JPS62286729A - Manufacture of hollow pipe made of fiber reinforced plastic - Google Patents
Manufacture of hollow pipe made of fiber reinforced plasticInfo
- Publication number
- JPS62286729A JPS62286729A JP61129318A JP12931886A JPS62286729A JP S62286729 A JPS62286729 A JP S62286729A JP 61129318 A JP61129318 A JP 61129318A JP 12931886 A JP12931886 A JP 12931886A JP S62286729 A JPS62286729 A JP S62286729A
- Authority
- JP
- Japan
- Prior art keywords
- prepreg sheet
- core
- metal
- tube
- core metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229920002430 Fibre-reinforced plastic Polymers 0.000 title claims description 6
- 239000011151 fibre-reinforced plastic Substances 0.000 title claims description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 8
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 6
- 239000013013 elastic material Substances 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 9
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 230000004927 fusion Effects 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006023 eutectic alloy Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229910001152 Bi alloy Inorganic materials 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
Description
【発明の詳細な説明】
3、発明の詳細な説明
a、発明の目的
(産業上の利用分野)
この発明に係る繊維強化プラスチック製中空管の製造方
法は、例えば炭素繊維により補強されたプリプレグシー
トを丸めて造られた管により、自転車のハンドル或はフ
ォークブレードの様に比較的複雑な形状を有する曲げ加
工管を量産する場合に利用出来る他、丈夫で軽量な事を
要求される自動車のドライブシャフトや、丈夫で軽量且
つ厳密な寸法精度を要求される鎮空宇宙機器搭載用極超
短波用導波管の基材を製作する場合等に利用出来る。Detailed description of the invention 3. Detailed description of the invention a. Object of the invention (industrial application field) Tubes made by rolling sheets can be used to mass produce bent tubes with relatively complex shapes, such as bicycle handles or fork blades, as well as for automobiles, which require strong and lightweight construction. It can be used to manufacture base materials for drive shafts and extremely high frequency waveguides for air and space equipment that require strong, lightweight, and strict dimensional accuracy.
(従来の技術とその問題点)
例えば自転車用ハンドルの場合、従来は鉄、或はアルミ
ニウム製の金属管を所望の形状に曲げ加工して造られて
いた。(Prior Art and Its Problems) For example, in the case of a bicycle handle, conventionally, a metal tube made of iron or aluminum is bent into a desired shape.
ところで、例えば自転車用ハンドルの場合、競技用のも
のを中心として、より軽量な材料により造る事が常に研
究されている。By the way, for example, in the case of bicycle handles, there is constant research into making them from lighter materials, mainly for bicycle handles used for competitions.
中空管状に形成する事が出来、しかも軽量で丈夫な材料
としては、例えばガラス繊維や炭素繊維により補強され
たプリプレグシートを丸めて管状に形成したものが考え
られる。An example of a lightweight and durable material that can be formed into a hollow tube shape is a material made by rolling a prepreg sheet reinforced with glass fiber or carbon fiber and forming it into a tube shape.
ところが、自転車用ハンドルの場合、形状が複雑で曲げ
加工が面倒であり、特に競技用やスポーツ用の自転車に
組み付けられるドロップハンドルの場合は、従来の技術
ではプリプレグシート製のものを得る事は出来なかった
。However, in the case of bicycle handlebars, the shape is complex and bending is troublesome, and in the case of drop handlebars, which are assembled on bicycles for competitions and sports, it is impossible to obtain handlebars made of prepreg sheets using conventional techniques. There wasn't.
即ち、ガラス繊維や炭素繊維により補強されたプリプレ
グシートを管状に加工する場合、熱硬化性樹脂のバイン
ダ一部分を熱硬化させる間中、完成後の中空管に相当す
る部分を、管の内側と外側とから所望の形状に保持する
と同時に、仕上り外観を良くする為に上記中空管に相当
する部分に圧力を加えている必要がある。That is, when processing a prepreg sheet reinforced with glass fibers or carbon fibers into a tube shape, during the heat curing of a portion of the thermosetting resin binder, the portion corresponding to the completed hollow tube is separated from the inside of the tube. It is necessary to maintain the desired shape from the outside and at the same time apply pressure to the portion corresponding to the hollow tube in order to improve the finished appearance.
ところが、曲げ加工管や、途中で断面形状が変化する中
空管の場合、プリプレグシート成型用として従来から広
く使用されている鋼製、或は黄銅製の芯金を使うと、芯
金に巻き付けた後熱硬化前の、機械的強度の低いプリプ
レグシートを傷っけない様に曲げ加工することが極めて
困難なだけでなくプリプレグシートの熱硬化後に芯金の
抜去を行なえなくなってしまう。However, in the case of bent pipes or hollow pipes whose cross-sectional shape changes midway through, if we use steel or brass core metals, which have been widely used for forming prepreg sheets, it is difficult to wrap the pipes around the core metal. Not only is it extremely difficult to bend the prepreg sheet, which has low mechanical strength, without damaging it, but it also becomes impossible to remove the core metal after the prepreg sheet has been heat-cured.
本発明の繊維強化プラスチック製中空管の製造方法は、
上述の様な事情に鑑みて発明されたものである。The method for manufacturing a fiber-reinforced plastic hollow tube of the present invention includes:
This invention was invented in view of the above-mentioned circumstances.
b 発明の構成
(問題を解決するための手段)
本発明の繊維強化プラスチック製中空管の製造方法は次
の(a)〜(e) に示した第一〜第五の5工程から成
っている。b. Structure of the invention (means for solving the problem) The method for manufacturing a fiber-reinforced plastic hollow tube of the present invention consists of the following five steps (a) to (e), first to fifth. There is.
即ち、
(a)低温で溶融する金属により造られた芯金の外周に
、この芯金を構成する金属の溶融温度よりも少しだけ低
い温度で硬化する熱硬化性のプリプレグシートを巻き付
ける第一工程。That is, (a) a first step of wrapping a thermosetting prepreg sheet that hardens at a temperature slightly lower than the melting temperature of the metal constituting the core around the outer periphery of a core made of a metal that melts at low temperatures; .
(b)第一工程で芯金の外周を囲む管状に形成されたプ
リプレグシートに、弾力性を有する材料製のテープを螺
旋状に巻くか、或は弾力性を有する材料製のチューブを
外嵌する事により、このプリプレグシートの外周を弾力
性を有する材料により囲む第二工程。(b) A tape made of an elastic material is spirally wound around the prepreg sheet formed into a tubular shape surrounding the outer periphery of the core metal in the first step, or a tube made of an elastic material is fitted around the prepreg sheet. The second step is to surround the outer periphery of this prepreg sheet with an elastic material.
(C)芯金と、第一工程に於いて管状に形成されたプリ
プレグシートと、第二工程に於いてプリプレグシートの
周囲を囲んだ弾力性を有する材料とを、曲げ加工或は断
面形状を変えるプレス加工を施す事により所望の形状に
加工する第三工程。(C) The core metal, the prepreg sheet formed into a tubular shape in the first step, and the resilient material surrounding the prepreg sheet in the second step are bent or shaped to have a cross-sectional shape. The third step is to process it into the desired shape by applying press processing.
(d)第三工程で曲げ加工或はプレス加工された各部材
を更にプリプレグシートの硬化温度に迄加熱する第四工
程。(d) A fourth step in which each member bent or pressed in the third step is further heated to the curing temperature of the prepreg sheet.
(e)熱硬化したプリプレグシート製の加工管を含む各
部材を更に金属製芯金の溶融温度以上に迄加熱し、溶融
した芯金をプリプレグシート製の加工管の内側から流失
させると共に、このプリプレグシート製の加工管の外周
から弾力性を有する材料製のテープ或はチューブを除去
する第五工程。(e) Each member including the thermoset prepreg sheet processed tube is further heated to a temperature higher than the melting temperature of the metal core, and the molten core is flowed out from the inside of the prepreg sheet processed tube. The fifth step is to remove the tape or tube made of elastic material from the outer periphery of the processed pipe made of prepreg sheet.
上記(a)〜(e)に示した第一〜第五の工程を順番に
行なう事で、プリプレグシートは全体を所望の形状に形
成された中空管状とされるが、プリプレグシートは硬化
する際、弾力性を有する材料製のテープ或はチューブに
よって外周から弾性的に抑えられている為、硬化後の曲
げ加工管の強度が大きくなる。又、曲げ加工時には芯金
の存在により、中空管状のプリプレグシートの断面が潰
れる事かない。By sequentially performing the first to fifth steps shown in (a) to (e) above, the prepreg sheet is made into a hollow tube shape with a desired shape as a whole, but when the prepreg sheet is cured, Since it is elastically restrained from the outer periphery by a tape or tube made of an elastic material, the strength of the bent pipe after hardening is increased. Furthermore, during bending, the presence of the core metal prevents the cross section of the hollow tubular prepreg sheet from being crushed.
尚、本発明を実施する場合に使用するプリブレグシート
としては、従来から知られた各種のプリプレグシートを
使用する事が出来るが、炭素繊維により補強されたプリ
プレグシートの場合、例えば化成ファイバーライト社製
のMSX7714/2534 (硬化温度121℃)等
を使用する事が出来る。In addition, as the prepreg sheet used when carrying out the present invention, various conventionally known prepreg sheets can be used, but in the case of a prepreg sheet reinforced with carbon fiber, for example, Kasei Fiberlite Co., Ltd. MSX7714/2534 (curing temperature: 121°C), etc. manufactured by Manufacturer Co., Ltd., can be used.
又、芯金を造る低温溶融金属としては、半田等各種金属
を使用する事が出来るが、金属マニュアル等に記載され
ているビスマスと鉛との共晶合金で、溶融温度が124
℃のものが、前記MSX7714/2534との組合せ
で好ましく使用出来る。上記共晶合金は、鋳造に伴なう
膨張、収縮量が極めて小さく、しかも鋳造後に急冷する
事で表面の奇麗な鋳造品を得られる為、鋳造後に機械加
工を施す事なく非常に寸法精度の良い芯金を得る事が出
来、且つ延性、展性に優れている為、曲げ加工や断面形
を変えるプレス加工を施し易いと言う利点がある。In addition, various metals such as solder can be used as the low-temperature melting metal for making the core metal, but the eutectic alloy of bismuth and lead described in metal manuals has a melting temperature of 124.
℃ can be preferably used in combination with the above MSX7714/2534. The above-mentioned eutectic alloy has extremely small expansion and contraction during casting, and can be rapidly cooled after casting to obtain a cast product with a beautiful surface, so it can achieve extremely high dimensional accuracy without the need for machining after casting. Since it is possible to obtain a good core metal and has excellent ductility and malleability, it has the advantage of being easy to bend and press to change the cross-sectional shape.
更に、プリプレグシートの加熱硬化時にこのプリプレグ
シートを外周から抑えるテープ、或はチューブを構成す
る弾力性を有する材料としては、ポリエチレン、或はポ
リプロピレン等を利用する事が出来る。更に加熱硬化時
に弾力性を保持出来るものであれば、弗素樹脂等の熱収
縮性合成樹脂を使用する事も出来る。Furthermore, polyethylene, polypropylene, or the like can be used as the elastic material constituting the tape or tube that restrains the prepreg sheet from its outer periphery when the prepreg sheet is heated and cured. Furthermore, heat-shrinkable synthetic resins such as fluororesin can also be used as long as they can maintain elasticity during heat curing.
(応用例)
前記(問題を解決するための手段)の欄に於いては、プ
リプレグシート製の中空管を製造する場合に必要不可欠
な要素を中心に述べたが、品質の良い軽量なプリプレグ
シート製の中空管を製造する場合には、更に、芯金の外
周面に剥離剤を塗布したり、前記第二工程に於いて芯金
の外周に巻き回したプリプレグシートの外周面に更に剥
離テープを巻き付ける事が効果がある。(Application example) In the above section (Means for solving the problem), we mainly described the essential elements when manufacturing hollow tubes made of prepreg sheets. When manufacturing a hollow tube made of a sheet, a release agent may be further applied to the outer circumferential surface of the core metal, or a release agent may be further applied to the outer circumferential surface of the prepreg sheet wound around the outer circumference of the core metal in the second step. Wrapping release tape is effective.
この内、芯金の外周面に塗布する剥離剤は、芯金とプリ
プレグシートとの付着を防止して、曲げ加工等を行なっ
た後に、加熱硬化済のプリプレグシート製の中空管の内
側から溶融した金属を完全に流失させ、完成後の中空管
の内側に金属が残留する事の防止を図る為のものであり
、プリプレグシートの外周面に巻き付ける剥離テープは
、加熱硬化済のプリプレグシート製の中空管の外周面か
ら弾性材製のテープ或はチューブを除去する作業を容易
且つ確実に行なえる様にする為のものである。Among these, the release agent applied to the outer peripheral surface of the core metal prevents adhesion between the core metal and the prepreg sheet, and is applied from the inside of the hollow tube made of heat-cured prepreg sheet after bending, etc. This is to ensure that the molten metal is completely washed away and to prevent metal from remaining inside the completed hollow tube. This is to facilitate and reliably remove an elastic tape or tube from the outer circumferential surface of a hollow tube made of plastic.
これら剥離剤や剥離テープは、従来から市販されている
ものを使用する事が出来る。As these release agents and release tapes, conventionally commercially available products can be used.
但し、完成後の中空管の内側に少量の金属が残留しても
構わないならば、芯金外周面の剥離剤は必ずしも必要で
はなく、プリプレグシート製の中空管の外周面は完成後
に研磨処理する為、必ずしも剥離テープを巻き回さなく
てもテープ或はチューブを中空管の外周面から完全に除
去する事が出来る。However, if it is okay for a small amount of metal to remain inside the hollow tube after completion, a release agent on the outer circumferential surface of the core bar is not necessarily necessary, and the outer circumferential surface of the hollow tube made of prepreg sheet may be Because of the polishing process, the tape or tube can be completely removed from the outer peripheral surface of the hollow tube without necessarily winding the release tape.
又、中空管を造るのに使用するプリプレグシートとして
は、炭素繊維により補強されたものが強度の面からも好
ましいが、自転車用ハンドル以外の用途に使用する中空
管で、それ程強度を要求しない場合は、ガラス繊維等地
の繊維により補強されトゴlゴI/ H5ノーにル椰田
ナス束り傅4スー更に、芯金の表面に切削等の機械加工
を施す事により、中空管の内側に補強用の螺旋条やリブ
を形成したり、或は中空管の開口端に継手用のフランジ
を一体に形成する事も出来る。即ち、芯金の表面に溝を
形成し、この芯金の外周面にプリプレグシートを巻き回
す際に、上記プリプレグシートの一部をこの溝の内側に
進入させれば、この進入部分が、熱硬化後に於いて補強
用の螺旋条やリプ、或は継手用フランジとなる。Additionally, prepreg sheets used to make hollow tubes that are reinforced with carbon fiber are preferred in terms of strength, but hollow tubes that are used for purposes other than bicycle handles require such strength. If not, the hollow tube can be made by reinforcing it with fibers of a material such as glass fiber, and then machining the surface of the core metal such as cutting. It is also possible to form reinforcing spiral strips or ribs on the inside of the tube, or to integrally form a flange for a joint on the open end of the hollow tube. In other words, if a groove is formed on the surface of the core metal, and when a prepreg sheet is wound around the outer circumferential surface of the core metal, a part of the prepreg sheet enters the inside of the groove. After curing, it becomes a reinforcing spiral strip or lip, or a flange for a joint.
本発明の方法により造られる中空管の品質をより向上さ
せる場合には、第四行程に於ける加熱硬化時に、芯金に
巻き回したプリプレグシートを更に外型に内嵌すれば、
完成後の中空管に熱歪や弾性戻りが生じて、この中空管
の寸法精度が狂う事を防止出来る。この際、必要に応じ
て、加熱炉内を高圧にすれば、プリプレグシートのバイ
ンダーに含まれるレジンの流失を完全に防止出来て更に
品質の良い中空管を得る事が出来る。In order to further improve the quality of the hollow tube produced by the method of the present invention, if the prepreg sheet wound around the core metal is further fitted into the outer mold during heat curing in the fourth step,
It is possible to prevent thermal distortion or elastic return from occurring in the completed hollow tube, which would cause the dimensional accuracy of the hollow tube to become inconsistent. At this time, if necessary, if the pressure inside the heating furnace is made high, it is possible to completely prevent the resin contained in the binder of the prepreg sheet from flowing out, and it is possible to obtain a hollow tube of even better quality.
C1発明の効果
本発明の繊維強化プラスチック製中空管の製造方法は以
上に述べた通り構成されるが、従来困難とされていた繊
維強化プラスチック製で複雑な形状を有する中空管の製
造を容易に行なう事が出来て、自転車用ハンドル等各種
物品の軽量化に果たす役割は大きい。C1 Effects of the Invention The method for manufacturing a fiber-reinforced plastic hollow tube of the present invention is configured as described above, and it is possible to manufacture a fiber-reinforced plastic hollow tube with a complicated shape, which has been considered difficult in the past. It is easy to perform and plays a large role in reducing the weight of various products such as bicycle handles.
Claims (1)
る繊維強化プラスチック製中空管の製造方法。 (a)低温で溶融する金属により造られた芯金の外周に
、この芯金を構成する金属の溶融温度よりも少しだけ低
い温度で硬化する熱硬化性のプリプレグシートを巻き付
ける第一工程。 (b)第一工程で芯金の外周を囲む管状に形成されたプ
リプレグシートに、弾力性を有する材料製のテープを螺
旋状に巻くか、或は弾力性を有する材料製のチューブを
外嵌する事により、このプリプレグシートの外周を弾力
性を有する材料により囲む第二工程。 (c)芯金と、第一工程に於いて管状に形成されたプリ
プレグシートと、第二工程に於いてプリプレグシートの
周囲を囲んだ弾力性を有する材料とを、曲げ加工或は断
面形状を変えるプレス加工を施す事により所望の形状に
加工する第三工程。 (d)第三工程で曲げ加工或はプレス加工された各部材
を更にプリプレグシートの硬化温度に迄加熱する第四工
程。 (e)熱硬化したプリプレグシート製の加工管を含む各
部材を更に金属製芯金の溶融温度以上に迄加熱し、溶融
した芯金をプリプレグシート製の加工管の内側から流失
させると共に、このプリプレグシート製の加工管の外周
から弾力性を有する材料製のテープ或はチューブを除去
する第五工程。[Scope of Claims] A method for manufacturing a fiber-reinforced plastic hollow tube comprising the first to fifth steps described in the following (a) to (e). (a) A first step of wrapping a thermosetting prepreg sheet that hardens at a temperature slightly lower than the melting temperature of the metal constituting the core around the outer periphery of a core made of a metal that melts at low temperatures. (b) A tape made of an elastic material is spirally wound around the prepreg sheet formed into a tubular shape surrounding the outer periphery of the core metal in the first step, or a tube made of an elastic material is fitted around the prepreg sheet. The second step is to surround the outer periphery of this prepreg sheet with an elastic material. (c) The core metal, the prepreg sheet formed into a tubular shape in the first step, and the elastic material surrounding the prepreg sheet in the second step are bent or shaped to have a cross-sectional shape. The third step is to process it into the desired shape by applying press processing. (d) A fourth step in which each member bent or pressed in the third step is further heated to the curing temperature of the prepreg sheet. (e) Each member including the thermoset prepreg sheet processed tube is further heated to a temperature higher than the melting temperature of the metal core, and the molten core is flowed out from the inside of the prepreg sheet processed tube. The fifth step is to remove the tape or tube made of elastic material from the outer periphery of the processed pipe made of prepreg sheet.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61129318A JPS62286729A (en) | 1986-06-05 | 1986-06-05 | Manufacture of hollow pipe made of fiber reinforced plastic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61129318A JPS62286729A (en) | 1986-06-05 | 1986-06-05 | Manufacture of hollow pipe made of fiber reinforced plastic |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS62286729A true JPS62286729A (en) | 1987-12-12 |
Family
ID=15006610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61129318A Pending JPS62286729A (en) | 1986-06-05 | 1986-06-05 | Manufacture of hollow pipe made of fiber reinforced plastic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62286729A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4917464A (en) * | 1972-06-05 | 1974-02-15 | ||
JPS5437175A (en) * | 1977-08-29 | 1979-03-19 | Mitsubishi Rayon Co Ltd | Production of pipe made of fiber reinforced plastic |
JPS5438376A (en) * | 1977-09-01 | 1979-03-22 | Mitsubishi Rayon Co Ltd | Molding of fiber reinforced plastic pipe |
-
1986
- 1986-06-05 JP JP61129318A patent/JPS62286729A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4917464A (en) * | 1972-06-05 | 1974-02-15 | ||
JPS5437175A (en) * | 1977-08-29 | 1979-03-19 | Mitsubishi Rayon Co Ltd | Production of pipe made of fiber reinforced plastic |
JPS5438376A (en) * | 1977-09-01 | 1979-03-22 | Mitsubishi Rayon Co Ltd | Molding of fiber reinforced plastic pipe |
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