JPS62273262A - Silicone oil composition - Google Patents
Silicone oil compositionInfo
- Publication number
- JPS62273262A JPS62273262A JP61116644A JP11664486A JPS62273262A JP S62273262 A JPS62273262 A JP S62273262A JP 61116644 A JP61116644 A JP 61116644A JP 11664486 A JP11664486 A JP 11664486A JP S62273262 A JPS62273262 A JP S62273262A
- Authority
- JP
- Japan
- Prior art keywords
- silicone oil
- group
- formula
- oil composition
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 4
- 230000002785 anti-thrombosis Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 11
- 239000010408 film Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- -1 poultices Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000865 liniment Substances 0.000 description 3
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 241000195940 Bryophyta Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000011929 mousse Nutrition 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical group CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- ADANNTOYRVPQLJ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C ADANNTOYRVPQLJ-UHFFFAOYSA-N 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- FBZANXDWQAVSTQ-UHFFFAOYSA-N dodecamethylpentasiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C FBZANXDWQAVSTQ-UHFFFAOYSA-N 0.000 description 1
- 229940087203 dodecamethylpentasiloxane Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 229940040145 liniment Drugs 0.000 description 1
- 239000008308 lipophilic cream Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- GSANOGQCVHBHIF-UHFFFAOYSA-N tetradecamethylcycloheptasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 GSANOGQCVHBHIF-UHFFFAOYSA-N 0.000 description 1
- 229940008424 tetradecamethylhexasiloxane Drugs 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Materials For Medical Uses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
末完【ＪＩはシリコーンオイル組成物、特にはある種の
ビニルシラン重合体をジメチルシリコーンオイルに溶解
してなる。柔軟で強度のあるビニルシラン重合体の皮膜
を与える、人工皮膚用塗布剤、ファンデーション、メイ
クアップ化粧用材料、湿布剤、クリーム材料、各種コー
ティング材料、光ファアイパー接合剤などに有用とされ
るシリコーフォイル組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) JI is a silicone oil composition, particularly a type of vinylsilane polymer dissolved in dimethyl silicone oil. A silicone foil composition that provides a flexible and strong vinyl silane polymer film and is useful for artificial skin liniments, foundations, makeup materials, poultices, cream materials, various coating materials, optical fiber bonding agents, etc. It is about things.
（従来の技術）
従来、シリコーンオイルに高分子物質を溶解したシリコ
ーンオイル組成物は知られているが、この公知のシリコ
ーンオイル組成物における高分子物質はシロキサン結合
を主体とする、いわゆるシリコーン樹脂に限定されてお
り、これ以外のものは知られていない。(Prior Art) Silicone oil compositions in which a polymer substance is dissolved in silicone oil have been known, but the polymer substance in this known silicone oil composition is a so-called silicone resin mainly composed of siloxane bonds. It is limited and nothing else is known.
しかして、このシリコーン樹脂を溶解したシリコーンオ
イル組成物は皮膜形成能を有するものであるけれども、
この皮膜は強度の極めて弱いもので、このシリコーンオ
イルの添加による！１１成物の増粘効果も低いためにこ
の組成物にはその用途が制限されるという不利があった
。However, although the silicone oil composition in which this silicone resin is dissolved has film-forming ability,
This film is extremely weak due to the addition of silicone oil! The thickening effect of Composition No. 11 was also low, so this composition had the disadvantage of being limited in its use.
（発明の構成）
本発明はこのような不利を解決したシリコーンオイル組
成物に関するものであり、これはＡ）一般式
％式％
（ここにＲ１、Ｒ２は同一または異種のメチル基、エチ
ル基、プロピル基、フェニル基から選択される基、ｎは
６００以上の整数）で示されるくり返し単位からなる重
合体を、Ｂ） 一般式（ここにａは３〜７の９！！数
）および／または一般式（ここにｂはＯ〜５の整数）で
示されるジメチルシリコーンオイルに、溶解してなるこ
とを特徴とするものである。(Structure of the Invention) The present invention relates to a silicone oil composition that solves such disadvantages, and is composed of A) general formula % (herein, R1 and R2 are the same or different methyl groups, ethyl groups, B) A polymer consisting of repeating units represented by a group selected from a propyl group and a phenyl group, where n is an integer of 600 or more) and/or It is characterized by being dissolved in dimethyl silicone oil represented by the general formula (where b is an integer of O to 5).
すなわち、本発明者らはシリコーン樹脂以外の高分子物
質をシリコーンオイルに溶解して、増粘効果を付与する
と共にそれ自身が良好なフィルム形成俺を有するシリコ
ーンオイル組成物を開発すべく種々検討した結果、前記
した一般式（１）で示されるくり返し単位からなるビニ
ルシラン重合体が意外にもジメチルシリコーンオイルに
溶解し、これを溶解したシリコーンオイル組成物はすぐ
れたフィルム形Ｉ＆ｆｆｆｉを宥するものであることを
見出すと共に、この一般式（１）で示されるくり返し単
位からなる重合体が高い酸素透過率、透明性と抗血栓性
を有する柔軟で強度の大きいポリトリオルガノビニルシ
ランの皮膜を与えるものであり、シリコーンオイルが生
体刺激性の小さいものであることから、この！１ｆｆｌ
物は人工皮膚用塗布剤、ファンデーションオイル用など
のメークアップ化粧料材料、湿布剤材料、クリーム材料
９頭髪用ムース材料などとして有用とされることを確認
し、このビニルシラン重合体、シリコーンオイルの種類
。That is, the present inventors have conducted various studies in order to develop a silicone oil composition which has a thickening effect by dissolving a polymer substance other than silicone resin in silicone oil and which itself has a good film-forming property. As a result, the vinylsilane polymer consisting of repeating units represented by the above-mentioned general formula (1) was unexpectedly dissolved in dimethyl silicone oil, and the silicone oil composition obtained by dissolving this was found to have excellent film form I&fffi. We have discovered that the polymer consisting of repeating units represented by the general formula (1) provides a flexible and strong polytriorganovinylsilane film that has high oxygen permeability, transparency, and antithrombotic properties. This is because silicone oil is a small bioirritant! 1ffl
It was confirmed that the product is useful as an artificial skin liniment, makeup cosmetic material such as foundation oil, poultice material, cream material, hair mousse material, etc., and the types of vinyl silane polymer and silicone oil. .
配合量などについての研究を進めて本発明を完成させた
。The present invention was completed by conducting research on the amount of compounding and other factors.
末完１１の組成物を構成するＡ）成分は一般式％式％）
で示され、このＲ１、Ｒ２は同一または異種のメチル基
、エチル基、プロピル基、フェニル基から選択される基
、ｎは６００以上の整数である基をくり返し単位とする
重合体とされ、これにはポリトリメチルビニルシラン、
ポリジメチルエチルビニルシラン、ポリメチルジエチル
ビニルシラン、ポリジメチルプロピルビニルシラン、ポ
リジメチルフェニルビニルシランなどが例示されるが、
これはＲ１、ｕ ２が旧記の基から選択されるものであ
ればそれらの共重合体であってもよいし、これらの混合
物であってもよい、また、このポリトリオルガノビニル
シランは上記した一般式（１）で示されるトリオルガノ
ビニルンリル基を５０モル％以上、好ましくは７０モル
％以上含有するものであればシリコーンオイルへの溶解
性が保持され２ので、これは他の七ツマ−９例えばスチ
レン、メチルメタクリレート、シロキサニルメタクリレ
ート、インプレンさらには他のポリシロ、ギナンとシ共
重合体であってもよいが、このものはシリコーンオイル
への粘性の付与効果および強度のある成膜を得るという
点から分子量が１００．００（１以上のものとすること
が好ましい。Component A) constituting the composition of Compound 11 is represented by the general formula %), where R1 and R2 are groups selected from the same or different methyl group, ethyl group, propyl group, phenyl group, n is a polymer whose repeating unit is a group that is an integer of 600 or more, and includes polytrimethylvinylsilane,
Examples include polydimethylethylvinylsilane, polymethyldiethylvinylsilane, polydimethylpropylvinylsilane, polydimethylphenylvinylsilane, etc.
This polytriorganovinylsilane may be a copolymer or a mixture thereof as long as R1 and u2 are selected from the above-mentioned groups. If it contains 50 mol % or more, preferably 70 mol % or more of the triorganovinyl group represented by formula (1), it maintains solubility in silicone oil2, so this is better than other seven For example, styrene, methyl methacrylate, siloxanyl methacrylate, imprene, and other polysilicon, ginane and cycopolymers may be used, but these have the effect of imparting viscosity to silicone oil and form a strong film. From this point of view, it is preferable that the molecular weight is 100.00 (1 or more).
また、末完【」の組成物を構成するＢ）成分としてのシ
リコーンオイルは一般式
で示され、ａは３〜７の整数である環状ジメチルシロキ
サン、または一般式
で示さり、ｂはＯ〜５整数とされる直鎖状ジメチルシロ
キサンとされるが、これらはそれぞれを単独で使用して
もこれらの混合物として使用してもよい、このシリコー
ンオイルとしてはへキサメチルシクロトリシロキサン、
オクタメチルシクロテトラシロキサン、デカメチルシク
ロペンタシロキナン、ドデカメチルシクロヘキサシロキ
サン、テトラデカメチルシクロヘプタシロキサン、ヘキ
サメチルジシロキサン、オクタメチルトリシロキサン、
デカメチルテトラシロ午サン、ドデカメチルペンタシロ
キサン、テトラデカメチルヘキサシロキサン、ヘキサデ
カメチルへブタシロキサンなどが例示されるが、これら
はいずれも揮発性であり、前記した置換ポリアセチレン
化合体に対する溶剤となり得るものである。In addition, the silicone oil as the component B) constituting the composition of [ ] is represented by the general formula, a is a cyclic dimethylsiloxane which is an integer of 3 to 7, or is represented by the general formula, and b is O to It is said to be a linear dimethylsiloxane with an integer of 5, but each of these may be used alone or as a mixture.As this silicone oil, hexamethylcyclotrisiloxane,
Octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetradecamethylcycloheptasiloxane, hexamethyldisiloxane, octamethyltrisiloxane,
Examples include decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, and hexadecamethylhexasiloxane, but all of these are volatile and can serve as solvents for the above-mentioned substituted polyacetylene compounds. It is something.
本発明のシリコーンオイル組成物は上記したＡ）成分と
してのポリトリオルガノビニルシランをＢ）ることがよ
く、１２０″Ｃ以下では均一な溶液が得られ難いので１
２０℃以上、好ましくは１４０℃以上で加熱溶解するこ
とが好ましい、この組成物を形成するポリトリオルガノ
ビニルシランとジメチルシリコーンオイルの組成比は目
的に応じて、適宜選択すればよい、一般的には、ポリト
リオルカッビニルシランが０．２重量％以下ではシリコ
ーンオイルの増結効果が小さく、また７０重量％以上で
は高粘性のため均一に混和することが困難となる場合が
あるので、これらは重量比で０．２： ９９．８〜７０
： ３０の範囲とすることが好ましいが、この範囲に限
定されるものではなく、あくまでも目的に応じて適宜選
択されるへきである。The silicone oil composition of the present invention preferably contains polytriorganovinylsilane as the above-mentioned component A).
It is preferable to heat and melt at 20°C or higher, preferably 140°C or higher. The composition ratio of polytriorganovinylsilane and dimethylsilicone oil forming this composition may be selected as appropriate depending on the purpose. Generally, If polytriolecvinylsilane is less than 0.2% by weight, the effect of increasing silicone oil will be small, and if it is more than 70% by weight, it may be difficult to mix uniformly due to high viscosity. 0.2: 99.8~70
: Although the range is preferably 30, it is not limited to this range and is merely a range that can be selected as appropriate depending on the purpose.
なお、このシリコーンオイル組成物に顔料１分散剤、可
塑剤、香料、防腐剤、酩化防市剤、紫外線吸収剤などを
添加することは任５をとされるし、またこの組成物の物
性改質のために各種の有機。It is optional to add pigment dispersants, plasticizers, fragrances, preservatives, intoxicants, ultraviolet absorbers, etc. to this silicone oil composition, and the physical properties of this composition Various organic for modification.
無機の粉体、各種油分、各種有機溶剤、繊維質物などを
添加することも任意とされる。It is also optional to add inorganic powder, various oils, various organic solvents, fibrous substances, etc.
上記のようにして得られた本発明のシリコーンオイル組
成物はこれを人体の皮膚面やガラス、金属、プラスチッ
ク、繊維、布などの表面あるいは水面などの液体面上に
所望の厚さに塗布あるいは展開したのち必要に応じて加
熱してシリコーンオイルを揮発させると、ここにポリト
リオルガノビニルシランの柔軟で強度の大きい薄膜を形
成させることができるが、この皮膜は高い酸素透過性と
透明性を示すし、このものは抗血栓性を有しており、こ
のシリコーンオイルが生体刺激性を小さいものであるこ
とから、人工皮膚塗布剤、ファンデーション、ネイル用
のメークアップ化粧用材料。The silicone oil composition of the present invention obtained as described above can be applied to a desired thickness on human skin, surfaces of glass, metal, plastic, fibers, cloth, etc., or liquid surfaces such as water. After the silicone oil is developed and heated as needed to volatilize the silicone oil, a flexible and strong thin film of polytriorganovinylsilane can be formed, and this film exhibits high oxygen permeability and transparency. However, this product has antithrombotic properties, and since this silicone oil has low bioirritant properties, it is used as a makeup cosmetic material for artificial skin liniments, foundations, and nails.
湿布剤材料、親油性りリーム材料２頭髪用ムース剤など
として有用とされるが、これはまた各種コーティング剤
などとしても有用とされる。It is said to be useful as a poultice material, a lipophilic cream material, and a hair mousse, but it is also useful as various coating agents.
つぎに本発明の実施例をあげるが、例中の部は重量部を
、粘度、酸素透過性、透光性はいずれも２５℃での測定
値を示したものである。Next, examples of the present invention will be given, in which parts are parts by weight, and viscosity, oxygen permeability, and light transmittance are all measured values at 25°C.
実施例１
分子Ｈ５ｔｏ、ｏｏｏのポリトリメチルビニルシラ７１
０部にオクタメチルシクロテトラシロキサン９０部を添
加し、１５０℃に加熱してポリトリメチルビニルシラン
を溶解させたところ、得られた溶液は室温に冷却後も安
定な溶液状で粘度４８０ＣｐＳ、透光度９６％の物性を
示した。Example 1 Polytrimethylvinylsilica 71 with molecules H5to, ooo
When 90 parts of octamethylcyclotetrasiloxane was added to 0 parts and heated to 150°C to dissolve polytrimethylvinylsilane, the resulting solution remained stable even after cooling to room temperature, with a viscosity of 480 CpS and a light transmittance. It showed 96% physical properties.
つぎにこの溶液をガラス板上にキャストしてオクタメチ
ルシクロテトラシロキサンを揮発させたところ、膜厚９
０ＡＬｍのポリトリメチルビニルシランの透明なフィル
ムが得られ、このフィルムは酸素透過係数が４．２ Ｘ
１０’ｃｍ３（ＳＴＰ） ・ｃｍ／ｃｒｒｒ’・秒・ｃ
ｍＨｇで良好な酸素透過性を示した。Next, when this solution was cast on a glass plate and the octamethylcyclotetrasiloxane was volatilized, the film thickness was 9.
A transparent film of polytrimethylvinylsilane with 0 ALm is obtained, which has an oxygen permeability coefficient of 4.2
10'cm3 (STP) ・cm/crrr'・sec・c
It showed good oxygen permeability at mHg.
また、この溶液をつめに塗ったところ、このものは皮膚
を刺激することなく乾燥して光沢のあるフィルムを形成
したので、マニキュア材料として有用であることを示し
た。When applied to the nails, the solution dried to form a glossy film without irritating the skin, indicating its usefulness as a nail polish material.
実施例２〜５
一般式（１）におけるｕ １ 、 ｕ ２の異なる第１
表に示した量の４種のポリトリメチルビニルシランに、
第１表に示した量の一般式（２）、（３）におけるａ値
。Examples 2 to 5 First example in which u 1 and u 2 in general formula (1) are different
To the four types of polytrimethylvinylsilane in the amounts shown in the table,
a value in general formulas (2) and (3) for the quantities shown in Table 1.
ｂ値を特定したジメチルシリコーンオイルを添加し、１
５０℃で加熱溶解してシリコーンオイル組成物を作り、
これらの粘度、透光度をしらべたとこる第１表に併記し
たとおりの結果が得られた。Add dimethyl silicone oil with a specified b value,
A silicone oil composition is prepared by heating and melting at 50°C.
The viscosity and light transmittance of these were examined and the results shown in Table 1 were obtained.
なお、これはいずれもシリコーンオイルに高粘性を付与
することができ、またコーティング剤として有用であっ
た。All of these were able to impart high viscosity to silicone oil and were useful as coating agents.
Claims (1)
エチル基、プロピル基、フェニル基から選択される基、
ｎは６００以上の整数）で示されるくり返し単位からな
る重合体を、 Ｂ）一般式▲数式、化学式、表等があります▼ （ここにａは３〜７の整数）および／または一般式 ▲数式、化学式、表等があります▼ （ここにｂは０〜５の整数）で示されるジメチルシリコ
ーンオイルに、 溶解してなることを特徴とするシリコーンオイル組成物
。 ２、重合体におけるＲ＾１がメチル基、Ｒ＾２がメチル
基、エチル基またはプロピル基のいずれかである特許請
求の範囲第１項記載のシリコーンオイル組成物。[Claims] 1) A) General formula ▲ Numerical formula, chemical formula, table, etc. ▼ (Here, R^1 and R^2 are the same or different methyl groups,
a group selected from ethyl group, propyl group, phenyl group,
B) General formula ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (where a is an integer from 3 to 7) and/or general formula ▲ Numerical formula , chemical formulas, tables, etc. ▼ (where b is an integer from 0 to 5) A silicone oil composition characterized by being dissolved in dimethyl silicone oil. 2. The silicone oil composition according to claim 1, wherein R^1 in the polymer is a methyl group, and R^2 is a methyl group, an ethyl group, or a propyl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61116644A JPS62273262A (en) | 1986-05-21 | 1986-05-21 | Silicone oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61116644A JPS62273262A (en) | 1986-05-21 | 1986-05-21 | Silicone oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62273262A true JPS62273262A (en) | 1987-11-27 |
| JPH031347B2 JPH031347B2 (en) | 1991-01-10 |
Family
ID=14692317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61116644A Granted JPS62273262A (en) | 1986-05-21 | 1986-05-21 | Silicone oil composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62273262A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021187276A1 (en) * | 2020-03-17 | 2021-09-23 | 株式会社 資生堂 | Composition for forming artifical skin, and usage method therefor |
-
1986
- 1986-05-21 JP JP61116644A patent/JPS62273262A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021187276A1 (en) * | 2020-03-17 | 2021-09-23 | 株式会社 資生堂 | Composition for forming artifical skin, and usage method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH031347B2 (en) | 1991-01-10 |
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