JPS6240322B2 - - Google Patents
Info
- Publication number
- JPS6240322B2 JPS6240322B2 JP7398583A JP7398583A JPS6240322B2 JP S6240322 B2 JPS6240322 B2 JP S6240322B2 JP 7398583 A JP7398583 A JP 7398583A JP 7398583 A JP7398583 A JP 7398583A JP S6240322 B2 JPS6240322 B2 JP S6240322B2
- Authority
- JP
- Japan
- Prior art keywords
- resins
- silicone
- resin
- present
- nails
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000020 Nitrocellulose Substances 0.000 claims description 5
- 229920001220 nitrocellulos Polymers 0.000 claims description 5
- 229920002050 silicone resin Polymers 0.000 claims description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- 229920006026 co-polymeric resin Polymers 0.000 claims description 4
- 229910001882 dioxygen Inorganic materials 0.000 claims description 4
- 230000035699 permeability Effects 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 206010051602 Laziness Diseases 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- FHYUCVWDMABHHH-UHFFFAOYSA-N toluene;1,2-xylene Chemical group CC1=CC=CC=C1.CC1=CC=CC=C1C FHYUCVWDMABHHH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は従来から使用されてきた女性の化粧品
の一種である爪用マニキユア剤に関するものであ
る。
従来のマニキユア剤はニトロセルロース系ラツ
カーに種々の色調の顔料又は色素を加え、爪に
“はけ”塗りを行い、低沸点溶剤により速効的に
乾燥させ、爪の美観を保つものである。
しかしながら人間の皮膚が呼吸をしているよう
に、爪自身も呼吸しており、従来からのニトロセ
ルロース系ラツカー等の遮蔽樹脂、すなわち通気
性のない樹脂を用いた場合、爪自身呼吸できず、
それにより爪の劣化、爪の割れ、塗布後の指の怠
さ等の問題を生ずる。
本発明者等はこれらの問題を解決すべく鋭意研
究の結果、従来用いられているニトロセルロース
系ラツカーに代つて酸素ガス透過性を有するシリ
コン樹脂又は、シリコン系コーポリマー樹脂を用
いることにより、前記のような従来のマニキユア
の欠点が全くない、安全でかつ優れた美観を有す
るマニキユア剤を完成した。
本発明のマニキユア剤に用いられる溶媒として
は沸点150℃以下の溶剤、例えばトルエンキシレ
ンのような芳香族系溶剤、エチルアルコール、ア
セトン、酢酸エチルの様な脂肪族系溶剤、又は水
が用いられる。
本発明のマニキユア剤に用いられる酸素ガス透
過性を有するシリコン樹脂、又はシリコン系コー
ポリマー樹脂とは例えばシリコン樹脂、シリコン
−アクリル系樹脂、シリコン−ウレタン系樹脂、
シリコン−スチレン系樹脂、シリコン−フツ素樹
脂ならびにそれらの初期縮合物等であり、更に必
要に応じて他の樹脂（たゞし、ニトロセルロース
系は除く）、たとえばアクリル系、スチレン系、
ウレタン系、エポキシ系、塩ビ系、酢ビ系等の一
種又は二種以上を混合せしめることも可能であ
る。
また、本発明のマニキユア剤に用いられる樹脂
は、水可溶性樹脂、エマルジヨン系樹脂、溶剤可
溶性樹脂等あらゆる性状の樹脂が使用可能であ
る。これらのシリコン系樹脂又はシリコンコーポ
リマー樹脂の一種又は二種以上を主成分（本発明
組成物中の樹脂原料の量に対し、65重量％以上、
好ましくは70重量％以上）とし、これに種々の色
素や香料を加え美観を添えることも可能である。
以下に安全性と優れた性能等を有する本発明の
マニキユア剤の実施例として表−１の処方例１〜
７による本発明のマニキユア剤及び処方例８、10
による本発明以外のマニキユア剤と処方例９によ
る従来のマニキユア剤とを皮膜形成性、塗布後の
指先の感触性及び長期間使用後の爪の損傷性につ
き比較性能評価を行い、その結果を表−２に示し
た。
The present invention relates to a manicure agent for nails, which is a type of cosmetic product for women that has been used in the past. Conventional nail polish agents are made by adding pigments or dyes of various tones to nitrocellulose lacquer, applying the paint to the nails with a brush, and quickly drying with a low boiling point solvent to maintain the beauty of the nails. However, just as human skin breathes, nails themselves breathe, and when conventional shielding resins such as nitrocellulose lacquer, that is, non-breathable resins, are used, the nails themselves cannot breathe.
This causes problems such as deterioration of nails, cracking of nails, and laziness of fingers after application. As a result of intensive research to solve these problems, the present inventors have succeeded in solving the above problems by using silicone resin or silicone copolymer resin having oxygen gas permeability instead of the conventionally used nitrocellulose lacquer. We have created a nail polish agent that is safe and has excellent aesthetic appearance, without any of the drawbacks of conventional nail polish. As the solvent used in the nail polish agent of the present invention, a solvent having a boiling point of 150° C. or lower, such as an aromatic solvent such as toluene xylene, an aliphatic solvent such as ethyl alcohol, acetone, or ethyl acetate, or water is used. The silicone resin or silicone copolymer resin having oxygen gas permeability used in the manicure agent of the present invention includes, for example, silicone resin, silicone-acrylic resin, silicone-urethane resin,
These include silicone-styrene resins, silicone-fluororesins, and their initial condensates, and if necessary, other resins (excluding nitrocellulose resins), such as acrylic resins, styrene resins,
It is also possible to mix one or more of urethane type, epoxy type, vinyl chloride type, vinyl acetate type, etc. Further, the resin used in the manicure agent of the present invention may be of any type such as water-soluble resin, emulsion resin, and solvent-soluble resin. The main component is one or more of these silicone resins or silicone copolymer resins (65% by weight or more based on the amount of resin raw materials in the composition of the present invention,
(preferably 70% by weight or more), and it is also possible to add various pigments and fragrances to add beauty. The following are formulation examples 1 to 1 in Table 1 as examples of the nail polish agent of the present invention having safety and excellent performance.
Nail polish agent of the present invention according to 7 and formulation examples 8 and 10
Comparative performance evaluations were performed on nail polish agents other than the present invention according to the invention and the conventional nail polish agent according to Formulation Example 9 in terms of film-forming properties, feel on fingertips after application, and damage to nails after long-term use, and the results are presented. -2.
【表】【table】
【表】【table】
【表】【table】
【表】
表−２の結果から明らかなように上記処方によ
る処方例１〜７は、全べての性能につき優秀な評
価が得られ、本発明のマニキユア剤の優れた特長
を表わしている。[Table] As is clear from the results in Table 2, Formulation Examples 1 to 7 based on the above formulations obtained excellent evaluations for all performances, demonstrating the excellent features of the manicure agent of the present invention.
Claims (1)
リコン系コーポリマー樹脂の一種又は二種を主成
分とし、更に必要に応じて他の樹脂（ただし、ニ
トロセルロース系樹脂は除く）、顔料、色素、香
料、パール化剤の一種又は二種以上を含有せしめ
てなる酸素ガス透過係数３×10-10（cm3（STP）
cm／cm2・sec・cmHg）以上を有するマニキユア
剤。1 The main component is one or two silicone resins or silicone copolymer resins that have oxygen gas permeability, and if necessary, other resins (excluding nitrocellulose resins), pigments, dyes, fragrances, Oxygen gas permeability coefficient 3×10 -10 (cm 3 (STP)) containing one or more pearlizing agents
cm/ cm2・sec・cmHg) or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7398583A JPS59199621A (en) | 1983-04-28 | 1983-04-28 | Manicure agent having oxygen gas permeability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7398583A JPS59199621A (en) | 1983-04-28 | 1983-04-28 | Manicure agent having oxygen gas permeability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59199621A JPS59199621A (en) | 1984-11-12 |
| JPS6240322B2 true JPS6240322B2 (en) | 1987-08-27 |
Family
ID=13533904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7398583A Granted JPS59199621A (en) | 1983-04-28 | 1983-04-28 | Manicure agent having oxygen gas permeability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59199621A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1276562C (en) * | 1985-04-22 | 1990-11-20 | Richard W. Schnetzinger | Silyl-containing nail enamel |
| JP2586764B2 (en) * | 1991-08-09 | 1997-03-05 | 日本ターナー株式会社 | Manicure products using aromatic paints |
| US5843412A (en) * | 1993-01-25 | 1998-12-01 | L'oreal | Quick-drying colored or clear nail varnish |
-
1983
- 1983-04-28 JP JP7398583A patent/JPS59199621A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59199621A (en) | 1984-11-12 |
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