JPS62263296A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPS62263296A JPS62263296A JP10731886A JP10731886A JPS62263296A JP S62263296 A JPS62263296 A JP S62263296A JP 10731886 A JP10731886 A JP 10731886A JP 10731886 A JP10731886 A JP 10731886A JP S62263296 A JPS62263296 A JP S62263296A
- Authority
- JP
- Japan
- Prior art keywords
- formulas
- tables
- group
- mathematical
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 24
- 239000003599 detergent Substances 0.000 title description 5
- 238000004140 cleaning Methods 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- -1 methylol group Chemical group 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims 6
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000005406 washing Methods 0.000 description 44
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 30
- 239000000460 chlorine Substances 0.000 description 30
- 229910052801 chlorine Inorganic materials 0.000 description 30
- 238000005562 fading Methods 0.000 description 22
- 238000002845 discoloration Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000012459 cleaning agent Substances 0.000 description 17
- 239000004753 textile Substances 0.000 description 16
- 239000008399 tap water Substances 0.000 description 13
- 235000020679 tap water Nutrition 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 239000000975 dye Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical class OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000000937 inactivator Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- WXQMFIJLJLLQIS-UHFFFAOYSA-N reactive blue 21 Chemical compound [Cu+2].C1=CC(S(=O)(=O)CCO)=CC=C1NS(=O)(=O)C1=CC=C2C([N-]3)=NC(C=4C5=CC=C(C=4)S(O)(=O)=O)=NC5=NC(C=4C5=CC=C(C=4)S(O)(=O)=O)=NC5=NC([N-]4)=C(C=C(C=C5)S(O)(=O)=O)C5=C4N=C3C2=C1 WXQMFIJLJLLQIS-UHFFFAOYSA-N 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- WNQPPENQFWLADQ-UHFFFAOYSA-J tetrasodium;4-hydroxy-5-[[4-[[4-[(8-hydroxy-3,6-disulfonatonaphthalen-1-yl)diazenyl]-2-methoxy-5-methylphenyl]carbamoylamino]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC(O)=C2C(N=NC3=C(C)C=C(C(=C3)OC)NC(=O)NC3=CC(C)=C(N=NC=4C5=C(O)C=C(C=C5C=C(C=4)S([O-])(=O)=O)S([O-])(=O)=O)C=C3OC)=CC(S([O-])(=O)=O)=CC2=C1 WNQPPENQFWLADQ-UHFFFAOYSA-J 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は洗濯時に使用される洗浄剤組成物に関するもの
であり、さらに詳しくは洗濯時に染色された繊維製品の
変色あるいは退色（以下、変退色という）を起こす活性
塩素の作用を防止しうる洗浄剤組成物に関する。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a detergent composition used during washing, and more specifically to discoloration or fading of dyed textile products during washing (hereinafter referred to as discoloration or fading). This invention relates to a cleaning composition that can prevent the action of active chlorine that causes
（従来の技術）
染色された繊維製品、特に染色されたセルロース系繊維
含有製品は、水道水にてくり返し洗濯されることにより
、変退色を起こすものが多く、中でも、セルロース系繊
維製品のうち、反応染料や直接染料によって染色された
製品において著しい事が知られている。(Prior Art) Many dyed textile products, especially dyed products containing cellulose fibers, undergo discoloration and fading when repeatedly washed with tap water. It is known that this phenomenon is noticeable in products dyed with reactive dyes or direct dyes.
洗濯時（”洗濯”とは洗浄剤を用いての洗浄工程及びす
すぎ工程をいい、以後”洗濯”と”洗浄”を区別する）
に繊維製品が変退色する原因は、一般的に洗濯に使用す
る水道水中に殺菌を目的として、活性塩素が地域・季節
によりことなるが、０．５〜ｌｐｐｍ添加されており、
この活性塩素が繊維製品を着色している染料に作用する
ためである。水道水中に含まれている活性塩素量は微量
であり一回の洗濯にては変退色の程度は軽微であるが、
長期にわたるくり返し洗濯による変退色の積み重ねにて
繊維製品の色がはなはだしく変化する。During washing ("washing" refers to the washing process using a detergent and the rinsing process; hereinafter, "washing" and "washing" will be distinguished)
The reason why textile products change color and fade is that activated chlorine is added to the tap water used for washing for the purpose of sterilization, depending on the region and season, but from 0.5 to 1 ppm.
This is because this active chlorine acts on the dyes that color textile products. The amount of active chlorine contained in tap water is small, and the degree of discoloration and fading is slight after one wash.
The color of textile products changes dramatically due to the accumulation of discoloration and fading due to repeated washing over a long period of time.
このくり返し洗濯による繊維製品の変退色を防止する目
的で、種々な試みがなされている。一つには染料構造自
体からのアプローチであり、他方は染色製品に対して、
洗濯耐久性のある塩素処理水堅牢度向上加工剤を後処理
で付与し、変退色を防止しようとするものである。また
別な方法として、尿素ホルマリン樹脂などの樹脂加工剤
を大量に用いる方法もある。Various attempts have been made to prevent the discoloration and fading of textile products due to repeated washing. One approach is from the dye structure itself, and the other approach is for dyed products.
This is to prevent discoloration and fading by adding a washing-durable chlorinated water fastness improving agent in post-treatment. Another method is to use a large amount of a resin processing agent such as urea-formalin resin.
（発明が解決しようとする問題点）
これらの方法は、総ての色相に対して塩素処理水堅牢度
良好な染料の得られていない事、塩素処理水堅牢度向上
剤による加工を行っていない繊維製品は変退色を生ずる
事、繊維製品の風合を損なう事（粗硬化）、日光に対す
る堅牢度の低下、遊離ホルマリンが認められるなどの欠
点があった。(Problems to be solved by the invention) These methods do not provide dyes with good fastness to chlorinated water for all hues, and do not process with chlorinated water fastness improvers. Textile products had disadvantages such as discoloration and fading, loss of texture (rough hardening), decreased fastness to sunlight, and free formalin was observed.
従来よりの観点をかえれば、繊維製品に何ら加工する事
なく、くり返し洗濯にての変退色をふせぐ事が可能とな
る。すなわち、洗濯に使用する水道水中に活性塩素が存
在する事が問題であり、活性塩素を含まない水を使用す
るか、あるいは活性塩素の酸化作用が不活性化されてお
ればこのような問題は生しないと考えられる。From a conventional perspective, it is possible to prevent discoloration and fading due to repeated washing without any processing of textile products. In other words, the problem is the presence of active chlorine in the tap water used for washing, and this problem can be avoided if water that does not contain active chlorine is used, or if the oxidation effect of active chlorine is inactivated. It is thought that it will not survive.
活性塩素を含む水道水を活性塩素を含まない水にしよう
とすれば、活性炭などの吸着剤を用いた浄水器に通す事
が考えられるが、洗濯中に完全に活性塩素を捕捉してい
る確証が得られない事、吸着剤の更新に経費がかかるな
どの欠点がある。If you want to make tap water that contains active chlorine free from active chlorine, you can consider passing it through a water purifier that uses an adsorbent such as activated carbon, but there is no guarantee that active chlorine is completely captured during washing. There are disadvantages such as not being able to obtain the desired amount of energy, and the cost of renewing the adsorbent.
それ故、洗濯に使用する水道水中の活性塩素の酸化作用
を不活性化する薬剤（以下、塩素不活性化剤という）の
使用を考えた。Therefore, we considered the use of an agent (hereinafter referred to as a chlorine inactivator) that inactivates the oxidizing effect of active chlorine in tap water used for washing.
塩素処理水の酸化還元電位は、ｐＨが低い程大きくなり
、例えば洗浄時に、弱アルカリ性の洗浄剤を使用した場
合には、酸化還元電位は非常に小さく、塩素不活性化剤
を用いなくとも、水道水の含有塩素量からして、はとん
どその活性は失われていると考えられる。しかし、中性
洗浄剤を使用した場合には、この限りではなく、塩素不
活性化剤が必要である。The oxidation-reduction potential of chlorinated water increases as the pH decreases. For example, if a weakly alkaline cleaning agent is used during cleaning, the oxidation-reduction potential of chlorinated water is very small, and even without the use of a chlorine deactivator, Judging from the amount of chlorine contained in tap water, it is thought that most of its activity has been lost. However, when a neutral detergent is used, this is not the case and a chlorine deactivator is required.
一方、すすぎは、オーバーフローすすぎが行われる場合
が多く、多量の水道水が使用される。また、ためすすぎ
を行う場合でも２〜３回の水替えを行うので、その際に
も、水道水の使用量は多いものとなる。 従って、水道
水中の活性塩素の酸化作用は洗浄時よりもむしろ、すす
ぎ時の方が、問題となる場合が多く、塩素不活性化剤が
必要と考えられる。On the other hand, for rinsing, overflow rinsing is often performed, and a large amount of tap water is used. Further, even when pre-rinsing is performed, the water is changed 2 to 3 times, so the amount of tap water used is also large. Therefore, the oxidizing effect of active chlorine in tap water often becomes a problem during rinsing rather than during washing, and a chlorine deactivator is considered necessary.
使用水中に一般に塩素不活性化剤としてよく知られてい
るところのチオ硫酸ナトリウムなどの使用も考えられる
が、洗濯の間中（とくにオーバーフローすすぎの場合）
、一定量の薬剤を常に供給しなければならず、コントロ
ールのむづかしさ、および操作の繁雑さより考えれば事
実上不可能である。The use of sodium thiosulfate, a commonly known chlorine deactivator, in the water used may also be considered, but should not be used during washing (especially during overflow rinsing).
However, a fixed amount of drug must be constantly supplied, which is virtually impossible considering the difficulty of control and the complexity of operation.
そこで洗濯する際、すすぎの終了時まで、その作用が残
るような塩素不活性化剤が、必要となる。Therefore, when washing, a chlorine deactivator is required that remains effective until the end of rinsing.
また、操作が繁雑にならないためには、洗濯を行う際に
必然的に行われる洗浄剤の投与時、すなわち洗浄剤中に
このものが含まれていることが望ましい。Furthermore, in order to avoid complicated operations, it is desirable that this substance be included in the cleaning agent when it is necessarily administered during washing, that is, in the cleaning agent.
更に、使用される塩素不活性化剤は、洗浄剤の一成分と
して、あらゆるタイプの洗浄剤に混入可能なものである
必要があり、また洗浄剤本来の性能、つまり、洗浄作用
、その他、必要な付随効果を消滅あるいは、減少させる
ような物質は不適切であり、加えて、洗浄剤の価格を大
きく上昇させるものであってはならない。Furthermore, the chlorine deactivator used must be able to be mixed into all types of cleaning agents as a component of the cleaning agent, and must also be able to maintain the inherent performance of the cleaning agent, i.e. its cleaning action and other necessary Substances that eliminate or reduce the associated effects are unsuitable and, in addition, must not significantly increase the price of the cleaning agent.
そこで本発明者らは鋭意検討の結果、洗濯開始時に少量
使用するだけで、洗濯中に使用される水道水中の活性塩
素を不活性化する能力を有し、洗浄剤の本来の性能およ
び付随する諸性能を低下させることなく、あらゆるタイ
プの洗浄剤に混入可能で、安価な塩素不活性化剤を見出
し、この物を含有してなる洗浄剤組成物を提供すること
により、活性塩素を含む水道水を用いてのくり返し洗）
Ｕによる繊維製品の変退色を防ごうとするものである。Therefore, as a result of intensive studies, the inventors of the present invention found that by using a small amount at the beginning of washing, it has the ability to inactivate active chlorine in the tap water used during washing, and that it has the ability to inactivate the active chlorine in the tap water used during washing. By discovering an inexpensive chlorine deactivator that can be mixed into all types of cleaning agents without degrading various performances, and by providing a cleaning agent composition containing this agent, we have developed a solution to water supply containing active chlorine. (Repeated washing with water)
This is intended to prevent discoloration and fading of textile products caused by U.
（問題を解決するための手段）
すなわち、本発明は特許請求の範囲に示した一般式（Ｉ
）、 （ＩＩ）、 （ＩＩＩ）で示される化合物の
うち一種または二種以上を含有する事を特徴とする洗浄
剤組成物に関するものである。(Means for solving the problem) That is, the present invention is based on the general formula (I) shown in the claims.
), (II), and (III).
本発明に用いる化合物は特許請求の範囲に示した一般式
（１）、 （ＩＩ）、 （Ｉ［Ｉ）であられされる
。The compounds used in the present invention are represented by the general formulas (1), (II), and (I[I) shown in the claims.
ここであられされたすべての置換基中の炭素数ならびに
直鎖、分岐の状態についてはとくに制限はない。There are no particular limitations on the number of carbon atoms and the linear or branched state of all the substituents herein.
本発明において言うところの染色された繊維製品とは、
木綿、麻、羊毛などの天然繊維や、ビスコースレーヨン
、銅アンモニアレーヨンなどの再生繊維、アセテートな
どの半合成繊維、あるいは、ポリアミド、ポリエステル
、ポリアクリロニトリルなどの合成繊維などの単独、ま
たは組み合わせにより構成されるファイバー、スライバ
ー、糸、織編物、不織布などを含む繊維製品で、染料あ
るいは顔料により、着色されたちの総てをいう。In the present invention, the dyed textile products are:
Consists of natural fibers such as cotton, linen, and wool, recycled fibers such as viscose rayon and copper ammonia rayon, semi-synthetic fibers such as acetate, and synthetic fibers such as polyamide, polyester, and polyacrylonitrile, singly or in combination. Textile products including fibers, slivers, threads, woven and knitted fabrics, non-woven fabrics, etc., which are colored with dyes or pigments.
また、本発明の効果が、特に顕著に認められるところの
染色されたセルロース系繊維含有製品とは、木綿、麻な
どの天然繊維および、ビスコースレーヨン、銅アンモニ
アレーヨンなどの再生セルロース繊維などの単独、また
は組み合わせにより構成されるファイバー、スライバー
、糸、織ｔｑ物、不織布などを含む繊維製品で、染料あ
るいは顔料により、着色されたちの全てをいう。In addition, dyed cellulose fiber-containing products for which the effects of the present invention are particularly noticeable include natural fibers such as cotton and hemp, and regenerated cellulose fibers such as viscose rayon and copper ammonia rayon. Textile products, including fibers, slivers, threads, woven TQ materials, non-woven fabrics, etc., that are colored with dyes or pigments.
本発明において言うところの洗浄剤組成物は、特許請求
の範囲に表した一般式（１）、 （ＩＩ）。In the present invention, the cleaning composition has the general formulas (1) and (II) shown in the claims.
（ＩＩＩ）で示される化合物のうち、一種または二種以
上を含有し、他に、活性成分、有機および／もしくは無
機ビルダー、そして必要に応じて、再汚染防止剤、制は
う剤、漂白剤、けい光増白剤、ケーキング防止剤、酵素
、香料、柔軟剤、顔料、殺菌剤、ヒドロトロープ剤など
を配合した組成物より成っている。Contains one or more of the compounds represented by (III), and also contains an active ingredient, an organic and/or inorganic builder, and, if necessary, a restaining inhibitor, an antifungal agent, and a bleaching agent. , a fluorescent brightener, an anti-caking agent, an enzyme, a fragrance, a softener, a pigment, a bactericide, a hydrotrope, etc.
本発明による塩素不活性化剤を洗浄剤組成物に含有させ
るにあたっては、粉末、結晶、溶液あるいは、場合によ
り、乳化、分散、可溶化など、どのような方法を用いて
配合してもよく、その配合方法により、本来の目的であ
る塩素不活性化作用、並びに、洗浄剤本来の性能および
、付随した諸性能を低下させるものでなければ、その配
合方法に関して、あえて、制限を設けるものではない。When incorporating the chlorine deactivator according to the present invention into a cleaning composition, it may be incorporated using any method such as powder, crystal, solution, or, depending on the case, emulsification, dispersion, or solubilization. No restrictions will be placed on the blending method as long as the blending method does not reduce the original purpose of the chlorine inactivation effect, the original performance of the cleaning agent, and the accompanying performance. .
本発明において言うところの洗浄剤組成物の配合比率に
関しては、特に限定を設けるものではないが、好ましく
は、その範囲は、次のごとくである。すなわち、全量に
対して、特許請求の範囲に表した一般式（１）、 （
ＩｒＬ、 （ＩＩＩ）で示される化合物の使用量は、
１８量で０．０１〜５０重景％、重量成分３〜５０重四
％、有機および／もしくは無機ビルダー０．１〜９５重
量％の範囲において配合されるものである。Although there are no particular limitations on the blending ratio of the cleaning composition as referred to in the present invention, the range is preferably as follows. That is, the general formula (1) expressed in the claims, (
The amount of the compound represented by IrL, (III) is:
The content of the organic and/or inorganic builder is 0.01 to 50% by weight, 3 to 50% by weight, and 0.1 to 95% by weight of the organic and/or inorganic builder.
ここに言うところの活性成分とは、その−例を示せば、
直鎖アルキルベンゼンスルホン酸塩、α−オレフィンス
ルホン酸塩、アルケンスルホン酸塩、ヒドロキシアルカ
ンスルホン酸塩、硫酸アルキル塩、硫酸アルキルポリオ
キシエチレン塩、２−スルホ脂肪酸エステル塩、二級ア
ルカンスルホン酸塩、セッケンなどの陰イオン活性剤や
、アルキルポリオキシエチレンエーテル、Ｐ−アルキル
フェニルポリオキシエチレンエーテルなどの非イオン活
性剤などが一般的であるが、陽イオン活性剤、両性活性
剤なども含まれ、これらの例に限定されるものではなく
、これらの一種または二種以上の組み合わせから成るも
のである。The active ingredients mentioned here are, for example:
Linear alkylbenzene sulfonate, α-olefin sulfonate, alkenesulfonate, hydroxyalkane sulfonate, alkyl sulfate salt, alkyl sulfate polyoxyethylene salt, 2-sulfo fatty acid ester salt, secondary alkanesulfonate, Anionic surfactants such as soaps and nonionic surfactants such as alkyl polyoxyethylene ether and P-alkylphenyl polyoxyethylene ether are common, but cationic surfactants and amphoteric surfactants are also included. It is not limited to these examples, and may consist of one kind or a combination of two or more kinds thereof.
ここに言うところの有機ビルダーとは、その−例を示せ
ば、カルボキシメチルセルロース、アルギン酸ナトリウ
ム、ポリアクリル酸アミド、ポリアクリロニトリル、エ
チレンジアミンテトラ酢酸ナトリウム、ニトリロトリ酢
酸ナトリウム、クエン酸三ナトリウムなどがあるが、こ
れに限定されるものではなく、これらの一種または二種
以上の組み合わせから成るものである。Examples of organic builders mentioned here include carboxymethyl cellulose, sodium alginate, polyacrylic acid amide, polyacrylonitrile, sodium ethylenediaminetetraacetate, sodium nitrilotriacetate, and trisodium citrate. It is not limited to these, and may consist of one or a combination of two or more thereof.
また、ここに言うところの無機ビルダーとは、その−例
を示せば、硫酸ナトリウム、トリポリリン酸ナトリウム
、ビロリン酸ナトリウム、ゼオライトなどがあるが、こ
れに限定されるものではなく、これらの一種または二種
以上の組み合、わせから成るものである。In addition, the inorganic builder mentioned here includes, for example, sodium sulfate, sodium tripolyphosphate, sodium birophosphate, zeolite, etc., but is not limited to these, and can include one or two of these. It is made up of combinations of more than species.
本発明に言うところの洗浄剤組成物は、弱アルカリ性洗
浄剤、中性洗浄剤などは、もちろん、あらゆるｐＨｊｌ
域で使用されるもの、であり、あえて、その使用ｐＨに
限定を設けるものではない。The cleaning composition according to the present invention can be used not only for weakly alkaline cleaning agents and neutral cleaning agents, but also for all pH levels.
There is no limit to the pH at which it can be used.
本発明に言うところの洗浄剤組成物の形状は、粉末状、
液状、ペースト状、粒状、錠剤状など、いずれでもよく
、あえてその形状に限定をもうけるものではない。The shape of the cleaning composition according to the present invention is powdery,
It may be in the form of liquid, paste, granules, tablets, etc., and there is no particular limitation on its shape.
本発明に言うところの洗浄剤組成物は、繊維製品、すな
わち、全体または一部が、繊維よりなる製品の洗浄に関
する一切の用途に使用できるものである。The cleaning composition according to the present invention can be used for all purposes related to cleaning textile products, that is, products made entirely or partially of textiles.
（実施例）
以下実施例によって、本発明を説明するが、本発明は、
この例にのみ限定されるものではない。(Example) The present invention will be explained below with reference to Examples.
It is not limited to this example.
本発明の実施例に用いた被染布は、以下の様に作製した
。The dyed fabrics used in the examples of the present invention were produced as follows.
・サンプルＡ
綿１００％より成る天竺ニットを精練の後、ＣＩリアク
ティブプラック５（２％６ ｗ ｆ ） 、芒硝７０
ｇ ／ （！、ソーダ灰３０ｇ／ｉをもちい浴比１：１
５で５０℃×６０分間常圧染色機で処理し、青味グレー
色のサンプルＡを得た。・Sample A After scouring a jersey knit made of 100% cotton, CI Reactive Plaque 5 (2% 6 w f ), Glauber's Salt 70
g / (!, using 30g/i of soda ash, bath ratio 1:1
5 at 50° C. for 60 minutes in an atmospheric pressure dyeing machine to obtain a bluish-gray sample A.
・サンプルＢ
ＣＩディスパースブルー６０ （３０ｇ／ｌ）にて連続
染色した混紡率５０１５０のポリエステル／綿ブロード
織物を、ＣＩリアクティブブルー２１ （１０ｇ／Ｉ
り、レマゾールソルトＦＤ”３０ ｇ ／ ｌ 、ダッ
クアルギンＮ５ＰＬＬ” （１０％溶液”）３０ｇ／ｌ
、尿素１００ ｇ／ｌなる染浴に含浸し、マングルで絞
り（ピックアップ率６５％）、１２０℃で１分間乾燥後
、１０５℃×１０分高温スチームで発色した。洗浄の後
乾燥して、ターキス色のサンプルＢを得た。・Sample B A polyester/cotton broad fabric with a blend ratio of 50150 that was continuously dyed with CI Disperse Blue 60 (30 g/l) was dyed with CI Reactive Blue 21 (10 g/l).
, Remazol Salt FD"30 g/l, Duck Algin N5PLL" (10% solution) 30 g/l
The sample was impregnated in a dye bath containing 100 g/l of urea, squeezed with a mangle (pickup rate 65%), dried at 120°C for 1 minute, and then colored with high temperature steam at 105°C for 10 minutes. After washing and drying, a turquoise sample B was obtained.
・サンプルＣ
綿１００％スムースニットを精練、シルケ、７トの後、
ＣＩダイレクトレッド７９ （０，５％ｏｗ「）、芒
硝５ ｇ ／ ｌをもちい浴比ｌ：１５で９２’Ｃｘ５
Ｑ分間常圧染色機で染色し、ピンク色のサンプルＣを得
た。・Sample C After scouring 100% cotton smooth knit, silting, and 7 tones,
CI Direct Red 79 (0.5%ow'), 92'Cx5 with mirabilite 5 g/l and bath ratio l:15
A pink sample C was obtained by staining with an atmospheric pressure dyeing machine for Q minutes.
・サンプルＤ
糊抜、精練したレーヨン乎織物に、ＣＩリアクティブイ
エロー８１ （１％ｏｗｐ） 、炭酸水素ナトリウム２
％、ＭＳパウダー３１０．５％、ダック７／Ｌ／ギンＮ
５ＰＬＬ” （１０％溶液）６０％を含む色糊をロータ
リースクリーン捺染機で印捺、乾燥後、１０５℃×７分
間高温スチームで発色した。・Sample D: CI Reactive Yellow 81 (1% owp), Sodium Bicarbonate 2 on desized and refined rayon fabric
%, MS Powder 310.5%, Duck 7/L/Gin N
A color paste containing 60% of 5PLL'' (10% solution) was printed using a rotary screen printing machine, dried, and then colored with high temperature steam at 105°C for 7 minutes.
洗浄後、乾燥して黄色のサンプルＤを得た。After washing and drying, a yellow sample D was obtained.
１）レマゾール染料用固着剤（ヘキスト製）２）低粘度
アルギン酸ナトリウム（鴨川化成製）
３）メタニトロペンセンスルホン酸ナトリウム（凹成化
学製）
（実施例１）
下記の配合を有する洗浄剤組成物を調整し、この組成物
を用いて、先に示した被染布、サンプルＡ、Ｂ、Ｃ，Ｄ
をくり返し、５０回洗濯した。1) Fixing agent for Remazol dye (manufactured by Hoechst) 2) Low viscosity sodium alginate (manufactured by Kamogawa Kasei) 3) Sodium metanitropense sulfonate (manufactured by Takosei Kagaku) (Example 1) Cleaning composition having the following formulation and using this composition, dyed fabrics shown above, samples A, B, C, D
The washing process was repeated 50 times.
洗濯に使用した水は、自動的に有効塩素量１゜Ｏｐｌ）
ｍになるように連続調整されており、５０回連続洗濯終
了時における、サンプルＡ、Ｂ、Ｃ。The water used for washing automatically has an effective chlorine content of 1° Opl)
Samples A, B, and C at the end of 50 consecutive washings.
Ｄの変退色の程度により、本発明の効果を確認した。The effect of the present invention was confirmed by the degree of discoloration and fading of D.
ａ）洗浄剤配合組成 第−表に示す。a) Cleaning agent composition Shown in Table 1.
ｂ）洗濯方法
三洋電機ＩＩ！！！、全自動電気洗濯機、ＡＳＷ−ｔ３
１５と辻井染機工業１ｍ製、洗濯試験自動制御装置、５
ＡＤ−１３５型との組み合わせによって、連続して５０
回の洗濯を行った。b) Washing method Sanyo Electric II! ! ! , fully automatic electric washing machine, ASW-t3
15 and Tsujii Senki Kogyo 1m, washing test automatic control device, 5
In combination with AD-135 type, 50
I did laundry twice.
洗浄並びにすすぎに使用した水は、塩素非処理水（井戸
水）に、定量ポンプによって、次亜塩素酸ナトリウム水
溶液を加え、常に、有効塩素量が、１、Ｑｐｐｍになる
ように調節した。The water used for washing and rinsing was chlorinated non-treated water (well water), and a sodium hypochlorite aqueous solution was added using a metering pump to adjust the amount of available chlorine to 1.Qppm at all times.
−回の洗濯サイクルを下に示す。- washing cycles are shown below.
給湯−洗浄剤投入−洗浄（５分）−排水（２分）−脱水
（３分）−すすぎ給水（４分）−オーバーフローすすぎ
（２分）−排水（２分）−脱水（３分）−すすぎ給水（
４分）−オーバーフローすすぎ（２分）−排水（２分）
−脱水（３分）洗浄条件は、ＪＩＳ Ｌ−０２１７（
１０３法）に準拠して、１回を４０℃×５分とした。Hot water supply - Cleaning agent injection - Washing (5 minutes) - Drainage (2 minutes) - Dehydration (3 minutes) - Rinse water supply (4 minutes) - Overflow rinse (2 minutes) - Drainage (2 minutes) - Dehydration (3 minutes) - Rinse water supply (
4 minutes) - Overflow rinse (2 minutes) - Drain (2 minutes)
- Dehydration (3 minutes) cleaning conditions are JIS L-0217 (
103 method), each time was set at 40°C for 5 minutes.
被洗濯布は、サンプルＡ、Ｂ、Ｃ，Ｄを同時に用いて、
全量で８００ｇとした。Samples A, B, C, and D were used for the fabric to be washed at the same time.
The total amount was 800g.
洗浄時の浴景は、４０１で、浴比はｌ：５０であった。The bath appearance during washing was 401, and the bath ratio was 1:50.
脱水率は、約５６％であった。The dehydration rate was about 56%.
すすぎは、常温で行い、その浴量は４２１で、毎分８Ｉ
！のオーバーフローすすぎを２分間行った。Rinsing is performed at room temperature, the bath volume is 421, and the rate is 8 I/min.
! An overflow rinse was performed for 2 minutes.
洗浄時の洗浄剤使用量は洗浄液に対してＩｇ／！とした
。The amount of cleaning agent used during cleaning is Ig/! And so.
洗浄剤は、予め、水により１０倍に希釈し、液状化した
ものをストックタンクに入れて、自動給液した。The cleaning agent was diluted 10 times with water in advance, and the liquefied product was placed in a stock tank for automatic liquid supply.
Ｃ）変退色の評価法
ａ）の洗浄剤配合組成に示したところの、本発明による
洗浄剤組成物■並びに比較品■■について、各々、別々
にｂ）の洗濯方法に示した５０回の連続洗濯を行い、被
洗濯布、サンプルｉ’、、Ｂ。C) Discoloration and fading evaluation method The cleaning composition (■) according to the present invention and the comparative product (■■) shown in the cleaning composition in a) were each washed 50 times as shown in the washing method in b). Continuous washing was performed, and the washed fabric, sample i', B.
Ｃ，Ｄの変退色の程度を染色堅牢度試験方法通則、ＪＩ
Ｓ Ｌ−０８０１，１０により、変退色用グレースケ
ールを用いて判定した。The degree of discoloration and fading of C and D is determined according to the dye fastness test method general rules, JI
Judgment was made using a gray scale for discoloration and fading according to SL-0801,10.
ｄ）結果 結果を第二表に示す。d) Results The results are shown in Table 2.
以上のように、本発明による洗浄剤組成物を使うことに
より、くり返し洗濯による変退色は、大幅に改良される
。また、比較晶■に見られるように、塩素を不活性化す
ることが、一般的に知られているところのチオ硫酸ナト
リウムでは、すすぎ時まで、その効果を持続することが
できず、被洗濯布の変退色をまったく防止することがで
きない。As described above, by using the cleaning composition of the present invention, discoloration and fading caused by repeated washing can be significantly improved. In addition, as seen in Comparative Crystal ■, sodium thiosulfate, which is generally known to inactivate chlorine, cannot maintain its effect until rinsing, and It is not possible to prevent the fabric from discoloring or fading at all.
第二表
（実施例２）
下記の配合を有する洗浄剤組成物を調整し、この組成物
を用いて、先に示した被洗布、サンプルＡ、Ｂ、Ｃ，Ｄ
をくり返し、５０回洗濯した。Table 2 (Example 2) A cleaning composition having the following formulation was prepared, and this composition was used to clean the previously shown washed fabrics, samples A, B, C, and D.
The washing process was repeated 50 times.
洗濯に使用した水は、自動的に有効塩素ｆｆ１１．
Ｏｐｐｍになるように連続調整されており、５０回連続
洗濯終了時における、サンプルＡ、Ｂ、Ｃ。The water used for washing is automatically converted to available chlorineff11.
Samples A, B, and C were continuously adjusted to OPPM and were washed 50 times in a row.
Ｄの変退色の程度により、本発明の効果を確認した。The effect of the present invention was confirmed by the degree of discoloration and fading of D.
ａ）洗浄剤配合組成 第三表に示す。a) Cleaning agent composition Shown in Table 3.
ｂ）洗濯方法 実施例１．に同じ。b) Washing method Example 1. Same as .
Ｃ）変退色の評価法 実施例１．に同じ。C) Evaluation method for discoloration and fading Example 1. Same as .
ｄ）結果 第四表に示す。d) Results Shown in Table 4.
以上のように、本発明による洗浄剤組成物を使うことに
より、くり返し洗濯による変退色は、大幅に改良される
。As described above, by using the cleaning composition of the present invention, discoloration and fading caused by repeated washing can be significantly improved.
また、比較品■に見られるように、塩素を不活性化する
ことが、−ａ的に知られているところのチオ硫酸ナトリ
ウムでは、すすぎ時まで、その効果を持続することがで
きず、被洗濯布の変退色をまったく防止することができ
ない。In addition, as seen in Comparative Product ■, sodium thiosulfate, which is known to inactivate chlorine, cannot maintain its effect until the time of rinsing, and It is not possible to prevent discoloration and fading of washed cloth at all.
第四表
（発明の効果）
本発明による洗浄剤を洗濯に使用することにより、染色
された繊維製品、特に、染色されたセルロース系繊維含
有製品がくり返し洗濯される場合に、使用される水道水
中に含まれる活性塩素によって、徐々に酸化され、変退
色を起こすことを防止することが可能となる。Table 4 (Effects of the Invention) By using the detergent according to the present invention for washing, when dyed textile products, especially products containing dyed cellulose fibers, are washed repeatedly, tap water used The active chlorine contained in the product can prevent gradual oxidation and discoloration and fading.
そして、本発明に付随する特徴としては、高堅牢染料の
選択や後加工などの特別な加工を必要としない為、現在
、市販されている繊維製品が、全色相にわたって、その
ままで、（り返し洗濯による変退色を防止されるところ
にある。従って、製品コストのアップや、風合の粗硬化
、日光に対する堅牢度の低下、遊離ホルマリンの問題等
を生ずることがないという効果も奏する。A feature associated with the present invention is that it does not require special processing such as selection of high fastness dyes or post-processing, so textile products currently on the market can be used as they are (repeated) in all hues. This prevents discoloration and fading due to washing.Therefore, there are also effects such as an increase in product cost, rough hardening of the texture, decrease in fastness to sunlight, and problems such as free formalin.
更に、洗濯時の操作としては、現在とかわることなく、
何ら、繁雑な操作を加える必要もない。Furthermore, the operation when washing is the same as it is now.
There is no need to add any complicated operations.
Claims (1)
る成分とし、かつ、下記の一般式（ I ）、（II）、（
III）で示される化合物の一種または二種以上をふくむ
ことを特徴とする洗浄剤組成物。 ▲数式、化学式、表等があります▼または▲数式、化学
式、表等があります▼（ I ） ▲数式、化学式、表等があります▼または▲数式、化学
式、表等があります▼（II） ▲数式、化学式、表等があります▼または▲数式、化学
式、表等があります▼（III） ここで、Ｒ＿１、Ｒ＿２、Ｒ＿３、Ｒ＿４はそれぞれ独
立して、水素、アルキル基、アミノ基、アルキル基で置
換されたアミノ基、メチロール基、アルコキシル基、ア
リル基、アリール基または、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼をあらわす。 Ｒ＿５、Ｒ＿６、Ｒ＿７、Ｒ＿８、Ｒ＿９、Ｒ＿１＿０
、Ｒ＿１＿１、Ｒ＿１＿２はそれぞれ独立して、水素、
水酸基、アルキル基、アルコキシル基、アリル基、アリ
ール基、アミノ基、アルキル基で置換されたアミノ基、
メチロール基で置換されたアミノ基、または、アルコキ
シル基で置換されたアミノ基をあらわす。 Ｒｍは、▲数式、化学式、表等があります▼、▲数式、
化学式、表等があります▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼ をあらわす。 Ｒｎは、▲数式、化学式、表等があります▼、▲数式、
化学式、表等があります▼、 ▲数式、化学式、表等があります▼をあらわす。[Claims] The main components are an active ingredient and an organic and/or inorganic builder, and the following general formulas (I), (II), (
A cleaning composition comprising one or more of the compounds represented by III). ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (I) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (II) ▲ Mathematical formulas , chemical formulas, tables, etc. ▼ or ▲ Numerical formulas, chemical formulas, tables, etc. ▼ (III) Here, R_1, R_2, R_3, and R_4 are each independently substituted with hydrogen, an alkyl group, an amino group, or an alkyl group. Amino group, methylol group, alkoxyl group, allyl group, aryl group or ▲Mathematical formula, chemical formula, table, etc.
There is a table etc. ▼ represents. R_5, R_6, R_7, R_8, R_9, R_1_0
, R_1_1 and R_1_2 each independently represent hydrogen,
hydroxyl group, alkyl group, alkoxyl group, allyl group, aryl group, amino group, amino group substituted with an alkyl group,
Represents an amino group substituted with a methylol group or an amino group substituted with an alkoxyl group. Rm has ▲mathematical formula, chemical formula, table, etc.▼, ▲mathematical formula,
There are chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas, chemical formulas,
There are tables etc. ▼ represents. Rn has ▲mathematical formula, chemical formula, table, etc.▼, ▲mathematical formula,
There are chemical formulas, tables, etc.▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10731886A JPS62263296A (en) | 1986-05-10 | 1986-05-10 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10731886A JPS62263296A (en) | 1986-05-10 | 1986-05-10 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62263296A true JPS62263296A (en) | 1987-11-16 |
Family
ID=14456026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10731886A Pending JPS62263296A (en) | 1986-05-10 | 1986-05-10 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62263296A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51143009A (en) * | 1975-06-05 | 1976-12-09 | Katsuraya Fuaingutsuzu Kk | Deodorizing and cleaning agent |
-
1986
- 1986-05-10 JP JP10731886A patent/JPS62263296A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51143009A (en) * | 1975-06-05 | 1976-12-09 | Katsuraya Fuaingutsuzu Kk | Deodorizing and cleaning agent |
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