JPS623809B2 - - Google Patents
Info
- Publication number
- JPS623809B2 JPS623809B2 JP54042546A JP4254679A JPS623809B2 JP S623809 B2 JPS623809 B2 JP S623809B2 JP 54042546 A JP54042546 A JP 54042546A JP 4254679 A JP4254679 A JP 4254679A JP S623809 B2 JPS623809 B2 JP S623809B2
- Authority
- JP
- Japan
- Prior art keywords
- powder
- parts
- oil
- composition
- baking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000843 powder Substances 0.000 claims description 133
- 239000000203 mixture Substances 0.000 claims description 109
- 239000003795 chemical substances by application Substances 0.000 claims description 63
- 239000002537 cosmetic Substances 0.000 claims description 47
- 229920001296 polysiloxane Polymers 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 28
- 239000000049 pigment Substances 0.000 claims description 22
- -1 polysiloxane Polymers 0.000 claims description 20
- 229920002545 silicone oil Polymers 0.000 claims description 10
- 239000003921 oil Substances 0.000 description 88
- 235000019198 oils Nutrition 0.000 description 88
- 239000002585 base Substances 0.000 description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 57
- 239000005871 repellent Substances 0.000 description 50
- 230000002940 repellent Effects 0.000 description 46
- 238000003756 stirring Methods 0.000 description 44
- 239000003960 organic solvent Substances 0.000 description 32
- 238000004519 manufacturing process Methods 0.000 description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 20
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- 230000000694 effects Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- 239000008096 xylene Substances 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 238000010410 dusting Methods 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000454 talc Substances 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 4
- 229940063655 aluminum stearate Drugs 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000011812 mixed powder Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 3
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 238000003776 cleavage reaction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 235000019359 magnesium stearate Nutrition 0.000 description 3
- 229940016286 microcrystalline cellulose Drugs 0.000 description 3
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 3
- 239000008108 microcrystalline cellulose Substances 0.000 description 3
- 239000004482 other powder Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000007017 scission Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000021302 avocado oil Nutrition 0.000 description 2
- 239000008163 avocado oil Substances 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001056 green pigment Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052627 muscovite Inorganic materials 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 229910052628 phlogopite Inorganic materials 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 235000013799 ultramarine blue Nutrition 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- DSVUBXQDJGJGIC-UHFFFAOYSA-N 3',6'-dihydroxy-4',5'-diiodospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C(I)=C1OC1=C(I)C(O)=CC=C21 DSVUBXQDJGJGIC-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- SEBIKDIMAPSUBY-ARYZWOCPSA-N Crocin Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O)OC(=O)C(C)=CC=CC(C)=C\C=C\C=C(/C)\C=C\C=C(C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)O1)O)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SEBIKDIMAPSUBY-ARYZWOCPSA-N 0.000 description 1
- SEBIKDIMAPSUBY-JAUCNNNOSA-N Crocin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C(=O)OC1OC(COC2OC(CO)C(O)C(O)C2O)C(O)C(O)C1O)C=CC=C(/C)C(=O)OC3OC(COC4OC(CO)C(O)C(O)C4O)C(O)C(O)C3O SEBIKDIMAPSUBY-JAUCNNNOSA-N 0.000 description 1
- QQILFGKZUJYXGS-UHFFFAOYSA-N Indigo dye Chemical compound C1=CC=C2C(=O)C(C3=C(C4=CC=CC=C4N3)O)=NC2=C1 QQILFGKZUJYXGS-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- BBMXVTPBLPQMAE-UHFFFAOYSA-K aluminum;docosanoate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O BBMXVTPBLPQMAE-UHFFFAOYSA-K 0.000 description 1
- KMJRBSYFFVNPPK-UHFFFAOYSA-K aluminum;dodecanoate Chemical compound [Al+3].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O KMJRBSYFFVNPPK-UHFFFAOYSA-K 0.000 description 1
- HSMXEPWDIJUMSS-UHFFFAOYSA-K aluminum;tetradecanoate Chemical compound [Al+3].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O HSMXEPWDIJUMSS-UHFFFAOYSA-K 0.000 description 1
- 229910052916 barium silicate Inorganic materials 0.000 description 1
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- UWHUTZOCTZJUKC-JKSUJKDBSA-N brazilin Chemical compound C12=CC(O)=C(O)C=C2C[C@]2(O)[C@H]1C1=CC=C(O)C=C1OC2 UWHUTZOCTZJUKC-JKSUJKDBSA-N 0.000 description 1
- UWHUTZOCTZJUKC-CVEARBPZSA-N brazilin Natural products C12=CC(O)=C(O)C=C2C[C@@]2(O)[C@@H]1C1=CC=C(O)C=C1OC2 UWHUTZOCTZJUKC-CVEARBPZSA-N 0.000 description 1
- 229940061587 calcium behenate Drugs 0.000 description 1
- SMBKCSPGKDEPFO-UHFFFAOYSA-L calcium;docosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O SMBKCSPGKDEPFO-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- DGQLVPJVXFOQEV-NGOCYOHBSA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-NGOCYOHBSA-N 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 229940114118 carminic acid Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000002425 furfuryl group Chemical group C(C1=CC=CO1)* 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- OBQVOBQZMOXRAL-UHFFFAOYSA-L magnesium;docosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O OBQVOBQZMOXRAL-UHFFFAOYSA-L 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 229940114937 microcrystalline wax Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 239000001057 purple pigment Substances 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229910052917 strontium silicate Inorganic materials 0.000 description 1
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229960005196 titanium dioxide Drugs 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- IJQXGKBNDNQWAT-UHFFFAOYSA-L zinc;docosanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O IJQXGKBNDNQWAT-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
Description
本発明は新規なメークアツプ化粧料に関するも
ので、化粧くずれがなく、肌への密着感がよく、
経時による化粧の浮き、くすみ等を防止し、更に
製品系におけるケーキングを防止し、のびが軽く
拡がりやすいメークアツプ化粧料を提供すること
を主な目的とする。
従来、一般に提供されているメークアツプ化粧
料特にルース状及びプレスト状メークアツプ化粧
料は、適用される粉体表面の親水化度と親油化度
の相違、粉体表面の活性化度の相違更には粉体の
表面に不均一に弱い力で付着或は吸着された油剤
の量や油剤の持つHLBの相違等により、肌へ塗
布しても化粧くずれや密着感に欠ける原因となつ
ているのが通例である。また粉体に混合される数
種の顔料間においては、その表面の親水化度、親
油化度、結晶形、表面活性度、親和度に伴う顔料
表面の濡れ現象などの相違により、経時と共に化
粧の浮き、くすみ等の化粧効果上の問題を生じ商
品の品質面で必ずしも満足し得るものではなかつ
た。
現在、水を使用しないで肌へ塗布し得るプレス
ト状メークアツプ化粧料の場合、塗布体であるパ
フが化粧料（ケーキ）の表面に常時置かれたり皮
脂や汗等で汚れたままパフを使用していると、パ
フに付着した油分、水分あるいは下地用フアンデ
ーシヨンの油分が化粧料の粒子の間に浸入し化粧
料のケーキング（塊状になりケーキの表面がひか
る状態）の原因になりやすく著しく製品価値を損
うものであつた。一方、水を使用して肌へ塗布す
るプレスト状メークアツプ化粧料の場合において
は、通常粉体と顔料との混合系に油剤、界面活性
剤を配合した油性系で構成され、この化粧料に水
を用いることにより水と油剤と界面活性剤が化粧
料表面で乳化されることを利用してこれを肌へ塗
布しているが、界面活性剤を配合した油性系の場
合、経時と共に化粧料表面に付着あるいは化粧料
中に浸入した水分との相互作用により可溶化現象
を起すため、油分が粉体、顔料を内包して硬いゲ
ル構造を形成し、化粧料表面が“ひかる”ような
感じのケーキングを生じるものであつた。
また、一般の粉状化粧料に適用されている粉体
原料は鱗片状（板状）、針状あるいは不定形で構
成されているものが殆んどで特に鱗片状の場合そ
の劈開性を利用してのびの軽く拡がりのよい製品
を提供していたが、このような製品においても適
用される油剤の配合量が多くなると劈開性が阻止
され、更に加えて針状あるいは不定形の粉体を併
用した場合、のびの軽さ、拡がりやすさを求める
には非常に困難を要するものであつた。
本発明者は種々実験研究の結果、この様な欠点
のない本発明を得たのである。
すなわち、本発明の主たる目的は化粧くずれが
なく、肌への密着感がよく、経時による化粧の浮
き、くすみ等を防止し、更に製品系におけるケー
キングがなく、のびが軽く拡がりやすいメークア
ツプ化粧料特にルース状及びプレスト状メークア
ツプ化粧料を提供することにある。
本発明は顔料および／または粉体（以下総称し
て粉体基剤と云う。）に撥水剤（以下本明細書中
において、本発明に用いられる撥水剤とは、メチ
ルハイドロジエンポリシロキサンを必須成分とし
て含むシリコーン油をいう。）および油剤を適宜
選択してコーテイング、焼付け処理して得られる
組成物を含有したメークアツプ化粧料に関するも
ので、更に詳しくは、
(1) 粉体基剤に撥水剤をコーテイングし、焼付け
処理を施し、更にこれを油剤にてコーテイング
し、焼付け処理して得られる三層の構造を有す
る組成物（以下組成物Ａと云う。）を含有した
メークアツプ化粧料。
(2) 粉体基剤に油剤をコーテイングし、焼付け処
理を施し、更にこれを撥水剤にてコーテイング
し、焼付け処理して得られる三層の構造からな
る組成物（以下組成物Ｂと云う。）を含有した
メークアツプ化粧料。
(3) 粉体基剤に撥水剤と油剤との混合物をコーテ
イングし、焼付け処理を施して得られる二層の
構造を有する組成物（以下組成物Ｃと云う。）
を含有したメークアツプ化粧料。
(4) 上記(3)の組成物Ｃと粉体基剤との混合物を撥
水剤および／または油剤にてコーテイングし、
焼付け処理して得られる組成物（以下組成物Ｄ
と云う）を含有したメークアツプ化粧料。
に関するものである。
本発明に係わる組成物Ａ、Ｂ、Ｃ、Ｄに適用さ
れる顔料としては平均粒子径0.01〜1.2μのもの
が好ましく、酸化チタン、酸化亜鉛等の無機白色
顔料、酸化鉄（弁柄）、チタン酸鉄等の無機赤色
系顔料、黄酸化鉄、黄土等の無機黄色系顔料、マ
ンゴバイオレツト、コバルトバイオレツト等の無
機紫色系顔料、酸化クロム、水酸化クロム、コバ
ルトチタン酸等の無機緑色系顔料、群青、紺青等
の無機青色系顔料、酸チタンコーテイツド雲母、
酸化チタンコーテイツドオキシ塩化ビスマス、オ
キシ塩化ビスマス、酸化チタンコーテイツド硫酸
バリウム、酸化チタンコーテイツドタルク、魚鱗
箔、着色酸化チタンコーテイツド雲母等の真珠光
沢顔料、アルミニウムパウダー、カツパーパウダ
ー等の金属粉末顔料、赤色104号の(1)、黄色４
号、黄色５号、緑色３号、青色１号、青色２号、
赤色202号、赤色226号、赤色227号、赤色20号の
(1)、橙色206号、橙色207号、黄色202号の(1)、緑
色201号、緑色204号、青色201号、緑色205号等の
タール色素、カルミン酸、ラツカイン酸、カルサ
ミン、ブラジリン、クロシン等の天然色素をレー
キ化したもの、等が挙げられる。粉体としては平
均粒子径1.0〜20μ程度のものが好ましく、化粧
品に用いられるものであれば特に限定はなく、例
えばタルク、カオリン、セリサイト、白雲母、合
成雲母、金雲母、紅雲母、黒雲母、リチア雲母、
バーミキユライト、炭酸マグネシウム、炭酸カル
シウム、珪ソウ土、ケイ酸マグネシウム、ケイ酸
カルシウム、ケイ酸アルミニウム、ケイ酸バリウ
ム、ケイ酸ストロンチウム、タングステン酸金属
塩、α−酸化鉄、水和酸化鉄、シリカ、ハイドロ
キシアパタイト等の無機粉体、ナイロンパウダ
ー、ポリエチレン、ベンゾグアナミンパウダー、
四弗化エチレンパウダー、ジスチレンベンゼンピ
ンホールポリマーパウダー、微結晶性セルロース
等の有機粉体が挙げられるが、のびの軽さ、拡が
りやすさ、ケーキング防止に著しい効果を得るた
めにはは球状のものを適宜選択して用いることが
好ましく、その含有量は粉体基剤全量中１〜30重
量％程度がよい。（尚、これらを二種以上用いる
場合は、予め粉砕機にてよく粉砕、混合、分散さ
せておくことが好ましい。）しかし、ハイライタ
ー等として粉体基剤の100重量％に有機粉体が用
いられることもある。
また、組成物Ａ、Ｂ、Ｃ、Ｄに適用されるメチ
ルハイドロジエンポリシロキサンを必須成分とし
て含むことのできるシリコーン油としては、次の
一般式〔〕で示されるシリコーン油が用いら
れ、またそれらとともに一般式〔〕で示される
金属石ケンも用いられるもので、例えば前者とし
てはメチルハイドロジエンシリコーン、ジメチル
シリコーン、メチルフエニルシリコーン、ポリエ
ーテル変性シリコーン、オレフイン変性シリコー
ン、フツ素変性シリコーン、アルコール変性シリ
コーン、高級脂肪酸変性シリコーン、アミノ変性
シリコーン等であり、
一般式〔〕
（式中、n1は重合度で１〜300の整数、R1は水素
原子、ハロゲン原子、低級アルキル基、ベンジル
基、シクロヘキシル基、ナフチル基、フルフリル
基から選択された基を示す。）
一般式〔〕
（R2COO）o2Ｍ
（式中、R2は炭素数６〜22の脂肪族又は環状炭化
水素基、Ｍはアルカリ金属以外の金属、n2はその
金属の原子価を示す）
後者としてはステアリン酸アルミニウム、同マ
グネシウム、同亜鉛、同カルシウム、パルミチン
酸亜鉛、同アルミニウム、同マグネシウム、同カ
ルシウム、ラウリン酸亜鉛、同アルミニウム、同
マグネシウム、同カルシウム、オレイン酸亜鉛、
同アルミニウム、同マグネシウム、同カルシウ
ム、ミリスチン酸アルミニウム、同マグネシウ
ム、同亜鉛、同カルシウム、ラウリン酸アルミニ
ウム、同マグネシウム、同亜鉛、同カルシウム、
ベヘニン酸マグネシウム、同アルミニウム、同亜
鉛、同カルシウム等が挙げられる。
油剤としては化粧品に適用できる原料油剤で水
との親和性がなく撥水効果を有するものであれば
よく、スクワラン、流動パラフイン、ワセリン、
マイクロクリスタリンワツクス、オゾケライト、
セレシン、ミリスチン酸、パルミチン酸、ステア
リン酸、オレインイソステアリン酸、セチルアル
コール、ヘキサデシルアルコール、オレイルアル
コール、２−オクチルドデシルミリステート、２
−オクチルドデシルガムエステル、２−オクチル
ドデシルアビエテート、２−オクチルドデシルオ
レエート、イソプロピルミリステート、イソステ
アリン酸トリグリセライド、ヤシ油脂肪酸トリグ
リセライド、オリーブ油、アボガド油、ミツロ
ウ、ミリスチルミリステート、オリカオイル、ミ
ンク油、ラノリン等の各種炭化水素、高級脂肪
酸、油脂類、高級アルコール、ロウ類などがそれ
ぞれ選択して用いられる。
本発明に適用される前記組成物Ａ、Ｂ、Ｃ、Ｄ
において、核となる粉体基剤に対するコーテイン
グ層である撥水剤の組成は１：0.006〜１：
0.035、油剤の組成は１：0.005〜１：0.05、粉体
基剤と撥水剤および／または油剤との混合物は
１：0.005〜１：0.05の範囲が各組成物に共通し
てとられる。また焼付け処理としては温度80〜
140℃、1.5〜４時間程度が適用される。ここにお
いて留意すべきことは、第一にコーテイング層で
ある撥水剤、油剤の組成は核となる粉体基剤の表
面を完全に被覆するのに必要な範囲がとられる事
である。従つて0.5％以下程度では充分でなく、
又５％以上では品質に与える影響に大差なく、用
いるメリツトがない。第二に撥水剤単独を粉体基
剤に被覆したのでは、ある程度の皮膜性を有する
が他の粉体基剤への濡れ現象が極めて悪く化粧効
果を損うものである。第三に油剤単独で粉体基剤
に被覆したのでは、他の粉体への濡れ現象が良い
が皮膜性が非常に弱く実用に耐えないものであ
る。第四に撥水剤と油剤との混合物を粉体基剤に
被覆して場合では油剤と撥水剤とが単に混和して
粉体基剤の表面に付着或は吸着しているのみで、
撥水剤単独、油剤単独の性質を別々にもち合せて
いるにすぎないものである。第五に、第四の場合
は粉体基剤の表面に付着或は吸着しているのみ
で、機械的力、衡撃力、遠心力等により粉体基剤
表面から容易に剥離しやすいものであり本発明の
目的とするものが得られない事である。
本発明の各組成物は粉体基剤に撥水剤、油剤を
適宜の形でコーテイングし焼付け処理する事によ
り、撥水剤と油剤間の結合とそれらと粉体基剤中
の官能基との相互作用更には付着力、吸着力との
相乗作用により、非常に強靭な被覆膜を形成し目
的とするものを得るものである。第六には140℃
以上の焼付け温度では油剤の変質、分解の原因に
なり被覆膜の強度の低下があり、目的とする化粧
効果が得られず好ましくない。又粉体基剤中のタ
ール色素や天然色素をレーキ化したものに被覆す
る場合、それらの変色、褪色、分解を防止する意
味から80〜100℃が好ましく、無機白色顔料、無
機赤色系顔料、無機黄色系顔料、無機緑色系顔
料、魚鱗箔を除く真珠光沢顔料、金属粉末、無機
粉体等は油剤の変質分解を起さない範囲で行えば
よく、好ましくは工業的、経済的ベース、生産性
を考慮した場合より短時間で効率的に生産出来る
120〜140℃がよい。焼付け処理時間は、実験結果
から粉体基剤と油剤と撥水剤間の複雑な反応を完
結させるには1.5〜４時間を費す必要がある。又
これ以上の焼付け処理時間の必要性はなく、又こ
れ以下の時間では焼付けが不完全であり、目的と
する被覆膜の強度と化粧効果は得られない。
本発明メークアツプ化粧料に含有される組成物
Ａ、Ｂ、Ｃ、Ｄの好ましい各含有量は、乳化タイ
プの場合1.0〜40重量％、オイルゲルタイプの場
合0.5〜30重量％、プレスタイプの場合15〜90重
量％、ルースタイプの場合10〜90重量％がとられ
る。また、組成物Ａ、Ｂ、Ｃ、Ｄは、フエースパ
ウダー、パウダーアイシヤドウ、ダステイングパ
ウダー等のメークアツプ化粧料として100重量％
そのまま使用されることもできる。
本発明に適用される組成物Ａ、Ｂ、Ｃ、Ｄを得
る方法としては、組成物Ａまたは組成物Ｂの場合
は、撥水剤もしくは油剤を有機溶媒に溶解し、次
いで粉体基剤にこれを注入、撹拌しながら有機溶
媒を留去させ（必要ならば適宜乾燥し）て、粉体
基剤を核とし撥水剤もしくは油剤を第一コーテイ
ング層とする二層体を得、これを焼付け処理して
被膜強度を持たせ、更に油剤もしくは撥水剤を溶
解させた有機溶媒にこれを注入し、撹拌後、有機
溶媒を留去（必要ならば適宜乾燥）し、撥水剤の
表面には油剤を、油剤の表面には撥水剤をコーテ
イングして三層の構造となし、再度焼付け処理し
て目的とする組成物を得る方法が好適である。ま
た組成物Ｃの場合は、撥水剤と油剤との混合物を
有機溶媒に溶解し、次いで粉体基剤をこれに注
入、撹拌後、有機溶媒を留去（必要ならば適宜乾
燥）して、粉体基剤を核とし撥水剤と油剤との混
合物をコーテイング層とする二層体を得、これを
焼付け処理して目的とする組成物を得る方法が好
適である。更にまた組成物Ｄを得る場合は、前記
組成物Ｃと粉体基剤を混合し（必要ならば粉砕、
混合、分散させ）、撥水剤および／または油剤を
溶解させた有機溶媒にこれを注入、撹拌後、有機
溶媒を留去（必要ならば適宜乾燥）し、焼付け処
理して目的とする組成物を得る方法が好適であ
る。前記各工程中において用いられる有機溶媒と
しては、エチルアルコール、イソプロピルアルコ
ール、酢酸エチル、酢酸エチルエステル、酢酸ブ
チル、オクタン、クロロホルム、ベンゼン、トル
エン、キシレン、石油エーテル、アセトン等が挙
げられる。
また本発明にいう“コーテイング”とは必ずし
も均一に被覆する状態を意味するものではなく、
少なくとも撥水剤、油剤等の薄膜が適宜の粉体基
材を完全に被覆し、かつ密着した状態であること
を云う。
次に本発明に適用される組成物Ａ、Ｂ、Ｃ、Ｄ
の製法について詳細に述べる。（ ）内は好適な
範囲である。
〔製法 １〕
一種または二種以上の粉体基剤（好ましくは加
熱処理により予め減圧乾燥した粉体基剤、以下同
様）100部に対し、有機溶媒５〜200（50〜100）
部に撥水剤を0.6〜3.5（1.0〜3.0）部溶解させた
ものを注入できれば徐々に注入し、100℃以下
（常温付近）にて５分〜10時間撹拌好ましくは低
速回転にて撹拌しながら有機溶媒を留去し（必要
ならば適宜乾燥させ）、粉体基剤を核として撥水
剤をコーテイングし、温度80〜140（90〜130）℃
にて1.5〜４時間焼付け処理を行ない、冷却また
は常温付近に戻し、次いで撥水剤が溶解しないで
油剤が溶解するような有機溶媒５〜200（50〜
100）部に油剤0.5〜5.0（1.0〜3.0）部を溶解させ
たものにこれを注入できれば徐々に注入し、100
℃以下（常温付近）にて５分〜10時間撹拌しなが
ら有機溶媒を留去し（必要ならば適宜乾燥さ
せ）、電気炉または乾燥機等の焼付け用機器にて
80〜140（90〜130）℃、1.5〜４時間焼付け処理
するか、あるいは80〜140（90〜130）℃の温度で
撹拌しながら有機溶媒の留去と焼付け処理を同時
に行ない好ましくは更に放冷あるいは冷却して目
的とする三層の構造を有する組成物を得る。
〔製法 ２〕
一種または二種以上の粉体基剤100部に対し、
有機溶媒５〜200（50〜100）部に油剤を0.5〜5.0
（1.0〜3.0）部溶解させたものを注入できれば
徐々に注入し、100℃以下（常温付近）にて５分
〜10時間撹拌好ましくは低速回転にて撹拌しなが
ら有機溶媒を留去し（必要ならば適宜乾燥さ
せ）、粉体基剤を核として油剤をコーテイングし
温度80〜140（90〜130）℃にて、1.5〜4.0時間焼
付け処理を行ない、冷却または常温付近に戻し次
いで油剤が溶解しないで撥水剤が溶解するような
有機溶媒５〜200（50〜100）部に撥水剤0.6〜3.5
（1.0〜3.0）部を溶解させたものにこれを注入で
きれば徐々に注入し、100℃以下（常温付近）に
て５分〜10時間撹拌しながら有機溶媒を留去し
（必要ならば適宜乾燥させ）、電気炉または乾燥機
等の焼付け用機器にて80〜140（90〜130）℃、２
〜10時間焼付け処理するか、あるいは80〜140
（90〜130）℃の温度で撹拌しながら有機溶媒の留
去と焼付け処理を同時に行ない好ましくは更に放
冷あるいは冷却して目的とする三層の構造を有す
る組成物を得る。
〔製法 ３〕
一種または二種の粉体基剤100部に対し、有機
溶媒５〜200（50〜100）部に撥水剤0.6〜3.5（1.0
〜3.0）部と油剤0.5〜5.0（1.0〜3.0）部を溶解さ
せたものを注入できれば徐々に注入し、100℃以
下（常温付近）にて５分〜10時間撹拌好ましくは
低速回転にて撹拌しながら有機溶媒を留去し（必
要ならば適宜乾燥させ）、粉体基剤を核として撥
水剤と油剤の混合物をコーテイングし、電気炉ま
たは乾燥機等の焼付け用機器にて80〜140（90〜
130）℃、1.5〜4.0時間焼付け処理するか、ある
いは80〜140（90〜130）℃の温度で撹拌しながら
有機溶媒の留去と焼付け処理を同時に行ない好ま
しくは更に放冷あるいは冷却して目的とする二層
の構造を有する組成物を得る。
〔製法 ４〕
上記製法により得られた組成物20〜80部に通常
の粉体基剤80〜20部をヘンシエルミキサー、リボ
ンブレンダー、ナウターミキサー、Ｖ型ブレンダ
ー等の混合機で混合し好ましくはこれを更に粉
砕、混合、分散させ、次いで撥水剤及び油剤のい
ずれにも溶解しない有機溶媒５〜200（50〜100）
部中に撥水剤0.7〜2.8部および／または油剤0.4〜
1.0部を入れたものにこれを注入できれば徐々に
注入し、100℃以下（常温付近）にて５分〜10時
間撹拌しながら有機溶媒を留去し（必要ならば適
宜乾燥させ）、電気炉または乾燥機等の焼付け用
機器にて80〜140（90〜130）℃、1.5〜4.0時間焼
付け処理するか、あるいは80〜140（90〜130）℃
の温度で撹拌しながら有機溶媒の鷹留去と焼付け
処理を同時に行ない好ましくは更に放冷あるいは
冷却して目的とする組成物を得る。
上記の如くして得られた組成物はメークアツプ
化粧料用としてそのまま、あるいは結合油剤と組
合せ、または他の粉体基剤と組合せ、更には結合
油剤と他の粉体基剤とを混合しプレスすればケー
キ状に容易になるものであり、ルース状において
も撥水度の高い原料で強固に皮膜化されたもので
構成されているために粉体基剤が直接的に油分や
水分等の影響を受けずケーキングの防止効果も有
するものである。又撥水度の高い原材料を層とし
てコーテイングしかつそれらに焼付け効果による
皮膜の強度の増強がなされているため、粉砕力に
も充分に耐え、ルース及びプレスト状メークアツ
プ化粧料として、粉体や顔料へ濡れの変化がなく
化粧の経時変化を完全に防止するものである。
しかも粉体表面の性質が撥水度の高い油剤或は
撥水剤、又はそれらの混合により強固な膜で均質
化されているために密着感が向上し更には油剤の
選択或は油量により影響を受けやすい、粉体の劈
開作用は、阻止されず、特に球状粉体を用いた場
合においては球状粉体の転動効果のため油量の多
い系に於いても粉体の劈開効果と球状粉体の転動
効果の相乗作用により、のびが軽く拡がりやすい
性質が充分に発揮される。
本発明メークアツプ化粧料において上記組成物
Ａ、Ｂ、Ｃ、Ｄと結合油剤を組合せて含有させる
場合は化粧料全重量中95：５〜10：90、上記組成
物Ａ、Ｂ、Ｃ、Ｄと他の粉体基剤の場合は全重量
中99：１〜50：50、上記組成物Ａ、Ｂ、Ｃ、Ｄと
結合油剤と粉体基剤との組合せによる場合は全重
量中90：５：５〜15：25：23.5の範囲が好適であ
る。ここにおいて用いられる結合油剤は前記組成
物に適用された油剤ならびに撥水剤から選択さ
れ、また粉体基剤は前記組成物に適用されたもの
と同様のものでよい。更に本発明に適用される各
組成物と結合油剤、粉体基剤との組合せについて
詳述するならば、まず組成物Ａ、Ｂ、Ｃ、Ｄと結
合油剤とを用いたときには、化粧持ちのよさ特に
密着感に優れていると共に充填性が非常によいが
延展性に若干欠けるため使用部位の面積が小さい
適用されるポイントメーク料特にアイカラー、ル
ージユ等に好適である。二番目の組成物Ａ、Ｂ、
Ｃ、Ｄと他の粉体基剤とを用いたときには、特に
粉体の流動性があり、さつぱりとした使用感、密
着感がありかつケーキングしにくいため使用面積
の広いベースメークアツプ料あるいはボデイーメ
ークアツプ料でルース状のものに好適である。最
後の組成Ａ、Ｂ、Ｃ、Ｄ、結合油剤および粉体の
三者の組合せの場合には、特にのびの軽さ、延展
性、密着感に優れかつ充填性がよいので使用面積
の比較的拡いベースメークアツプ料特にプレスト
状タイプのものに好適である。これら各組合せは
特にプレスト状メークアツプ化粧料の場合、処方
中の総油量が35％以上になると、化粧用具特にパ
フ材を使用したときには、中皿より内容物が外側
にタレてくるタレ現象がみられるので、パフ材を
使用する際は、35％以下が好適である。
本発明において重要なことは、従来粉体基剤、
撥水剤、油剤を用いたものとして特開昭54−
14528においてプレス状メークアツプ組成物が見
出されているが、ここにおいては通常のプレス状
メークアツプ化粧料の製法により上記各成分を単
に混合したものが得られており、この場合粉体基
剤（特開昭54−14528中においてはこれらを化粧
料用粉体としている）は撥水剤、油剤との結合
（吸着、付着）が弱く、粉砕工程で化粧料粉体と
撥水剤、油剤とが一部分離し、水を使用した場合
の化粧の浮き、くすみがみられ肌への付着力も低
下し密着感を損うものであることが本発明者によ
り知見されたことである。本発明メークアツプ化
粧料において適用される各組成物は前述した如く
粉体基剤、撥水剤、油剤とが単に混合されたもの
ではなく、粉体基剤を核として撥水剤および油剤
でこれをコーテイングしかつ焼付け処理したもの
で、その被覆膜は非常に強固でしかも堅固な膜で
あり単一体となつて挙動し、種々の物性において
単なる混合物とは異なるものである。また特開昭
54−14528においては撥水剤が５％以下では撥水
効果はないとされているが、本発明の場合は有機
溶媒を用いた方法により化粧料粉体の表面を完全
に油剤及び撥水剤が被覆しているので５％以下で
も充分な撥水効果を得られるものである。
次に本発明メークアツプ化粧料が従来の特開昭
54−15428のプレス状メークアツプ組成物と比べ
如何に優れているかを実証するために行なつた(a)
比表面積（SN2m2／ｇ）、(b)水蒸気量（SH2Om2／
ｇ）、(c)粉体表面の親水化度（SH2O／SN2）、(d)
粉体表面の親油化度（１−〔SH2O／SN2〕）等の各
測定結果を次の第１表に示す。測定方法として
は、本発明後記実施例１、５、９と特開昭54−
14528の実施例１の各試料を0.6ｇを予め常温にて
減圧乾燥機で10時間程度前処理しこれを粉砕し、
下記第二表の測定条件にて、比表面積及び吸着測
定装置（島津製作所製）を用いて行なつた。
The present invention relates to a new makeup cosmetic, which does not cause makeup smearing and has good adhesion to the skin.
The main purpose is to provide a makeup cosmetic that prevents makeup from floating, dulling, etc. over time, prevents caking in the product system, and is light and easy to spread. Conventionally, commonly available make-up cosmetics, especially loose and pressed make-up cosmetics, differ in the degree of hydrophilicity and lipophilicity of the powder surface to which they are applied, as well as the difference in the degree of activation of the powder surface. The amount of oil that is unevenly attached or adsorbed to the surface of the powder with weak force and the differences in the HLB of the oil can cause makeup to smear or lack a sense of adhesion even when applied to the skin. It is customary. In addition, differences in the degree of hydrophilicity, degree of lipophilicity, crystal form, surface activity, and wetting phenomenon of the pigment surface due to the degree of affinity between the several types of pigments that are mixed into the powder occur over time. Problems with cosmetic effects such as floating makeup and dullness occurred, and the quality of the product was not always satisfactory. Currently, in the case of pressed makeup cosmetics that can be applied to the skin without using water, the puff that is applied is constantly placed on the surface of the cosmetic (cake), or the puff is used while it is dirty with sebum or sweat. If the powder is wet, oil or water on the puff or oil from the base foundation can easily penetrate between the particles of the cosmetic and cause cosmetic caking (a condition where the surface of the cake becomes shiny). This damaged the product value. On the other hand, in the case of pressed make-up cosmetics that are applied to the skin using water, they are usually composed of an oily system that is a mixture of powder and pigments, as well as oils and surfactants. When applied to the skin, water, oil, and surfactant are emulsified on the surface of the cosmetic. Due to the solubilization phenomenon caused by interaction with moisture that has adhered to the skin or penetrated into the cosmetic, the oil encapsulates powder and pigments and forms a hard gel structure, giving the surface of the cosmetic a ``shiny'' feel. This caused caking. In addition, most of the powder raw materials used in general powder cosmetics are composed of scale-like (plate-like), needle-like, or irregular shapes. However, even in such products, when the amount of oil applied increases, cleavage is inhibited, and in addition, acicular or irregularly shaped powders are When used in combination, it was extremely difficult to find ease of spreading and ease of spreading. As a result of various experimental studies, the present inventor has obtained the present invention which does not have such drawbacks. In other words, the main purpose of the present invention is to provide a makeup cosmetic that does not cause makeup to smear, has good adhesion to the skin, prevents makeup from lifting or dulling over time, does not cause caking in the product system, and is light and easy to spread. To provide loose and pressed makeup cosmetics. The present invention applies a pigment and/or powder (hereinafter collectively referred to as a powder base) to a water repellent (hereinafter, in this specification, the water repellent used in the present invention is methylhydrodiene polysiloxane). This refers to a make-up cosmetic containing a composition obtained by coating and baking with an appropriately selected silicone oil and an oil agent as an essential ingredient. A make-up cosmetic containing a composition having a three-layer structure (hereinafter referred to as composition A) obtained by coating with a water repellent, performing a baking treatment, further coating this with an oil agent, and performing a baking treatment. . (2) A composition consisting of a three-layer structure obtained by coating a powder base with an oil agent, baking it, coating it with a water repellent, and baking it (hereinafter referred to as composition B). Make-up cosmetics containing .). (3) A composition having a two-layer structure obtained by coating a powder base with a mixture of a water repellent agent and an oil agent and performing a baking process (hereinafter referred to as composition C).
Make-up cosmetics containing. (4) Coating the mixture of composition C in (3) above and a powder base with a water repellent and/or oil agent,
Composition obtained by baking treatment (hereinafter referred to as composition D)
make-up cosmetics containing It is related to. The pigments applied to compositions A, B, C, and D according to the present invention preferably have an average particle diameter of 0.01 to 1.2μ, and include inorganic white pigments such as titanium oxide and zinc oxide, iron oxide (bengara), Inorganic red pigments such as iron titanate, inorganic yellow pigments such as yellow iron oxide and loess, inorganic purple pigments such as mango violet and cobalt violet, inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate. pigments, inorganic blue pigments such as ultramarine blue and navy blue, acid titanium coated mica,
Pearlescent pigments such as titanium oxide coated bismuth oxychloride, bismuth oxychloride, titanium oxide coated barium sulfate, titanium oxide coated talc, fish scale foil, colored titanium oxide coated mica, aluminum powder, cutpur powder Metal powder pigments such as Red No. 104 (1), Yellow No. 4
No., Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2,
Red No. 202, Red No. 226, Red No. 227, Red No. 20.
(1), Orange No. 206, Orange No. 207, Yellow No. 202 (1), Tar pigments such as Green No. 201, Green No. 204, Blue No. 201, Green No. 205, carminic acid, latscaic acid, calsamine, Brazilin, Examples include lakes of natural pigments such as crocin. The powder preferably has an average particle diameter of about 1.0 to 20 μm, and is not particularly limited as long as it can be used in cosmetics, such as talc, kaolin, sericite, muscovite, synthetic mica, phlogopite, rhodochite, black mica, lithium mica,
Vermiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, magnesium silicate, calcium silicate, aluminum silicate, barium silicate, strontium silicate, metal tungstate, α-iron oxide, hydrated iron oxide, silica , inorganic powder such as hydroxyapatite, nylon powder, polyethylene, benzoguanamine powder,
Examples include organic powders such as tetrafluoroethylene powder, distyrene benzene pinhole polymer powder, and microcrystalline cellulose. It is preferable to select and use an appropriate amount of the powder base, and the content thereof is preferably about 1 to 30% by weight based on the total amount of the powder base. (In addition, when using two or more of these, it is preferable to thoroughly crush, mix, and disperse them in a crusher in advance.) However, as a highlighter, etc., 100% by weight of the powder base contains organic powder. Sometimes used. In addition, as the silicone oil that can contain methylhydrodiene polysiloxane as an essential component, which can be applied to compositions A, B, C, and D, silicone oils represented by the following general formula [] are used; In addition, metal soaps represented by the general formula [] are also used; examples of the former include methylhydrogen silicone, dimethyl silicone, methylphenyl silicone, polyether-modified silicone, olefin-modified silicone, fluorine-modified silicone, and alcohol-modified silicone. silicone, higher fatty acid-modified silicone, amino-modified silicone, etc., with the general formula [] (In the formula, n 1 is the degree of polymerization and is an integer from 1 to 300, and R 1 is a group selected from a hydrogen atom, a halogen atom, a lower alkyl group, a benzyl group, a cyclohexyl group, a naphthyl group, and a furfuryl group.) General Formula [] (R 2 COO) o2 M (In the formula, R 2 is an aliphatic or cyclic hydrocarbon group having 6 to 22 carbon atoms, M is a metal other than an alkali metal, and n 2 represents the valence of the metal) The latter include aluminum stearate, magnesium stearate, zinc stearate, calcium stearate, zinc palmitate, aluminum stearate, magnesium stearate, calcium stearate, zinc laurate, aluminum stearate, magnesium stearate, calcium stearate, zinc oleate,
Aluminum, Magnesium, Calcium, Aluminum myristate, Magnesium, Zinc, Calcium, Aluminum laurate, Magnesium, Zinc, Calcium,
Examples include magnesium behenate, aluminum behenate, zinc behenate, and calcium behenate. The oil agent may be a raw material oil agent that can be used in cosmetics, as long as it has no affinity with water and has a water-repellent effect, such as squalane, liquid paraffin, petrolatum,
Microcrystalline wax, ozokerite,
Ceresin, myristic acid, palmitic acid, stearic acid, oleic isostearic acid, cetyl alcohol, hexadecyl alcohol, oleyl alcohol, 2-octyldodecyl myristate, 2
-Octyldodecyl gum ester, 2-octyldodecyl abietate, 2-octyldodecyl oleate, isopropyl myristate, isostearic acid triglyceride, coconut oil fatty acid triglyceride, olive oil, avocado oil, beeswax, myristyl myristate, orica oil, mink oil, Various hydrocarbons such as lanolin, higher fatty acids, oils and fats, higher alcohols, waxes, etc. are selected and used. The compositions A, B, C, D applied to the present invention
In the above, the composition of the water repellent which is the coating layer for the powder base which is the core is 1:0.006 to 1:
0.035, the composition of the oil agent is in the range of 1:0.005 to 1:0.05, and the mixture of the powder base and the water repellent and/or oil agent is in the range of 1:0.005 to 1:0.05 in common for each composition. Also, as a baking process, the temperature is 80~
140°C for about 1.5 to 4 hours is applied. The first thing to keep in mind here is that the composition of the water repellent agent and oil agent that constitute the coating layer is within the range necessary to completely cover the surface of the core powder base. Therefore, 0.5% or less is not sufficient,
Moreover, if it exceeds 5%, there is no significant difference in the effect on quality, and there is no merit in using it. Second, when a powder base is coated with a water repellent alone, it has a certain degree of film properties, but the wetting phenomenon to other powder bases is extremely poor, impairing the cosmetic effect. Thirdly, when a powder base is coated with an oil agent alone, the wetting phenomenon to other powders is good, but the film properties are very weak and cannot be put to practical use. Fourth, when a powder base is coated with a mixture of a water repellent and an oil, the oil and water repellent simply mix and adhere or adsorb to the surface of the powder base.
It simply combines the properties of a water repellent alone and an oil agent alone. Fifth, in the fourth case, the material is only attached or adsorbed to the surface of the powder base, and is easily peeled off from the surface of the powder base due to mechanical force, equilibrium force, centrifugal force, etc. Therefore, the object of the present invention cannot be obtained. Each of the compositions of the present invention is produced by coating a powder base with a water repellent agent and an oil agent in an appropriate form and baking it to form a bond between the water repellent agent and the oil agent and the functional groups in the powder base. The synergistic effect of the interaction with the adhesion and adsorption forces forms a very tough coating film to obtain the desired product. The sixth is 140℃
A baking temperature higher than this is undesirable because it causes deterioration and decomposition of the oil agent and reduces the strength of the coating film, making it impossible to obtain the desired cosmetic effect. In addition, when coating tar pigments or natural pigments in a powder base in the form of a lake, the temperature is preferably 80 to 100 °C in order to prevent discoloration, fading, and decomposition. Inorganic yellow pigments, inorganic green pigments, pearlescent pigments other than fish scale foil, metal powders, inorganic powders, etc. may be used as long as they do not cause alteration or decomposition of the oil, preferably on an industrial, economical basis, and production. It can be produced more efficiently in a shorter time than when considering the
120-140℃ is good. Based on experimental results, the baking process requires 1.5 to 4 hours to complete the complex reaction between the powder base, oil, and water repellent. Further, there is no need for a longer baking time; if the baking time is shorter than this, the baking will be incomplete and the intended strength and cosmetic effect of the coating film will not be achieved. The preferable contents of compositions A, B, C, and D contained in the makeup cosmetic of the present invention are 1.0 to 40% by weight in the case of emulsion type, 0.5 to 30% by weight in case of oil gel type, and 15% by weight in case of press type. ~90% by weight, and 10-90% by weight for loose types. In addition, compositions A, B, C, and D can be used at 100% by weight as makeup cosmetics such as face powder, powder eye shadow, and dusting powder.
It can also be used as is. In the case of composition A or composition B, the method for obtaining compositions A, B, C, and D applied to the present invention is to dissolve the water repellent or oil agent in an organic solvent, and then add it to the powder base. Inject this and distill off the organic solvent while stirring (and dry as necessary) to obtain a two-layered product with the powder base as the core and the water repellent or oil agent as the first coating layer. Baking treatment is performed to give the film strength, and this is then injected into an organic solvent in which an oil or water repellent has been dissolved. After stirring, the organic solvent is distilled off (and dried if necessary), and the surface of the water repellent is A suitable method is to coat the surface of the oil agent with an oil agent and a water repellent agent to form a three-layer structure, and then bake the product again to obtain the desired composition. In the case of composition C, a mixture of a water repellent agent and an oil agent is dissolved in an organic solvent, and then the powder base is poured into this, and after stirring, the organic solvent is distilled off (and dried if necessary). A preferred method is to obtain a two-layered product having a powder base as a core and a coating layer of a mixture of a water repellent agent and an oil agent, and then bake this to obtain the desired composition. Furthermore, when obtaining composition D, the composition C and a powder base are mixed (pulverized if necessary).
Mix and disperse), pour this into an organic solvent in which a water repellent and/or oil agent has been dissolved, stir, then distill off the organic solvent (and dry as necessary), and bake to obtain the desired composition. The preferred method is to obtain . Examples of the organic solvent used in each step include ethyl alcohol, isopropyl alcohol, ethyl acetate, ethyl acetate, butyl acetate, octane, chloroform, benzene, toluene, xylene, petroleum ether, acetone, and the like. Furthermore, "coating" as used in the present invention does not necessarily mean a state of uniform coating;
This means that at least a thin film of water repellent, oil, etc. completely covers and adheres to the appropriate powder base material. Next, compositions A, B, C, D applied to the present invention
The manufacturing method will be described in detail. The values in parentheses are suitable ranges. [Production method 1] 5 to 200 (50 to 100) organic solvent per 100 parts of one or more powder bases (preferably powder bases that have been previously dried under reduced pressure by heat treatment, the same applies hereinafter).
If possible, gradually inject 0.6 to 3.5 (1.0 to 3.0) parts of a water repellent into the mixture, and stir at 100°C or below (near room temperature) for 5 minutes to 10 hours, preferably at low speed. The organic solvent is distilled off (dried as necessary if necessary), the water repellent is coated using the powder base as a core, and the temperature is 80-140 (90-130)℃.
Baking treatment for 1.5 to 4 hours at
If possible, gradually inject this into a solution of 0.5 to 5.0 (1.0 to 3.0) parts of an oil agent in 100 parts.
Distill the organic solvent away while stirring for 5 minutes to 10 hours at a temperature below ℃ (near room temperature) (dry as necessary), and use baking equipment such as an electric furnace or dryer.
Baking treatment at 80-140 (90-130) °C for 1.5-4 hours, or simultaneous distillation of the organic solvent and baking treatment with stirring at a temperature of 80-140 (90-130) °C, preferably further baking. A composition having the desired three-layer structure is obtained by cooling or cooling. [Production method 2] For 100 parts of one or more powder bases,
0.5 to 5.0 parts of oil to 5 to 200 (50 to 100) parts of organic solvent
(1.0 to 3.0%) of dissolved material is injected gradually if possible, and stirred for 5 minutes to 10 hours at 100℃ or below (near room temperature). Distill the organic solvent off while stirring preferably at low speed (nearly normal temperature). If so, dry as appropriate), coat the oil using the powder base as a core, perform baking treatment at a temperature of 80 to 140 (90 to 130) ℃ for 1.5 to 4.0 hours, cool or return to around room temperature, and then the oil will dissolve. Add 0.6 to 3.5 parts of water repellent to 5 to 200 (50 to 100) parts of an organic solvent in which the water repellent can be dissolved.
(1.0 to 3.0) parts dissolved, if possible, slowly inject it, and while stirring at 100℃ or below (near room temperature) for 5 minutes to 10 hours, distill off the organic solvent (if necessary, dry it as necessary). 80-140 (90-130)℃, 2 in baking equipment such as electric furnace or dryer
Baking process for ~10 hours or 80~140
Distillation of the organic solvent and baking treatment are carried out at the same time with stirring at a temperature of (90 to 130) DEG C., and preferably, the mixture is allowed to stand or is further cooled to obtain a composition having the desired three-layer structure. [Production method 3] 100 parts of one or two types of powder base, 5 to 200 (50 to 100) parts of organic solvent, and 0.6 to 3.5 (1.0) parts of water repellent.
If possible, slowly inject a mixture of ~3.0 parts) and 0.5 to 5.0 parts (1.0 to 3.0) parts of an oil agent, and stir for 5 minutes to 10 hours at 100°C or below (near room temperature), preferably at low speed. The organic solvent is distilled off (and dried if necessary), and a mixture of water repellent and oil is coated using the powder base as a core. (90～
130)℃ for 1.5 to 4.0 hours, or simultaneously distilling off the organic solvent and baking while stirring at a temperature of 80 to 140 (90 to 130)℃, preferably further cooling or leaving it for the purpose. A composition having a two-layer structure is obtained. [Production method 4] Preferably, 20 to 80 parts of the composition obtained by the above production method is mixed with 80 to 20 parts of a normal powder base using a mixer such as a Henschel mixer, a ribbon blender, a Nauta mixer, or a V-type blender. This is further pulverized, mixed, and dispersed, and then an organic solvent 5 to 200 (50 to 100) that does not dissolve in either the water repellent or the oil agent is added.
0.7 to 2.8 parts of water repellent and/or 0.4 to 2.8 parts of oil agent
If possible, gradually inject this into a container containing 1.0 part of it, and distill off the organic solvent while stirring for 5 minutes to 10 hours at 100°C or below (near room temperature) (dry as necessary), and heat in an electric furnace. Or bake in a dryer or other baking equipment at 80 to 140 (90 to 130) degrees Celsius for 1.5 to 4.0 hours, or 80 to 140 (90 to 130) degrees Celsius.
The organic solvent is distilled off and the baking treatment is carried out at the same time with stirring at a temperature of 10.degree. C., and the desired composition is preferably left to stand or cooled. The composition obtained as described above can be used as a make-up cosmetic as it is, or in combination with a binder oil, or in combination with another powder base, or mixed with a binder oil and another powder base and pressed. Even in loose form, it is made of a highly water-repellent raw material with a strong coating, so the powder base directly absorbs oil, moisture, etc. It is unaffected and also has the effect of preventing caking. In addition, since the coating is coated with a layer of highly water-repellent raw materials and the strength of the coating is enhanced by the baking effect, it can withstand crushing forces and can be used as a powder or pigment for loose and pressed make-up cosmetics. There is no change in wetness and completely prevents makeup from changing over time. Moreover, the properties of the powder surface are homogenized with a strong film formed by a highly water-repellent oil or water repellent, or a mixture thereof, which improves the adhesion. The cleavage effect of the powder, which is easily affected, cannot be prevented, and especially when spherical powder is used, the rolling effect of the spherical powder will prevent the cleavage effect of the powder even in a system with a large amount of oil. Due to the synergistic effect of the rolling effect of the spherical powder, the property of being light and easy to spread is fully exhibited. When the make-up cosmetics of the present invention contain a combination of the above compositions A, B, C, and D and a binding oil agent, the proportion of the above compositions A, B, C, and D in the total weight of the cosmetic is 95:5 to 10:90. In the case of other powder bases, it is 99:1 to 50:50 in the total weight, and in the case of a combination of the above compositions A, B, C, and D, the binding oil agent, and the powder base, it is 90:5 in the total weight. :5 to 15:25:23.5 is suitable. The binder oil used herein is selected from the oils and water repellents applied to the composition, and the powder base may be the same as that applied to the composition. Furthermore, to explain in detail the combinations of each composition applied to the present invention, a binder oil agent, and a powder base, first, when compositions A, B, C, and D and a binder oil agent are used, the makeup lasts longer. Although it has excellent adhesion and very good filling properties, it is slightly lacking in spreadability, so it is suitable for point makeup, especially eye color, rouge, etc., where the area to be used is small. second composition A, B,
When C, D and other powder bases are used, it is a base make-up that can be used over a wide area because the powder has fluidity, has a refreshing feel, has a feeling of adhesion, and is difficult to cake. Alternatively, it is suitable for use as a body make-up agent in loose form. In the case of the last combination of compositions A, B, C, and D, the binder oil agent, and the powder, it is particularly easy to spread, has excellent spreadability, adhesion, and has good filling properties, so the area used is relatively small. Suitable for spreading base makeup, especially pressed type. These combinations are particularly important in the case of pressed makeup cosmetics, and if the total amount of oil in the formulation exceeds 35%, when using cosmetic tools, especially puff materials, the contents may drip from the inner tray to the outside. Therefore, when using puff material, 35% or less is suitable. What is important in the present invention is that the conventional powder base,
Unexamined Japanese Patent Publication 1973-1987 as a product using water repellent and oil agent.
A pressed make-up composition has been found in No. 14528, in which the above-mentioned components are simply mixed together using a conventional method for producing pressed make-up cosmetics, and in this case, a powder base (especially During the 1973-14528 period, these were used as powders for cosmetics), but the bond (adsorption, adhesion) with water repellents and oil agents is weak, and the cosmetic powders and water repellents and oil agents are separated during the crushing process. The inventor of the present invention found that the makeup partially separates, and when water is used, makeup floats and becomes dull, and the adhesion to the skin decreases, impairing the feeling of adhesion. As mentioned above, each composition applied in the make-up cosmetics of the present invention is not simply a mixture of a powder base, a water repellent, and an oil agent, but is a mixture of a powder base, a water repellent agent, and an oil agent. The coating film is a very strong and solid film that behaves as a single body, and is different from a simple mixture in various physical properties. Also Tokkai Akira
54-14528, it is said that there is no water repellent effect if the water repellent is less than 5%, but in the case of the present invention, the surface of the cosmetic powder is completely coated with oil and water repellent by a method using an organic solvent. Since it is coated with water, a sufficient water repellent effect can be obtained even if the amount is 5% or less. Next, the make-up cosmetics of the present invention are
This study was conducted to demonstrate how superior this composition is compared to the pressed makeup composition of No. 54-15428 (a)
Specific surface area (SN 2 m 2 /g), (b) water vapor content (SH 2 Om 2 /
g), (c) degree of hydrophilicity of powder surface (SH 2 O/SN 2 ), (d)
The results of measurements such as the degree of lipophilization of the powder surface (1-[SH 2 O/SN 2 ]) are shown in Table 1 below. The measuring method is as follows: Examples 1, 5, and 9 of the present invention, and JP-A-1989-1999-
0.6 g of each sample of Example 1 of 14528 was pretreated in a vacuum dryer at room temperature for about 10 hours, and then pulverized.
The measurements were carried out using a specific surface area and adsorption measuring device (manufactured by Shimadzu Corporation) under the measurement conditions shown in Table 2 below.
【表】
第二表 測定条件
検出器内の温度65℃ 電流75ｍＡ
ヘリウムガスの流量26.67ml／分
カラム温度 50℃ 電圧32ｍＶ
チツソガスの流量12.04ml／分
（評価）
第一表において、本発明の場合粉体表面を完全
に被覆していることの目安となる粉体表面の親油
化度はいずれもほゞ１に相当し、粉砕されても油
剤、撥水剤が粉体基剤に強固に結合されているこ
とが判る。これに対し、特開昭54−14528は約1/2
であり不充分な結合すなわち単なる付着、あるい
は吸着にすぎない。従つて本発明が特開昭54−
14528と異なる構造を有することは明らかであ
る。
次に後記実施例１、３と市販のパウダーフアン
デーシヨン、特開昭54−14528の実施例１とのそ
れぞれについて、女性パネル250名を対象として
１ケ月の使用テストを行なつた官能評価の結果を
第三表に示す。Xaは本発明実施例１、Xbは本発
明実施例３、Ｙは市販のパウダーフアンデーシヨ
ン、Ｚは特開昭54−14528の実施例１である。[Table] Table 2 Measurement conditions Temperature inside the detector 65℃ Current 75mA
Helium gas flow rate 26.67ml/min Column temperature 50℃ Voltage 32mV
Chitsuso gas flow rate 12.04 ml/min (evaluation) In Table 1, in the case of the present invention, the lipophilicity degree of the powder surface, which is a guideline for completely covering the powder surface, is approximately 1. However, it can be seen that even after being crushed, the oil agent and water repellent agent are firmly bonded to the powder base. On the other hand, JP-A-54-14528 is about 1/2
This is insufficient bonding, that is, mere adhesion or adsorption. Therefore, the present invention is disclosed in Japanese Patent Application Laid-Open No. 1983-
It is clear that it has a different structure from 14528. Next, we conducted a one-month usage test on 250 female panelists for the sensory evaluation of Examples 1 and 3 described below and the commercially available powder foundation, Example 1 of JP-A-14528. The results are shown in Table 3. Xa is Example 1 of the present invention, Xb is Example 3 of the present invention, Y is a commercially available powder foundation, and Z is Example 1 of JP-A No. 54-14528.
次に、本発明に適用される組成物について、コ
ーテイング強度試験を行ないその結果を第四表に
示す。このとき、対照品としては従来の粉体とし
て、粉体にメチルハイドロジエンポリシロキサン
（以下シリコーンＡと略す。）を焼付け処理し、さ
らにオイルコーテイングした処理粉体を用いた。
溶出率が小さい程、コーテイング強度が大きく、
優れていることを意味している。試験方法は下記
の通りである。
＜試料＞
●粉体
セリサイト45部、白雲母20部、球状多孔質ケイ
酸カルシウム20部、カオリン10部、弁柄５部をヘ
ンシエルミキサーで均一に混合したものを混合粉
体Ａとして用いる。
●油剤
イソプロピルミリステート１部、アボカド油１
部、オレイン酸１部を均一に混合したものを油剤
Ｂとして用いる。
(イ) 混合粉体A100部に、シリコーンA2部をキシ
レン70部に溶解せしめた溶液を徐々に加えなが
ら攪拌し、均一なものとし、さらに温度90℃で
９時間攪拌を続けてキシレンを除去する。次
に、温度130℃で３時間焼付処理を行なつた
後、常温に戻し、これに油剤B3部をイソプロ
パノール50部に溶解せしめた溶液を徐々に加え
ながら攪拌し、均一なものとし、さらに温度90
℃で４時間攪拌を続けて、イソプロパノールの
留去と焼付処理を同時に行ない試料(イ)の粉体を
得る。（本発明品）
(ロ) 混合物体100部に、油剤B3部をイソプロパノ
ール50部に溶解せしめた溶液を徐々に加えなが
ら攪拌し、均一なものとし、さらに熱風乾燥機
を用いて温度60℃でイソプロパノールを留去す
る。次に、温度80℃で５時間焼付処理を行なつ
た後、常温に戻し、これにシリコーンA2部を
キシレン70部に溶解せしめた溶液を徐々に加え
ながら攪拌し、均一なものとし、これを温度85
℃で５時間攪拌を続けて、キシレンを留去し、
さらに温度130℃で３時間焼付処理を行ない試
料(ロ)の粉体を得る。（本発明品）
(ハ) 混合粉体A100部に、シリコーンA2部及び油
剤B3部をイソプロパノールとキシレンの１：
１重量混合物70部に溶解せしめた溶液を徐々に
加えながら攪拌し、均一なものとし、さらに熱
風乾燥機を用いて温度60℃で溶媒を留去した
後、温度130℃で３時間焼付処理を行ない試料
(ハ)の粉体を得る。（本発明品）
(ニ) ベンゾグアナミンパウダー100部に、シリコ
ーンA2部及び油剤B3部をイソプロパノールと
ベンゼンの１：１重量混合物70部に溶解せしめ
た溶液を徐々に加えながら攪拌し、均一なもの
とし、さらに熱風乾燥機を用いて温度60℃で溶
媒を留去した後、温度80℃で５時間焼付処理を
行う。得られた処理粉体に微結晶性セルロース
量50部を加えて均一に混合し、これにシリコー
ンA2部をベンゼン70部に溶解せしめた溶液を
徐々に加えながら攪拌して均一なものとし、熱
風乾燥機を用いて温度60℃で溶媒を留去した
後、温度80℃で３時間焼付処理を行ない試料(ニ)
の粉体を得る。
(ホ) 混合粉体A100部に、シリコーンA2部をキシ
レン70部に溶解せしめた溶液を徐々に加えなが
ら攪拌し、均一なものとし、さらに温度90℃で
９時間攪拌を続けてキシレンを留去する。次
に、温度130℃で３時間焼付処理を行なつた
後、常温に戻し、これに油剤B3部をスプレー
ノズルを用いて噴霧し、ヘンシエルミキサーに
より均一に混合して試料(ホ)の粉体を得る。（対
照品）
＜試験方法＞
各試料５ｇをそれぞれソツクスレー抽出器に入
れ、ｎ−ヘキサン100mlを用いて、温度80℃で12
時間抽出し、溶出する油分を抽出液として採取す
る。次に、この抽出液を温度105℃で１時間加熱
し、ｎ−ヘキサンを留去、乾燥して得られた油分
重量を測定して、これを溶出油分重量とし、下式
により溶出率を算出し結果を第四表に示す。
溶出率（％）＝溶出油分重量（ｇ）／試料重量（ｇ
）×100
Next, a coating strength test was conducted on the composition applied to the present invention, and the results are shown in Table 4. At this time, as a control product, a treated powder was used as a conventional powder, which was treated by baking methylhydrodiene polysiloxane (hereinafter referred to as silicone A) and further coated with oil.
The smaller the elution rate, the greater the coating strength.
It means being excellent. The test method is as follows. <Sample> ●Powder 45 parts of sericite, 20 parts of muscovite, 20 parts of spherical porous calcium silicate, 10 parts of kaolin, and 5 parts of Bengara are uniformly mixed in a Henschel mixer and used as mixed powder A. . ●Oil agent: 1 part isopropyl myristate, 1 part avocado oil
A homogeneous mixture of 1 part of oleic acid and 1 part of oleic acid is used as oil agent B. (b) Gradually add a solution of 2 parts of silicone A dissolved in 70 parts of xylene to 100 parts of mixed powder A and stir until homogeneous. Continue stirring at a temperature of 90°C for 9 hours to remove xylene. . Next, after performing baking treatment at a temperature of 130°C for 3 hours, the temperature was returned to room temperature, and a solution of 3 parts of oil agent B dissolved in 50 parts of isopropanol was gradually added to this while stirring to make it uniform, and the temperature was further increased. 90
Stirring was continued at ℃ for 4 hours, and the isopropanol was distilled off and baked at the same time to obtain a powder sample (a). (Product of the present invention) (b) A solution prepared by dissolving 3 parts of oil agent B in 50 parts of isopropanol was gradually added to 100 parts of the mixture, stirring to make it homogeneous, and then drying it at a temperature of 60°C using a hot air dryer. Distill off the isopropanol. Next, after performing baking treatment at a temperature of 80°C for 5 hours, the temperature was returned to room temperature, and a solution of 2 parts of silicone A dissolved in 70 parts of xylene was gradually added and stirred to make it homogeneous. temperature 85
Continue stirring at °C for 5 hours to distill off xylene.
Further, baking treatment was performed at a temperature of 130°C for 3 hours to obtain a powder sample (b). (Product of the present invention) (c) 100 parts of mixed powder A, 2 parts of silicone A, 3 parts of oil agent B, and 1 part of isopropanol and xylene.
A solution dissolved in 70 parts of 1 weight mixture was gradually added and stirred to make it homogeneous, and then the solvent was distilled off using a hot air dryer at a temperature of 60°C, and then baked at a temperature of 130°C for 3 hours. conduct sample
Obtain the powder (c). (Product of the present invention) (d) A solution prepared by dissolving 2 parts of silicone A and 3 parts of oil agent B in 70 parts of a 1:1 weight mixture of isopropanol and benzene is gradually added to 100 parts of benzoguanamine powder and stirred until homogeneous. Further, after distilling off the solvent at a temperature of 60°C using a hot air dryer, a baking treatment is performed at a temperature of 80°C for 5 hours. 50 parts of microcrystalline cellulose was added to the obtained treated powder and mixed uniformly. A solution of 2 parts of silicone A dissolved in 70 parts of benzene was gradually added to this while stirring to make it homogeneous. After distilling off the solvent at a temperature of 60℃ using a dryer, baking treatment was performed at a temperature of 80℃ for 3 hours to obtain sample (d).
powder is obtained. (e) Gradually add a solution of 2 parts of silicone A dissolved in 70 parts of xylene to 100 parts of mixed powder A, stir to make it homogeneous, and continue stirring at a temperature of 90°C for 9 hours to distill off xylene. do. Next, after performing baking treatment at a temperature of 130°C for 3 hours, the temperature was returned to room temperature, and 3 parts of oil agent B was sprayed on this using a spray nozzle, and mixed uniformly with a Henschel mixer to form a sample (E) powder. Get a body. (Control product) <Test method> 5 g of each sample was placed in a Soxhlet extractor, and 100 ml of n-hexane was used at a temperature of 80°C for 12 hours.
Extract for a time and collect the eluted oil as an extract. Next, this extract was heated at a temperature of 105℃ for 1 hour, n-hexane was distilled off, and the weight of the oil obtained was measured. This was taken as the weight of the eluted oil, and the elution rate was calculated using the following formula. The results are shown in Table 4. Elution rate (%) = eluted oil weight (g) / sample weight (g)
)×100
【表】
上記の実験データより明らかな如く、本発明に
適用される組成物は、シリコーン油及び油剤と粉
体が強固に固着しており、有機溶媒等に油分が溶
出しにくいものである。これは、焼付け処理によ
りシリコーン油と油剤の相互作用的な固着化が進
行する為ではないかと本発明者等は推察した。一
方、従来の粉体である対照品は油剤が粉体に固着
されておらず、単なる付着状態であるので有機溶
媒等により容易に油剤が溶出してしまうので、化
粧料に配合した場合には化粧くずれ等を引き起こ
し易いのである。
次に本発明に適用される組成物について、その
優秀性を証明する為、官能評価を行ない結果を第
五表に示す。尚、試料はコーテイング強度試験に
用いたものと同じものを使用した。試験方法は下
記の通りである。
官能テスト：
男女混合計20名のパネラーにより官能評価項目
として化粧持続性、肌への付着性、皮膚上での伸
びの良さ、肌へのつきの均一性の４項目について
下記のような基準において評価し、20名の平均値
を評価点とした。[Table] As is clear from the above experimental data, in the composition applied to the present invention, the silicone oil and oil agent are firmly adhered to the powder, and the oil component is difficult to dissolve into organic solvents and the like. The present inventors surmised that this was due to the interactive fixation between the silicone oil and the oil agent progressing during the baking process. On the other hand, in the conventional powder-based control product, the oil agent is not fixed to the powder and is simply attached, so the oil agent is easily eluted by organic solvents, etc., so when incorporated into cosmetics, This can easily cause makeup to come off. Next, in order to prove the superiority of the composition applied to the present invention, a sensory evaluation was conducted and the results are shown in Table 5. Note that the same sample used in the coating strength test was used. The test method is as follows. Sensory test: A panel of 20 mixed men and women evaluated the following four sensory evaluation items: makeup persistence, adhesion to the skin, spreadability on the skin, and uniformity of application on the skin. The average value of the 20 participants was used as the evaluation score.
【表】
に なら に
いと
も
[Table] ni if ni
Ito
too
【表】
数値は官能テスト評価点
以上の如く本発明に適用される組成物は皮膚上
に塗布した場合に、化粧持続性に優れており、肌
への付着性、皮膚上での伸びの良さ、肌へのつき
の均一性などの官能特性にも優れている。したが
つて、本発明に用いる上記の組成物（コーテイン
グ粉体）は従来の化粧品用顔料には見られない優
れた特性を有する粉体であることがわかる。
次に本発明メークアツプ化粧料の実施例を述べ
る。配合割合は重量部である。
実施例 １
フエースパウダー
タルク10部、セリサイト30部、酸化チタン７
部、球状ケイ酸マグネシウム４部、弁柄４部、合
成雲母45部等の予め減圧乾燥した粉体基剤計100
部に対し、キシレン70部にメチルハイドロジエン
ポリシロキサン2.0部を溶解させたものを徐々に
注入し、80℃にて30分間低速回転にて撹拌しなが
ら有機溶媒をぜ留去し、粉体基剤を核としてメチ
ルハイドロジエンポリシロキサンを100：２の割
合でコーテイングし、130℃にて1.5時間焼付け処
理を行ない、常温付近に戻し、次いでエチルアル
コール50部にイソプロピルミリステート1.0部、
セチルアルコール1.0部を溶解させたものにこれ
を徐々に注入し、120℃にて４時間撹拌しながら
有機溶媒を留去と焼付け処理を同時に行ない冷却
後取り出した組成物98部を得、粉砕機にて粉砕し
て製品フエースパウダーとする。
実施例 ２
フアンデーシヨン[Table] Numerical values are sensory test evaluation points As described above, the composition applied to the present invention has excellent makeup persistence when applied to the skin, and has good adhesion to the skin and good spreadability on the skin. It also has excellent organoleptic properties such as uniformity of application to the skin. Therefore, it can be seen that the above composition (coating powder) used in the present invention is a powder having excellent properties not found in conventional cosmetic pigments. Next, examples of the makeup cosmetics of the present invention will be described. The blending ratio is in parts by weight. Example 1 Phase powder: 10 parts of talc, 30 parts of sericite, 7 parts of titanium oxide
A total of 100 parts of powder base dried under reduced pressure, such as 4 parts of spherical magnesium silicate, 4 parts of Bengara, and 45 parts of synthetic mica.
2.0 parts of methylhydrodienepolysiloxane dissolved in 70 parts of xylene was gradually poured into 100 parts of the powder base, and the organic solvent was distilled off while stirring at low speed for 30 minutes at 80°C. Using the agent as a core, coat methylhydrodiene polysiloxane in a ratio of 100:2, bake at 130°C for 1.5 hours, return to room temperature, then add 50 parts of ethyl alcohol, 1.0 part of isopropyl myristate,
This was gradually poured into a solution of 1.0 part of cetyl alcohol, and while stirring at 120°C for 4 hours, the organic solvent was distilled off and baked at the same time. After cooling, 98 parts of the composition was taken out. The powder is ground into the product face powder. Example 2 Foundation
【表】
製法：ＡとＢとを別々に溶解して80℃に保持しＡ
にＢを少しずつ添加し、充分に撹拌し乳化す
る。乳化が終了した時点でＣを添加し80℃で３
分間撹拌し水冷し40℃まで冷却し、取り出し容
器に充填して製品とする。
実施例 ３
固型フアンデーシヨン[Table] Manufacturing method: Melt A and B separately and hold at 80℃.
Add B little by little and stir thoroughly to emulsify. When emulsification is completed, add C and heat at 80℃ for 3
Stir for a minute, cool with water and cool to 40°C, take out and fill into containers to prepare the product. Example 3 Solid foundation
【表】
製法：ＡにＢをヘンシエルミキサーで３分間混合
した後粉砕機で粉砕する。その後、ヘンシエル
ミキサーに粉砕物をうつし、Ｃを添加し７分間
混合撹拌し、取り出し、ブロワーシフターで均
質化した後、容器に充填して製品とする。
実施例 ４
プレストパウダー[Table] Production method: Mix A and B in a Henschel mixer for 3 minutes, and then crush in a pulverizer. Thereafter, the pulverized product was transferred to a Henschel mixer, C was added thereto, mixed and stirred for 7 minutes, taken out, homogenized using a blower sifter, and then filled into containers to produce a product. Example 4 Pressed powder
【表】
製法：Ａをリンボンミキサー内に仕込みＢとＣ添
加し30分間混合する。その後取り出し、粉砕機
で粉砕しプレス充填して製品とする。
実施例 ５
パウダーアイシヤドウ
セリサイト49.9部、球状シリカ（シリカビー
ズ）15部、酸化チタン８部、カオリン４部、ケイ
ソウ土16.1部、群青3.5部、弁柄1.0部、炭酸カル
シウム2.5部計100部に対し、酢酸エチルエステル
60部に２−オクチルドデシルミリステート1.5部
及びオレイン酸2.0部を溶解させたものを徐々に
注入し、40℃にて20分間撹拌しながら留去．し、
熱風乾燥機（75℃、４時間）で乾燥させ、粉体基
剤を核として２−オクチルドデシルミリステート
及びオレイン酸を100：3.5の割合でコーテイング
し、120℃で４時間焼付け処理を行ない、冷却し
次いでイソプロピルアルコール50部にメチルハイ
ドロジエンポリシロキサン1.5部およびメチルフ
エニルポリシロキサンを溶解させたものに低速回
転にてこれを徐々に注入し、85℃にて２時間撹拌
しながら有機溶媒を留去し、熱風乾燥機にて85
℃、３時間乾燥させ、続いて140℃、1.5時間焼付
け処理を行ない冷却後取り出した組成物104部を
得、粉砕機にて粉砕して製品パウダーアイシヤド
ーとする。
実施例 ６
リキツドコントロールカラーフアンデーシヨン[Table] Manufacturing method: Place A into a Rinbon mixer, add B and C, and mix for 30 minutes. After that, it is taken out, crushed in a crusher, and press-filled to make a product. Example 5 Powder Eye Shadow 49.9 parts of sericite, 15 parts of spherical silica (silica beads), 8 parts of titanium oxide, 4 parts of kaolin, 16.1 parts of diatomaceous earth, 3.5 parts of ultramarine blue, 1.0 part of Bengara, 2.5 parts of calcium carbonate Total 100 per part of ethyl acetate
A solution of 1.5 parts of 2-octyldodecyl myristate and 2.0 parts of oleic acid dissolved in 60 parts was gradually poured into the solution and distilled off while stirring at 40°C for 20 minutes. death,
Dry in a hot air dryer (75℃, 4 hours), coat the powder base with 2-octyldodecyl myristate and oleic acid at a ratio of 100:3.5, and bake at 120℃ for 4 hours. After cooling, this was gradually poured into a solution of 1.5 parts of methylhydrodiene polysiloxane and methylphenyl polysiloxane in 50 parts of isopropyl alcohol at low speed rotation, and the organic solvent was stirred at 85°C for 2 hours. Distill and dry in hot air dryer at 85
℃ for 3 hours, followed by baking treatment at 140℃ for 1.5 hours, and after cooling, 104 parts of the composition was taken out and crushed in a pulverizer to obtain a powder eye shadow product. Example 6 Liquid control color foundation
【表】
製法：ＡとＢを別々に溶解して80℃に保持しＡに
Ｂを少しずつ添加し充分撹拌して乳化する。乳
化が終了した時点で80℃で５分間撹拌し水冷し
50℃まで冷却する。その後Ｃを添加し40℃まで
冷却し取り出し容器に充填して製品とする。
実施例 ７
アイライナー[Table] Production method: Dissolve A and B separately, maintain at 80°C, add B little by little to A, and emulsify by stirring thoroughly. When emulsification is complete, stir at 80℃ for 5 minutes and cool with water.
Cool to 50°C. Thereafter, C is added, the mixture is cooled to 40°C, and the product is taken out and filled into containers. Example 7 Eyeliner
【表】
製法：ＡとＢを実施例６の方法で乳化した後、Ｃ
を加えて40分間撹拌し、更にＤを加えて２分間
撹拌して取り出し容器に充填して製品とする。
実施例 ８
ルースダステイングパウダー[Table] Production method: After emulsifying A and B by the method of Example 6, C
Add and stir for 40 minutes, then add D and stir for 2 minutes, then take out and fill into containers to prepare the product. Example 8 Loose dusting powder
【表】
製法：Ａをナウターミキサーに仕込んだ後Ｂを仕
込み15分間混合した後、更にＣを加えて３分間
撹拌をつづけ取り出しブロワーシフターを通
し、取り出し容器に充填して製品とする。
実施例 ９
ダステイングパウダー
タルク20.1部、酸化チタン10.0部、球状ベンゾ
グアナミンパウダー９部、球状シリカ５部、セリ
サイト49.9部、弁柄２部、カオリン４部等の粉砕
した粉体基剤計100部にオクタン80部にアルミニ
ウムステアレート1.0部、メチルハイドロジエン
ポリシロキサン1.0部、スクワラン1.0部を溶解さ
せたものを徐々に注入し、80℃にて40分間低速回
転で撹拌しながら有機溶媒を留去し、粉末基剤を
核として撥水剤と油剤との混合物を100：３の割
合でコーテイングし、130℃で３時間焼付け処理
を行ない冷却後取り出した組成物101部を得、粉
砕機にて粉砕し製品ダステイングパウダーとす
る。
実施例 10
アンダーメークアツプ[Table] Manufacturing method: Charge A into a Nauta mixer, then charge B and mix for 15 minutes, then add C, continue stirring for 3 minutes, take out, pass through a blower sifter, take out and fill in a container to prepare the product. Example 9 Dusting powder Total of 100 parts of pulverized powder base such as 20.1 parts of talc, 10.0 parts of titanium oxide, 9 parts of spherical benzoguanamine powder, 5 parts of spherical silica, 49.9 parts of sericite, 2 parts of Bengara, 4 parts of kaolin, etc. A solution of 1.0 part of aluminum stearate, 1.0 part of methylhydrodiene polysiloxane, and 1.0 part of squalane in 80 parts of octane was gradually injected into the mixture, and the organic solvent was distilled off while stirring at low speed for 40 minutes at 80°C. Then, the powder base was used as a core and coated with a mixture of water repellent and oil at a ratio of 100:3, baked at 130°C for 3 hours, cooled, and taken out to obtain 101 parts of the composition. Grind and use as product dusting powder. Example 10 Under makeup
【表】
製法：ＡとＢを別々に溶解して80℃に保持しＡに
Ｂを少しずつ添加し充分撹拌し乳化する。乳化
が終了した時点で80℃で３分間撹拌し水却し、
40℃まで冷却する。そのＣを添加して30℃まで
冷却し、取り出し容器に充填して製品とする。
実施例 11
口 紅[Table] Production method: Dissolve A and B separately, maintain at 80°C, add B little by little to A, stir thoroughly, and emulsify. When emulsification is complete, stir at 80℃ for 3 minutes and cool in water.
Cool to 40°C. The C is added, cooled to 30°C, taken out and filled into containers to produce the product. Example 11 Lipstick
【表】
製法：Ａを80〜85℃に加熱撹拌した後徐々にＢを
加えて撹拌しながら脱泡してＣを加え成型器に
流し込み30℃まで空冷し、更に10℃まで冷却し
て後成型器よりとり出し、容器に入れて製品と
する。
実施例 12
プレストルージユ[Table] Manufacturing method: After heating and stirring A to 80-85℃, gradually add B, defoaming while stirring, add C, pour into a molding machine, air cool to 30℃, further cool to 10℃, and then Take it out from the molding machine and put it in a container to make a product. Example 12 Press Rouge
【表】
製法：Ａをヘンシエルミキサーで５分間混合した
後Ｂを加え２分間更に撹拌し粉砕機で分散させ
た後ブロワーシフターえを通し、プレス充填し
て製品とする。
実施例 13
カバーマークパウダー
実施例９と同様の製法により得られた組成物50
部にタルク25部、金雲母25部を混合し、更に混
合、分散させ、次いで酢酸エチル70部中にメチル
ハイドロジエンポリシロキサン1.5部を入れたも
のにこれを徐々に注入し、75℃にて４時間撹拌し
ながら有機溶媒を留去し、120℃、３時間焼付け
処理を行ない放冷後取り出した組成物99部を得、
粉砕機にて粉砕後プレス充填し製品カバーマーク
パウダーを得た。
実施例 14
油性コンパクトフアンデーシヨン[Table] Manufacturing method: Mix A for 5 minutes with a Henschel mixer, then add B, stir for 2 minutes, disperse with a pulverizer, pass through a blower sifter, and press fill to form a product. Example 13 Covermark powder Composition 50 obtained by the same manufacturing method as Example 9
25 parts of talc and 25 parts of phlogopite were mixed and dispersed, and then gradually poured into a mixture of 1.5 parts of methylhydrodiene polysiloxane in 70 parts of ethyl acetate, and heated to 75°C. The organic solvent was distilled off while stirring for 4 hours, and 99 parts of the composition was obtained after baking at 120°C for 3 hours and taken out after cooling.
After pulverizing with a pulverizer, the powder was press-filled to obtain a product cover mark powder. Example 14 Oil-based compact foundation
【表】
製法：Ａを80〜85℃に加熱し溶解、分散させて脱
泡して後Ｃを加え、中皿に流し込み30℃まで空
冷し、更に５〜10℃まで冷却し容器にいれて製
品とする。
実施例 15
ツーウエーケーキ[Table] Manufacturing method: Heat A to 80-85℃, dissolve, disperse, defoam, add C, pour into a medium plate, air cool to 30℃, further cool to 5-10℃, and put in a container. Product. Example 15 Two-way cake
【表】【table】
【表】
製法：粉体基剤Ａをヘンシエルミキサーに仕込
み、次いでＢを仕込んだ後１分間混合し取り出
し、粉砕機で分散混合せしめる。その後粉砕物
をヘンシエルにうつしＣを加えて10分間撹拌
し、更にＤを加えて１分間撹拌する。その後取
り出しブロワーシフターを通し、中皿に充填し
て製品とする。
実施例 16
固型ダステイングパウダー[Table] Manufacturing method: Powder base A is charged into a Henschel mixer, then B is mixed for 1 minute, taken out, and dispersed and mixed using a pulverizer. Thereafter, transfer the pulverized product to Henschel, add C and stir for 10 minutes, then add D and stir for 1 minute. After that, it is taken out, passed through a blower sifter, and filled into a medium tray to produce a product. Example 16 Solid dusting powder
【表】
製法：リボンミキサーにＡとＢとＣを仕込み30分
間混合した後、ブロワーシフターを通す。その
後、中皿にプレス充填し製品とする。
実施例 17
ケーキ状アイカラー
重量部
(A) カオリン 5.0
ステアリン酸亜鉛 3.5
実施例１の組成物 10
実施例５の組成物 10
実施例９の組成物 10
シリコーン被覆二酸化チタン 16.5
黒酸化鉄 4.0
弁 柄 10.0
雲母チタン 8.0
(B) ミツロウ 1.5
セタノール 0.8
流動パラフイン 2.5
(C) 香料 0.2
（製法）
上記(A)の処方物を高速混合機（ヘンシエル型ミ
キサー）にて２分間混合後、粉砕機にて粉砕、混
合する。このものを80℃にて上記(B)の処方物とヘ
ンシエルミキサー中で５分間低速混合し、20℃に
冷却後、上記(C)の香料を加えて２分間低速混合す
る。このものを粉砕機にて粉砕後とり出して、プ
レスする。
実施例 18
ハイライター
ベンゾグアナミンパウダー100部に、シリコー
ンA2部及び油剤B3部をイソプロパノールとベン
ゼンの１：１重量混合部70部に溶解せしめた溶液
を徐々に加えながら攪拌し、均一なものとし、さ
らに熱風乾燥機を用いて温度60℃で溶媒を留去し
た後、温度80℃で３時間焼付処理を行う。得られ
た処理粉体に微結晶性セルロース50部を加えて均
一に混合し、これにシリコーンA2部をベンゼン
70部に溶解せしめた溶液を徐々に加えながら攪拌
して均一なものとし、熱風乾燥機を用いて温度60
℃で溶媒を留去した後、温度80℃で３時間焼付処
理を行ない冷却後取り出した組成物151部を得、
粉砕機にて粉砕し製品ハイライターとする。[Table] Manufacturing method: Place A, B, and C in a ribbon mixer, mix for 30 minutes, and then pass through a blower sifter. Thereafter, the product is press-filled into a medium tray. Example 17 Cake eye color Parts by weight (A) Kaolin 5.0 Zinc stearate 3.5 Composition of Example 1 10 Composition of Example 5 10 Composition of Example 9 10 Silicone-coated titanium dioxide 16.5 Black iron oxide 4.0 Valve pattern 10.0 Titanium mica 8.0 (B) Beeswax 1.5 Setanol 0.8 Liquid paraffin 2.5 (C) Fragrance 0.2 (Production method) Mix the formulation in (A) above for 2 minutes in a high-speed mixer (Hensiel type mixer), then crush it in a pulverizer. , mix. This mixture is mixed at low speed with the formulation (B) above in a Henschel mixer at 80°C for 5 minutes, and after cooling to 20°C, the fragrance (C) above is added and mixed at low speed for 2 minutes. After pulverizing this material in a pulverizer, it is taken out and pressed. Example 18 Highlighter A solution prepared by dissolving 2 parts of silicone A and 3 parts of oil agent B in 70 parts of a 1:1 weight mixture of isopropanol and benzene was gradually added to 100 parts of benzoguanamine powder with stirring to make it homogeneous. After distilling off the solvent at a temperature of 60°C using a hot air dryer, a baking treatment is performed at a temperature of 80°C for 3 hours. Add 50 parts of microcrystalline cellulose to the obtained treated powder and mix uniformly, and add 2 parts of silicone A to this with benzene.
Gradually add 70 parts of the solution and stir to make it homogeneous.
After distilling off the solvent at °C, baking treatment was performed at a temperature of 80 °C for 3 hours, and 151 parts of the composition was taken out after cooling.
Grind it in a grinder and use it as a product highlighter.
Claims (1)
エンポリシロキサンを必須成分として含むシリコ
ーン油をコーテイングし、焼付け処理を施し、更
にこれを油剤にてコーテイングし、焼付け処理し
て得られる三層の構造を有する組成物を含有する
ことを特徴とするメークアツプ化粧料。 ２ 顔料および／または粉体に油剤をコーテイン
グし、焼付け処理を施し、更にこれをメチルハイ
ドロジエンポリシロキサンを必須成分として含む
シリコーン油にてコーテイングし、焼付け処理し
て得られる三層の構造を有する組成物を含有する
ことを特徴とするメークアツプ化粧料。 ３ 顔料および／または粉体にメチルハイドロジ
エンポリシロキサンを必須成分として含むシリコ
ーン油と油剤との混合物をコーテイングし、焼付
け処理して得られる二層の構造を有する組成物を
含有することを特徴とするメークアツプ化粧料。 ４ 顔料および／または粉体にメチルハイドロジ
エンポリシロキサンを必須成分として含むシリコ
ーン油と油剤との混合物をコーテイングし、焼付
け処理を施し、更にこれと顔料および／または粉
体との混合物をメチルハイドロジエンポリシロキ
サンを必須成分として含むシリコーン油および／
または油剤にてコーテイングし、焼付け処理して
得られる組成物を含有することを特徴とするメー
クアツプ化粧料。[Scope of Claims] 1. Obtained by coating a pigment and/or powder with a silicone oil containing methylhydrodiene polysiloxane as an essential component, subjecting it to a baking treatment, further coating this with an oil agent, and baking it. A make-up cosmetic comprising a composition having a three-layer structure. 2 It has a three-layer structure obtained by coating the pigment and/or powder with an oil, baking it, then coating it with a silicone oil containing methylhydrodiene polysiloxane as an essential component, and baking it. A makeup cosmetic characterized by containing a composition. 3. It is characterized by containing a composition having a two-layer structure obtained by coating a pigment and/or powder with a mixture of a silicone oil and an oil agent containing methylhydrodiene polysiloxane as an essential component and baking the mixture. Make-up cosmetics. 4 The pigment and/or powder is coated with a mixture of silicone oil and oil containing methylhydrodiene polysiloxane as an essential component, subjected to a baking treatment, and the mixture of this and the pigment and/or powder is coated with methylhydrodiene polysiloxane. Silicone oil containing empolysiloxane as an essential component and/or
Or a make-up cosmetic characterized by containing a composition obtained by coating with an oil and baking treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4254679A JPS55136213A (en) | 1979-04-10 | 1979-04-10 | Make-up cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4254679A JPS55136213A (en) | 1979-04-10 | 1979-04-10 | Make-up cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55136213A JPS55136213A (en) | 1980-10-23 |
| JPS623809B2 true JPS623809B2 (en) | 1987-01-27 |
Family
ID=12639048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4254679A Granted JPS55136213A (en) | 1979-04-10 | 1979-04-10 | Make-up cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55136213A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63194911U (en) * | 1987-05-29 | 1988-12-15 |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5936881B2 (en) * | 1977-07-05 | 1984-09-06 | 株式会社小林コ−セ− | Pressed makeup composition |
| JPS5616404A (en) * | 1979-07-20 | 1981-02-17 | Isehan:Kk | Cosmetic using powder treated at high temperature |
| JPS57200306A (en) * | 1981-06-02 | 1982-12-08 | Toshiba Silicone Co Ltd | Pressed make-up cosmetic |
| US4609545A (en) * | 1982-11-24 | 1986-09-02 | Schlossman Mitchell L | Compressing aid for compressing powders |
| US4591502A (en) * | 1982-11-24 | 1986-05-27 | Schlossman Mitchell L | Compressing aid for cosmetic powders |
| ES8506444A1 (en) * | 1983-10-03 | 1985-08-01 | Revlon | Nail enamel containing silicone-coated pigments. |
| JPS60126210A (en) * | 1983-12-09 | 1985-07-05 | Pola Chem Ind Inc | Solid powdered cosmetic |
| DE3411759C1 (en) * | 1984-03-30 | 1985-04-25 | Th. Goldschmidt Ag, 4300 Essen | Particles modified on their surface by hydrophilic and hydrophobic groups |
| JPS63113081A (en) * | 1985-07-29 | 1988-05-18 | Shiseido Co Ltd | Modified powder |
| JPS62246507A (en) * | 1986-04-17 | 1987-10-27 | Shiseido Co Ltd | Make-up cosmetic |
| JPH0774142B2 (en) * | 1986-07-17 | 1995-08-09 | ポーラ化成工業株式会社 | Make-up cosmetics |
| US4863800A (en) * | 1987-03-06 | 1989-09-05 | Miyoshi Kasei Co., Ltd. | Surface-treated pigment material |
| FR2632962A1 (en) * | 1988-06-17 | 1989-12-22 | Pola Chem Ind Inc | WATERPROOFING AND OLEOFUGE COATING POWDERS, PROCESS FOR THE PRODUCTION THEREOF AND COSMETIC PRODUCTS CONTAINING THEM |
| US5766577A (en) * | 1992-09-10 | 1998-06-16 | Elizabeth Arden Co., Division Of Conopco, Inc. | Color cosmetic composition |
| JP4602506B2 (en) * | 1999-07-08 | 2010-12-22 | 三好化成株式会社 | Novel coated powder having super-dispersibility and cosmetics containing the same |
| JP2013147477A (en) * | 2012-01-23 | 2013-08-01 | Shiseido Co Ltd | Powder cosmetic |
| JP6012983B2 (en) * | 2012-02-28 | 2016-10-25 | 石原産業株式会社 | Coated powder and method for producing the same |
| JP2015048305A (en) * | 2013-08-30 | 2015-03-16 | ポーラ化成工業株式会社 | Surface treated powder and external preparation for skin containing surface treated powder |
| JP2015048304A (en) * | 2013-08-30 | 2015-03-16 | ポーラ化成工業株式会社 | Particulate metal oxide, and external preparation for skin containing particulate metal oxide |
| JP7038452B1 (en) * | 2021-09-15 | 2022-03-18 | 株式会社 サンエース | Method for manufacturing surface-treated particles and surface-treated particles |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491769A (en) * | 1972-04-26 | 1974-01-09 | ||
| JPS5414528A (en) * | 1977-07-05 | 1979-02-02 | Kobayashi Kose Co | Press state makeup composition |
-
1979
- 1979-04-10 JP JP4254679A patent/JPS55136213A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491769A (en) * | 1972-04-26 | 1974-01-09 | ||
| JPS5414528A (en) * | 1977-07-05 | 1979-02-02 | Kobayashi Kose Co | Press state makeup composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63194911U (en) * | 1987-05-29 | 1988-12-15 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55136213A (en) | 1980-10-23 |
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