JPS62281810A - Separation-type liquid hair-dressing composition - Google Patents
Separation-type liquid hair-dressing compositionInfo
- Publication number
- JPS62281810A JPS62281810A JP12422186A JP12422186A JPS62281810A JP S62281810 A JPS62281810 A JP S62281810A JP 12422186 A JP12422186 A JP 12422186A JP 12422186 A JP12422186 A JP 12422186A JP S62281810 A JPS62281810 A JP S62281810A
- Authority
- JP
- Japan
- Prior art keywords
- water
- phase
- composition
- hair
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title abstract description 27
- 239000007788 liquid Substances 0.000 title abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 16
- 235000019441 ethanol Nutrition 0.000 claims abstract description 10
- 239000004677 Nylon Substances 0.000 claims abstract description 8
- 229920001778 nylon Polymers 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 150000005215 alkyl ethers Chemical class 0.000 claims description 4
- 239000012071 phase Substances 0.000 abstract description 30
- -1 polyalkylene glycol Chemical compound 0.000 abstract description 11
- 239000007864 aqueous solution Substances 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000008346 aqueous phase Substances 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- 241000272525 Anas platyrhynchos Species 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
３、発明の詳細な説明
〔産業上の利用分野〕
本発明は、分離型液体整髪料に係り、特に美麗でファツ
ショナブルな外表を示す分離型液体整髪料に関する。Detailed Description of the Invention 3. Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a separate liquid hair styling product, and particularly to a separating liquid hair styling product that exhibits a beautiful and fashionable exterior.
従来、水性相−疎水性液体相系の２相分点型液体整髪料
が知られているが、この１の抜本整髪料は疎水ａ液体を
多量に配合する必要があるため、毛髪にベタツキが生ず
る等の使用上の欠点があった。毛髪は首筋等の肌に直接
触れるものであり、また手入れの９′：Ａには必ず手で
触れらｉする部分であるから、このようなベタツキは徹
底的に嫌われるため、好ましくない。Hitherto, two-phase liquid hair styling preparations with an aqueous phase and a hydrophobic liquid phase system have been known, but this first hair styling preparation requires a large amount of hydrophobic a liquid to be blended, so it does not leave the hair sticky. There were disadvantages in use, such as: Hair is a part that comes into direct contact with the skin of the nape of the neck, and is a part that must be touched by hand in step 9': A of care, so such stickiness is completely disliked and is therefore undesirable.
上記の欠点を防止する九めには、疎水性液体を用いない
ことが必要であるが、そのような２相分離型液体整髪料
はこれまで知られていなかった。The ninth way to prevent the above-mentioned drawbacks is to avoid using a hydrophobic liquid, but such a two-phase separation type liquid hair styling preparation has not been known so far.
特に、水性相−水性相系の２相分離梨夜体整髪料のｖＩ
４製は困難であった。In particular, vI of the two-phase separated pear-shaped hair conditioner of aqueous phase-aqueous phase system.
4 production was difficult.
本発明は、このような事情に謹みなされたもので、美麗
な外ａｔ−示す水性相−水性相系の２相分離型夜本整髪
料組成物を提供することを自重とする。The present invention has been made in consideration of these circumstances, and its purpose is to provide a two-phase separated type Yomoto hair styling composition of an aqueous phase-aqueous phase system that exhibits a beautiful exterior.
〔問題点を解決するための手段及び作用〕本発明の分１
Ｉｉｌ型液体整髪料は、エチルアルコール２０〜８Ｑｉ
Ｊｉ％と、ｄｅ ’）アルキレングリコール、ポリオキ
ソアルキレンアルキルエーテルリン酸又ハ七の塩および
アルキルポリシロキサン−ポリオキシアルキレン共重合
体から選択された少なくとも１種からなる整髪主剤１０
〜３０重量％と、水溶性ナイロンおよびポリビニルピロ
リドンから選択された少なくともＩ Ｅ＊からなる水溶
性ポリマー ０．５〜３０重ｉ％とを含有することを特
徴とする。[Means and effects for solving the problems] Part 1 of the present invention
Iil type liquid hair conditioner contains 20 to 8 Qi of ethyl alcohol.
Hair styling main agent 10 consisting of at least one selected from Ji% and de') alkylene glycol, polyoxoalkylene alkyl ether phosphoric acid or ha7 salt, and alkyl polysiloxane-polyoxyalkylene copolymer
~30% by weight, and 0.5 to 30% by weight of a water-soluble polymer consisting of at least IE* selected from water-soluble nylon and polyvinylpyrrolidone.
本発明の嘉１の必須成分はエチルアルコールであり、七
の配合量は２０〜８０重量％、好ましくは２０〜７０重
ｆ％である。２０％未満では組成物は実質的に分離せず
、８０％を越えると組成物が整髪料として機能し難くな
り、好ましくない。The essential component of Ka1 of the present invention is ethyl alcohol, and the blending amount of Ka1 is 20 to 80% by weight, preferably 20 to 70% by weight. If it is less than 20%, the composition will not substantially separate, and if it exceeds 80%, it will be difficult for the composition to function as a hair conditioner, which is not preferable.
本発明の第２の必須成分は、ポリアルキノングリコール
、ポリオキノアルキレンアルキルエーテルリン酸（塩）
、およびアルキルポリノロキサンポリオキシアルキレン
共重合体の１種又は２種以上からなる＃ｉ髪主剤でちる
。ポリアルキノングリコールとしては、ポリオキシエチ
レン（ＥＯ：１０〜６０モル）アルキル（Ｃｔ〜ｔｏ
）エーテル、ポリオキシエチレンン（）’Ｏ：１０〜６
０モル）アルキルＣＣＶ−＜。）エーテル、ポリオキシ
エチレン（ｇｏ：ｔｏ〜６０モル）ポリオキシプロピレ
ン（ＰＯ：１０〜６０モル）アルキル（ａｔ〜ｔｏ ）
エーテル等が挙ケられる。ポリオキシアルキレンアルキ
ルエーテルリン酸（塩）としては、ポリオキシエチレン
（ＥＯ：１．０〜６０モル）アルキル（Ｃ２〜８゜）エ
ーテルリン酸、ポリオキシプロピレン（ＰＯ：１０〜６
０モル）アルキル（Ｃｚ、２゜）エーテルリン酸又はこ
れらのアルカノールアミン塩等が１’られる。アルキル
ポリノロキサンポリオキシアルキレン共重合体としては
、ジメチル又ｉ１’−！−ｆルホリシロキサンーポリオ
キノアルキレン（ｇｏ又はＰＯ：１０〜５０モル）共ム
合体等が挙げられる。The second essential component of the present invention is polyalkynon glycol, polyquinoalkylene alkyl ether phosphoric acid (salt)
, and an alkyl polynoloxane polyoxyalkylene copolymer. As the polyalquinone glycol, polyoxyethylene (EO: 10 to 60 mol) alkyl (Ct to
) ether, polyoxyethylene ()'O: 10-6
0 mol) alkyl CCV-<. ) ether, polyoxyethylene (go: to ~60 mol) polyoxypropylene (PO: 10 ~ 60 mol) alkyl (at ~ to)
Examples include ether. Examples of polyoxyalkylene alkyl ether phosphoric acid (salt) include polyoxyethylene (EO: 1.0 to 60 mol) alkyl (C2 to 8°) ether phosphoric acid, polyoxypropylene (PO: 10 to 6
0 mol) alkyl (Cz, 2°) ether phosphoric acid or an alkanolamine salt thereof, etc. As the alkyl polynoloxane polyoxyalkylene copolymer, dimethyl or i1'-! Examples include -f sulfolisiloxane-polyokinoalkylene (GO or PO: 10 to 50 moles) co-merger.
第２０必須成分の配合量は１０〜３０鬼オ輻、好ましく
は１５〜２５重量％である。１Ｏｔｔ％未満では組成物
は実質的に分離せず、３０重Ｊ％を越えると分離相がゲ
ル化し、好ましくない。The content of the 20th essential component is 10 to 30% by weight, preferably 15 to 25% by weight. If it is less than 1 Ott%, the composition will not be substantially separated, and if it exceeds 30% by weight, the separated phase will gel, which is not preferable.
本発明の第３の必須成分は、水溶性ナイロンおよび／ま
ｔはポリビニルピロリドンから予る水溶性ポリマーであ
る。水溶性ナイロンは、水やアルコールに溶解する機能
を付与した変性アルミドであり、へＱナイロン（−一７
０、Ａ−９０、Ｐ−７０）（東し法式会社型）として市
販さルている。The third essential component of the present invention is a water-soluble polymer made from water-soluble nylon and/or polyvinylpyrrolidone. Water-soluble nylon is a modified alumide that has the ability to dissolve in water and alcohol.
0, A-90, P-70) (Toshiho Shiki Kaisha type).
水溶性ポリマーの配合量は０．５〜３０重ｉｔ％、好ま
しくは１〜２０重量軸である。０．５直置％未膚では組
成物は実質的に分離せず、３０重ｔ％を越えると分（，
１相がゲル化してしまい、好ましくない。The blending amount of the water-soluble polymer is 0.5 to 30% by weight, preferably 1 to 20% by weight. The composition does not substantially separate when placed directly on the skin at 0.5%, and when it exceeds 30% by weight,
One phase becomes gelled, which is not preferable.
Ｌ拭上の３１の必須成分全配合してなる本発明の分ｊ雅
型ｉ髪科ｄ戎物に野しては、通常の整髪料に用いらルる
種々の任意成分、例えば色素、香料等を配合することが
できる。The hair care product of the present invention, which is formulated with all 31 essential ingredients of the L towel, contains various optional ingredients used in ordinary hair styling products, such as pigments and fragrances. etc. can be blended.
本発明の分離型整髪料組成物ｔよ、水を加えることによ
り２相の水溶液相に明瞭に分離し、美麗な外覗を呈する
。また、損とつすることにより容易に見掛は上均−な単
−相全形成し、整髪料として良好ＶＣ便用可能である。The separated hair styling composition t of the present invention clearly separates into two aqueous solution phases by adding water, and exhibits a beautiful appearance. In addition, by removing the hair, it can be easily formed into a single phase with a uniform appearance, and can be used as a hair styling product with good VC properties.
相分離比率は、各成分の種類や配合ｔによって変化する
が、水溶性ポリマーの配合量による影響が最も大きく、
水溶性ポリマーの配合量を変化させることによシ２〜７
０容量％の範囲で調整可能である。The phase separation ratio varies depending on the type and composition of each component, but is most influenced by the amount of water-soluble polymer blended.
2 to 7 by changing the amount of water-soluble polymer blended.
It can be adjusted within the range of 0% by volume.
以下、本発明の実施例を示し、本発明の効果を具体的に
説明する。EXAMPLES Hereinafter, examples of the present invention will be shown and effects of the present invention will be specifically explained.
実施例１
下記の各成分を混合溶解して、整髪料組成′Ｉ！ｌｊ七
調裂し九。Example 1 The following ingredients were mixed and dissolved to create a hair conditioner composition 'I! lj seven tones split nine.
ポリオキシプロピレン（ＰＯ：４０モル）ブチルエーテ
ル ２０鬼１％エタノール
７０人Ｑナイロン（入−９０）
２香料 ０．５色累
（黄色４号） ０．０００３この組
成物を室盟下で静置すると、矢のような美麗な２相に分
離し九。Polyoxypropylene (PO: 40 mol) Butyl ether 20% 1% ethanol
70 people Q nylon (entering -90)
2 Fragrance 0.5 Color (Yellow No. 4) 0.0003 When this composition is left to stand under a room temperature, it separates into two beautiful arrow-like phases.
上相：８５容ｔ％、水溶性ポリマーが低濃度の無色透明
水溶液
下相：１５容盪％、水溶性ポリマーが高！１度の黄色透
明水溶液
次に、この分離した組成物を振とぅすると、下相が５〜
５０μｍ径の微細な液滴となって上相に分散し、みかけ
上均−な溶液を形成した。この状態の組成物を整髪料と
して使用したところ、良好な整髪性を示した。ま友、こ
の組成物は、水溶性ポリマーを配合しているため、水溶
性ポリマー無配合のものに比べ、より良好なセット力を
示した。Upper phase: 85 vol. %, colorless transparent aqueous solution with low concentration of water-soluble polymer Lower phase: 15 vol. %, high concentration of water-soluble polymer! 1 degree yellow transparent aqueous solution. Next, when this separated composition is shaken, the lower phase is
Fine droplets with a diameter of 50 μm were dispersed in the upper phase, forming an apparently uniform solution. When the composition in this state was used as a hair styling product, it showed good hair styling properties. Well, since this composition contains a water-soluble polymer, it exhibited better setting power than a composition that did not contain a water-soluble polymer.
更にま九、この組成物は、分離相として油性成分を用い
ていないため、毛髪がペタっくことがなかった。Furthermore, since this composition did not use an oily component as a separate phase, the hair did not become sticky.
実施例２
下記の各成分を混合溶解して、整髪料組成物を調製した
。Example 2 A hair styling composition was prepared by mixing and dissolving the following components.
ポリオキシエチレンポリオキシプロピレン ２０
ｆｉｊ１％ブチルエーテル（ｎｏ、ＰＯ： ３０〜５０
七ル）エタノール ５０ポリビニ
ルピロリドン（Ｋ−３０）１０香料
０．５色素（緑色３号）
０．０００５水
残部この組成物を室温下で静置すると、
次のような美麗な２相に分離した。Polyoxyethylene polyoxypropylene 20
fij 1% butyl ether (no, PO: 30-50
7) Ethanol 50 Polyvinylpyrrolidone (K-30) 10 Fragrance
0.5 dye (green No. 3)
0.0005 water
The remainder: When this composition is left to stand at room temperature,
It separated into two beautiful phases as shown below.
上相：６０容量鴨、水溶性ポリマーが低濃度の薄い青色
透明水溶液
下相：４０容量鴨、水溶性ポリマーが高濃度の濃肯色透
明水溶液
次に、この分離した組成物を振とうすると、下相が５〜
５０μ罵径の微細な液滴となって上相に分散し、みかけ
上均−な溶液七形底した。この状態の組成分を整髪料と
して使用したところ、艮好な整髪性を示した。その他、
この組成物は、実施例１の組成物と同様の優れた性能を
示し之。Upper phase: 60 volumes of duck, a pale blue transparent aqueous solution with a low concentration of water-soluble polymer. Lower phase: 40 volumes of duck, a dark-colored transparent aqueous solution with a high concentration of water-soluble polymer. Next, when this separated composition is shaken, The lower phase is 5~
Fine droplets with a diameter of 50 μm were dispersed in the upper phase, forming an apparently uniform solution. When the composition in this state was used as a hair styling product, it showed excellent hair styling properties. others,
This composition showed excellent performance similar to the composition of Example 1.
実施例３
ポリオキシプロピレンプチルエーテルリ４（トリエタノ
−ルアばン中和）（ｐｏ平均２１モル＞ ２５
］［ｔ％エタノール ３０ポ
リビニルピロリドン（Ｋ−３０） ５
香料 ０．５色素（
肯色４０３号） ０．０００５〃
（黄色４号） ０．０００３水
バ
５７ｘこの組成物を室温で静置すると以下の様に美麗な
２相に分離した。Example 3 Polyoxypropylene butyl ether 4 (triethanolabane neutralized) (po average 21 mol > 25
] [t% Ethanol 30 Polyvinylpyrrolidone (K-30) 5
Fragrance 0.5 pigment (
No. 403) 0.0005
(Yellow No. 4) 0.0003 water
When this composition was allowed to stand at room temperature, it separated into two beautiful phases as shown below.
上相：８０容盪％、水溶性ポリマーが低ａ度の青色透明
水溶液
下相：２０容量％、水溶性ポリマーが高濃度の黄色透明
水溶液
振とうによシ容易に均一な溶液（上相中に下相が５〜５
０μの液滴で分散）になり、この状態で使用すると良好
な整髪力を示し九。Upper phase: 80% by volume, a blue, transparent aqueous solution containing a water-soluble polymer at a low a degree. Lower phase: 20% by volume, a yellow, transparent aqueous solution containing a high concentration of a water-soluble polymer. Lower phase is 5-5
(Dispersed in droplets of 0μ), and when used in this state, it exhibits good hair styling power.9.
実施例４
エタノール ６０ＡＱナイロ
ン（入−７０）３
香料 ０．５色素（赤色１
０６号） ０．０００５水
バランスこの組成物を室温下で
静置すると矢の様な美麗な２相に分離した。Example 4 Ethanol 60AQ nylon (containing -70) 3 Fragrance 0.5 Pigment (red 1
06) 0.0005 water
Balance When this composition was allowed to stand at room temperature, it separated into two beautiful arrow-like phases.
上相：８５容量％、ポリマーが低濃度のピンク色透明水
溶液
下相：１５容ｊｋ％、ポリマーが高０度の無色透明水溶
液
次に、この分離した組成物を振とうすると均一な溶ｉＣ
上相中に下相が５〜５０μの液滴で分散）になυ、この
状態で使用すると良好な整髪力を示し九。Upper phase: 85% by volume, a pink transparent aqueous solution with a low concentration of polymer Lower phase: 15% by volume, a colorless transparent aqueous solution with a high concentration of polymer Next, when this separated composition is shaken, a uniform solution of iC
The lower phase is dispersed in droplets of 5 to 50 microns in the upper phase, and when used in this state, it exhibits good hair styling power.
Claims (1)
グリコール、ポリオキシアルキレンアルキルエーテルリ
ン酸又はその塩およびアルキルポリシロキサン−ポリオ
キシアルキレン共重合体から選択された少なくとも１種
からなる整髪主剤１０〜３０重量％と、水溶性ナイロン
およびポリビニルピロリドンから選択された少なくとも
１種からなる水溶性ポリマー０．５〜３０重量％とを含
有することを特徴とする分離型液体整髪料組成物。10-30% by weight of a main hair styling agent consisting of 20-80% by weight of ethyl alcohol and at least one selected from polyalkylene glycol, polyoxyalkylene alkyl ether phosphoric acid or its salt, and alkylpolysiloxane-polyoxyalkylene copolymer and 0.5 to 30% by weight of a water-soluble polymer made of at least one selected from water-soluble nylon and polyvinylpyrrolidone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12422186A JPS62281810A (en) | 1986-05-29 | 1986-05-29 | Separation-type liquid hair-dressing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12422186A JPS62281810A (en) | 1986-05-29 | 1986-05-29 | Separation-type liquid hair-dressing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62281810A true JPS62281810A (en) | 1987-12-07 |
Family
ID=14879990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12422186A Pending JPS62281810A (en) | 1986-05-29 | 1986-05-29 | Separation-type liquid hair-dressing composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62281810A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6001339A (en) * | 1996-07-10 | 1999-12-14 | Helene Curtis, Inc. | Hair styling composition |
| JP2003081786A (en) * | 2001-09-11 | 2003-03-19 | Hoyu Co Ltd | Hair grooming agent composition |
| JP2006315974A (en) * | 2005-05-11 | 2006-11-24 | Shiseido Co Ltd | Water-based skin cosmetic |
-
1986
- 1986-05-29 JP JP12422186A patent/JPS62281810A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6001339A (en) * | 1996-07-10 | 1999-12-14 | Helene Curtis, Inc. | Hair styling composition |
| JP2003081786A (en) * | 2001-09-11 | 2003-03-19 | Hoyu Co Ltd | Hair grooming agent composition |
| JP2006315974A (en) * | 2005-05-11 | 2006-11-24 | Shiseido Co Ltd | Water-based skin cosmetic |
| JP4491377B2 (en) * | 2005-05-11 | 2010-06-30 | 株式会社資生堂 | Aqueous skin cosmetics |
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