JPS6266150A - Dew-drop sensor - Google Patents

Dew-drop sensor

Info

Publication number
JPS6266150A
JPS6266150A JP20603485A JP20603485A JPS6266150A JP S6266150 A JPS6266150 A JP S6266150A JP 20603485 A JP20603485 A JP 20603485A JP 20603485 A JP20603485 A JP 20603485A JP S6266150 A JPS6266150 A JP S6266150A
Authority
JP
Japan
Prior art keywords
sensor
electrodes
dew condensation
dew
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20603485A
Other languages
Japanese (ja)
Inventor
Hisahiro Takeuchi
寿浩 竹内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Original Assignee
Honda Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd filed Critical Honda Motor Co Ltd
Priority to JP20603485A priority Critical patent/JPS6266150A/en
Publication of JPS6266150A publication Critical patent/JPS6266150A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a dew-drop sensor by providing a pair of electrodes having a surface worked to a rough surface, on a film-shaped insulating substrate, and providing a hydrophilic group layer on the surface of the electrode. CONSTITUTION:Opposed electrodes 9, 10 of a Cu-Ni alloy are formed in a shape of the teeth of a comb on the surface of an epoxy resin film whose thickness is 2mu. Next, a minute uneven part is formed by corroding and removing only Cu by a water solution of FeCl, and a hydrophilic polymer or Na salt of a higher fatty acid, etc. 11 are stuck. This dew-drop sensor 7 and an ammeter 15 are connected in series to a power source 14, and the dew-drop quantity is detected as a variation of a resistance value of the sensor. According to this constitution, the water content condensed on the sensor does not become a water droplet but becomes a smooth film shape and spreads uniformly on the surface of the sensor, and collects in a gap 12 between the electrodes. Therefore, a contact area between the electrodes 9, 10 and the condensed water content increases, the measurement can be executed with a high sensitivity, and the structure is extremely simple.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、基板上に対向して形成された電極間の電気抵
抗変化により結露量を測定する結露センサに関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a dew condensation sensor that measures the amount of dew condensation based on a change in electrical resistance between electrodes formed facing each other on a substrate.

〈従来の技術〉 車輌、住宅、産業施設などに於て、空気調和或いは結露
を嫌う機器の保護のために空気中の水分が結露している
か否かを検出する必要がある場合がある。従来から、基
板上に一対の電極を形成し、基板上に結露する水分によ
る両電極間の電気抵抗変化を検出して結露を判定する結
露センサが知られているが、結露した水分が表面張力に
より電極上にて水滴状に凝縮する傾向があり、電極上に
は水分が付着しているにもかかわらず、これを検知でき
なかったり、或いは結露量に比例した抵抗値変化を得る
ことができず、測定値のばらつきが大きい欠点があった
<Prior Art> In vehicles, houses, industrial facilities, etc., it is sometimes necessary to detect whether or not moisture in the air has condensed for air conditioning or to protect equipment that dislikes condensation. Conventionally, dew condensation sensors have been known that determine dew condensation by forming a pair of electrodes on a substrate and detecting changes in electrical resistance between the two electrodes due to moisture condensing on the substrate. This tends to condense in the form of water droplets on the electrode, and even though moisture is attached to the electrode, it may not be detected, or a change in resistance value cannot be obtained in proportion to the amount of condensation. First, there was a drawback that the measured values varied widely.

例えば、第1図に示したように、このような公知の結露
センサ1によれば、基板2の上に積層された電極3.4
は保水性の表面を有するものであるため、凝縮した空気
中の水分が電極3.4の表面或いは電極間空隙5内にて
粒状化することとなリ、第1に測定感度が悪く、第2に
電極の表面状態によつそ水滴6の大きざ、発生箇所が変
動することとなり、測定上のばらつきが大きくなる。
For example, as shown in FIG. 1, according to such a known dew condensation sensor 1, electrodes 3.
Since it has a water-retaining surface, moisture in the condensed air becomes granular on the surface of the electrode 3.4 or in the inter-electrode gap 5. Firstly, the measurement sensitivity is poor; Second, the size and location of the water droplets 6 vary depending on the surface condition of the electrode, resulting in large variations in measurement.

そこで、例えば特開昭53−48792号公報に開示さ
れているように、多数の電極をそれぞれ電極間の間隙が
異なるように設けることにより、結露■に対応した出力
を得る技術が提案されているが、検出出力が結露量に応
じて段階的に変化することとなり、必ずしも満足できる
測定精度を得ることができない。
Therefore, as disclosed in, for example, Japanese Patent Laid-Open No. 53-48792, a technique has been proposed in which a large number of electrodes are provided with different gaps between the electrodes to obtain an output that is compatible with dew condensation. However, the detection output changes stepwise according to the amount of dew condensation, and it is not always possible to obtain a satisfactory measurement accuracy.

そこで電極表面に感湿膜を形成し、該感湿膜を湿潤する
水分による電極間抵抗値変化を検出することも考えられ
るが、特開昭56−70449@公報に於て指摘されて
いるように、感湿膜を湿潤する水分が結露条件解消後も
残存し、感湿膜内の水分が自然乾燥するまで結露はンサ
が使用不能となる不都合があり、これを解消するために
は湿度センサにヒータを付設してこのような水分を積極
的に除去することが提案されているが、加熱により湿度
センサが劣化し、構造が複雑化する不都合がある。
Therefore, it is conceivable to form a moisture-sensitive film on the electrode surface and detect the change in resistance value between the electrodes due to moisture moistening the moisture-sensitive film, but as pointed out in JP-A-56-70449@. Another problem is that the moisture that wets the moisture-sensitive membrane remains even after the condensation condition is resolved, and the sensor becomes unusable until the moisture inside the moisture-sensitive membrane dries naturally. It has been proposed to actively remove such moisture by attaching a heater to the sensor, but there are disadvantages in that the humidity sensor deteriorates due to heating and the structure becomes complicated.

〈発明か解決しようとする問題点〉 このような従来技術の欠点に鑑み、本発明の主な目的は
、単llTlな構造を有し、しかも結露量に比例した出
力を発生し得る結露センサを提供することにある。
<Problems to be Solved by the Invention> In view of the drawbacks of the prior art, the main object of the present invention is to provide a dew condensation sensor that has a single Tl structure and can generate an output proportional to the amount of dew condensation. It is about providing.

〈問題点を解決するための手段〉 このような目的は、本発明によれば、測定面に貼付可能
なフィルム状絶縁材からなる基板と、前記基板上に積層
されかつ粗面加工された表面を有する一対の電極と、前
記電極表面に被着された親水基層とを備えることを特徴
とする結露センサを提供することにより達成される。
<Means for Solving the Problems> According to the present invention, the present invention provides a substrate made of a film-like insulating material that can be attached to a measurement surface, and a roughened surface laminated on the substrate. This is achieved by providing a dew condensation sensor characterized by comprising: a pair of electrodes having the following properties; and a hydrophilic base layer deposited on the surface of the electrodes.

〈作用〉 電極上に親水基層が被着されているため、凝縮した水分
が粒状になることなく、電極面及び電極間空隙を一様に
覆う水膜となり、結露量に比例した出力を得ることがで
き、また結露条件が解消した時には、結露センサ上の水
分が直ちに蒸発することとなり、上記した不都合が解消
される。また、基板を、測定面に貼付可能なフィルム状
材料からなるものとすることにより、測定面の結露条件
を正確に検知することが可能となる。
<Function> Since the hydrophilic base layer is coated on the electrode, the condensed water does not turn into particles, but forms a water film that uniformly covers the electrode surface and the gap between the electrodes, resulting in an output proportional to the amount of dew condensation. Moreover, when the dew condensation condition is resolved, the moisture on the dew condensation sensor immediately evaporates, eliminating the above-mentioned disadvantage. Further, by making the substrate made of a film-like material that can be attached to the measurement surface, it becomes possible to accurately detect the dew condensation conditions on the measurement surface.

〈実施例〉 以下、本発明の好適実施例を添付の図面について詳しく
説明する。
<Embodiments> Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

第2図及び第2図は本発明に基づく結露センサを示す。2 and 2 show a condensation sensor according to the invention.

基板8は、約2ミクロンの厚さを有するエポキシ樹脂フ
ィルムからなり、その表面に一対の電極9.10がそれ
ぞれ櫛歯状に対向するように積層されている。この電極
は、例えば銅ニツケル合金からなり、これを塩化第2鉄
の水溶液により銅のみを選択的にエツチングし、その表
面に微細な凹凸を形成してなるものである。このように
して粗面加工された電極9.100表面には親水性ポリ
マ或いは高級脂肪酸のナトリウム塩などからなる親水基
層11が被着されている。
The substrate 8 is made of an epoxy resin film having a thickness of about 2 microns, and a pair of electrodes 9 and 10 are laminated on the surface thereof so as to face each other in a comb-like shape. This electrode is made of, for example, a copper-nickel alloy, and only the copper is selectively etched with an aqueous solution of ferric chloride to form fine irregularities on its surface. A hydrophilic base layer 11 made of a hydrophilic polymer or a sodium salt of a higher fatty acid is adhered to the surface of the electrode 9.100 which has been roughened in this manner.

特に、第3図は、この結露センサ7の使用要領を示して
おり、電源14に、電流計15と結露センサ7とを直列
に接続することにより、結露センサ上の結露量を、セン
サの抵抗値変化即ち電流計15に於ける電流値の変化と
して検出することができる。
In particular, FIG. 3 shows how to use this dew condensation sensor 7. By connecting the ammeter 15 and the dew condensation sensor 7 in series to the power supply 14, the amount of dew condensation on the dew condensation sensor can be measured by the resistance of the sensor. It can be detected as a value change, that is, a change in the current value in the ammeter 15.

本発明に基づく結露センサによれば、基板が薄膜からな
るため、測定面とセンサとの間の熱抵抗が非常に小ざく
、測定面の温度とセンサ電極面との温度差を小さくする
ことができる。そのため、測定面に於ける結露量とセン
サ表面に於ける結露量との差を小さくすることができ、
センサ周囲の条件に対する忠実度の高い検出が可能とな
る。特に、基板の裏面に粘着層を設け、測定面に簡便に
貼付し得るようにすると良い。
According to the dew condensation sensor based on the present invention, since the substrate is made of a thin film, the thermal resistance between the measurement surface and the sensor is very small, making it possible to reduce the temperature difference between the measurement surface and the sensor electrode surface. can. Therefore, the difference between the amount of condensation on the measurement surface and the amount of condensation on the sensor surface can be reduced.
High-fidelity detection of the conditions surrounding the sensor is possible. In particular, it is preferable to provide an adhesive layer on the back side of the substrate so that it can be easily attached to the measurement surface.

また電極表面が粗面加工されていることから、親水基層
11を均一に被着することができ、しかも長期間の使用
後も親水基層が剥@するなどの問題が生じない。
Furthermore, since the electrode surface is roughened, the hydrophilic base layer 11 can be uniformly applied, and problems such as peeling of the hydrophilic base layer do not occur even after long-term use.

本発明に基づく結露センサ6上にて空気中の水分か結露
した場合、凝縮した水分は水滴状となることなく、滑ら
かな膜状となってセンサ表面に均一に拡がり、電極間の
間隙12内に24)留することとなる。そのため、電極
9.10と凝縮水分との間の接触面積が大きくなり、感
度の高い測定が可能となると共に、結露量に比例する抵
抗値変化を発生することができる。また、電極と水との
間の接触面積が大きいことから、比較的低い電圧による
測定が可能となり、測定用の電流による発熱に起因する
測定誤差を回避することが可能となる。
When moisture in the air condenses on the dew condensation sensor 6 according to the present invention, the condensed moisture does not form into water droplets, but forms a smooth film that spreads uniformly over the sensor surface and within the gap 12 between the electrodes. 24). Therefore, the contact area between the electrodes 9 and 10 and the condensed water becomes large, making it possible to perform highly sensitive measurements and to generate a change in resistance proportional to the amount of dew condensation. Furthermore, since the contact area between the electrode and water is large, measurement can be performed using a relatively low voltage, and measurement errors caused by heat generation due to the measurement current can be avoided.

本発明に基づく結露センサは、上記したように結露量を
精度良く測定する用途に広く応用可能でおるが、特に車
室内の結露を検出するためにウィンドシールドなどの窓
ガラスに貼付する目的に特に適している。
The dew condensation sensor based on the present invention can be widely applied to the purpose of accurately measuring the amount of dew condensation as described above, but is especially suitable for being attached to window glass such as a windshield to detect dew condensation inside a vehicle. Are suitable.

〈発明の効果〉 このように、本発明によれば、極めて簡単な構成により
精度良く結露量を検出することができ、例えば車室内に
て運転者の視野を狭める可能性のおる結露を早期に検出
し、空調機器などの自動運転により結露を防止し、車輌
運転の快適性及び安全性を改善する上で極めて大なる効
果を奏することができる。
<Effects of the Invention> As described above, according to the present invention, the amount of dew condensation can be detected with high accuracy using an extremely simple configuration, and, for example, condensation that may narrow the driver's field of vision in the vehicle interior can be detected at an early stage. It is possible to prevent dew condensation through automatic operation of air conditioners and other devices, which can be extremely effective in improving the comfort and safety of vehicle driving.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来技術に基づく結露センサを示す拡大断面図
である。 第2図は本発明に基づく結露センサを示す断面図である
。 第3図は本発明に基づく結露センサを示す平面図である
。 1・・・結露センサ   2・・・基板3.4・・・電
極    5・・・空隙6・・・水滴      7・
・・結露センサ8・・・基板      9.10・・
・電極11・・・親水基層   12・・・空隙13・
・・水膜     14・・・電源15・・・電流計 特 許 出 願 人 本田技研工業株式会社代   理
   人  弁理士 大 島 陽 −第1− 第2図 第3図
FIG. 1 is an enlarged sectional view showing a dew condensation sensor based on the prior art. FIG. 2 is a sectional view showing a dew condensation sensor according to the present invention. FIG. 3 is a plan view showing a dew condensation sensor according to the present invention. 1... Dew condensation sensor 2... Substrate 3. 4... Electrode 5... Gap 6... Water droplet 7.
... Condensation sensor 8 ... Board 9.10 ...
・Electrode 11...Hydrophilic base layer 12...Void 13・
...Water film 14...Power source 15...Ammeter patent Applicant: Honda Motor Co., Ltd. Agent: Patent attorney: Yo Oshima - 1st - Figure 2 Figure 3

Claims (2)

【特許請求の範囲】[Claims] (1)基板上に対向して形成された電極間の電気抵抗変
化により結露量を測定する結露センサであって、 測定面に貼付可能なフィルム状絶縁材からなる基板と、 前記基板上に積層されかつ粗面加工された表面を有する
一対の電極と、 前記電極表面に被着された親水基層とを備えることを特
徴とする結露センサ。
(1) A dew condensation sensor that measures the amount of dew condensation based on a change in electrical resistance between electrodes formed facing each other on a substrate, comprising: a substrate made of a film-like insulating material that can be attached to a measurement surface; and a layer laminated on the substrate. A dew condensation sensor comprising: a pair of electrodes having a roughened and roughened surface; and a hydrophilic base layer deposited on the electrode surfaces.
(2)前記電極が、少なくとも2種の金属からなり、こ
れら金属の選択的なエッチングによりその表面を粗面加
工してなることを特徴とする特許請求の範囲第1項に記
載の結露センサ。
(2) The dew condensation sensor according to claim 1, wherein the electrode is made of at least two kinds of metals, and the surface thereof is roughened by selectively etching these metals.
JP20603485A 1985-09-18 1985-09-18 Dew-drop sensor Pending JPS6266150A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20603485A JPS6266150A (en) 1985-09-18 1985-09-18 Dew-drop sensor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20603485A JPS6266150A (en) 1985-09-18 1985-09-18 Dew-drop sensor

Publications (1)

Publication Number Publication Date
JPS6266150A true JPS6266150A (en) 1987-03-25

Family

ID=16516799

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20603485A Pending JPS6266150A (en) 1985-09-18 1985-09-18 Dew-drop sensor

Country Status (1)

Country Link
JP (1) JPS6266150A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019044640A1 (en) * 2017-09-01 2019-03-07 国立研究開発法人物質・材料研究機構 Hygroscopic sensor
WO2020100778A1 (en) * 2018-11-12 2020-05-22 国立研究開発法人物質・材料研究機構 Condensation detection element

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019044640A1 (en) * 2017-09-01 2019-03-07 国立研究開発法人物質・材料研究機構 Hygroscopic sensor
US11486843B2 (en) 2017-09-01 2022-11-01 National Institute For Materials Science Dryness/wetness responsive sensor
WO2020100778A1 (en) * 2018-11-12 2020-05-22 国立研究開発法人物質・材料研究機構 Condensation detection element
JPWO2020100778A1 (en) * 2018-11-12 2021-09-09 国立研究開発法人物質・材料研究機構 Condensation detection element

Similar Documents

Publication Publication Date Title
JP4832695B2 (en) Method and apparatus for measuring substances in liquid
JP2005506528A (en) Electrochemical cell
JP6058442B2 (en) Corrosion sensor, corrosion rate measuring method and corrosion rate measuring apparatus using the same
CA2481195A1 (en) Improved electrochemical biosensor test strip
CA2402354A1 (en) Rapid response glucose sensor
CN110501282A (en) Wetness sensor and the corrosion tests carried out with the sensor
WO2013117924A1 (en) Electrochemical-based analytical test strip with fill-speed configured reagent layer
WO1989008837A1 (en) A device for measuring thermal properties of a sample of a substance
EP0640830B1 (en) Detector and method for observation of the presence of a liquid and/or of a change of phase in same
WO2020100778A1 (en) Condensation detection element
JPS6266150A (en) Dew-drop sensor
RU2003104357A (en) HEMOGLOBIN SENSOR
JP4623870B2 (en) Biosensor and method for adjusting measurement sensitivity thereof
JP3810324B2 (en) Gas sensor
JP2601409Y2 (en) Temperature and humidity sensor
JPS6222960Y2 (en)
US9437798B2 (en) Combo bio and temperature disposable sensor on flexible foil
JPH05203604A (en) Measuring method and device for oxygen concentration
WO2021138405A1 (en) Temperature compensated biosensors and methods of manufacture and use thereof
EP0701123A1 (en) Formaldehyde vapour detector
JPH01123140A (en) Dew condensation sensor
JPH0192652A (en) Air corrosion monitor
JP2000030910A (en) Electric resistor having at least two connecting and contacting fields on ceramic substrate and its manufacture
JP2002296291A (en) Sensor for wind direction and wind velocity
JPS594553Y2 (en) sheet heating element