。
Conventionally, chromium and nickel are used in the ultraviolet blocking film of photomasks used to process photoresists.

酸化鉄等が用いられている。これらの薄膜はあらかじめ
ガラス上全面へ均一に膜付けしたのち、フォトレジスト
を用いて加工していたが、全面膜付は時に発生するピン
ホール欠陥とフォトレジスト塗布時に発生するピンホー
ル欠陥が存在し、フォトマスク!1造の歩留りを悪くし
ていた。また、前? 配索外線遮断Paは全て真空装者等による膜付は工程と
フォトエツチング工程が必要であシ、フォトマスク製造
工程が繁雑になっている。
Iron oxide etc. are used. These thin films were applied uniformly over the entire surface of the glass in advance and then processed using photoresist.However, when applying a film over the entire surface, there are pinhole defects that sometimes occur and pinhole defects that occur when applying the photoresist. , Photomask! This was causing a decline in the yield of 1-bu. Also, before? All of the wiring external wire cutoffs Pa require a process for attaching a film by a vacuum installer or the like and a photoetching process, making the photomask manufacturing process complicated.

〔発明が解決しようとする間嘔点〕[The problem that the invention attempts to solve]

そこで本発明は、これら製造上の欠陥の低減と薄膜加工
工程の省略によるフォトマスクm’aom略化を目的と
している。
Therefore, the present invention aims at reducing these manufacturing defects and simplifying the photomask m'aom by omitting the thin film processing step.

〔問題点を解決するための手段〕[Means for solving problems]

本発明のフォトマスクは゛、紫外線遮断膜部分に銀塩乳
剤膜を設けた透明基板面に、前記銀塩乳剤膜よりも硬い
透明な膜をコーティングしたことを特徴としている。
The photomask of the present invention is characterized in that the surface of a transparent substrate provided with a silver salt emulsion film in the ultraviolet blocking film portion is coated with a transparent film that is harder than the silver salt emulsion film.

〔実施例〕〔Example〕

本発明を図面にもとづいて説明する。−第5図は本発明
にもとづき行なった具体的なフォトマスク形成剤である
。第1図のガラス基板上の銀塩乳剤をフォトプロッター
で4光後、現(象を行なうと、銀塩乳剤がバターングさ
れて12図となる。次に第5図に示すように保護膜であ
る酸化ケイ素を2000(X)スパッタリングにより形
成する。表1に示すように、フォトマスク紫外線遮断膜
面の洗浄用として常時使用されているアセトンふきに対
する強度においても、全く溶解せず十分な耐久性がある
The present invention will be explained based on the drawings. - FIG. 5 shows a specific photomask forming agent made according to the present invention. When the silver salt emulsion on the glass substrate shown in Figure 1 is exposed four times using a photoplotter, the silver salt emulsion is patterned as shown in Figure 12.Next, as shown in Figure 5, a protective film is applied. A certain silicon oxide is formed by 2000(X) sputtering.As shown in Table 1, it does not dissolve at all and has sufficient durability even with acetone wipes, which are regularly used for cleaning the surface of the photomask ultraviolet blocking film. There is.

表 1 本発明にもとづいて作成された他の実施例として、銀塩
乳剤膜の保護膜に丁クリル系紫外線硬化樹脂を使用する
。バターニングされた銀塩乳剤膜上にアクリル系紫外線
硬化樹脂をzoooXスピンコードした後、紫外線を照
射させアクリル系樹脂の保護膜の強度を十分とした例で
ある。
Table 1 As another example prepared based on the present invention, a chlorine-acrylic ultraviolet curing resin is used as a protective film for a silver salt emulsion film. This is an example in which an acrylic ultraviolet curing resin was subjected to zoooX spin coding on a patterned silver salt emulsion film, and then ultraviolet rays were irradiated to increase the strength of the acrylic resin protective film.

〔発明の効果〕〔Effect of the invention〕

以上説明した本発明による効果は、銀塩乳剤膜上に酸化
ケイ素全コーティングしてフォトマスクとすることKよ
り (1)紫外光速Ffr膜付は前のガラス基板焼津工程、
遮光膜付は工程、遮光幅エッチング工程の省略が可能と
なる。
The effects of the present invention explained above are as follows: (1) The ultraviolet light speed Ffr film is attached to the glass substrate in the previous Yaizu process,
The process of adding a light shielding film and the process of etching the light shielding width can be omitted.

121クロム。ニッケル等で発生していた紫外線遮光I
戻のピンホールがフォトマスクの不良項目から除かれる
為、遮光パターン部分の不良が低減される。
121 chrome. Ultraviolet ray blocking I caused by nickel etc.
Since the return pinhole is excluded from the defects of the photomask, defects in the light-shielding pattern portion are reduced.

以上により、簡易な半導体および大型液晶表示%+を用
のtc用フォトマスクとして有効であるのみならず、同
州のプロセスを必要とする他の装(虚におけるフォトマ
スクとしても有用である。
As described above, it is not only effective as a TC photomask for simple semiconductors and large liquid crystal displays, but also useful as a photomask for other devices that require the same process.

【図面の簡単な説明】[Brief explanation of drawings]

第1図〜第5図は本発明の詳細な説明図。 1・・・銀塩乳剤 2・・・ガラス )・・・保護膜 以   上 出8人 エプソン株式会社 1 to 5 are detailed explanatory diagrams of the present invention. 1...Silver salt emulsion 2...Glass )···Protective film that's all 8 people from Epson Corporation

Claims (1)

【特許請求の範囲】[Claims] 透明基板上に銀塩乳剤膜を設け、該銀塩乳剤膜で紫外線
遮断をパターン状に行なうフォトマスクにおいて、前記
銀塩乳剤膜を設けた前記透明基板面に前記銀塩乳剤膜よ
りも硬い透明な膜をコーティングしたことを特徴とする
フォトマスク。
In a photomask in which a silver salt emulsion film is provided on a transparent substrate, and the silver salt emulsion film blocks ultraviolet rays in a pattern, the surface of the transparent substrate on which the silver salt emulsion film is provided has a transparent material harder than the silver salt emulsion film. A photomask characterized by being coated with a film.
JP60225748A 1985-10-09 1985-10-09 Photomask Pending JPS6285254A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60225748A JPS6285254A (en) 1985-10-09 1985-10-09 Photomask

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60225748A JPS6285254A (en) 1985-10-09 1985-10-09 Photomask

Publications (1)

Publication Number Publication Date
JPS6285254A true JPS6285254A (en) 1987-04-18

Family

ID=16834212

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60225748A Pending JPS6285254A (en) 1985-10-09 1985-10-09 Photomask

Country Status (1)

Country Link
JP (1) JPS6285254A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001002908A1 (en) * 1999-06-30 2001-01-11 Hitachi, Ltd. Method for manufacturing semiconductor integrated circuit device, optical mask used therefor, method for manufacturing the same, and mask blanks used therefor
US6303262B1 (en) 1998-06-18 2001-10-16 Mitsubishi Paper Mills Ltd. Photomask material, photomask and methods for the production thereof
WO2001092957A1 (en) * 2000-06-01 2001-12-06 Nippon Paper Industries Co., Ltd. Transfer sheet for transferring protective layer for photographic emulsion face and photomask with protective layer

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6303262B1 (en) 1998-06-18 2001-10-16 Mitsubishi Paper Mills Ltd. Photomask material, photomask and methods for the production thereof
WO2001002908A1 (en) * 1999-06-30 2001-01-11 Hitachi, Ltd. Method for manufacturing semiconductor integrated circuit device, optical mask used therefor, method for manufacturing the same, and mask blanks used therefor
US6677107B1 (en) 1999-06-30 2004-01-13 Hitacji, Ltd. Method for manufacturing semiconductor integrated circuit device, optical mask used therefor, method for manufacturing the same, and mask blanks used therefor
US7125651B2 (en) 1999-06-30 2006-10-24 Renesas Technology Corp. Method of manufacturing semiconductor integrated circuit device optical mask therefor, its manufacturing method, and mask blanks
WO2001092957A1 (en) * 2000-06-01 2001-12-06 Nippon Paper Industries Co., Ltd. Transfer sheet for transferring protective layer for photographic emulsion face and photomask with protective layer
US6844116B2 (en) 2000-06-01 2005-01-18 Nippon Paper Industries Co., Ltd Transfer sheet for transferring protective layer for photographic emulsion face and photomask with protective layer

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