JPS62289669A - Polyester fiber product and its production - Google Patents
Polyester fiber product and its productionInfo
- Publication number
- JPS62289669A JPS62289669A JP12562286A JP12562286A JPS62289669A JP S62289669 A JPS62289669 A JP S62289669A JP 12562286 A JP12562286 A JP 12562286A JP 12562286 A JP12562286 A JP 12562286A JP S62289669 A JPS62289669 A JP S62289669A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- polyester fiber
- fiber product
- halogenated
- product according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims description 35
- 239000000835 fiber Substances 0.000 title claims description 28
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 35
- -1 cycloalkane compound Chemical class 0.000 claims description 17
- 239000004744 fabric Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 239000004753 textile Substances 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims 2
- 239000003063 flame retardant Substances 0.000 description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 14
- 238000004043 dyeing Methods 0.000 description 8
- 208000016253 exhaustion Diseases 0.000 description 7
- 239000000975 dye Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YAOMHRRYSRRRKP-UHFFFAOYSA-N 1,2-dichloropropyl 2,3-dichloropropyl 3,3-dichloropropyl phosphate Chemical compound ClC(Cl)CCOP(=O)(OC(Cl)C(Cl)C)OCC(Cl)CCl YAOMHRRYSRRRKP-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、ポリエステルtllLFJ品及びその製造方
法に関し、その目的とする所は防炎性、1!1合等が良
好でかつその耐久性に優れたポリエステル繊維製品を提
供することにある。[Detailed Description of the Invention] <Industrial Application Field> The present invention relates to a polyester tllLFJ product and a method for manufacturing the same, and its purpose is to achieve good flame retardancy, 1:1 ratio, etc., and to improve its durability. Our goal is to provide superior polyester fiber products.
〈従来技術〉
従来、ポリエステルIIAMの後加工法による防炎剤と
しては、ハロゲン化リン酸エステル、環状リン酸エステ
ル及びハロゲン化シクロアルカン化合物(以下HCAと
いう)等がある(特開昭57−137377号公報)。<Prior art> Conventionally, flame retardants produced by post-processing of polyester IIAM include halogenated phosphate esters, cyclic phosphate esters, and halogenated cycloalkane compounds (hereinafter referred to as HCA) (Japanese Patent Laid-Open No. 57-137377 Publication No.).
ハロゲン化リン酸エステル及び環状リン酸エステル化合
物の欠点は、両者共液状である為、染色布に適応する場
合摩擦堅牢度、あるいは経時中に色移行が生じ白湯汚染
の発生等が起るので染色布には使用し難い点である。The disadvantages of halogenated phosphate esters and cyclic phosphate ester compounds are that they are both in liquid form, so when applied to dyed fabrics, the color fastness to friction may be affected, or color migration may occur over time, resulting in hot water contamination. This is difficult to use on cloth.
更に、防炎効果が低い為、目付が小さく柄もブレーンな
レースカーテン等にしか防炎性を付与する事が出来ない
為用途が極めて限定される。一方、HCAは、防炎性は
比較的良好であり通常のレースカーテン、ドレープカー
テンにも用いることができる。しかし、最近ではカーテ
ンの多様化、高級化、複合機能化等の要請が強くなって
おり、特に、黒原着糸使い、意匠糸使いカーテン、起毛
カーテン等には、ハロゲン化シクロアルカン化合物を使
用しても防炎性が不充分なものもあるため、防炎性を一
段と向上させる必要がある。Furthermore, since the flame retardant effect is low, flame retardant properties can only be imparted to lace curtains with a small basis weight and a simple pattern, so its uses are extremely limited. On the other hand, HCA has relatively good flame retardancy and can be used for ordinary lace curtains and drape curtains. However, recently there has been a strong demand for curtains to be diversified, sophisticated, and have multiple functions, and in particular, halogenated cycloalkane compounds are being used for curtains using black dope-dyed yarn, curtains using designed yarn, and raised curtains. However, there are some materials whose flame retardant properties are insufficient, so it is necessary to further improve their flame retardant properties.
また、)(CAを布帛へ付与する方法としては、微粉末
状HCAを染色浴へ添加し吸尽法により付与する方法が
一般的に用いられるが、HCA(比重≧ 1.1.融点
≧ 140℃)は布帛への吸尽率が低いため、染色釜の
汚染等が生じ工程工種々のトラブルが発生しやすいとい
う欠点がある。本発明省らは、これらの点に鑑み鋭意検
討した結果、ポリエステルgANにハロゲン化シクロア
ルカン化合物及び特定のホスフェート化合物を併用する
ことにより予期せぬ相剰効果があり、単独の化合物では
えられない防炎性能が得られるとともにHCAの吸@率
を向上せしめ染色釜の汚染等の問題を改善できることを
見出し本発明に到達したものである。In addition, )(As a method for applying CA to fabric, a method is generally used in which finely powdered HCA is added to a dyeing bath and applied by an exhaustion method. °C) has a low rate of exhaustion into the fabric, which has the disadvantage of contaminating the dyeing pot and causing various problems in the process.The Ministry of Invention and others conducted extensive studies in view of these points, and found that The combined use of a halogenated cycloalkane compound and a specific phosphate compound in polyester gAN has an unexpected additive effect, resulting in flame retardant performance that cannot be achieved with a single compound, as well as improving HCA absorption and dyeing. The present invention was achieved by discovering that problems such as pot contamination can be improved.
〈発明の目的〉
すなわち本発明の目的は、前記防炎化の困難なポリエス
テル繊維製品に対しても十分な防炎性を付与するととも
に染料の泣き出し、ヌメリ、ベトッキ等がなく風合、堅
牢度等の優れた防炎性ポリエステル繊維製品を提供する
とともに製造工程においてHCAの吸尽率を向上せしめ
、かつ染色釜の汚染を防止できる製造方法を提供する。<Objective of the Invention> In other words, the object of the present invention is to impart sufficient flame retardancy even to polyester fiber products that are difficult to make flame retardant, and to provide a material with good texture and durability without bleeding of dyes, sliminess, stickiness, etc. To provide a flame-retardant polyester fiber product with excellent heat resistance, and to provide a manufacturing method capable of improving the exhaustion rate of HCA in the manufacturing process and preventing contamination of a dyeing pot.
〈発明の構成〉
上記目的を達成するための本発明の構成は以下のとおり
である。<Configuration of the Invention> The configuration of the present invention for achieving the above object is as follows.
(1) ポリエステルIImにハロゲン化シクロアル
カン化合物(A)と下記一般式(I)で表わされる化合
物(B)とを付着せしめてなるポリエステル繊1製品。(1) A polyester fiber product made by adhering a halogenated cycloalkane compound (A) and a compound (B) represented by the following general formula (I) to polyester IIm.
Z+ 0
Z2 −0−P=0 (I)(ここ
に、Z+ 、Z2及びZ3は脂肪族基、芳香族基、ハロ
ゲン化脂肪族基及びハロゲン化芳香族基から選ばれた基
)
(2) 化合物(A)を30〜90重皇%、化合物(
B)を70〜10重量%の割合で付着せしめた特許請求
の範囲第(1)項に記載のポリエステル繊維製品。Z+ 0 Z2 -0-P=0 (I) (where Z+, Z2 and Z3 are groups selected from aliphatic groups, aromatic groups, halogenated aliphatic groups and halogenated aromatic groups) (2) 30-90% compound (A), compound (A)
The polyester fiber product according to claim (1), to which B) is attached in a proportion of 70 to 10% by weight.
(3) 化合物(A>および化合物(B)をtl維製
品に対し1〜8重量重量着付しめた特許請求の範囲第(
1)項または第(2)項に記載のポリエステル繊III
製品。(3) Claim No. 1 in which the compound (A> and the compound (B) are applied to a TL textile product by 1 to 8 weights)
Polyester fiber III according to item 1) or item (2)
product.
’[4) m雑製品が染色布である特許請求の範囲第
(1)項〜第(3)項のいずれかに記載のポリエステル
繊維製品。[4] The polyester fiber product according to any one of claims (1) to (3), wherein the miscellaneous product is a dyed cloth.
(5) 繊維製品がカーテンである特許請求の範囲第
(1)項〜第(4)項のいずれかに記載のポリエステル
繊維製品。(5) The polyester fiber product according to any one of claims (1) to (4), wherein the fiber product is a curtain.
(6) ポリエステル1!帷をハロゲン化シクロアル
カン化合物(A)と下記一般式で表されるホスフェート
化合物(B)とで処理した後、120〜240℃で熱処
理することを特徴とするポリエステル繊維製品の製造方
法。(6) Polyester 1! A method for producing a polyester fiber product, which comprises treating a cloth with a halogenated cycloalkane compound (A) and a phosphate compound (B) represented by the following general formula, and then heat-treating the cloth at 120 to 240°C.
Z+ −0
220−P=0
(ここに、Z+ 、Z2及びZ3は脂肪族基、芳香族基
、ハロゲン化脂肪族基及びハロゲン化芳香族基から選ば
れた基)
(7)化合物<A)と化合物(B)との混合分散液で処
理する特許請求の範囲第(6)項に記載のポリエステル
繊維製品の製造方法。Z+ -0 220-P=0 (where Z+, Z2 and Z3 are groups selected from aliphatic groups, aromatic groups, halogenated aliphatic groups and halogenated aromatic groups) (7) Compound <A) The method for producing a polyester fiber product according to claim (6), which comprises treating the polyester fiber product with a mixed dispersion of the compound (B) and the compound (B).
(8)化合物(A)の分散液と化合物(B)の分散液と
で個別に処理する特許請求の範囲第(6)項に記載のポ
リエステルlll1l製品の製造方法。(8) The method for producing a polyester lllll product according to claim (6), wherein the dispersion of compound (A) and the dispersion of compound (B) are separately treated.
本発明において防炎剤として用いられるハロゲン化シク
ロアルカン化合物(A)とは、7〜12個の環構成炭素
原子と該炭素原子に結合した3〜6個のハロゲン原子を
有するシクロアルカン化合物を指し、特に融点が140
〜190℃のものが好適であり、後記する如く、平均粒
子径は1ミクロン以下であるとよい。特に好ましい例と
しては、1,2゜5.6.9.10−へキサブロモシク
ロドデカンである。The halogenated cycloalkane compound (A) used as a flame retardant in the present invention refers to a cycloalkane compound having 7 to 12 ring-constituting carbon atoms and 3 to 6 halogen atoms bonded to the carbon atoms. , especially when the melting point is 140
-190°C is suitable, and as described later, the average particle size is preferably 1 micron or less. A particularly preferred example is 1,2°5.6.9.10-hexabromocyclododecane.
また、前記一般式(I)で表される化合物(B)として
は、たとえば、トリオクチルホスフェート。Moreover, as the compound (B) represented by the general formula (I), for example, trioctyl phosphate.
トリス(クロロエチル)ホスフェート、トリス(ジクロ
ロプロピル)ホスフェート、トリクレジルホスフェート
、トリキシレニルホスフェート。Tris (chloroethyl) phosphate, tris (dichloropropyl) phosphate, tricresyl phosphate, tricylenyl phosphate.
クレジルジフェニルホスフェート等が挙げられる。Examples include cresyl diphenyl phosphate.
化合物(B)は常温で液状のものがポリエステル!l維
の可塑化作用、HCAの可溶化作用に層れ、相開効果が
得られ易い。Compound (B) is polyester when it is liquid at room temperature! The plasticizing action of l fibers and the solubilizing action of HCA make it easy to obtain a phase opening effect.
化合物(A)と化合物(B)とをポリニスデル11$1
に付着せしめる方法としては、化合物(A)と化合物(
B)との水分散液を染色浴に添加し、高圧染色法により
、吸尽処理する方法が有効であるが、浸漬・絞液法、ス
プレー法、コーティング法等によっても可能である。化
合物(A)と化合物(B)とをポリエステル繊維に付着
させた後、120〜240℃の温度で熱処理する。Compound (A) and compound (B) were added to polynisdel 11$1.
As a method for attaching compound (A) and compound (
An effective method is to add an aqueous dispersion of B) to a dye bath and carry out an exhaustion treatment using a high-pressure dyeing method, but methods such as a dipping/squeezing method, a spray method, a coating method, etc. are also possible. After attaching compound (A) and compound (B) to polyester fiber, heat treatment is performed at a temperature of 120 to 240°C.
処理する時期は、紡糸以降であれば任意の段階でよく、
例えば、延伸前後、編織物その地布状物を作製する前後
のいずれでもよい。The treatment may be performed at any stage after spinning.
For example, it may be carried out before or after stretching, or before or after producing a knitted fabric or a ground cloth.
化合物(A)の分散液調整法としては、ボールミル、サ
ンドグラインダー、ディスククラッシャーや乾式法でも
可能であるが、好ましくは、水平型湿式超微粉分散機を
用いて平均粒子径が1ミクロン以下に微粉化する。平均
粒子径が1ミクロン以下であると、分散助剤を必ずしも
必要としない。The dispersion of compound (A) can be prepared by using a ball mill, sand grinder, disk crusher, or dry method, but it is preferable to use a horizontal wet ultrafine powder dispersion machine to form a fine powder with an average particle size of 1 micron or less. become When the average particle diameter is 1 micron or less, a dispersion aid is not necessarily required.
化合物(A)と化合物(B)との付着割合は、前者が3
0〜90重量%、後者が70〜10重量%とするのが望
ましい。両者の比が、この範囲外であると相開効果が十
分発揮されない。また、化合物(A)及び化合物(B)
の繊維製品に対する付着率は、約1〜8重1%である。The adhesion ratio of compound (A) and compound (B) is 3 for the former.
It is desirable that the content be 0 to 90% by weight, and the latter be 70 to 10% by weight. If the ratio of both is outside this range, the phase opening effect will not be sufficiently exhibited. Also, compound (A) and compound (B)
The adhesion rate to textile products is about 1-8% by weight.
付着率が約1重量%未満では得られる繊維製品に防炎性
を十分付与できない。一方、8重量%を越えても格別こ
れらの性能は向上せず不経済でもあり、また繊維製品自
体が有する風合、感触等を悪化させる。If the adhesion rate is less than about 1% by weight, sufficient flame retardancy cannot be imparted to the resulting textile product. On the other hand, if the content exceeds 8% by weight, these properties will not be particularly improved and it will be uneconomical, and the texture, feel, etc. of the textile product itself will be deteriorated.
ポリエステルIIIIIM品とは、ポリエチレンテレフ
タレート、又はポリブチレンテレフタレート等のポリエ
ステルを主たる構成成分とする繊維製品であって、具体
的には、防炎性、風合等を要求されるポリエステルカー
テン、染色布等を挙げることができる。尚、特に耐光堅
牢度が要求される場合は、ベンゾトリアゾール系、ベン
ゾフェノン系等の紫外線吸収剤を併用してもよい。Polyester IIIM products are textile products whose main component is polyester such as polyethylene terephthalate or polybutylene terephthalate, and specifically include polyester curtains, dyed fabrics, etc. that require flame retardant properties, texture, etc. can be mentioned. In addition, when particularly light fastness is required, ultraviolet absorbers such as benzotriazole type and benzophenone type may be used in combination.
〈発明の効果〉
本発明によれば、従来防炎化が困難であった黒色の原着
糸を用いた織物あるいは起毛織物等にも十分応用するこ
とができ、極めて優れた防炎性とともに洗濯耐久性、風
合、耐光堅牢性などをポリエステル繊維製品に具備せし
めるとともに、HCAの吸尽率向上、染色釜の汚染防止
も一挙に解決される。<Effects of the Invention> According to the present invention, it can be fully applied to fabrics using black dyed yarn or raised fabrics, etc., which have been difficult to flameproof in the past, and have excellent flameproofing properties as well as washability. In addition to providing polyester fiber products with durability, texture, light fastness, etc., it also solves the problem of improving the exhaustion rate of HCA and preventing pollution of dyeing pots.
〈実施例〉 以下に実施例により本発明を具体的に説明する。<Example> The present invention will be specifically explained below using Examples.
実施例1
ポリエチレンテレフタレート織物(経糸300デニール
ウーリー加工系、経方向織密度100本/インチ、緯糸
150デニ一ル黒原着糸フィラメント。Example 1 Polyethylene terephthalate fabric (warp 300 denier woolly processed, warp direction weave density 100 pieces/inch, weft 150 denier black spun-dyed yarn filament).
緯方向織密度60本/インチ、8枚朱子織、目付290
g/Td)を精練後、Resolin 31ue F
B L2%owf及び第1表に示したとおりの化合物(
A)と化合物(B)との配合液を添加した染浴で染色温
度130℃、染色時間30分で染色吸尽処理した後、遠
心脱水、乾燥、熱処理(ピンテンターで190℃。Weft density: 60/inch, 8-ply satin weave, weight: 290
g/Td), Resolin 31ue F
B L2%owf and compounds as shown in Table 1 (
After dye exhaustion treatment at a dyeing temperature of 130°C and a dyeing time of 30 minutes in a dye bath containing a mixed solution of A) and compound (B), centrifugal dehydration, drying, and heat treatment (190°C with a pin tenter).
30秒間の処理)を施したのち、防炎性、防炎剤吸尽率
等について評価した。After performing the treatment for 30 seconds, flame retardant properties, flame retardant exhaustion rate, etc. were evaluated.
結果を第1表に示す。The results are shown in Table 1.
実施例2〜3.比較例1〜3
実施例1で使用した織物を用いて、防炎剤(A)と(B
)との配合比率を第1表の如く変更した以外は実施例1
と全く同様に処理した。Examples 2-3. Comparative Examples 1 to 3 Using the fabric used in Example 1, flame retardant (A) and (B
) Example 1 except that the blending ratio with ) was changed as shown in Table 1.
was treated in exactly the same way.
結果を第1表に示す。The results are shown in Table 1.
尚、防炎性は消防庁告示第11号[防炎性能に係る耐洗
濯性能の基準」に従って水洗い洗濯後、消防法の45°
ミクロバーナー法(着炎3秒テスト)及びコイル法によ
り測定した。合否判定は、残炎が3秒以下でかつ、コイ
ル法接炎回数が3回以上を合格とした。In addition, flame retardant properties are measured at 45° after washing with water in accordance with Fire and Disaster Management Agency Notification No. 11 [Standards for washing resistance performance related to flame retardant performance].
It was measured by the micro burner method (flaming 3 seconds test) and the coil method. In the pass/fail judgment, if the afterflame was 3 seconds or less and the number of times the coil was contacted with the flame was 3 or more times, the test was judged as passing.
Claims (8)
合物(A)と下記一般式( I )で表わされる化合物(
B)とを付着せしめてなるポリエステル繊維製品。 ▲数式、化学式、表等があります▼( I ) (ここに、Z_1、Z_2及びZ_3は脂肪族基、芳香
族基、ハロゲン化脂肪族基及びハロゲン化芳香族基から
選ばれた基)(1) A polyester fiber containing a halogenated cycloalkane compound (A) and a compound represented by the following general formula (I) (
A polyester fiber product made by adhering B). ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (I) (Here, Z_1, Z_2, and Z_3 are groups selected from aliphatic groups, aromatic groups, halogenated aliphatic groups, and halogenated aromatic groups)
を70〜10重量%の割合で付着せしめた特許請求の範
囲第(1)項に記載のポリエステル繊維製品。(2) 30 to 90% by weight of compound (A), compound (B)
The polyester fiber product according to claim (1), wherein 70 to 10% by weight of the polyester fiber product is attached.
し1〜8重量%付着せしめた特許請求の範囲第(1)項
または第(2)項に記載のポリエステル繊維製品。(3) The polyester fiber product according to claim (1) or (2), wherein 1 to 8% by weight of compound (A) and compound (B) are attached to the fiber product.
項〜第(3)項のいずれかに記載のポリエステル繊維製
品。(4) Claim No. (1) in which the textile product is dyed cloth
The polyester fiber product according to any one of Items to Items (3).
)項〜第(4)項のいずれかに記載のポリエステル繊維
製品。(5) Claim No. 1 in which the textile product is a curtain
The polyester fiber product according to any one of items ) to item (4).
合物(A)と下記一般式で表されるホスフェート化合物
(B)とで処理した後、120〜240℃で熱処理する
ことを特徴とするポリエステル繊維製品の製造方法。 ▲数式、化学式、表等があります▼ (ここに、Z_1、Z_2及びZ_3は脂肪族基、芳香
族基、ハロゲン化脂肪族基及びハロゲン化芳香族基から
選ばれた基)(6) Production of a polyester fiber product characterized by treating polyester fiber with a halogenated cycloalkane compound (A) and a phosphate compound (B) represented by the following general formula, and then heat-treating it at 120 to 240°C. Method. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (Here, Z_1, Z_2, and Z_3 are groups selected from aliphatic groups, aromatic groups, halogenated aliphatic groups, and halogenated aromatic groups)
理する特許請求の範囲第(6)項に記載のポリエステル
繊維製品の製造方法。(7) The method for producing a polyester fiber product according to claim (6), which is treated with a mixed dispersion of compound (A) and compound (B).
個別に処理する特許請求の範囲第(6)項に記載のポリ
エステル繊維製品の製造方法。(8) The method for producing a polyester fiber product according to claim (6), which comprises treating the dispersion of compound (A) and the dispersion of compound (B) separately.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12562286A JPS62289669A (en) | 1986-06-02 | 1986-06-02 | Polyester fiber product and its production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12562286A JPS62289669A (en) | 1986-06-02 | 1986-06-02 | Polyester fiber product and its production |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62289669A true JPS62289669A (en) | 1987-12-16 |
JPH0346585B2 JPH0346585B2 (en) | 1991-07-16 |
Family
ID=14914625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12562286A Granted JPS62289669A (en) | 1986-06-02 | 1986-06-02 | Polyester fiber product and its production |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62289669A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04352876A (en) * | 1991-05-30 | 1992-12-07 | Teijin Ltd | Fabric for flameproof sheet |
-
1986
- 1986-06-02 JP JP12562286A patent/JPS62289669A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04352876A (en) * | 1991-05-30 | 1992-12-07 | Teijin Ltd | Fabric for flameproof sheet |
Also Published As
Publication number | Publication date |
---|---|
JPH0346585B2 (en) | 1991-07-16 |
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