JPS623222Y2 - - Google Patents
Info
- Publication number
- JPS623222Y2 JPS623222Y2 JP1982124209U JP12420982U JPS623222Y2 JP S623222 Y2 JPS623222 Y2 JP S623222Y2 JP 1982124209 U JP1982124209 U JP 1982124209U JP 12420982 U JP12420982 U JP 12420982U JP S623222 Y2 JPS623222 Y2 JP S623222Y2
- Authority
- JP
- Japan
- Prior art keywords
- waterproof sheet
- corners
- reinforcing
- adhesive
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000853 adhesive Substances 0.000 claims description 17
- 239000012790 adhesive layer Substances 0.000 claims description 16
- 230000003014 reinforcing effect Effects 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229920001971 elastomer Polymers 0.000 claims description 9
- 229920005549 butyl rubber Polymers 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 5
- 238000004073 vulcanization Methods 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 description 13
- 230000002787 reinforcement Effects 0.000 description 7
- 238000010276 construction Methods 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 239000004636 vulcanized rubber Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- -1 methylene ethyl Chemical group 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- DZCCLNYLUGNUKQ-UHFFFAOYSA-N n-(4-nitrosophenyl)hydroxylamine Chemical compound ONC1=CC=C(N=O)C=C1 DZCCLNYLUGNUKQ-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000003348 petrochemical agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 1
- FDPIMTJIUBPUKL-UHFFFAOYSA-N dimethylacetone Natural products CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 1
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 229940068124 pine tar Drugs 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Building Environments (AREA)
Description
本考案はコーナー部補強貼り用防水シートに係
り、詳しくは出隅、入隅あるいはパイプ回り等の
複雑箇所コーナー部を短時間に補強貼りできる防
水シートに関する。
ここで、補強貼りとは、複雑箇所において採用
される工法で、広巾防水シートを貼る前に予め、
小面積の防水シートを貼る工法を言い、複雑箇所
の防水を確実にするものである。
従来における複雑箇所、例えば出隅コーナー部
の補強貼りは通常、第１図に示すようにほゞ正方
形にカツトした防水シート１とほゞ正方形で下半
分を切り込んだ防水シート２を組合せて行なうも
のであり、まず、防水シート１，２の裏面ならび
に下地３に接着剤４を塗布した後、防水シート１
を下地に貼り付けて転圧した後、この防水シート
１の他方の防水シート２とラツプする箇所に接着
剤を塗布してオープンタイムをとつた後、他方の
防水シート２を貼り付けていた。ところが、この
種の防水シートを使用すると接着剤が必要である
ため、所定の塗布量、オープンタイム、適度な圧
着等の制約条件があり、この条件は作業時の環境
条件によつて大きく左右されている。例えば、強
風時には砂塵の付着によつて接着阻害を生じた
り、高温時にはオープンタイムが短かくなり乾燥
オーバーによる接着不良を起したり、また、低温
時にはオープンタイムが長くなつて施工能率に影
響し更には高温時には接着剤表面に結露水が付着
して接着不良を生じることもあつて環境条件を十
分に把握する必要があつた。また、それだけでな
く塗布むらによる接着力のバラツキ、転圧不足に
よる接着不良など、接着不良要因も非常に多い。
従つて、接着剤による複雑箇所コーナー部の補
強貼り作業はそのときの環境に大きく左右され、
また施工時間を非常に要するものであつた。
しかも、それだけでなく、加硫ゴムシートを用
いて補強貼りする場合、加硫ゴムシートがコーナ
ー部において下地面と密着しにくくコンクリート
等の下地中の水蒸気が日中膨脹してシートをふく
らませることがあり、また、防水シートを敷設す
る過程で一旦、下地面との間に空気を内包して了
うとその後の転圧過程でも空気を除去するのが困
難となり、これによつて防水シートの納まりが悪
く水みちを作り漏水することがあつた。
本考案は上述の如き実状に鑑み、このような点
を改善すべく、主に作業時の環境に左右されず、
短時間に、かつ確実にして容易に複雑箇所のコー
ナー部の補強貼りが可能となる防水シートを提供
することを目的とするものである。
即ち、本考案の特徴とするところは、出隅、入
隅あるいはパイプ回り等の複雑箇所コーナー部を
補強貼りするのに用いる防水シートであつて、エ
チレン−プロピレン−タ−ポリマー、ブチルゴム
あるいはこれらのブレンド物からなる加硫ゴムシ
ートの基材にエチレン−プロピレン−タ−ポリマ
ー、ブチルゴムあるいはこれらのブレンド物から
なるゴム質ポリマーに加硫剤、加硫促進剤等を含
みムーニー粘度（ML1＋５，100℃）５〜20で自
着性を有する自然加硫可能な粘着層を積層接着し
てなる構成を有する点にある。
以下、更に本考案を添付図面に従つて詳細に説
明する。
第２図は本考案の防水シートに係る断面図を示
し、該防水シート５は加硫ゴムシートの基材６に
自然加硫可能な粘着層７を貼合せた構成からなつ
ており、このうち、基材６は耐候性に優れたエチ
レン−プロピレン−タ−ポリマー、ブチルゴムあ
るいはこれらのブレンド物からなる加硫ゴムシー
トであり、そして粘着層７はエチレン−プロピレ
ン−タ−ポリマー、ブチルゴムあるいはこれらの
ブレンド物からなるゴム質ポリマーに加硫剤、加
硫促進剤、粘着剤、そしてて軟化剤の外、ステア
リン酸、カーボンブラツク、無機充填剤、ZnO等
が適宜必要に応じて混合配合されて配層される。
なお、ここで使用される加硫剤としては硫黄，
モルホリン．ジスルフアイド，含リンポリスルフ
アイド，塩化硫黄等の含硫黄化合物からなる硫黄
系，Ｐ−キノンジオキシム，Ｐ−Ｐ−ジベンゾイ
ル．キノンジオキシム等のオキシム系あるいはα
−クミルハイドロパ−オキサイド，メチレンエチ
ルケトンパ−オキサイド，過酸化水素，アセチル
アセトンパ−オキサイド，ｔ−ブチルハイドロパ
−オキサイド，ｔ−ブチルパ−オキシベンゾエ−
ト等のパ−オキサイド系などが挙げられ、これら
の加硫剤はゴム質ポリマー100重量部に対して１
〜６重量部程度の割合で使用される。
また、加硫促進剤としては、２−メルカプトベ
ンゾチアゾール，ジ．ベンゾチアゾール．ジサル
フアイド等のチアゾール系，テトラメチルチウラ
ム．モノサルフアイド，テトラメチルチウラム．
ジサルフアイド，ジペンタメチレンチウラム．ヘ
キサルフアイド等のチウラム系あるいはZn−ジ
−ｎ−ブチルジチオカルバメート等のジチオカル
バメート系，そしてPbO2，トリメンベース等が
ある。そして、これらの加硫促進剤の使用量は、
ゴム質ポリマー100重量部に対して通常２〜10重
量部である。
更に混合される粘着剤としては、石油系炭化水
素樹脂であるペトロジン（三井石油化学社製）等
の芳香族系炭化水素樹脂，ハイレツツ（三井石油
化学社製）等の脂肪族系環状炭化水素，エスコレ
ツツ（エツツケミカル社製）等の不飽和炭化水素
の重合体、クツクエース（三井石油化学社製）等
の炭化水素系粘着樹脂，あるいはフエノールホル
ムアルデヒド樹脂であるフエノール樹脂等があ
り、こられの粘着剤は通常、好ましい使用量とし
てゴム質ポリマー100重量部に対して30〜100重量
部程度混合される。また、これらの粘着剤と共に
使用される軟化剤としては公知のものが使用さ
れ、その代表的なものとしてはプロセスオイル，
ポリブデン，流動パラフイン，パインタール，そ
の他石油系高沸点化合物などを挙げることができ
る。そして、これらの軟化剤の使用量としては、
ゴム質ポリマー100重量部に対して好ましくは30
〜150重量部である。
次に、本考案において使用する前記粘着層７は
他の防水シートの基材との初期接着強度、即ち、
接合部をローラー等により転圧した後の自着力と
して1.0〜3.0Kg／25cm程度発生しなけばならず、
この自着力がなければコーナー部の補強貼り時に
おいて防水シートを引張つた場合に接合部で防水
シートのずれ変形が生じる。そのため、この自着
力を満足させるためには粘着力をゴム質ポリマー
100重量部に対して30〜100重量部を加えて表面タ
ツクをもたせ、更に軟化剤を30〜150重量部添加
して粘着層のムーニー粘度（ML1＋５，100℃）
を５〜20の範囲にすることが肝要で、このムーニ
ー粘度であれば他の被着体の表面にゴミ，砂ほこ
りが付着しても、粘着層がこれらの異物を包囲
し、かつ、この異物が粘着層の内部へ侵入するた
めに防水シートと他の被着体との接着力はあまり
影響を受けない。
ここにおいて、前記被着体例えば接着テープの
厚みは0.5〜2.0mmの範囲とし、2.0mm以上にすると
接合部において防水シートとの段差ができ、接合
初期に剥離し易くなるので好ましくない。そのう
ち、前記粘着層７の厚みは0.5〜2.0mmとするのが
好適である。
次に、本考案に係る防水シート５を複雑箇所コ
ーナー部の補強貼りに使用する例を説明すると、
第３図は出隅コーナー部における補強貼りを示す
斜視図であり、まず、ほゞ正方形にカツトされた
防水シート５を粘着層７が下地３に面するように
して敷いた後、転圧し、続いて下半分の中央部を
切り込んだ他の防水シート５′を各下地３に敷く
と共に上記防水シート５とラツプ部８を設けた
後、全面を転圧して補強貼り作業を終える。
一方、第４図は入隅コーナー部の補強貼りを示
す斜視図であり、下半分の中央部を切り込んだ
ほゞ正方形の防水シート５′を各下地面に敷設す
ると共に、下地面の１部で防水シート５を２重に
重ねた後、シート全面を転圧して補強貼りを終え
たものである。
かくして、以上のようにして補強貼り作業を行
なうが、本考案防水シートによつて補強貼りを行
なつたときの作業好適性を更に具体的に説明すべ
く、従来の防水シートと接着剤を併用して行なつ
た第２図に示す出隅コーナー部の補強貼りと本考
案の防水シート（基材６と粘着層７の配合は第１
表に示す）を使用して第３図に示す出隅コーナー
部の補強貼りを行なつた場合の各作業時間を比較
したところ、第２表の如き結果を得た。
第１表
(1) 基材（合成ゴム加硫シート）
配合組成（重量比）
IIR 30〜50
EPDM 70〜50
ZnO ５
ステアリン酸 １
カーボン 60
無機充填剤 30
パラフイン系軟化剤 20〜30
促進剤 TT １〜３
促進剤 Ｍ 0.5〜２
イオウ １〜３
(2) 粘着層配合組成（重量比）
IIR 70〜50
EPPM 30〜50
ZnO ５
ステアリン酸 １
カーボン 50
無機充填剤 50
石油系樹脂 30〜60
パラフイン系軟化剤 30〜60
GMF １〜５
PbO2 １〜５
次に、第２表を示すが、この第２表の作業時間
の比較に使用した防水シートの面積は0.1m2で、
施工時期は６月であつた。又、第２表中、１，
２，５，５′は添付図面中の符号である。
The present invention relates to a waterproof sheet for reinforcing corners, and more particularly, to a waterproof sheet that can be used to reinforce corners in complex areas such as outside corners, inside corners, and around pipes in a short time. Here, reinforcement pasting is a construction method adopted in complex areas, and before pasting the wide waterproof sheet,
This is a method of pasting a waterproof sheet over a small area to ensure waterproofing in complex areas. Conventionally, reinforcement pasting of complicated areas, such as protruding corners, is usually done by combining a waterproof sheet 1 cut into an approximately square shape and a waterproof sheet 2 whose lower half is cut into an approximately square shape, as shown in Fig. 1. First, after applying adhesive 4 to the back surfaces of waterproof sheets 1 and 2 and the base 3,
After pasting the waterproof sheet 1 on the base and rolling it, adhesive was applied to the parts of the waterproof sheet 1 where it overlapped with the other waterproof sheet 2, and after an open time, the other waterproof sheet 2 was pasted. However, since adhesive is required when using this type of waterproof sheet, there are constraints such as a prescribed amount of application, open time, and appropriate pressure bonding, and these conditions are greatly influenced by the environmental conditions at the time of work. ing. For example, in strong winds, adhesion is inhibited by adhesion of dust, in high temperatures the open time becomes short and over-drying causes adhesion failure, and in low temperatures the open time increases, affecting construction efficiency and further. At high temperatures, condensation water may adhere to the adhesive surface, resulting in poor adhesion, so it was necessary to fully understand the environmental conditions. In addition, there are many other causes of poor adhesion, such as variations in adhesive strength due to uneven coating and poor adhesion due to insufficient rolling pressure. Therefore, reinforcing the corners of complex areas using adhesives is greatly influenced by the environment at the time.
Furthermore, the construction required a considerable amount of time. Moreover, when applying reinforcement using a vulcanized rubber sheet, it is difficult for the vulcanized rubber sheet to adhere to the underlying surface at the corners, and water vapor in the substrate such as concrete may expand during the day, causing the sheet to swell. Also, once air is trapped between the waterproof sheet and the underlying surface during the process of laying the waterproof sheet, it becomes difficult to remove the air during the subsequent compaction process, and this causes the waterproof sheet to not fit properly. There were cases where a bad water path was created and water leaked. In view of the above-mentioned actual situation, this invention aims to improve these points by providing a system that is not affected by the work environment.
It is an object of the present invention to provide a waterproof sheet that can be easily and reliably reinforced at corners of complicated locations in a short time. That is, the feature of the present invention is that it is a waterproof sheet used for reinforcing and pasting corners of complicated places such as outside corners, inside corners, or around pipes, and is made of ethylene-propylene-terpolymer, butyl rubber, or these materials. The base material of the vulcanized rubber sheet made of a blend contains ethylene-propylene terpolymer, butyl rubber, or a rubbery polymer made of a blend thereof, a vulcanizing agent, a vulcanization accelerator, etc., and has a Mooney viscosity (ML 1 + 5) . , 100°C) 5 to 20°C) and has a structure in which self-curable adhesive layers that are self-adhesive and can be self-vulcanized are laminated and bonded. Hereinafter, the present invention will be further described in detail with reference to the accompanying drawings. FIG. 2 shows a sectional view of the waterproof sheet of the present invention, and the waterproof sheet 5 is composed of a base material 6 of a vulcanized rubber sheet and an adhesive layer 7 that can be naturally vulcanized. The base material 6 is a vulcanized rubber sheet made of ethylene-propylene terpolymer, butyl rubber, or a blend thereof, which has excellent weather resistance, and the adhesive layer 7 is made of ethylene-propylene terpolymer, butyl rubber, or a blend thereof. In addition to a vulcanizing agent, a vulcanization accelerator, an adhesive, and a softening agent, stearic acid, carbon black, inorganic fillers, ZnO, etc. are appropriately mixed and blended into the rubbery polymer consisting of a blend. Layered. The vulcanizing agents used here include sulfur,
Morpholine. Sulfur-based compounds consisting of sulfur-containing compounds such as disulfide, phosphorus-containing polysulfide, sulfur chloride, P-quinone dioxime, P-P-dibenzoyl. Oxime series such as quinone dioxime or α
-cumyl hydroperoxide, methylene ethyl ketone peroxide, hydrogen peroxide, acetylacetone peroxide, t-butyl hydroperoxide, t-butyl peroxybenzoate
These vulcanizing agents can be used in an amount of 1 part by weight per 100 parts by weight of the rubbery polymer.
It is used in a proportion of about 6 parts by weight. Further, as the vulcanization accelerator, 2-mercaptobenzothiazole, di. Benzothiazole. Thiazoles such as disulfide, tetramethylthiuram. Monosulfide, tetramethylthiuram.
Disulfide, dipentamethylenethiuram. Examples include thiuram-based materials such as hexulfide, dithiocarbamate-based materials such as Zn-di-n-butyldithiocarbamate, and PbO 2 and trimene-based materials. The amount of these vulcanization accelerators used is
The amount is usually 2 to 10 parts by weight per 100 parts by weight of the rubbery polymer. Adhesives to be further mixed include aromatic hydrocarbon resins such as petroleum-based hydrocarbon resin Petrozin (manufactured by Mitsui Petrochemicals), aliphatic cyclic hydrocarbons such as Hiretz (manufactured by Mitsui Petrochemicals), These adhesives include unsaturated hydrocarbon polymers such as Escorets (manufactured by Etsutsu Chemical Co., Ltd.), hydrocarbon adhesive resins such as Kutsuku Ace (manufactured by Mitsui Petrochemicals Co., Ltd.), and phenol resins such as phenol formaldehyde resin. Usually, the preferred amount used is about 30 to 100 parts by weight per 100 parts by weight of the rubbery polymer. In addition, known softeners are used with these adhesives, typical examples of which are process oil,
Examples include polybutene, liquid paraffin, pine tar, and other petroleum-based high-boiling compounds. The amount of these softeners used is
Preferably 30 parts by weight of rubbery polymer
~150 parts by weight. Next, the adhesive layer 7 used in the present invention has an initial adhesive strength with the base material of another waterproof sheet, that is,
The self-adhesive force after rolling the joint with a roller, etc. must be approximately 1.0 to 3.0 kg/25 cm.
Without this self-adhesive force, when the waterproof sheet is pulled when reinforcing the corners, the waterproof sheet will shift and deform at the joints. Therefore, in order to satisfy this self-adhesive strength, the adhesive strength must be adjusted using a rubbery polymer.
Add 30 to 100 parts by weight to 100 parts by weight to give the surface tack, and further add 30 to 150 parts by weight of a softener to increase the Mooney viscosity of the adhesive layer (ML 1 + 5 , 100℃)
It is important to keep the viscosity in the range of 5 to 20. With this Mooney viscosity, even if dirt or dust adheres to the surface of other adherends, the adhesive layer will surround these foreign substances and will not disturb them. Since foreign matter penetrates into the adhesive layer, the adhesion between the waterproof sheet and other adherends is not affected much. Here, the thickness of the adherend, for example, the adhesive tape, should be in the range of 0.5 to 2.0 mm; if it is more than 2.0 mm, a step will be created at the joint with the waterproof sheet, which is not preferable because it will be likely to peel off at the initial stage of joining. Among these, the thickness of the adhesive layer 7 is preferably 0.5 to 2.0 mm. Next, an example of using the waterproof sheet 5 according to the present invention for reinforcing the corners of complicated areas will be explained.
FIG. 3 is a perspective view showing reinforcing pasting at the protruding corners. First, a waterproof sheet 5 cut into a substantially square shape is laid down with the adhesive layer 7 facing the base 3, and then rolled and pressed. Subsequently, another waterproof sheet 5' with a cut in the center of the lower half is laid on each base 3, and after the above-mentioned waterproof sheet 5 and the wrap portion 8 are provided, the entire surface is rolled to complete the reinforcing pasting work. On the other hand, Fig. 4 is a perspective view showing the reinforcing of the inner corners, in which a substantially square waterproof sheet 5' with a cut in the center of the lower half is laid on each base surface, and a part of the base surface is After layering the waterproof sheet 5 in two layers, the entire surface of the sheet was rolled to complete the reinforcement application. Thus, reinforcing pasting work is carried out as described above, but in order to more specifically explain the suitability of work when performing reinforcing pasting using the waterproof sheet of the present invention, we will explain in more detail the suitability of work when performing reinforcing pasting using the waterproof sheet of the present invention. The waterproof sheet of the present invention (the composition of the base material 6 and the adhesive layer 7 was
When reinforcing the protruding corners shown in FIG. 3 was carried out using the following materials (as shown in the table), the respective working times were compared, and the results shown in Table 2 were obtained. Table 1 (1) Base material (synthetic rubber vulcanized sheet)
Blend composition (weight ratio) IIR 30-50 EPDM 70-50 ZnO 5 Stearic acid 1 Carbon 60 Inorganic filler 30 Paraffin softener 20-30 Accelerator TT 1-3 Accelerator M 0.5-2 Sulfur 1-3 (2 ) Adhesive layer composition (weight ratio) IIR 70-50 EPPM 30-50 ZnO 5 Stearic acid 1 Carbon 50 Inorganic filler 50 Petroleum resin 30-60 Paraffin softener 30-60 GMF 1-5 PbO 2 1-5 Next, Table 2 is shown. The area of the tarpaulin sheet used to compare the working times in Table 2 is 0.1 m 2 ,
The construction period was June. In addition, in Table 2, 1,
2, 5, 5' are the symbols in the accompanying drawings.
【表】【table】
【表】
以上のように、本考案防水シートは複雑箇所コ
ーナー部の補強貼りには防水シートをそのコーナ
ー部の形状に応じてカツトしあるいは切り込みを
入れるだけで即座にコーナー部の下地に敷設し転
圧するだけでその施工を終えることができるた
め、従来のものに比べて短かい時間で補強貼り作
業が可能であり、また、従来の複雑箇所コーナー
部の補強貼りにはその形状の複雑さにより防水シ
ートを敷設する過程で下地面との間に空気を内包
することがあり、これがひいてはシート納まりが
悪く水みちを作り漏水につながるために、かなり
の施工熟練を要していたが、一定肉厚の粘着層を
有する本考案の防水シートにあつては、転圧工程
で粘着層の変形によつて防水シートは下地とよく
なじみ、かつ離型紙を剥がしながら施工できるた
め空気を除外して空気を内包することもないた
め、未熟練者にも簡単に施工できる利点がある。
しかも本考案防水シートは粘着層が十分な表面タ
ツクを有しているために、転圧後も下地から浮き
上がることもなく、また、太陽熱，環境温度で自
然加硫し、被着体との強固な接着性を長期に供給
する性能を有している。[Table] As shown above, the waterproof sheet of the present invention can be used to reinforce corners of complex areas by simply cutting or notching the waterproof sheet according to the shape of the corner and immediately laying it on the base of the corner. Because the installation can be completed simply by rolling, it is possible to perform the reinforcing work in a shorter time than with conventional methods.In addition, due to the complexity of the shape, it is possible to apply reinforcement to the corners of complex areas. During the process of laying a tarpaulin sheet, air may be trapped between the sheet and the underlying surface, which in turn causes the sheet to not fit properly, creating a water channel and leading to water leakage, which requires considerable construction skill. In the case of the waterproof sheet of the present invention, which has a thick adhesive layer, the waterproof sheet blends well with the substrate due to the deformation of the adhesive layer during the rolling process, and can be applied while peeling off the release paper, so air is excluded and air is removed. It has the advantage that even unskilled workers can easily install it because it does not contain any substances.
Moreover, since the adhesive layer of the waterproof sheet of this invention has sufficient surface tack, it does not lift up from the base even after compaction, and it is naturally vulcanized by solar heat and environmental temperature, creating a strong bond with the adherend. It has the ability to provide long-term adhesive properties.
第１図は従来における出隅コーナー部の補強貼
り状態を示す斜視図、第２図は本考案の防水シー
トを示す断面図、第３図は本考案の防水シートを
出隅コーナー部に補強貼りした状態を示す斜視
図、第４図は本考案の防水シートを入隅コーナー
部に補強貼りした状態を示す斜視図である。
５，５′…防水シート、６…基材、７…粘着
層。
Fig. 1 is a perspective view showing the state of conventional reinforcement applied to the protruding corners, Fig. 2 is a cross-sectional view showing the waterproof sheet of the present invention, and Fig. 3 is the waterproof sheet of the present invention applied with reinforcement to the protruding corners. FIG. 4 is a perspective view showing a state in which the waterproof sheet of the present invention is reinforced and pasted on an inside corner. 5, 5'... Waterproof sheet, 6... Base material, 7... Adhesive layer.
Claims (1)
コーナー部を補強貼りするのに用いる防水シート
であつて、エチレン−プロピレン−タ−ポリマ
ー、ブチルゴムあるいはこれらのブレンド物から
なる加流ゴムシートの基材にエチレン−プロピレ
ン−タ−ポリマー、ブチルゴムあるいはこれらの
ブレンド物からなるゴム質ポリマーに加硫剤、加
硫促進剤等を含み、ムーニー粘度（ML1＋５，
100℃）５〜20で自着性を有する自然加硫可能な
粘着層を積層接着してなることを特徴とするコー
ナー部補強貼り用防水シート。 This is a waterproof sheet used for reinforcing the corners of complex areas such as outside corners, inside corners, or around pipes, and is based on a hot-flow rubber sheet made of ethylene-propylene terpolymer, butyl rubber, or a blend thereof. The material is a rubbery polymer made of ethylene-propylene terpolymer, butyl rubber, or a blend thereof, containing a vulcanizing agent, a vulcanization accelerator, etc., and has a Mooney viscosity (ML 1 + 5 ,
A waterproof sheet for reinforcing corners, characterized by laminating and adhering adhesive layers that are naturally vulcanizable and self-adhesive at temperatures of 100°C to 20°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12420982U JPS5929226U (en) | 1982-08-16 | 1982-08-16 | Waterproof sheet for reinforcing corners |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12420982U JPS5929226U (en) | 1982-08-16 | 1982-08-16 | Waterproof sheet for reinforcing corners |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5929226U JPS5929226U (en) | 1984-02-23 |
| JPS623222Y2 true JPS623222Y2 (en) | 1987-01-24 |
Family
ID=30283236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12420982U Granted JPS5929226U (en) | 1982-08-16 | 1982-08-16 | Waterproof sheet for reinforcing corners |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5929226U (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4649653B2 (en) * | 2001-09-28 | 2011-03-16 | オカモト株式会社 | Forming method of waterproof sheet for construction |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5684940A (en) * | 1979-11-15 | 1981-07-10 | Mitsuboshi Belting Ltd | Bonding technique for vulcanized synthetic rubber waterproof sheet |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS572110Y2 (en) * | 1978-11-16 | 1982-01-13 |
-
1982
- 1982-08-16 JP JP12420982U patent/JPS5929226U/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5684940A (en) * | 1979-11-15 | 1981-07-10 | Mitsuboshi Belting Ltd | Bonding technique for vulcanized synthetic rubber waterproof sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5929226U (en) | 1984-02-23 |
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