JPS62265971A - Sustained release ethanol preparation - Google Patents
Sustained release ethanol preparationInfo
- Publication number
- JPS62265971A JPS62265971A JP10759086A JP10759086A JPS62265971A JP S62265971 A JPS62265971 A JP S62265971A JP 10759086 A JP10759086 A JP 10759086A JP 10759086 A JP10759086 A JP 10759086A JP S62265971 A JPS62265971 A JP S62265971A
- Authority
- JP
- Japan
- Prior art keywords
- ethanol
- adsorbent
- adsorbed
- amino group
- food
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 238000013268 sustained release Methods 0.000 title claims description 7
- 239000012730 sustained-release form Substances 0.000 title claims description 7
- 239000003463 adsorbent Substances 0.000 claims abstract description 12
- 125000003277 amino group Chemical group 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 7
- 235000013305 food Nutrition 0.000 abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003957 anion exchange resin Substances 0.000 abstract description 4
- 230000006866 deterioration Effects 0.000 abstract description 4
- 239000000796 flavoring agent Substances 0.000 abstract description 4
- 235000019634 flavors Nutrition 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 229910052814 silicon oxide Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 230000004936 stimulating effect Effects 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000002337 glycosamines Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000004471 Glycine Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- -1 belent Substances 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920001308 poly(aminoacid) Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 108010039918 Polylysine Proteins 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001371 alpha-amino acids Chemical class 0.000 description 1
- 235000008206 alpha-amino acids Nutrition 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009920 food preservation Methods 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000724 poly(L-arginine) polymer Polymers 0.000 description 1
- 108010054442 polyalanine Proteins 0.000 description 1
- 108010011110 polyarginine Proteins 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 108010094020 polyglycine Proteins 0.000 description 1
- 229920000232 polyglycine polymer Polymers 0.000 description 1
- 229920000656 polylysine Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は食品の保存に適した徐放性エタノール製剤に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a sustained release ethanol formulation suitable for food preservation.
包装食品の防黴技法として、エタノールガスを利用する
方法、つまり、エタノール剤をエタノールガス透過性容
器に密封したものを、食品の包装時、包装容器内に配置
する方法が普及している。As a mold-proofing technique for packaged foods, a method using ethanol gas, that is, a method in which an ethanol agent is sealed in an ethanol gas-permeable container and placed inside the packaging container when packaging the food has become widespread.
この方法がとられている食品としては、洋菓子、和菓子
、−１水産転装品類がある。Foods for which this method is used include Western confectionery, Japanese confectionery, and -1 modified seafood products.
食品の包装系内に配置したエタノール剤を含んだ容器か
らエタノールガスが徐々に食品の包装系内の空間に拡散
し、拡散したエタノールガスが食品の表面に吸着されて
、溶解し、エタノール層を形成し、防黴効果を発揮して
いる。エタノール剤により防黴効果が発揮されるがｊ副
次的にエタノール剤中の低沸点の揮発性夾雑物により食
品の香味の劣化がしばしば問題になっている。Ethanol gas gradually diffuses into the space inside the food packaging system from the container containing the ethanol agent placed inside the food packaging system, and the diffused ethanol gas is adsorbed to the surface of the food and dissolves, forming an ethanol layer. It forms and exhibits an anti-mildew effect. Ethanol agents have an anti-mold effect, but as a side effect, low boiling point volatile contaminants in ethanol agents often cause deterioration of the flavor of foods.
本発明者らは上記問題解決のため檀々検討した結果、従
来の徐放性エタノール剤に固体状のアミノ基を有する物
質を併用すると食品の香味の劣化が押さえられることを
見い出した。The inventors of the present invention have conducted extensive studies to solve the above-mentioned problems, and have found that when a solid substance having an amino group is used in combination with a conventional sustained-release ethanol agent, deterioration of the flavor of foods can be suppressed.
本発明は上記知見に基づいて完成されたものである。The present invention was completed based on the above findings.
即ち１本発明は吸着剤に吸着されたエタノール及び固体
状のアミノ基を有する物質を含有する徐放性エタノール
製剤に関する。That is, one aspect of the present invention relates to a sustained release ethanol preparation containing ethanol adsorbed on an adsorbent and a solid amino group-containing substance.
本発明で使用するエタノールを吸着させる吸着剤として
は１例えば紙、綿やセルロース粉末、メチルセルロース
、澱粉、デキストリン、カルボキシビニルポリマー、二
酸化ケイ素、タルク、ゼオライト、セビオライト、黄土
、カオリン、ケイソウ土、ベントナイト、パーライト、
白土、アルミナなどの粉末があげられるが、二酸化ケイ
素が好ましく、又、後記の固体状のアミノ基を有する物
質も使用しつる。Adsorbents for adsorbing ethanol used in the present invention include paper, cotton, cellulose powder, methylcellulose, starch, dextrin, carboxyvinyl polymer, silicon dioxide, talc, zeolite, seviolite, loess, kaolin, diatomaceous earth, bentonite, perlite,
Examples include powders of clay, alumina, etc., but silicon dioxide is preferred, and solid substances having amino groups as described below may also be used.
これらの吸着剤へのエタノールの吸着量は、吸着剤１０
０重量部に対しエタノール３０重量部以上好ましくは５
０〜１００重量部さらに好ましくは６０〜８０重量部程
度である。The amount of ethanol adsorbed on these adsorbents is 10
0 parts by weight to 30 parts by weight or more of ethanol, preferably 5 parts by weight
The amount is about 0 to 100 parts by weight, more preferably about 60 to 80 parts by weight.
又１本発明で使用する固体状のアミノ基を有する物質と
しては１例えばアミノ酸や高分子アミノがあげられるが
高分子アミノが好ましい。The solid amino group-containing substance used in the present invention includes, for example, amino acids and polymeric aminos, with polymeric aminos being preferred.
アミノ酸としては、例えばグリシン、グルタミン酸、リ
ジン、アルギニン、などのα−アミノ酸があげられる。Examples of amino acids include α-amino acids such as glycine, glutamic acid, lysine, and arginine.
高分子アミノとしては、高分子中に１級アミノ。Polymeric aminos include primary amino acids in polymers.
２級アミ／、３級アミノ、及び／又は４級アンモニクム
を含むものなら特に制限ないが、好ましくは１弱塩基性
陰イオン交換樹脂、ポリアミノ酸。There are no particular restrictions as long as it contains secondary amino, tertiary amino, and/or quaternary ammonium, but mono-weakly basic anion exchange resins and polyamino acids are preferred.
アミノ糖を有するポリマーなどがあげられる。ここで陰
イオン交換樹脂としては例えばアンノ（−ライトエＲＡ
４５（ローム アントノ・−ス社ｓ ＞ 。Examples include polymers having amino sugars. Here, examples of the anion exchange resin include Anno(-Lite RA).
45 (ROHM Antonos & Co., Ltd.).
デュオライトＡ−３６５（ダイアモンドンヤムロツタ社
製）などがあげられるが、交換基としてポリアミノを有
するものが好ましい。Examples include Duolite A-365 (manufactured by Diamond Don Yamuratsuta Co., Ltd.), but those having polyamino as an exchange group are preferred.
ポリアミノ酸としては特に制限はなく１例えばポリリジ
ン、ポリアラニン、ポリグルタミン酸、ポリグリシン、
ポリアルギニンなどのホモポリマー、ポリ（アラニン−
グリシン）、グルタミン酸−７−メチル−ウレタン共重
合体などのコポリマーがあげられるが、構成成分として
リジンやアＡ・ギニンなどの塩基性アミノ酸を有するも
のが好ましい。その平均分子量は特に制限はないが１例
えば４０００〜Ｉ Ｑ、 ０００程度が実用的である。There are no particular restrictions on the polyamino acids, such as polylysine, polyalanine, polyglutamic acid, polyglycine,
Homopolymers such as polyarginine, poly(alanine-
Examples include copolymers such as glycine) and 7-methyl glutamate-urethane copolymer, but those having a basic amino acid such as lysine or AA-ginine as a constituent are preferred. The average molecular weight is not particularly limited, but is practically about 4,000 to IQ, 1,000, for example.
又その粒間は１０メツシュ以下、好ましくは５０メツシ
ユ以下、さらに好ましくは１００〜２５０メツシユ程度
がよい。The grain spacing is preferably 10 meshes or less, preferably 50 meshes or less, and more preferably about 100 to 250 meshes.
アミノ糖を有するポリ１−としては例えば、キチンやキ
トサンなどのアミノ糖からなる多糖類などがあげられる
。Examples of poly-1- containing amino sugars include polysaccharides made of amino sugars such as chitin and chitosan.
本発明においてエタノールとアミノ基を有する物質の割
合は前者１００重量部に対し後者１重量部以上、好まし
くは３〜１０００重量部、さらに好ましくは５〜３００
重量部程度である。In the present invention, the ratio of ethanol and the substance having an amino group is 1 part by weight or more, preferably 3 to 1000 parts by weight, more preferably 5 to 300 parts by weight, to 100 parts by weight of the former.
It is about parts by weight.
本発明の徐放性エタノール製剤を製造するには例えば次
のようにすればよい。即ち、エタノールを吸着剤に吸着
させ１次いでアミノ基を有する物質と混合し、その後エ
タノールガス透過性の容器に封入すればよい。封入する
エタノールは吸着剤に吸着させて粉状にしたものが一般
的であるが。For example, the sustained-release ethanol preparation of the present invention may be produced as follows. That is, ethanol may be adsorbed onto an adsorbent, first mixed with a substance having an amino group, and then sealed in an ethanol gas permeable container. The ethanol to be sealed is generally adsorbed onto an adsorbent and turned into powder.
粒状、ベレント状、タブレット状など、任意の形状にし
て封入してもよい。It may be encapsulated in any shape such as granule, belent, or tablet.
ここで封入される吸着剤に吸着されたエタノールの童は
、使用目的に応じて異なるが、１封当り。The amount of ethanol adsorbed by the adsorbent enclosed here differs depending on the purpose of use, but per package.
通常０．２〜８Ｐ程度である。It is usually about 0.2 to 8P.
次に本発明の効果を実験例により示す。 Next, the effects of the present invention will be illustrated by experimental examples.
実験例
（１） 試 料
二酸化ケイ素１００重量部にエタノール７０重量部を吸
着させた吸着体１０１に一定量のアミノ基を有する物質
を添加混合し１次いでこの粉末を穴あきポリエチレンに
和紙をラミネートした小袋に充填密封し１本発明の試料
とした。又、上記吸着体１０？のみを上記小袋に充填密
封したものを対照試料とした。Experimental Example (1) Sample: A certain amount of a substance having an amino group was added and mixed to the adsorbent 101, which was made by adsorbing 70 parts by weight of ethanol to 100 parts by weight of silicon dioxide, and then this powder was laminated with Japanese paper on perforated polyethylene. A small bag was filled and sealed to serve as a sample of the present invention. Also, the above adsorbent 10? A control sample was prepared by filling and sealing only the above sachet.
（２） 実験方法
試料を１００ａｅの容器に入れ、容器中の刺戟的香気の
程度を官能試験で調べた。(2) Experimental method A sample was placed in a 100ae container, and the level of stimulating aroma in the container was examined by a sensory test.
（３） 実験結果 結果を表１に示す。(3) Experiment results The results are shown in Table 1.
表１
舛 弱塩基性陰イオン交換樹脂、アンパーライトエＲＡ
−４５使用汁＊ （＋）： シーンとした刺戟的香
気あり（±）：若干の刺戟的香気あり
（−）：刺戟的香気はとんどなし
表１から明らかなように１本発明のエタノール製剤は従
来の徐放性エタノール剤に比し、刺戟的香気が大幅に軽
減されている。Table 1 Weakly basic anion exchange resin, Amperlite RA
-45 Used juice* (+): Has a strong stimulating aroma (±): Has a slight stimulating aroma (-): Almost no stimulating aroma As is clear from Table 1, the ethanol of the present invention The formulation has significantly less irritating odor than conventional sustained-release ethanol formulations.
従って１本発明は、香味の劣化の少ない食品用保存剤と
して期待される。Therefore, the present invention is expected to be used as a food preservative with little deterioration of flavor.
Claims (1)
を有する物質を含有する徐放性エタノール製剤Sustained-release ethanol preparation containing ethanol adsorbed to an adsorbent and a solid substance having an amino group
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61107590A JPH066050B2 (en) | 1986-05-13 | 1986-05-13 | Sustained release ethanol preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61107590A JPH066050B2 (en) | 1986-05-13 | 1986-05-13 | Sustained release ethanol preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62265971A true JPS62265971A (en) | 1987-11-18 |
| JPH066050B2 JPH066050B2 (en) | 1994-01-26 |
Family
ID=14463010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61107590A Expired - Lifetime JPH066050B2 (en) | 1986-05-13 | 1986-05-13 | Sustained release ethanol preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH066050B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01174370A (en) * | 1987-12-28 | 1989-07-10 | Nippon Kayaku Co Ltd | Sustainedly releasing ethanol preparation |
| DE3922282A1 (en) * | 1988-07-07 | 1990-01-11 | Chisso Corp | ETHANOL PREPARATIONS FOR FOOD PRESERVATION |
| JP2014501516A (en) * | 2010-12-02 | 2014-01-23 | ブルー ズメッド ソシエテ アノニム | New uses of food compositions and food products comprising oxides and / or hydroxides |
| CN111296556A (en) * | 2020-02-27 | 2020-06-19 | 山东商业职业技术学院 | Fresh-cut fruit and vegetable ethanol fumigation preservation packaging box and preservation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5112377A (en) * | 1974-07-20 | 1976-01-30 | Mitsubishi Chem Ind | HAIGASUNOSHORIHOHO |
| JPS552273A (en) * | 1978-06-20 | 1980-01-09 | Shinko Electric Co Ltd | Synchronously governing linear reciprocating drive device |
| JPS626665A (en) * | 1985-07-03 | 1987-01-13 | Freunt Ind Co Ltd | Food preservative |
-
1986
- 1986-05-13 JP JP61107590A patent/JPH066050B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5112377A (en) * | 1974-07-20 | 1976-01-30 | Mitsubishi Chem Ind | HAIGASUNOSHORIHOHO |
| JPS552273A (en) * | 1978-06-20 | 1980-01-09 | Shinko Electric Co Ltd | Synchronously governing linear reciprocating drive device |
| JPS626665A (en) * | 1985-07-03 | 1987-01-13 | Freunt Ind Co Ltd | Food preservative |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01174370A (en) * | 1987-12-28 | 1989-07-10 | Nippon Kayaku Co Ltd | Sustainedly releasing ethanol preparation |
| DE3922282A1 (en) * | 1988-07-07 | 1990-01-11 | Chisso Corp | ETHANOL PREPARATIONS FOR FOOD PRESERVATION |
| DE3922282C2 (en) * | 1988-07-07 | 2000-07-06 | Chisso Corp | Ethanol preparations for food preservation |
| JP2014501516A (en) * | 2010-12-02 | 2014-01-23 | ブルー ズメッド ソシエテ アノニム | New uses of food compositions and food products comprising oxides and / or hydroxides |
| CN111296556A (en) * | 2020-02-27 | 2020-06-19 | 山东商业职业技术学院 | Fresh-cut fruit and vegetable ethanol fumigation preservation packaging box and preservation method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH066050B2 (en) | 1994-01-26 |
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